{"id":244891,"date":"2022-12-18T06:32:34","date_gmt":"2022-12-17T22:32:34","guid":{"rendered":"\/\/m.iemloyee.com\/?p=244891"},"modified":"2022-12-18T10:56:19","modified_gmt":"2022-12-18T02:56:19","slug":"%e8%bf%99%e7%af%87science-%e5%b7%a7%e7%94%a8%e6%b6%b2%e4%bd%93%e9%87%91%e5%b1%9e%ef%bc%8c%e6%8f%90%e5%8f%96%e9%9b%aa%e8%8a%b1%e6%99%b6%e4%bd%93","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=244891","title":{"rendered":"\u8fd9\u7bc7Science \u628a\u91d1\u5c5e\u73a9\u51fa\u4e86\u82b1\uff01\uff01\uff01"},"content":{"rendered":"<p>\u4e00\u3001\u5bfc\u8bfb<\/p>\n<p>\u7269\u8d28\u5728\u7279\u5b9a\u7684\u7269\u7406\u548c\u5316\u5b66\u6761\u4ef6\u4e0b\u53ef\u4ee5\u7531\u6c14\u76f8\u3001\u6db2\u76f8\u6216\u56fa\u76f8\u5f62\u6210\u6676\u4f53\u3002\u6309\u7167\u6676\u4f53\u751f\u957f\u7684\u60c5\u51b5\uff0c\u6676\u4f53\u5e38\u751f\u957f\u6210\u4e3a\u9762\u5e73\u3001\u68f1\u76f4\u7684\u591a\u9762\u4f53\u5f62\u6001\u3002\u5176\u4e2d\uff0c\u6bd4\u8f83\u5947\u7279\u7684\u5f62\u72b6\u662f\u81ea\u7136\u754c\u4e2d\u7684\u516d\u8fb9\u5f62\u96ea\u82b1\u72b6\u6676\u4f53\u3002\u96ea\u82b1\u6676\u4f53\u7684\u7814\u7a76\uff0c\u5728\u6211\u56fd\u6700\u65e9\u53ef\u4ee5\u8ffd\u6eaf\u5230\u897f\u6c49\u65f6\u671f\uff0c\u5b66\u8005\u97e9\u5a74\u5728\u300a\u97e9\u8bd7\u5916\u4f20\u2022\u8865\u9057\u300b\u4e2d\u8bb0\u8f7d\uff1a\u201c\u51e1\u8349\u6728\u82b1\u591a\u4e94\u51fa\uff0c\u96ea\u82b1\u72ec\u516d\u51fa\u3002\u201d\u76ee\u524d\u5bf9\u4e8e\u96ea\u82b1\u6676\u4f53\u7684\u7ed3\u6676\u8fc7\u7a0b\uff0c\u4ecd\u7136\u662f\u6676\u4f53\u5b66\u9886\u57df\u79d1\u5b66\u5bb6\u7814\u7a76\u7684\u76ee\u6807\u3002<\/p>\n<p>\u90a3\u4e48\uff0c\u5229\u7528\u96ea\u82b1\u6676\u4f53\u7684\u5f62\u6001\u6f14\u5316\u77e5\u8bc6\uff0c\u5728\u8bb8\u591a\u5929\u7136\u548c\u5408\u6210\u4f53\u7cfb\u4e2d\u53d1\u73b0\u7684\u9ad8\u5ea6\u590d\u6742\u7684\u6676\u4f53\u751f\u957f\u884c\u4e3a\uff0c\u4f1a\u4ea7\u751f\u4ec0\u4e48\u6837\u7684\u706b\u82b1\u5462\uff1f<\/p>\n<p>\u4e8c\u3001\u6210\u679c\u63a0\u5f71<\/p>\n<p>\u91d1\u5c5e\u5728\u9ad8\u6e29\u4e0b\u5f88\u5bb9\u6613\u6eb6\u89e3\u5728\u6db2\u6001\u9553\u4e2d\uff0c\u51b7\u5374\u540e\u4ece\u6eb6\u6db2\u4e2d\u6790\u51fa\u3002\u7136\u800c\uff0c\u6db2\u6001\u91d1\u5c5e\u7684\u9ad8\u8868\u9762\u5f20\u529b\u4f7f\u5f97\u63d0\u53d6\u8fd9\u4e9b\u6676\u4f53\u975e\u5e38\u56f0\u96be\u3002\u901a\u8fc7\u4f7f\u7528\u7535\u6bdb\u7ec6\u7ba1\u8c03\u5236\u548c\u771f\u7a7a\u8fc7\u6ee4\u76f8\u7ed3\u5408\u7684\u65b9\u6cd5\u964d\u4f4e\u5176\u8868\u9762\u5f20\u529b\uff0c\u4ece\u6db2\u6001\u91d1\u5c5e\u6eb6\u5242\u4e2d\u63d0\u53d6\u8fd9\u4e9b\u91d1\u5c5e\u6676\u4f53\u3002<\/p>\n<p>\u4ece\u6db2\u6001\u91d1\u5c5e\u6eb6\u5242