{"id":245922,"date":"2023-01-23T06:00:19","date_gmt":"2023-01-22T22:00:19","guid":{"rendered":"\/\/m.iemloyee.com\/?p=245922"},"modified":"2023-01-22T21:40:28","modified_gmt":"2023-01-22T13:40:28","slug":"%e3%80%90%e5%b7%b2%e5%ae%a1%e3%80%91%e6%9d%8e%e9%a1%ba%e6%96%b9%e5%bc%a0%e6%8c%af%e5%ae%87nano-lett-%ef%bc%9a%e6%8f%ad%e7%a4%ba%e5%8d%95%e5%8e%9f%e5%ad%90%e5%82%ac%e5%8c%96%e5%89%82","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=245922","title":{"rendered":"\u674e\u987a\u65b9&#038;\u5f20\u632f\u5b87Nano Lett.\uff1a\u63ed\u793a\u5355\u539f\u5b50\u50ac\u5316\u5242\u201c\u7535\u8377-\u81ea\u65cb\u534f\u540c\u50ac\u5316\u201d\u673a\u5236"},"content":{"rendered":"<p><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u8fd1\u5341\u5e74\u6765\uff0c\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u7406\u8bba\u8bbe\u8ba1\u548c\u5b9e\u9a8c\u5236\u5907\u5df2\u7ecf\u6210\u4e3a\u50ac\u5316\u9886\u57df\u56fd\u9645\u7814\u7a76\u70ed\u70b9\u4e4b\u4e00\u3002\u78c1\u6027\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08Magnetic Single-atom Catalysts, MSAC\uff09\u5728\u81ea\u65cb\u81ea\u7531\u5ea6\u4e0a\u8868\u73b0\u51fa\u66f4\u4e30\u5bcc\u7684\u65b0\u7269\u7406\u73b0\u8c61\u3002\u5bf9\u4e8e\u8bb8\u591a\u91cd\u8981\u7684\u6c27\u5316\u8fc7\u7a0b\uff0c\u7279\u522b\u662fO<sub>2<\/sub>\u5206\u5b50\u6240\u6d89\u53ca\u7684\u6c27\u5316\u8fc7\u7a0b\uff0cO<sub>2<\/sub>\u7684\u6d3b\u5316\u6d89\u53ca\u4ece\u81ea\u65cb\u4e09\u91cd\u6001\u5230\u81ea\u65cb\u5355\u6001\u7684\u6fc0\u53d1\u548c\u8dc3\u8fc1\u3002\u5728\u6b64\u8fc7\u7a0b\u4e2d\uff0c\u9996\u5148\uff0c\u6574\u4e2a\u4f53\u7cfb\u5fc5\u987b\u9075\u5b88\u7535\u8377\u5b88\u6052\uff1b\u53e6\u5916\uff0c\u6839\u636e\u91cf\u5b50\u529b\u5b66\u7684\u57fa\u672c\u539f\u7406\uff0c1928\u5e74Wigner\u63d0\u51fa\u5728\u81ea\u65cb\u8f68\u9053\u8026\u5408\u5f3a\u5ea6\u4e0d\u660e\u663e\u7684\u60c5\u51b5\u4e0b\uff0c\u4f53\u7cfb\u7684\u81ea\u65cb\u4e5f\u5fc5\u987b\u9075\u4ece\u81ea\u65cb\u5b88\u6052\u9009\u62e9\u5b9a\u5219\u3002\u7136\u800c\uff0c\u591a\u5e74\u6765\u5404\u79cd\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u81ea\u65cb\u5b88\u6052\u7684\u5fae\u89c2\u7269\u7406\u673a\u5236\u548c\u8fc7\u7a0b\u5e76\u4e0d\u5341\u5206\u6e05\u695a\u3002<\/p>\n<p><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u90d1\u5dde\u5927\u5b66\u674e\u987a\u65b9\u6559\u6388\u548c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5f20\u632f\u5b87\u6559\u6388<\/strong>\u8054\u5408\u4ee5O<sub>2<\/sub>\u5728\u4e8c\u7ef4\u94c1\u78c1\u6709\u673a\u91d1\u5c5e\u6846\u67b6Mn<sub>2<\/sub>C<sub>18<\/sub>H<sub>12<\/sub>-MSAC\u4f53\u7cfb\u4e0a\u7684\u6fc0\u53d1\u548cCO\u6c27\u5316\u4e3a\u4f8b\uff0c\u901a\u8fc7\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u6a21\u62df\uff0c\u9996\u6b21\u53d1\u73b0\u8be5MSAC\u4f53\u7cfb\u9ad8\u6548\u6fc0\u53d1O<sub>2<\/sub>\u7684\u7269\u7406\u673a\u5236\u4e3a\u4e00\u79cd\u65b0\u5947\u7684\u201c\u7535\u8377-\u81ea\u65cb\u7684\u53cc\u91cd\u534f\u540c\u673a\u5236\u201d\u3002\u5f53O<sub>2<\/sub>\u5206\u5b50\u5438\u9644\u5728\u8be5\u94c1\u78c1\u6027\u7684MSAC\u4f53\u7cfb\u4e0a\u7684\u67d0\u4e2aMn\u5355\u539f\u5b50\u6d3b\u6