{"id":245224,"date":"2023-01-01T06:00:23","date_gmt":"2022-12-31T22:00:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=245224"},"modified":"2022-12-30T13:12:07","modified_gmt":"2022-12-30T05:12:07","slug":"angew%ef%bc%9a%e5%8f%97%e6%8e%a7%e7%9a%84diels-alder%e7%82%b9%e5%87%bb%e7%ad%96%e7%95%a5%e7%94%a8%e4%ba%8e%e5%ae%9e%e7%8e%b0%e6%9c%ba%e6%a2%b0%e5%8f%96%e5%90%91%e4%b8%bb%e9%93%be","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=245224","title":{"rendered":"Angew\uff1a\u53d7\u63a7\u7684Diels-Alder\u201c\u70b9\u51fb\u201d\u7b56\u7565\u7528\u4e8e\u5b9e\u73b0\u673a\u68b0\u53d6\u5411\u4e3b\u94fe\u6db2\u6676\u7f51\u7edc"},"content":{"rendered":"<p><strong>01<\/strong><strong>\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u53d6\u5411\u6db2\u6676\u805a\u5408\u7269\u662f\u7535\u5b50\u3001\u5149\u5b66\u3001\u751f\u7269\u548c\u8f6f\u673a\u5668\u4eba\u5e94\u7528\u4e2d\u611f\u5174\u8da3\u7684\u6750\u6599\u3002\u8fd9\u4e9b\u6750\u6599\u7684\u5236\u9020\u548c\u52a0\u5de5\u5df2\u7ecf\u88ab\u5e7f\u6cdb\u63a2\u7d22\uff0c\u5176\u4e2d\u673a\u68b0\u5bf9\u51c6\u7531\u4e8e\u5176\u6613\u4e8e\u4f7f\u7528\u548c\u5e7f\u6cdb\u7684\u9002\u7528\u6027\u800c\u6210\u4e3a\u4f18\u9009\u7684\u65b9\u6cd5\u3002\u7136\u800c\uff0c\u673a\u68b0\u5bf9\u51c6\u6240\u9700\u7684\u4e24\u6b65\u805a\u5408\u80cc\u540e\u7684\u57fa\u672c\u5316\u5b66\u673a\u5236\u5728\u5236\u9020\u548c\u886c\u5e95\u517c\u5bb9\u6027\u65b9\u9762\u90fd\u6709\u9650\u5236\u3002<\/p>\n<p><strong>02<\/strong><strong>\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u52a0\u5dde\u5927\u5b66\u5723\u5854\u82ad\u82ad\u62c9\u5206\u6821Javier Read De Alaniz\u7b49\u4eba<\/strong>\u4ecb\u7ecd\u4e86\u4e00\u79cd\u65b0\u7684\u4fdd\u62a4-\u53bb\u4fdd\u62a4\u65b9\u6cd5\uff0c\u8be5\u65b9\u6cd5\u5229\u7528\u4e24\u9636\u6bb5Diels\u2013Alder\u73af\u620a\u4e8c\u70ef-\u9a6c\u6765\u9170\u4e9a\u80fa\u9010\u6b65\u589e\u957f\u805a\u5408\u6765\u5b9e\u73b0\u6e29\u548c\u800c\u9ad8\u6548\u3001\u5feb\u901f\u3001\u53ef\u63a7\u3001\u53ef\u518d\u73b0\u548c\u7528\u6237\u53cb\u597d\u7684\u805a\u5408\uff0c\u4ece\u800c\u62d3\u5bbd\u4e86\u6db2\u6676\u4f53\u7cfb\u7684\u8303\u56f4\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u901a\u8fc7DSC\u3001DMA\u3001POM\u548cWAXD\u5bf9\u8584\u819c\u8fdb\u884c\u4e86\u5168\u9762\u7684\u8868\u5f81\uff0c\u8bc1\u660e\u4e86\u5177\u6709\u70ed\u673a\u68b0\u9a71\u52a8\u80fd\u529b\u7684\u5355\u8f74\u53d6\u5411\u6db2\u6676\u7f51\u7edc\u7684\u6210\u529f\u5408\u6210\u3002<\/p>\n<p>\u76f8\u5173\u7814\u7a76\u6587\u7ae0\u4ee5\u201c<strong><em>Controlled Diels\u2013Alder \u201cClick\u201d Strategy to Access Mechanically Aligned Main-Chain Liquid Crystal Networks<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728<strong><em>Angew. Chem. Int. Ed.<\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245225\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F0.png\" alt=\"\" width=\"1042\" height=\"446\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F0.png 1042w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F0-300x128.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F0-768x329.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F0-1024x438.png 1024w\" sizes=\"(max-width: 1042px) 100vw, 1042px\" \/><\/p>\n<p><strong>03<\/strong><strong>\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>\u672c\u6587\u5f00\u53d1\u4e86\u673a\u68b0\u53d6\u5411\u6db2\u6676\u7f51\u7edc(LCNs)\u7684\u53d7\u63a7\u4e24\u9636\u6bb5\u805a\u5408\u7b56\u7565\uff0c\u5b9e\u73b0\u4e86\u5c06\u4eb2\u6838\u6216\u81ea\u7531\u57fa\u654f\u611f\u5206\u5b50\u5f15\u5165\u5149\u9a71\u52a8\u7684LCNs\u3002<\/p>\n<p><strong>04<\/strong><strong>\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245226\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F1.png\" alt=\"\" width=\"840\" height=\"1014\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F1.png 