\u4e2d\u63d0\u53d6\u5408\u6210\u7684\u6676\u4f53\uff0c\u540c\u65f6\u4fdd\u7559\u5176\u5fae\u89c2\u7cbe\u7ec6\u7279\u5f81\uff0c\u5e76\u663e\u793a\u5176\u66b4\u9732\u7684\u6676\u4f53\u9762\uff0c\u8fd9\u662f\u4e00\u4e2a\u76f8\u5f53\u5927\u7684\u6311\u6218\u3002\u5c06\u6db2\u6001Ga\u4e3a\u6eb6\u5242\uff0c\u89c2\u5bdf\u6eb6\u89e3\u91d1\u5c5e\u6676\u4f53\u5f62\u6210\u8fc7\u7a0b\u7684\u5f62\u8c8c\u548c\u6210\u5206\u9009\u62e9\uff0c\u8bc1\u660e\u4e86\u7535\u6bdb\u7ec6\u7ba1\u8c03\u5236\u548c\u771f\u7a7a\u8fc7\u6ee4\u76f8\u7ed3\u5408\u53ef\u4ee5\u6709\u6548\u5730\u4ece\u6db2\u6001Ga\u6eb6\u5242\u4e2d\u63d0\u53d6\u91d1\u5c5e\u6676\u4f53\u3002\u4e00\u7bc7\u53d1\u8868\u5728<em>Science<\/em>\u4e0a\uff0c\u9898\u76ee\u4e3a\u201cLiquid metal synthesis solvents for metallic crystals\u201d\u7684\u6587\u7ae0\u4ecb\u7ecd\u4e86\u76f8\u5173\u5185\u5bb9\u3002\u7b2c\u4e00\u4f5c\u8005\u4e3aShuhada A. Idrus-Saidi\u3001Jianbo Tang\uff0c\u901a\u8baf\u4f5c\u8005\uff1aKourosh Kalantar-Zadeh\u3001Nicola Gaston\u3001Torben Daeneke\uff0c\u901a\u8baf\u5355\u4f4d\uff1a\u6fb3\u5927\u5229\u4e9a\u65b0\u5357\u5a01\u5c14\u58eb\u5927\u5b66\u3001\u65b0\u897f\u5170\u5965\u514b\u5170\u5927\u5b66\u3001\u6fb3\u5927\u5229\u4e9a\u7687\u5bb6\u58a8\u5c14\u672c\u7406\u5de5\u5927\u5b66\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-244892\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/0-5.png\" alt=\"\" width=\"1015\" height=\"347\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/0-5.png 1015w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/0-5-300x103.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/0-5-768x263.png 768w\" sizes=\"(max-width: 1015px) 100vw, 1015px\" \/><\/p>\n<p>\u4e09\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/p>\n<p>\u672c\u5de5\u4f5c\u9996\u5148\u5c1d\u8bd5\u901a\u8fc7\u591a\u5b54\u5c3c\u9f99\u6ee4\u819c(\u5b54\u5f84: 20\u03bcm)\u8fc7\u6ee4\u91d1\u5c5e\u80f6\u4f53\u6eb6\u6db2\uff0c\u7528\u6765\u514b\u670d\u6db2\u6001Ga\u7684\u9ad8\u8868\u9762\u5f20\u529b\u963b\u788d\u91d1\u5c5e\u6676\u4f53\u6790\u51fa\u7269\u4e0e\u6db2\u6001\u91d1\u5c5e\u6eb6\u5242\u7684\u5206\u79bb\u3002<\/p>\n<p>\u4e3a\u4e86\u964d\u4f4e\u8868\u9762\u5f20\u529b\uff0c\u5728NaOH\u6eb6\u6db2\u4e2d\u5bf9\u6db2\u6001\u91d1\u5c5e\u65bd\u52a0\u6b63\u76845 V\u7684\u7535\u4f4d\uff0c\u540c\u65f6\u65bd\u52a0\u771f\u7a7a\u8f85\u52a9\u8fc7\u6ee4\u3002\u7535\u5316\u5b66\u9a71\u52a8\u5df2\u88ab\u8bc1\u660e\u53ef\u4ee5\u4f7f\u6db2\u6001\u91d1\u5c5e\u7684\u8868\u9762\u5f20\u529b\u4ece\u81ea\u7136\u503c\u8c03\u8282\u5230\u63a5\u8fd1\u96f6\u3002<\/p>\n<p>\u5229\u7528AIMD\u6a21\u62df\u9884\u6d4b\u7684Zn(0001)\u62e9\u4f18\u53d6\u5411\uff0c\u5728\u6db2\u6001Ga\u4e2dZn\u6676\u4f53\u751f\u957f\u7684\u5b9e\u9a8c\u89c2\u5bdf\u5f97\u5230\u4e86\u9a8c\u8bc1\u3002<\/p>\n<p>\u56db\u3001\u6570\u636e\u6982\u89c8<\/p>\n<p><strong>\u56fe<\/strong><strong>1 <\/strong>\u6676\u4f53\u5f62\u6210\u548c\u63d0\u53d6\u7b56\u7565\u7684\u793a\u610f\u56fe\u3002(A)\u5728\u6db2\u6001\u91d1\u5c5e\u6eb6\u5242\u4e2d\u751f\u957f\u91d1\u5c5e\u6676\u4f53\u7684\u5b9e\u9a8c\u7a0b\u5e8f\u3002\u6307\u51fa\u4e86\u91d1\u5c5e\u6eb6\u8d28\u3001\u91d1\u5c5e\u6eb6\u5242\u4ee5\u53ca\u51b3\u5b9a\u6676\u4f53\u7ed3\u6784\u548c\u5c3a\u5bf8\u7684\u53c2\u6570(\u5305\u62ec\u6e29\u5ea6T\u3001\u6d53\u5ea6C\u3001\u538b\u529bP\u548c\u65f6\u95f4T)\u3002(B)\u5229\u7528\u7535\u573a\u548c\u771f\u7a7a\u8fc7\u6ee4\u5c06\u6676\u4f53\u4ece\u6db2\u6001\u91d1\u5c5e\u4e2d\u5206\u79bb\u51fa\u6765\u3002(C)\u5177\u6709\u4e0d\u540c\u5f62\u6001\u548c\u7ec4\u6210\u7684\u5404\u79cd\u7c7b\u578b\u6676\u4f53\u7684\u4f8b\u5b50\u3002(D) Zn(0001)\u548c(E) Zn (101(-)0)\u4e0e\u6db2\u6001Ga\u754c\u9762\u7684\u4fef\u89c6\u56fe\u7ed3\u6784\u3002(F) Zn(0001)\u548cZn(101(-)0)\u8868\u9762\u7aef\u90e8\u4e0e\u6db2\u6001Ga\u754c\u9762\u65f6\u7684\u5f84\u5411\u5206\u5e03\u548c\u89d2\u5ea6\u5206\u5e03\u529f\u80fd\u5206\u6790\u3002\u00a9 2022 AAAS<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-244893\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/1-8.png\" alt=\"\" width=\"856\" height=\"820\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/1-8.png 856w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/1-8-300x287.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/1-8-768x736.png 768w\" sizes=\"(max-width: 856px) 100vw, 856px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56fe<\/strong><strong>2<\/strong> \u6db2\u6001Zn<sub>10<\/sub>Ga<sub>90<\/sub>\u5408\u91d1\u4e2dZn\u7ed3\u6676\u8fc7\u7a0b\u7684\u8868\u5f81\u3002(A-C)\u5728350\u00b0C\u7684\u521d\u59cb\u6e29\u5ea6\u4e0b(A)\u751f\u957f1\u5929\uff0c(B)\u751f\u957f2\u5929\uff0c(C)\u751f\u957f10\u5929\u540e\u83b7\u5f97\u7684Zn\u6676\u4f53\u7684SEM\u56fe\u50cf\u3002(D)\u5728550\u00b0C\u521d\u59cb\u6e29\u5ea6\u4e0b\u751f\u957f1\u5929\u540eZn\u6676\u4f53\u7684SEM\u56fe\u50cf\u3002(E) \u538b\u529b\u4e3a5 bar\u4e0b1\u5929\u540e\u5f62\u6210\u7684Zn\u6676\u4f53\u7684SEM\u56fe\u50cf\u3002(F)\u4e0d\u540c\u5b9e\u9a8c\u6761\u4ef6\u4e0b(A) ~ (E)\u6676\u4f53\u7684\u5c3a\u5bf8\u5206\u5e03\u3002(G) (A) ~ (E)\u63d0\u53d6\u6676\u4f53\u4e2d\u4e0d\u540c\u6676\u4f53\u5f62\u6001(\u6811\u72b6\u5927\u5206\u5b50\u3001\u5206\u5f62\u548c\u5e73\u677f)\u7684\u6bd4\u4f8b\u3002(H)\u63d0\u53d6\u6676\u4f53\u7684XRD\u56fe\u8c31\u663e\u793a\u5355\u76f8Zn (Miller\u6307\u6570) \u00a9 2022 AAAS<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-244894\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/2-9.png\" alt=\"\" width=\"857\" height=\"842\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/2-9.png 857w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/2-9-300x295.