027\u4f4d\u65f6\uff08\u6807\u8bb0\u4e3aMn-I\uff09\uff0cO<sub>2<\/sub>\u5b9e\u73b0\u4e86\u4ece\u81ea\u65cb\u4e09\u91cd\u6001\u5230\u81ea\u65cb\u5355\u91cd\u6001\u7684\u8f6c\u53d8\uff1b\u66f4\u91cd\u8981\u7684\u662f\uff0c\u79d1\u7814\u56e2\u961f\u53d1\u73b0Mn-I\u6d3b\u6027\u4f4d\u70b9\u4e0e\u5176\u8fd1\u90bbMn-II\u5355\u539f\u5b50\u5728\u7535\u8377\u548c\u81ea\u65cb\u81ea\u7531\u5ea6\u4e0a\u5177\u6709\u8fe5\u7136\u4e0d\u540c\u7684\u5206\u5de5\u4e0e\u5408\u4f5c\uff1aO<sub>2<\/sub>\u5438\u9644\u65f6\uff0c\u7535\u8377\u8f6c\u79fb\u4e3b\u8981\u7531Mn-I\u63d0\u4f9b\u548c\u4e3b\u5bfc\uff0c\u7136\u800c\u6839\u636eWigner\u81ea\u65cb\u5b88\u6052\u9009\u62e9\u5b9a\u5219\uff0cMn-II\u5bb9\u7eb3\u4e86\u4eceO<sub>2<\/sub>\u5206\u5b50\u4e0a\u8f6c\u79fb\u6765\u7684\u5927\u90e8\u5206\u81ea\u65cb\u78c1\u77e9\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9O<sub>2<\/sub>\u4ece\u81ea\u65cb\u4e09\u91cd\u6001\u5230\u81ea\u65cb\u5355\u6001\u7684\u6709\u6548\u6fc0\u53d1\uff0c\u8be5\u91cf\u5b50\u534f\u540c\u673a\u5236\u6709\u6548\u964d\u4f4e\u4e86CO\u50ac\u5316\u6c27\u5316\u53cd\u5e94\u8fc7\u7a0b\u7684\u51b3\u901f\u6b65\u52bf\u5792\u3002\u8fd9\u79cd\u65b0\u5947\u7684\u201c\u7535\u8377-\u81ea\u65cb\u534f\u540c\u50ac\u5316\u201d\u7684\u91cf\u5b50\u6548\u5e94\u8fd8\u88ab\u8fdb\u4e00\u6b65\u63a8\u5e7f\u5230\u591a\u79cd\u78c1\u6027X<sub>2<\/sub>C<sub>18<\/sub>H<sub>12<\/sub>(X=Mn\u3001Fe\u3001Co\u548cNi)\u4f53\u7cfb\uff0c\u5e76\u53d1\u73b0\u8fd9\u4e9bMSAC\u4f53\u7cfb\u5bf9O<sub>2<\/sub>\u6fc0\u53d1\u7684\u5316\u5b66\u6d3b\u6027\u7a0b\u5ea6\u4e0e\u81ea\u65cb\u6fc0\u53d1\u80fd\u4e4b\u95f4\u5b58\u5728\u660e\u786e\u7684\u7ebf\u6027\u6807\u5ea6\u5173\u7cfb\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong>Synergetic Charge Transfer and Spin Selection in CO Oxidation at Neighboring Magnetic Single-Atom Catalyst Sites<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520a<strong><em>Nano Letters<\/em><\/strong>\u4e0a\uff0c\u90d1\u5dde\u5927\u5b66\u4e3a\u7b2c\u4e00\u4f5c\u8005\u5355\u4f4d\uff0c\u90d1\u5dde\u5927\u5b66\u7269\u7406\u5b66\u9662\u535a\u58eb\u7814\u7a76\u751f\u5f20\u4e3d\u83b9\u548c\u9752\u5e74\u6559\u5e08\u4efb\u6653\u71d5\u526f\u6559\u6388\u4e3a\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245923\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/a-1.png\" alt=\"\" width=\"600\" height=\"220\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/a-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/a-1-300x110.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>\u6784\u7b51\u4e86\u5177\u6709\u78c1\u6027\u6d3b\u6027\u4e2d\u5fc3\u7684MSAC\uff0c\u901a\u8fc7\u81ea\u65cb-\u81ea\u65cb\u8026\u5408\u901a\u9053\u9ad8\u6548\u4fc3\u8fdbO<sub>2<\/sub>\u81ea\u65cb\u4e09\u91cd\u6001-\u81ea\u65cb\u5355\u6001\u7684\u6fc0\u53d1\u548c\u8f6c\u5316\uff0c\u5e76\u9610\u660e\u8be5\u8fc7\u7a0b\u4e2d\u7684\u7535\u8377\u548c\u81ea\u65cb\u5b88\u6052\u7684\u5fae\u89c2\u673a\u5236\u3002<\/p>\n<p><strong>\u56db\u3001\u3010\u8bba\u6587\u63a0\u5f71\u3011<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245924\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/b-1.png\" alt=\"\" width=\"600\" height=\"669\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/b-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/b-1-269x300.png 