{"id":245767,"date":"2023-01-17T06:00:55","date_gmt":"2023-01-16T22:00:55","guid":{"rendered":"\/\/m.iemloyee.com\/?p=245767"},"modified":"2023-01-16T22:07:51","modified_gmt":"2023-01-16T14:07:51","slug":"%e3%80%90%e5%b7%b2%e5%ae%a1%e3%80%91green-chemistry%ef%bc%9a%e4%b8%80%e7%a7%8d%e6%97%a0%e9%ab%98%e5%8e%8b%e6%b0%94%e4%bd%93%e5%8a%a0%e6%b0%a2%e7%9a%84%e7%ae%80%e5%8d%95%e3%80%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=245767","title":{"rendered":"Green Chemistry\uff1a\u4e00\u79cd\u201c\u65e0\u9ad8\u538b\u6c14\u4f53\u201d\u52a0\u6c22\u7684\u7b80\u5355\u3001\u5b89\u5168\u3001\u53ef\u9760\u7684\u7cfb\u7edf"},"content":{"rendered":"<p style=\"text-align: center;\">\u3010\u5bfc\u8bfb\u3011<\/p>\n<p>\u73b0\u4ee3\u5408\u6210\u5b9e\u9a8c\u5ba4\u65e5\u76ca\u589e\u52a0\u7684\u5b89\u5168\u89c4\u5b9a\u9650\u5236\u4e86\u6709\u6bd2\u548c\u5371\u9669\u6c14\u4f53\u7684\u5904\u7406\u548c\u4f7f\u7528\u3002\u4ece\u5546\u4e1a\u4e0a\u53ef\u83b7\u5f97\u7684\u4f4e\u6bd2\u6027\u548c\u6613\u5904\u7406\u7684\u66ff\u4ee3\u7269\u5c31\u5730\u548c\u6309\u9700\u4ea7\u751f\u6709\u6bd2\u6216\u5371\u9669\u6c14\u4f53\uff0c\u4e3a\u5e38\u89c4\u6c14\u4f53\u5904\u7406\u5b9e\u9a8c\u5ba4\u64cd\u4f5c\u63d0\u4f9b\u4e86\u5408\u9002\u7684\u66ff\u4ee3\u65b9\u6848\uff0c\u800c\u4e0d\u9700\u8981\u989d\u5916\u7684\u9884\u9632\u63aa\u65bd\u3002\u5728\u6d89\u53ca\u6c22\u7684\u8f6c\u5316\u7684\u60c5\u51b5\u4e0b\uff0c\u201c\u65e0\u6c14\u4f53\u201d\u6c22\u5316\u53cd\u5e94\u7684\u53d1\u5c55\u662f\u975e\u5e38\u6709\u5438\u5f15\u529b\u7684\u3002<\/p>\n<p style=\"text-align: center;\">\u3010\u6210\u679c\u63a0\u5f71\u3011<\/p>\n<p>\u897f\u73ed\u7259\u6d77\u6885\u4e00\u4e16\u5927\u5b66Jose A. Mata\u6559\u6388\u548cEduardo Garc\u00eda-Verdugo\u6559\u6388\u62a5\u9053\u4e86\u4e00\u79cd\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u8fde\u7eed\u3001\u5c31\u5730\u548c\u6309\u9700\u751f\u6210\u6c22\u6c14\u7684\u7b80\u5355\u3001\u5b89\u5168\u3001\u53ef\u9760\u7684\u7cfb\u7edf\u3002\u8be5\u88c5\u7f6e\u7531\u5305\u542b\u8d1f\u8f7d\u5728\u77f3\u58a8\u70ef(NHC-Ru-rGO)\u4e0a\u7684\u948cN-\u6742\u73af\u5361\u5bbe\u7edc\u5408\u7269[Ru(\u82b3\u70c3)(Cl)<sub>2<\/sub>(NHC)]\u7684\u586b\u5145\u5e8a\u53cd\u5e94\u5668\u548c\u6db2-\u6c14\u5206\u79bb\u5668\u7ec4\u6210\uff0c\u5141\u8bb8\u7845\u70f7\u548c\u9187\u5728\u6e29\u548c\u4e14\u5b89\u5168\u7684\u6761\u4ef6\u4e0b\u8131\u6c22\u5076\u8054\u4ea7\u751f\u6c22\u6c14\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<strong>A simple, safe and robust system for\u00a0 hydrogenation \u201cwithout high-pressure gases\u201d under batch and flow conditions using a liquid\u00a0 organic hydrogen carrier<\/strong>\u201d\u53d1\u8868\u5728<strong><em>Green Chemistry<\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245768\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72471-12.png\" alt=\"\" width=\"554\" height=\"243\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72471-12.png 