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/2-9-768x755.png 768w\" sizes=\"(max-width: 857px) 100vw, 857px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3<\/strong> \u00a0Zn\u6676\u4f53\u7684\u5f62\u8c8c\u56fe\u3002(A)\u5728\u76f8\u540c\u6e29\u5ea6(350\u00b0C)\u548c\u538b\u529b(\u5927\u6c14\u538b)\u6761\u4ef6\u4e0b\uff0c\u6839\u636eZn\u6676\u4f53\u7c7b\u578b\u4f5c\u4e3a\u6676\u4f53\u751f\u957f\u65f6\u95f4\u548cZn\u6d53\u5ea6\u7684\u51fd\u6570\u7ed8\u5236\u7684\u5f62\u8c8c\u56fe\u3002(B)\u751f\u957f2\u5929\u540e\u4e0d\u540c\u950c\u6210\u5206\u950c\u6676\u4f53\u7684\u4f8b\u5b50\u3002\u00a9 2022 AAAS<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-244895\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/3-9.png\" alt=\"\" width=\"707\" height=\"733\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/3-9.png 707w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/3-9-289x300.png 289w\" sizes=\"(max-width: 707px) 100vw, 707px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4<\/strong> \u00a0\u9664Zn-Ga\u5916\u7684\u91d1\u5c5eGa\u7cfb\u5f62\u6210\u548c\u63d0\u53d6\u6676\u4f53\u3002(A ~ G)\u4ece(A)Sn-Ga\uff0c (B) Bi-Ga\uff0c (C) Ag-Ga\uff0c(D) Mn- ga\uff0c(E) Ni-Ga\uff0c(F) Cu-Ga\uff0c(G) Pt-Ga\u4e8c\u5143\u4f53\u7cfb(\u53f3\u4fa7\u56fe\u50cf\u663e\u793a\u677f\u72b6\u548c\u68d2\u72b6\u7ed3\u6784)\u4e2d\u63d0\u53d6\u7684\u6676\u4f53(H) SEM\u56fe\u50cf\uff0c\u663e\u793aAl\u548cMn\u5206\u5e03\u7684EDS\u5143\u7d20\u6620\u5c04\uff0cAl-Mn- ga\u4e09\u5143\u5408\u91d1\u4f53\u7cfb\u7684XRD\u8c31\u56fe\u548c\u5c3a\u5bf8\u5206\u5e03\u3002\u6240\u6709\u6676\u4f53\u7684\u751f\u957f\u6761\u4ef6\u8bbe\u7f6e\u4e3a1\u5929\u7684\u751f\u957f\u65f6\u95f4\uff0c350\u00b0C\u7684\u521d\u59cb\u6e29\u5ea6\u548c\u5927\u6c14\u538b \u00a9 2022 AAAS<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-244896\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/4-8.png\" alt=\"\" width=\"428\" height=\"663\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/4-8.png 428w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/12\/4-8-194x300.png 194w\" sizes=\"(max-width: 428px) 100vw, 