{"id":245510,"date":"2023-01-10T06:00:10","date_gmt":"2023-01-09T22:00:10","guid":{"rendered":"\/\/m.iemloyee.com\/?p=245510"},"modified":"2023-01-05T17:21:33","modified_gmt":"2023-01-05T09:21:33","slug":"%e5%8a%a8%e6%80%81%e5%85%b1%e4%bb%b7%e7%bd%91%e7%bb%9c%e7%9a%84%e8%ae%be%e8%ae%a1%e4%b8%8e%e5%ba%94%e7%94%a8%e8%8b%af%e9%85%9a%e7%82%b9%e5%87%bb%e5%8f%8d%e5%ba%94%e5%8f%8a%e5%a4%9a%e5%ad%94%e8%86%9c","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=245510","title":{"rendered":"\u52a8\u6001\u5171\u4ef7\u7f51\u7edc\u7684\u8bbe\u8ba1\u4e0e\u5e94\u7528:\u82ef\u915a\u70b9\u51fb\u53cd\u5e94\u53ca\u591a\u5b54\u819c\u7684\u5236\u5907"},"content":{"rendered":"<p>\u3010\u5bfc\u8bfb\u3011<\/p>\n<p>\u4f17\u6240\u5468\u77e5\uff0c\u57fa\u4e8e\u52a8\u6001\u4ea4\u6362\u53cd\u5e94\u7684\u7f51\u7edc\u91cd\u6392\u8d4b\u4e88\u52a8\u6001\u5171\u4ef7\u7f51\u7edc\uff08DCNs\uff09\u518d\u52a0\u5de5\u548c\u91cd\u5851\u80fd\u529b\uff0c\u76f8\u5173\u7814\u7a76\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u201c\u70b9\u51fb\u201d\u5316\u5b66\u662f\u7f8e\u56fd\u5316\u5b66\u5bb6\u5361\u5c14\u00b7\u5df4\u91cc\u00b7\u590f\u666e\u5229\u65af\uff08Karl\u00a0B.\u00a0Sharpless\uff09\u4e8e2001\u5e74\u63d0\u51fa\u3002\u56e0\u5176\u53cd\u5e94\u7684\u9ad8\u6548\u6027\u548c\u9009\u62e9\u6027\uff0c\u201c\u70b9\u51fb\u201d\u5316\u5b66\u5df2\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6709\u673a\u5408\u6210\uff0c\u751f\u7269\u5408\u6210\uff0c\u805a\u5408\u7269\u5236\u5907\u7b49\u9886\u57df\u3002\u76ee\u524d\u5df2\u6709\u4f17\u591a\u201c\u70b9\u51fb\u201d\u5316\u5b66\u53cd\u5e94\u88ab\u53d1\u6398\uff0c\u5305\u62ec\u5def\u57fa-\u70ef\u201c\u70b9\u51fb\u201d\u53cd\u5e94\uff0c\u5def\u57fa-\u7094\u201c\u70b9\u51fb\u201d\u53cd\u5e94\uff0cDiels-Alder\u53cd\u5e94\u7b49\u3002\u5176\u4e2d\uff0c\u53e0\u6c2e-\u7094\u201c\u70b9\u51fb\u201d\u53cd\u5e94\u548c\u5def\u57fa-\u70ef\u70b9\u51fb\u53cd\u5e94\u5e38\u5e38\u88ab\u7528\u4e8e\u805a\u5408\u7269\u6750\u6599\u7684\u529f\u80fd\u5316\u548c\u4ea4\u8054\u3002\u7136\u800c\u8fd9\u4e24\u79cd 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decoding=\"async\" class=\"aligncenter size-full wp-image-245511\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u5c01\u9762.jpg\" alt=\"\" width=\"600\" height=\"134\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u5c01\u9762.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u5c01\u9762-300x67.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/b><\/strong><\/p>\n<p>1.\u672c\u6587\u9996\u6b21\u5229\u7528\u7094-\u9187\u70b9\u51fb\u53cd\u5e94\u5236\u5907\u70ef\u9187-\u916e\u57fa<strong>DCN<\/strong>\uff0c\u5728\u5c0f\u5206\u5b50\u6a21\u578b\u53cd\u5e94\u4e2d\uff0c\u5c06(E)-3-\u82ef\u6c27\u57fa\u4e19\u70ef\u9178\u4e59\u916f\uff08EPA\uff09\u4e0e\u8fc7\u91cf\u7684\u5bf9\u7532\u57fa\u82ef\u915a\uff08\u6469\u5c14\u6bd4\u4e3a1:10\uff09\u5728180\u2103\u4e0b\u53cd\u5e9418\u5c0f\u65f6\uff0cEPA\u9010\u6e10\u8f6c\u5316\u4e3a\u4e59\u57fa(E)-3-(p-\u7532\u6c27\u57fa)\u4e19\u70ef\u9178\u916f\uff08ETA\uff09\uff1b<\/p>\n<p>2.\u7814\u7a76\u4e86\u70ef\u9187-\u916e\u57fa\u4ea4\u6362\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u901a\u8fc7\u6838\u78c1\u5171\u632f\u56fe\u8c31\u76d1\u6d4b\u548c\u5b9a\u91cf\u4e0d\u540c\u53cd\u5e94\u65f6\u95f4\u7684EPA\u6d53\u5ea6\uff0c\u7136\u540e\u6839\u636e\u4e00\u7ea7\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u65b9\u7a0b\u62df\u5408EPA\u6d53\u5ea6\u4f5c\u4e3a\u53cd\u5e94\u65f6\u95f4\u7684\u51fd\u6570\uff0c\u7136\u540e\u5f97\u5230\u76f8\u5e94\u7684\u53cd\u5e94\u901f\u7387\u5e38\u6570\u3002<\/p>\n<p><strong><b>\u3010\u6570\u636e\u6982\u89c8\u3011<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245512\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe1.jpg\" alt=\"\" width=\"600\" height=\"455\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe1-300x228.