554w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72471-12-300x132.png 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u3010<\/strong>\u6838\u5fc3\u521b\u65b0\u70b9<strong>\u3011<\/strong><\/p>\n<p>\u672c\u7814\u7a76\u62a5\u9053\u4e86\u4e00\u79cd\u751f\u6210\u6c22\u6c14\u7684\u7cfb\u7edf\uff0c\u751f\u6210\u7684\u9ad8\u7eaf\u6c22\u53ef\u7528\u4e8e\u95f4\u6b47\u548c\u8fde\u7eed\u6d41\u52a8\u6761\u4ef6\u4e0b\u7684\u8fdb\u4e00\u6b65\u52a0\u6c22\u53cd\u5e94\u3002<\/p>\n<p style=\"text-align: center;\">\u3010\u6570\u636e\u6982\u89c8\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" 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srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72475-13.png 554w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72475-13-300x204.png 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p>\u56fe4\u88c5\u7f6e\u7684LOHC\u7684\u6d41\u901f\u548cLHSV\u4e0e\u5c31\u5730\u751f\u6210\u6c22\u7684\u6d41\u901f\u3002\u00a92022 Royal Society of Chemistry<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245773\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72476-5.png\" alt=\"\" width=\"554\" height=\"455\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72476-5.png 554w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72476-5-300x246.png 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p>\u56fe5\u5206\u6279\u6761\u4ef6\u4e0b\u52a0\u6c22\u7684\u8bbe\u7f6e\u3002\u00a92022 Royal Society of Chemistry<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245774\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72477-2.png\" alt=\"\" width=\"554\" height=\"515\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72477-2.png 554w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72477-2-300x279.png 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p>\u56fe6\u4e0d\u540c\u5e95\u7269\u5728\u6d41\u52a8\u6761\u4ef6\u4e0b\u52a0\u6c22\u7684\u8bbe\u7f6e\u3002\u00a92022 Royal Society of Chemistry<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\">\u3010\u6210\u679c\u542f\u793a\u3011<\/p>\n<p>\u603b\u8a00\u4e4b\uff0c\u672c\u6587\u7684\u7ed3\u679c\u8868\u660e\uff0c\u8be5\u7cfb\u7edf\u6ee1\u8db3\u5b89\u5168\u3001\u539f\u4f4d\u548c\u6309\u9700\u5236\u6c22\u7684\u6240\u6709\u8981\u6c42\uff0c\u5e76\u53ef\u8fdb\u4e00\u6b65\u7528\u4e8e\u5176\u4ed6\u6c22\u5316\u53cd\u5e94\u3002\u8be5\u7cfb\u7edf\u7684\u4e3b\u8981\u7279\u70b9\u662f:(i)H<sub>2<\/sub>\u53ef\u5728\u5ba4\u6e29\u4e0b\u83b7\u5f97\u3002(ii)\u6c22\u6c14\u5728\u77ed\u7684\u53cd\u5e94\u65f6\u95f4\u5185\u4ee5\u6052\u5b9a\u7684\u6d41\u91cf\u91ca\u653e\uff0c\u5e76\u4e14\u6d41\u91cf\u53ef\u4ee5\u4ec5\u901a\u8fc7\u8c03\u8282\u6db2\u6001\u6709\u673a\u6c22\