{"id":244207,"date":"2022-11-19T06:44:13","date_gmt":"2022-11-18T22:44:13","guid":{"rendered":"\/\/m.iemloyee.com\/?p=244207"},"modified":"2022-11-18T22:02:13","modified_gmt":"2022-11-18T14:02:13","slug":"%e6%b8%a4%e6%b5%b7%e5%a4%a7%e5%ad%a6%e8%94%a1%e5%85%8b%e8%bf%aa-%e9%83%9e%e7%ac%91%e7%9f%b3%e5%9b%a2%e9%98%9f%ef%bc%86%e5%8c%97%e7%90%86%e5%b7%a5%e7%8e%8b%e6%8c%af%e5%8d%8ecomposites-part-b%ef%bc%9ati","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=244207","title":{"rendered":"\u6e24\u6d77\u5927\u5b66\u8521\u514b\u8fea\u90de\u7b11\u77f3\uff06\u5317\u7406\u5de5\u738b\u632f\u534eComposites Part B\uff1aTiO2-VOx\u5f02\u8d28\u7ed3\u5b9e\u73b0\u5bf9\u591a\u786b\u5316\u9502\u7684\u4e00\u6b65\u5438\u9644-\u6269\u6563-\u8f6c\u5316"},"content":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/p>\n<p>\u8fd1\u5e74\u6765\uff0c\u9502\u786b\uff08Li-S\uff09\u7535\u6c60\u56e0\u5176\u5728\u50a8\u80fd\u88c5\u7f6e\u3001\u7535\u52a8\u6c7d\u8f66\u548c\u5176\u4ed6\u7eff\u8272\u80fd\u6e90\u9886\u57df\u7684\u5b9e\u9645\u5e94\u7528\u524d\u666f\u5e7f\u9614\u800c\u5907\u53d7\u5173\u6ce8\u3002Li-S\u7535\u6c60\u901a\u8fc7\u786b\u548c\u9502\u7684\u7535\u5316\u5b66\u53cd\u5e94\u63d0\u4f9b\u6781\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\uff081675 mAh g<sup>-1<\/sup>\uff09\uff0c\u4e14\u73af\u5883\u53cb\u597d\u3001\u5b89\u5168\u548c\u4f4e\u6210\u672c\u662f\u4e0d\u53ef\u5426\u8ba4\u7684\u4f18\u52bf\u3002\u7136\u800c\uff0cLi-S\u7535\u6c60\u7684\u53d1\u5c55\u53d7\u5230\u8bb8\u591a\u56fa\u6709\u95ee\u9898\u7684\u963b\u788d\u3002\u4f8b\u5982S<sub>8<\/sub>\u548cLi<sub>2<\/sub>S\u4f4e\u7684\u7535\u5bfc\u7387\u3001\u7531\u5bc6\u5ea6\u5dee\u5f15\u8d77\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u81a8\u80c0\u3001\u591a\u786b\u5316\u9502\uff08LiPSs\uff09\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u201c\u7a7f\u68ad\u6548\u5e94\u201d\u7b49\u3002\u8fd9\u4e9b\u95ee\u9898\u5bfc\u81f4\u53cd\u5e94\u52a8\u529b\u5b66\u6162\u3001\u5bb9\u91cf\u5feb\u901f\u4e0b\u964d\u548c\u5faa\u73af\u6027\u80fd\u5dee\u3002\u5df2\u7ecf\u63d0\u51fa\u4e86\u5404\u79cd\u7b56\u7565\u6765\u514b\u670d\u9502\u786b\u7535\u6c60\u7684\u6280\u672f\u969c\u788d\u3002DFT\u7406\u8bba\u8ba1\u7b97\u8bc1\u660e\u4e86LiPSs\u5728\u6781\u6027\u5316\u5408\u7269\u4e2d\u901a\u8fc7\u8303\u5fb7\u534e\u76f8\u4e92\u4f5c\u7528\u7684\u5f3a\u7684\u5438\u9644\u80fd\u529b\uff0c\u901a\u8fc7\u8fd9\u79cd\u5316\u5b66\u951a\u5b9a\u6291\u5236\u7a7f\u68ad\u6548\u5e94\uff0c\u4f46\u5355\u4e00\u6dfb\u52a0\u5242\u603b\u662f\u5b9e\u73b0\u5355\u9762\u529f\u80fd\u3002\u56e0\u6b64\uff0c\u5efa\u7acb\u4e86\u4e00\u79cd\u72ec\u7279\u7684\u5f02\u8d28\u7ed3\u6784\uff0c\u5177\u6709\u5bf9\u591a\u786b\u5316\u7269\u7684\u9ad8\u5438\u9644\u548c\u5feb\u901f\u50ac\u5316\u8f6c\u5316\uff0c\u8fd9\u4e5f\u5b9e\u73b0\u4e86\u5176\u5404\u81ea\u529f\u80fd\u7684\u534f\u540c\u6548\u5e94<\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u6e24\u6d77\u5927\u5b66\u8521\u514b\u8fea\u6559\u6388\u3001\u90de\u7b11\u77f3\u526f\u6559\u6388\uff06\u5317\u7406\u5de5\u738b\u632f\u534e\u6559\u6388\u3001\u738b\u5766\u535a\u58eb\u7814\u7a76\u751f<\/strong>\u901a\u8fc7\u5f02\u8d28\u754c\u9762\u548c\u7f3a\u9677\u5de5\u7a0b\u7684\u53cc\u91cd\u7b56\u7565\uff0c\u8bbe\u8ba1\u4e86\u7528\u4e8e\u957f\u5bff\u547dLi-S\u7535\u6c60\u7684\u5177\u6709TiO<sub>2<\/sub>-VO<sub>x<\/sub>\u5f02\u8d28\u7ed3\u6784\u7684\u82cd\u8033\u72b6\u786b\u4e3b\u4f53\uff08CTVHs\uff09\uff0c\u5e76\u83b7\u5f97\u4e86\u5bf9LiPSs\u5728CTVHs\u4e0a\u5438\u9644\u884c\u4e3a\u7684\u539f\u5b50\u7ea7\u7406\u89e3\u3002\u9ad8\u5438\u9644\u80fd\u5f02\u8d28\u7ed3\u754c\u9762\u63d0\u4f9b\u5f3a\u5927\u7684LiPSs\u6355\u83b7\u4e2d\u5fc3\uff0c\u5e76\u786e\u4fdd\u5feb\u901f\u6269\u6563\u5230VO<sub>x<\/sub>\u8868\u9762\u3002\u6b64\u5916\uff0c\u5bcc\u542b\u7f3a\u9677\u7684\u591a\u523aVO<sub>x<\/sub>\u5177\u6709\u5bf9LiPSs\u7684\u9ad8\u50ac\u5316\u6d3b\u6027\u548c\u5feb\u901f\u7684\u9502\u79bb\u5b50\u8fc1\u79fb\uff0c\u4ece\u800c\u6709\u6548\u5730\u5b9e\u73b0\u4e00\u6b65\u5438\u9644-\u6269\u6563-\u8f6c\u5316\u3002DFT\u8ba1\u7b97\u8868\u660e\uff0c\u5f15\u5165\u5f02\u8d28\u7ed3\u6784\u53ef\u4ee5\u6539\u53d8\u7535\u5b50\u7ed3\u6784\uff0c\u4f7f\u5176\u53cd\u952e\u8f68\u9053\u88ab\u91d1\u5c5e\u8f68\u9053\u5360\u636e\uff0c\u4ece\u800c\u63d0\u9ad8CTVHs\u7684\u5438\u9644\u80fd\u529b\u3002\u7535\u5316\u5b66\u6d4b\u8bd5\u63ed\u793a\u4e86\u5f02\u8d28\u7ed3\u6784\u7684\u6709\u6548\u8c03\u8282\u548c\u5229\u7528\u4ee5\u53ca\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002CTVHs\/S\u7535\u6781\u57280.5 C\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af1400\u6b21\uff0c\u63d0\u4f9b\u6bcf\u5faa\u73af0.029%\u7684\u7f13\u6162\u5bb9\u91cf\u8870\u51cf\u7387\u3002\u5f02\u8d28\u7ed3\u6784\u7684\u5f15\u5165\u4fc3\u8fdb\u4e86LiPSs\u7684\u8f6c\u5316\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u4ece\u800c\u6291\u5236\u4e86\u7a7f\u68ad\u6548\u5e94\uff0c\u8fd9\u4e3aLi-S\u7535\u6c60\u7684\u7ed3\u6784\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u7b56\u7565\u548c\u89c1\u89e3\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cA cocklebur-like sulfur host with the TiO<sub>2<\/sub>-VO<sub>x<\/sub> heterostructure efficiently implementing one-step adsorption-diffusion-conversion towards long-life Li\u2013S batteries\u201d\u53d1\u8868\u5728Composites Part B-Engineering\uff08IF=11.322\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-244208\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/1-17.png\" alt=\"\" width=\"692\" height=\"290\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/1-17.png 692w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/1-17-300x126.png 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/p>\n<p>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-244209\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72472-8.png\" alt=\"\" width=\"1232\" height=\"272\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72472-8.png 1232w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72472-8-300x66.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72472-8-768x170.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72472-8-1024x226.png 1024w\" sizes=\"(max-width: 1232px) 100vw, 1232px\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-244210\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72473-1.jpg\" alt=\"\" width=\"1268\" height=\"505\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72473-1.jpg 1268w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72473-1-300x119.