840w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F1-249x300.png 249w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F1-768x927.png 768w\" sizes=\"(max-width: 840px) 100vw, 840px\" \/><\/p>\n<p><strong>\u56fe\u4e00\u3001a)\u5229\u7528\u4e24\u4e2a\u72ec\u7acb\u805a\u5408\u6b65\u9aa4\u7684\u673a\u68b0\u53d6\u5411\u6db2\u6676\u7f51\u7edc\u7684\u603b\u793a\u610f\u56fe\u3002b)\u4ee5\u524d\u7528\u4e8e\u5b9e\u73b0\u673a\u68b0\u53d6\u5411\u6db2\u6676\u7f51\u7edc\u7684\u4e24\u6b65\u805a\u5408\u7684\u6280\u672f:\u4e0d\u540c\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u548c\u4e0d\u540c\u7684\u53cd\u5e94\u523a\u6fc0\u3002c)<\/strong> <strong>Diels\u2013Alder<\/strong><strong>\u5316\u5b66\u65b9\u6cd5\uff0c\u8be5\u65b9\u6cd5\u4f7f\u7528\u521d\u59cb\u7684\u5206\u6b65\u751f\u957fDiels\u2013Alder\u805a\u5408\uff0c\u968f\u540e\u662f\u6f5c\u5728\u7684\u70ed\u53bb\u4fdd\u62a4\u4ee5\u9501\u5b9a\u673a\u68b0\u6392\u5217\uff0c\u4ece\u800c\u63d0\u4f9b\u79bb\u6563\u7684\u4e24\u6b65\u805a\u5408\u3002\u00a9 2022 Wiley<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245227\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F2.png\" alt=\"\" width=\"1269\" height=\"478\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F2.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F2-300x113.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F2-768x289.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F2-1024x386.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p><strong>\u56fe\u4e8c\u3001a)\u7528\u4e8e\u9010\u6b65\u589e\u957fDA\u805a\u5408\u7684\u5e26\u6709\u9a6c\u6765\u9170\u4e9a\u80fa\u548c\u73af\u620a\u4e8c\u70ef\u90e8\u5206\u7684\u53cc\u5b98\u80fd\u5355\u4f53\u3002b)\u6e29\u5ea6\u8c03\u8282\u805a\u5408\u7684\u793a\u610f\u56fe\u3002c)\u7ebf\u6027\u805a\u5408\u7684\u52a8\u529b\u5b66\u3002\u9a6c\u6765\u9170\u4e9a\u80fa(\u7ea2\u8272)\u3001\u73af\u620a\u4e8c\u70ef(\u6d45\u84dd\u8272)\u7684\u6d88\u8017\u3001\u88ab\u4fdd\u62a4\u7684\u5185\u544b\u5583-\u9a6c\u6765\u9170\u4e9a\u80fa\u52a0\u5408\u7269\u7684\u8131\u4fdd\u62a4(\u7d2b\u8272)\u548c\u5177\u6709\u9a6c\u6765\u9170\u4e9a\u80fa\u7684\u73af\u620a\u4e8c\u70ef\u884d\u751f\u7269(DA Cp-mal\uff0c\u7070\u8272)\u7684\u751f\u6210\u4f5c\u4e3a\u65f6\u95f4\u548c\u6e29\u5ea6\u7684\u51fd\u6570\u4f5c\u56fe\u3002\u00a9 2022 Wiley<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245228\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F3.png\" alt=\"\" width=\"1269\" height=\"991\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F3.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F3-300x234.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F3-768x600.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F3-1024x800.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p><strong>\u56fe\u4e09\u3001\u8584\u819c\u5236\u5907\u793a\u610f\u56fe\u3002Diels\u2013Alder\u6db2\u6676\u7f51\u7edc\u7684\u7b80\u6613\u5236\u5907\u3002\u5728\u6ca1\u6709\u50ac\u5316\u5242\u7684\u5de5\u4f5c\u53f0\u4e0a\u5236\u5907\u7684\u8584\u819c\uff0c\u66b4\u9732\u5728\u7a7a\u6c14\u548c\u73af\u5883\u6761\u4ef6\u4e0b\u3002\u56fe\u4e2d\u663e\u793a\u4e86\u7b2c\u4e00\u6b21\u548c\u7b2c\u4e8c\u6b21\u805a\u5408\u540e\u7684\u8584\u819c\u4ee5\u53ca\u8be5\u8fc7\u7a0b\u7684\u5361\u901a\u56fe\u50cf\u3002\u00a9 2022 Wiley<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245229\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F4.png\" alt=\"\" width=\"774\" height=\"1014\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F4.png 774w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F4-229x300.png 229w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F4-768x1006.png 768w\" sizes=\"(max-width: 774px) 100vw, 774px\" \/><\/p>\n<p><strong>\u56fe\u56db\u3001a)\u5728\u4e24\u4e2a\u5149\u4ea4\u53c9\u504f\u632f\u5668\u4e4b\u95f4\u768445\u00b0\u548c0\u00b0\u5904\u7684DA Cp-mal LCN\u7684\u504f\u632f\u5149\u5b66\u663e\u5fae\u672f\u3002b)\u62c9\u4f38\u81f3\u5176\u521d\u59cb\u957f\u5ea6\u7684400 %\u7684DA Cp-mal LCN\u7684\u4e8c\u7ef4\u5e7f\u89d2X\u5c04\u7ebf\u884d\u5c04\u3002c)DA Cp-mal LCN\u7684\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\uff0c\u5176\u4e2d\u53ef\u4ee5\u572810 \u2103\/min\u7684\u5347\u6e29\u901f\u7387(\u5de6\u8f74)\u4e0b\u89c2\u5bdf\u523063\u2103\u7684\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\uff0c\u4ee5\u53ca\u901a\u8fc7\u52a8\u6001\u673a\u68b0\u5206\u6790\u57280.005 N\u7684\u62c9\u4f38\u6052\u529b\u4e0b\u4ee53 \u2103\/min\u7684\u5347\u6e29\u901f\u7387(\u53f3\u8f74)\u6d4b\u91cf\u7684\u4f5c\u4e3a\u6e29\u5ea6\u51fd\u6570\u7684\u5e94\u53d8\u53d8\u5316\u3002\u00a9 2022 Wiley<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245230\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F5.png\" alt=\"\" width=\"1269\" height=\"526\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F5.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F5-300x124.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F5-768x318.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/F5-1024x424.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p><strong>\u56fe\u4e94\u3001\u70ed\u9a71\u52a8\u524da)\u548c\u70ed\u9a71\u52a8\u540eb)\u7684LCN\u56fe\u50cf\u3002\u00a9 2022 Wiley<\/strong><\/p>\n<p><strong>05<\/strong><strong>\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u672c\u5de5\u4f5c\u4f7f\u7528\u5feb\u901f\u548c\u7a33\u5b9a\u7684\u73af\u620a\u4e8c\u70ef\u9a6c\u6765\u9170\u4e9a\u80fa\u9010\u6b65\u589e\u957f\u805a\u5408\u5efa\u7acb\u4e86\u7528\u4e8e\u673a\u68b0\u53d6\u5411\u6db2\u6676\u7f51\u7edc\u7684\u53d7\u63a7\u4e24\u9636\u6bb5\u805a\u5408\u7684\u4fdd\u62a4-\u53bb\u4fdd\u62a4\u65b9\u6cd5\u3002\u8fd9\u4e3a\u5c06\u4eb2\u6838\u6216\u81ea\u7531\u57fa\u654f\u611f\u5206\u5b50\u5f15\u5165\u5149\u9a71\u52a8LCN\u63d0\u4f9b\u4e86\u4e00\u4e2a\u6709\u524d\u9014\u7684\u7b56\u7565\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u7f51\u7edc\u5f62\u6210\u7684\u6027\u8d28\uff0c\u8fd9\u79cd\u5149\u9a71\u52a8LCN\u6709\u53ef\u80fd\u5b9e\u73b0\u66f4\u5927\u7684\u91c7\u6837\u5668\u51e0\u4f55\u5f62\u72b6\u3002<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5\uff1aJ. Guillen Campos, F. Stricker, K. D. Clark, M. Park, S. J. Bailey, A. S. Kuenstler, R. C. Hayward, J. Read de Alaniz. Controlled Diels\u2013Alder \u201cClick\u201d Strategy to Access Mechanically Aligned Main-Chain Liquid Crystal Networks. Angew. Chem. Int. Ed. 2022, e202214339.<\/strong><\/p>\n<p><strong>https:\/\/doi.org\/10.1002\/anie.202214339<\/strong><\/p>\n<p>\u672c\u6587\u7531\u666f\u884c\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>01\u3010\u5bfc\u8bfb\u3011 \u53d6\u5411\u6db2\u6676\u805a\u5408\u7269\u662f\u7535\u5b50\u3001\u5149\u5b66\u3001\u751f\u7269\u548c\u8f6f\u673a\u5668\u4eba\u5e94\u7528\u4e2d\u611f\u5174\u8da3\u7684\u6750\u6599\u3002\u8fd9\u4e9b\u6750\u6599\u7684\u5236\u9020\u548c\u52a0\u5de5\u5df2\u7ecf\u88ab\u5e7f\u6cdb\u63a2\u7d22\uff0c\u5176\u4e2d\u673a\u68b0\u5bf9\u51c6\u7531\u4e8e\u5176\u6613\u4e8e\u4f7f\u7528\u548c\u5e7f\u6cdb\u7684\u9002\u7528\u6027\u800c\u6210\u4e3a\u4f18&#8230;<\/p>\n","protected":false},"author":36004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-245224","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/245224"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/36004"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=245224"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/245224\/revisions"}],"predecessor-version":[{"id":245295,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/245224\/revisions\/245295"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=245224"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=245224"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=245224"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}