u8f7d\u4f53\uff08LOHC\uff09\u6eb6\u6db2\u4e0e\u50ac\u5316\u5242\u7684\u63a5\u89e6\u65f6\u95f4\u6765\u63a7\u5236\u3002(iii)\u6db2\u6001\u6709\u673a\u6c22\u8f7d\u4f53(\u5373\u7845\u70f7\u548c\u7532\u9187)\u53ef\u4ee5\u5bb9\u6613\u548c\u5b89\u5168\u5730\u5904\u7406\uff0c\u4f7f\u5f97\u5b83\u4eec\u80fd\u591f\u5728\u6d41\u52a8\u6761\u4ef6\u4e0b\u4f7f\u7528\u3002(iv)\u8be5\u8fc7\u7a0b\u4ea7\u751f\u9ad8\u7eaf\u5ea6\u6c22\u6c14\uff0c\u4e0d\u542b\u4efb\u4f55\u6b8b\u4f59\u7269(\u5373CO<sub>2<\/sub>\u3001CO\u3001N<sub>2<\/sub>\u3001\u76d0\u7b49)\uff0c\u80fd\u591f\u907f\u514d\u5e72\u6270\u5176\u540e\u7eed\u4f7f\u7528\u3002(v)\u7528\u8be5\u88c5\u7f6e\u751f\u4ea7\u7684H<sub>2<\/sub>\u53ef\u7528\u4e8e\u6279\u91cf\u548c\u6d41\u52a8\u540e\u7eed\u8fc7\u7a0b\u3002(vi)\u50ac\u5316\u5242\u9ad8\u5ea6\u7a33\u5b9a\uff0c\u53ef\u4ee5\u5728\u5ba4\u6e29\u4e0b\u50a8\u5b58\uff0c\u65e0\u9700\u4efb\u4f55\u989d\u5916\u7684\u9884\u9632\u63aa\u65bd\uff0c\u5728\u957f\u65f6\u95f4\u5185\u4fdd\u6301\u5176\u6d3b\u6027\u3002(vii)\u7531\u4e8e\u5176\u9ad8\u6d3b\u6027\uff0c\u4ec5\u9700\u8981\u5c11\u91cf\u7684\u50ac\u5316\u5242\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1aPorcar, R., Mollar-Cuni, A., Ventura-Espinosa, D., Luis, S.V., Garc\u00eda-Verdugo, E., and Mata, J.A. (2022). A simple, safe and robust system for hydrogenation \u201cwithout high-pressure gases\u201d under batch and flow conditions using a liquid organic hydrogen carrier. Green Chemistry 24(5), 2036-2043.<\/p>\n<p>https:\/\/doi.org\/10.1039\/d1gc03850h<\/p>\n<p>&nbsp;<\/p>\n<p>\u672c\u6587\u7531\u6625\u56fd\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5bfc\u8bfb\u3011 \u73b0\u4ee3\u5408\u6210\u5b9e\u9a8c\u5ba4\u65e5\u76ca\u589e\u52a0\u7684\u5b89\u5168\u89c4\u5b9a\u9650\u5236\u4e86\u6709\u6bd2\u548c\u5371\u9669\u6c14\u4f53\u7684\u5904\u7406\u548c\u4f7f\u7528\u3002\u4ece\u5546\u4e1a\u4e0a\u53ef\u83b7\u5f97\u7684\u4f4e\u6bd2\u6027\u548c\u6613\u5904\u7406\u7684\u66ff\u4ee3\u7269\u5c31\u5730\u548c\u6309\u9700\u4ea7\u751f\u6709\u6bd2\u6216\u5371\u9669\u6c14\u4f53\uff0c\u4e3a\u5e38\u89c4\u6c14\u4f53\u5904\u7406\u5b9e&#8230;<\/p>\n","protected":false},"author":34544,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-245767","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/245767"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/34544"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=245767"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/245767\/revisions"}],"predecessor-version":[{"id":246011,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/245767\/revisions\/246011"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=245767"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=245767"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=245767"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}