269w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1<\/strong><strong>\u3001\u80fd\u5e26\u7ed3\u6784\u3001\u6001\u5bc6\u5ea6\u548c<\/strong><strong>O<sub>2<\/sub><\/strong><strong>\u6fc0\u53d1<\/strong><strong> \u00a92022 ACS Publications<\/strong><\/p>\n<p>\uff08a\uff09Mn<sub>2<\/sub>C<sub>18<\/sub>H<sub>12<\/sub> MOF\u7684\u80fd\u5e26\u7ed3\u6784\u548cDOS\u3002<\/p>\n<p>\uff08b\uff09Mn<sub>2<\/sub>C<sub>18<\/sub>H<sub>12<\/sub>\u4e0aO<sub>2<\/sub>\u5438\u9644\u7684\u4f18\u5316\u6700\u7a33\u5b9a\u7ed3\u6784\u7684\u4fef\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245925\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/c-1.png\" alt=\"\" width=\"600\" height=\"357\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/c-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/c-1-300x179.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe\u4e8c\u3001\u7535\u8377\u8f6c\u79fb\u5206\u6790<\/strong><strong> \u00a92022 ACS Publications<\/strong><\/p>\n<p>\u5f53O<sub>2<\/sub>\u5206\u5b50\u5438\u9644\u5728\u5177\u6709\u7b49\u8868\u9762\u7684Mn-I\u4f4d\u70b9\u4e0a\u65f6\uff0c\uff08a-c\uff09\u7535\u8377\u548c\uff08d-f\uff09\u81ea\u65cb\u5bc6\u5ea6\u5206\u6790\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245926\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/d-1.png\" alt=\"\" width=\"600\" height=\"418\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/d-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/d-1-300x209.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe\u4e09\u3001<\/strong><strong>CO<\/strong><strong>\u6c27\u5316\u8fc7\u7a0b\u5206\u6790<\/strong><strong> \u00a92022 ACS Publications<\/strong><\/p>\n<p>\uff08a\uff09Mn<sub>2<\/sub>C<sub>18<\/sub>H<sub>12<\/sub>\u7684Mn-I\u4f4d\u70b9\u4e0a\u7684CO\u6c27\u5316\u3002<\/p>\n<p>\uff08b-c\uff09\uff08a\uff09\u4e2d\u63d0\u51fa\u7684\u56fa\u5b9a\u7684TS2\/TS3\u7ed3\u6784\u7684\u76f8\u5bf9\u80fd\u91cf\u0394<em>E<\/em>\u4f5c\u4e3a\u4f18\u5316\u503c\u5468\u56f4\u7684Mn-II\u4f4d\u70b9\u4e0a\u7ea6\u675f\u7684\u8fd8\u539fMM\u7684\u51fd\u6570\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245927\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/e.png\" alt=\"\" width=\"600\" height=\"507\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/e.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/e-300x254.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe\u56db\u3001<\/strong><strong>&#8220;<\/strong><strong>\u534f\u540c\u7535\u8377<\/strong><strong>&#8211;<\/strong><strong>\u81ea\u65cb\u50ac\u5316<\/strong><strong>&#8220;<\/strong><strong>\u7684\u666e\u9002\u6027<\/strong><strong> \u00a92022 ACS