428px\" \/><\/p>\n<p>\u4e94\u3001\u6210\u679c\u542f\u793a<\/p>\n<p>\u672c\u6587\u901a\u8fc7\u4f7f\u7528\u4e8c\u5143\u950c-\u9553(Zn- ga)\u4f53\u7cfb\u4f5c\u4e3a\u4e3b\u8981\u6a21\u578b\uff0c\u4ea7\u751f\u4e86\u5404\u79cd\u7c7b\u578b\u7684\u9ad8\u5ea6\u5bf9\u79f0\u7684Zn\u7ed3\u6784\uff0c\u7c7b\u4f3c\u4e8e\u516d\u652f\u96ea\u82b1\u6676\u4f53\u3002\u7814\u7a76\u4e86\u6eb6\u8d28\u6d53\u5ea6\u3001\u6676\u4f53\u751f\u957f\u65f6\u95f4\u3001\u6e29\u5ea6\u548c\u538b\u529b\u5bf9Zn-Ga\u4f53\u7cfb\u96ea\u82b1\u72b6\u6676\u4f53\u5f62\u6001\u7684\u5f71\u54cd\u3002\u540c\u65f6\uff0c\u6d4b\u8bd5\u4e86\u9521(Sn)\u3001\u94cb(Bi)\u3001\u94f6(Ag)\u3001\u9530(Mn)\u3001\u954d(Ni)\u3001\u94dc(Cu)\u3001\u94c2(Pt)\u7b49\u5176\u4ed6\u6eb6\u8d28\u91d1\u5c5e\uff0cMn\u548c\u94dd(Al)\u7684\u6eb6\u8d28\u91d1\u5c5e\u5076\u8054\uff0c\u4ee5\u53ca\u6eb6\u5242\u6548\u5e94\uff0c\u4ee5\u8bc1\u660e\u6676\u4f53\u7684\u5f62\u6001\u548c\u6210\u5206\u591a\u6837\u6027\uff0c\u5e76\u5c55\u793a\u5176\u5e94\u7528\u3002\u65bd\u52a0\u7535\u538b\u540e\uff0c\u6db2\u6001\u91d1\u5c5e\u56e0\u5176\u8868\u9762\u5f20\u529b\u7684\u6025\u5267\u4e0b\u964d\u800c\u77ac\u95f4\u6241\u5e73\u81a8\u80c0\u3002\u964d\u4f4e\u8868\u9762\u5f20\u529b\u540e\uff0c\u6db2\u6001Ga\u80fd\u591f\u4e0eNaOH\u6eb6\u6db2\u4e00\u8d77\u901a\u8fc7\u8fc7\u6ee4\u5668\u3002<\/p>\n<p>\u901a\u8fc7\u5bf9\u6db2\u6001\u91d1\u5c5e\u6eb6\u6db2\u65bd\u52a0\u7535\u538b\u540c\u65f6\u8fdb\u884c\u771f\u7a7a\u8fc7\u6ee4\u7684\u63d0\u53d6\u65b9\u6cd5\u3002\u7531\u6b64\u4ea7\u751f\u7684\u6676\u4f53\u53ef\u80fd\u5177\u6709\u96ea\u82b1\u72b6\u7684\u6676\u4f53\u7ed3\u6784\u3002\u8fd9\u4e00\u7b56\u7565\u53ef\u4ee5\u5e94\u7528\u5728\u5404\u79cd\u5f62\u6001\u7684\u91d1\u5c5e\u9897\u7c92\uff0c\u5e94\u7528\u5728\u4e0d\u540c\u5143\u7d20\u548c\u5408\u91d1\u4e2d\u3002\u6db2\u6001Ga\u5728\u6210\u6838\u540e\u6676\u4f53\u751f\u957f\u8fc7\u7a0b\u4e2d\u53ef\u4ee5\u901a\u8fc7\u504f\u597d\u5bf9\u79f0\u6216\u53d6\u5411\u6765\u4f18\u5148\u6307\u5bfc\u6eb6\u8d28\u91d1\u5c5e\u7ed3\u6784\u7684\u751f\u957f\u3002\u53e6\u5916\uff0c\u8fd9\u9879\u5de5\u4f5c\u53ef\u4ee5\u5bf9\u4e8e\u76ee\u524d\u5df2\u5b58\u5728\u7684\u6676\u4f53\u5e93\uff0c\u901a\u8fc7\u5bf9\u6db2\u6001\u91d1\u5c5e\u6eb6\u5242\u751f\u957f\u6cd5\u751f\u957f\u5316\u5408\u7269\u6676\u4f53\u7684\u53ef\u80fd\u6027\uff0c\u6781\u5927\u5730\u6269\u5c55\u6676\u4f53\u5e93\u6570\u636e\u3002\u8be5\u7b56\u7565\u5bf9\u4e8e\u4ece\u6db2\u6001\u91d1\u5c5e\u6eb6\u5242\u4e2d\u5236\u5907\u9ad8\u5ea6\u7ed3\u6676\u3001\u5f62\u72b6\u53ef\u63a7\u7684\u91d1\u5c5e\u6216\u591a\u91d1\u5c5e\u7cbe\u7ec6\u7ed3\u6784\uff0c\u63d0\u4f9b\u4e86\u65b0\u7684\u8bbe\u8ba1\u601d\u8def\u3002<\/p>\n<p><strong>\u8bba\u6587\u5730\u5740\uff1a<\/strong><\/p>\n<p>https:\/\/www.science.org\/doi\/10.1126\/science.abm2731<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u5bfc\u8bfb 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