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>\u4e00<\/b><\/strong><strong><b>\u3001\u65b0\u578bDCN\u7684\u5236\u5907<\/b><\/strong><strong><b>\u8fc7\u7a0b\u00a9 2022 ACS<\/b><\/strong><\/p>\n<p>\uff08a\uff09EPA\u4e0ep-\u7532\u57fa\u82ef\u915a\u5728180\u2103\u4e0b\u7684\u4ea4\u6362\u53cd\u5e94\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08b\uff09\u5728\u4e0d\u540c\u53cd\u5e94\u65f6\u95f4\u8bb0\u5f55\u7684 <sup>1<\/sup>H NMR\u56fe\u8c31\uff1b<\/p>\n<p>\uff08c\uff09\u5728180\u2103\u3001190\u2103\u548c200\u2103\u4e0b\uff0c\u4e0d\u540c\u7684\u53cd\u5e94\u65f6\u95f4\u5b9a\u91cfEPA\u7ec4\u5206\uff1b<\/p>\n<p>\uff08d\uff09\u7528\u963f\u4f26\u5c3c\u4e4c\u65af\u56fe\u5206\u6790\u4e86EPA\u4e0ep-\u7532\u57fa\u82ef\u915a\u4e4b\u95f4\u7684\u4ea4\u6362\u53cd\u5e94\u3002<strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245513\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2.jpg\" alt=\"\" width=\"600\" height=\"597\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2-150x150.jpg 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2-300x300.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>\u4e8c\u3001\u52a8\u6001\u4ea4\u8054\u7f51\u7edc\u7684\u5236\u5907\u00a9 2022 ACS<\/b><\/strong><\/p>\n<p>\uff08a\uff09\u57fa\u4e8e\u7094-\u9187\u70b9\u51fb\u53cd\u5e94\u5236\u5907\u4e24\u79cd\u7684\u52a8\u6001\u5171\u4ef7\u7f51\u7edc\uff1b<\/p>\n<p>\uff08b\uff09BPA-TH\u7f51\u7edc\u70ed\u538b\u56de\u6536\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08c\uff09BPA-TH\u548cVPV-TH\u6837\u54c1\u5728\u4e09\u6b21\u91cd\u5851\u524d\u540e\u7684\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08d\uff09\u5c06BPA-TH\u548cVPV-TH\u7684\u5f52\u4e00\u5316\u5e94\u529b\u677e\u5f1b\u66f2\u7ebf\u7ed8\u5236\u4e3a\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u65f6\u95f4\u51fd\u6570\uff1b<\/p>\n<p>\uff08e\uff09\u5bf9BPA-TH\u548cVPV-TH\u8fdb\u884c\u963f\u4f26\u5c3c\u4e4c\u65af\u5206\u6790\uff0c\u4ee5\u8ba1\u7b97\u7f51\u7edc\u4e2d\u70ef\u9187-\u82ef\u915a\u4ea4\u6362\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\uff1b<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245514\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe3.jpg\" alt=\"\" width=\"600\" height=\"307\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe3-300x154.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>\u4e09<\/b><\/strong><strong><b>\u3001\u591a\u5b54\u7ed3\u6784<\/b><\/strong><strong><b>\u5408\u6210<\/b><\/strong><strong><b>\u793a\u610f\u56fe<\/b><\/strong><strong><b>\u00a9 2022 ACS<\/b><\/strong><\/p>\n<p>\uff08a\uff09\u901a\u8fc7BPA-TH\u548cVPV-TH DCN\u7684\u878d\u5408\u4ee5\u53ca\u968f\u540e\u7684\u9009\u62e9\u6027\u964d\u89e3\u6765\u751f\u6210\u591a\u5b54\u7ed3\u6784\u7684\u793a\u610f\u56fe\uff1b<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245515\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe4.jpg\" alt=\"\" width=\"600\" height=\"630\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe4.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe4-286x300.jpg 286w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>\u56db<\/b><\/strong><strong><b>\u3001\u591a\u5b54\u7ed3\u6784\u8fc7\u7a0b<\/b><\/strong><strong><b>\u53ca\u5176\u8868\u5f81\u00a9 2022 ACS<\/b><\/strong><\/p>\n<p>\uff08a\uff09\u5236\u5907\u591a\u5b54\u7ed3\u6784\u8fc7\u7a0b\u56fe\uff1b<\/p>\n<p>\uff08b\uff09\u542b\u4e0d\u540cBPATH\/VPV-TH\u542b\u91cf\u7684\u7194\u878dDCNs\u7684DSC\u66f2\u7ebf\u3002<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245516\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe5.jpg\" alt=\"\" width=\"600\" height=\"437\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe5.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe5-300x219.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>\u4e94<\/b><\/strong><strong><b>\u30011B1V-THS<\/b><\/strong><strong><b>\u7684\u5236\u5907\u53ca\u8868\u5f81\u00a9 2022 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