Publications<\/strong><\/p>\n<p>\uff08a-c\uff09O<sub>2<\/sub>\u5206\u5b50\u7684\u5438\u9644\u80fd\u91cf\u3001O<sub>2<\/sub>\u5206\u5b50\u4e0e\u57fa\u5e95\u95f4\u7535\u8377\u8f6c\u79fb\u503c\u0394\u03c1\u4ee5\u53ca\u57fa\u5e95\u4e0e\u7ea2\u79fb\u7684O-O\u4f38\u7f29\u632f\u52a8\u9891\u7387<em>\u03bd<\/em>\u4e0e\u4e24\u4e2a\u76f8\u90bb\u7684X\u91d1\u5c5e\u539f\u5b50\uff08\u0394M(X-II)\uff09\u4e4b\u95f4\u7684\u81ea\u65cb\u534f\u540c\u503c\u4e4b\u95f4\u7684\u7ebf\u6027\u5173\u7cfb\u3002<\/p>\n<p>\uff08d\uff09\u0394M(X-II)\u4e0e\u81ea\u65cb\u6fc0\u53d1\u80fd\uff08SEE\uff09\u4e4b\u95f4\u7684\u5173\u7cfb\u3002<\/p>\n<p><strong>\u4e94\u3001\u3010\u603b\u7ed3\u5c55\u671b\u3011<\/strong><\/p>\n<p>\u57fa\u4e8e\u6700\u5148\u8fdb\u7684\u7b2c\u4e00\u539f\u7406\u8ba1\u7b97\uff0c\u7814\u7a76\u4eba\u5458\u57282D-MOF Mn<sub>2<\/sub>C<sub>18<\/sub>H<sub>12<\/sub>\u7ed3\u6784\u4e0a\u5efa\u7acb\u4e86O<sub>2<\/sub>\u6fc0\u53d1\/CO\u6c27\u5316\u7684\u65b0\u5947\u7684\u201c\u534f\u540c\u7535\u8377-\u81ea\u65cb\u50ac\u5316\u201d\u673a\u5236\uff0c\u5176\u4e2dMn\u5355\u4f53\u5728MSAC\u7684\u516d\u8fb9\u5f62\u6676\u683c\u5185\u5747\u5300\u5206\u5e03\u3002\u4e0e\u4f20\u7edf\u7684\u7535\u8377\u8f6c\u79fb\u673a\u5236\u4e0d\u540c\uff0c\u8fd9\u79cd\u72ec\u7279\u7684\u201c\u534f\u540c\u7535\u8377-\u81ea\u65cb\u50ac\u5316\u201d\u8fc7\u7a0b\u662f\u901a\u8fc7\u7535\u8377\u8f6c\u79fb\u7684\u534f\u540c\u8fc7\u7a0b\u6765\u4fc3\u8fdb\u7684\u3002\u91cd\u8981\u7684\u662f\uff0c\u8fdb\u4e00\u6b65\u53d1\u73b0\u8fd9\u79cd\u65b0\u5947\u7684\u534f\u540c\u673a\u5236\u5e7f\u6cdb\u9002\u7528\u4e8eX<sub>2<\/sub>C<sub>18<\/sub>H<sub>12<\/sub>\u4f53\u7cfb\uff08X=Mn\u3001Fe\u3001Co\u548cNi\uff09\u4e0a\u7684O<sub>2<\/sub>\u5438\u9644\uff0c\u5728\u5316\u5b66\u6d3b\u6027\u548c\u81ea\u65cb\u6fc0\u53d1\u80fd\u4e4b\u95f4\u5177\u6709\u660e\u786e\u7684\u7ebf\u6027\u6bd4\u4f8b\u5173\u7cfb\u3002\u672c\u7814\u7a76\u7ed3\u679c\u6709\u671b\u4e3a\u9ad8\u81ea\u65cb\u7269\u79cd\u5728\u78c1\u6027\u50ac\u5316\u5242\u4e0a\u7684\u5316\u5b66\u53cd\u5e94\u63d0\u4f9b\u65b0\u7684\u89c1\u89e3\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.nanolett.2c00711\" target=\"_blank\" rel=\"noopener\">Synergetic Charge Transfer and Spin Selection in CO Oxidation at Neighboring Magnetic Single-Atom Catalyst Sites<\/a> (<em>Nano Lett.<\/em> <strong>2022<\/strong>, <em>22<\/em>, 3744-3750)<\/p>\n<p>\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u8fd1\u5341\u5e74\u6765\uff0c\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u7406\u8bba\u8bbe\u8ba1\u548c\u5b9e\u9a8c\u5236\u5907\u5df2\u7ecf\u6210\u4e3a\u50ac\u5316\u9886\u57df\u56fd\u9645\u7814\u7a76\u70ed\u70b9\u4e4b\u4e00\u3002\u78c1\u6027\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08Magnetic Single-atom Catal&#8230;<\/p>\n","protected":false},"author":1004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-245922","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/245922"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1004"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=245922"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/245922\/revisions"}],"predecessor-version":[{"id":246238,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/245922\/revisions\/246238"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=245922"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=245922"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=245922"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}