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72473-1-768x306.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72473-1-1024x408.jpg 1024w\" sizes=\"(max-width: 1268px) 100vw, 1268px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1<\/strong><strong>\u3001<\/strong><strong>CTVHs<\/strong><strong>\u7684\u5236\u5907\u5de5\u827a\u548c\u8bbe\u8ba1\u539f\u7406<\/strong><\/p>\n<p>\uff08a\uff09CTVHs\u6750\u6599\u7684\u5408\u6210\u793a\u610f\u56fe\uff0c\uff08b\u3001c\uff09CTVHs\u548c\uff08d\uff09CTVHs\/S\u7684SEM\u56fe\uff0c\uff08e\u3001f\uff09CTVHs\u7684TEM\u548cHRTEM\u56fe\uff0c\uff08g-j\uff09CTVHs\u7684EDS\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-244211\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72474-7.png\" alt=\"\" width=\"1818\" height=\"995\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72474-7.png 1818w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72474-7-300x164.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72474-7-768x420.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72474-7-1024x560.png 1024w\" sizes=\"(max-width: 1818px) 100vw, 1818px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2<\/strong><strong>\u3001<\/strong><strong>CTVHs<\/strong><strong>\u7684\u5316\u5b66\u8868\u5f81<\/strong><\/p>\n<p>\uff08a\uff09CTVHs\u7684XRD\u56fe\uff0c\uff08b\uff09CTVHs\u548cCTVHs\/S\u7684\u62c9\u66fc\u5149\u8c31\u56fe\uff0c\uff08c\uff09\u786b\u8d1f\u8f7d\u540eCTVHs\u7684TG\u5206\u6790\uff0c\uff08d\u3001e\uff09CTVHs\u7684V<sub>2p<\/sub>\u548cTi<sub>2p<\/sub>\u7684XPS\u5149\u8c31\u56fe\uff0c\uff08f\uff09CTVHs\/S\u3001TiO<sub>2<\/sub>\u548cV<sub>2<\/sub>O<sub>5<\/sub>\u7684N<sub>2<\/sub>\u5438\u9644\u8131\u9644\u66f2\u7ebf\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-244212\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72475-7.png\" alt=\"\" width=\"1240\" height=\"507\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72475-7.png 1240w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72475-7-300x123.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72475-7-768x314.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72475-7-1024x419.png 1024w\" sizes=\"(max-width: 1240px) 100vw, 1240px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-244214\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72476-6.png\" alt=\"\" width=\"1215\" height=\"695\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72476-6.png 1215w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72476-6-300x172.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72476-6-768x439.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72476-6-1024x586.png 1024w\" sizes=\"(max-width: 1215px) 100vw, 1215px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3<\/strong><strong>\u3001\u50ac\u5316\u6027\u80fd\u53ca\u5bf9\u79f0\u7535\u6c60\u6d4b\u8bd5<\/strong><\/p>\n<p>\uff08a\uff09\u7d2b\u5916-\u53ef\u89c1\u5149\u8c31\u548c\u4e0d\u540c\u6837\u54c1\u5bf9Li<sub>2<\/sub>S<sub>6<\/sub>\u6eb6\u6db2\u7684\u5438\u9644\u7167\u7247\uff0c\uff08b\uff09\u5bf9\u79f0\u7535\u6c60\u572810 mV s<sup>-1<\/sup>\u4e0b\u7684CV\u66f2\u7ebf\uff0c\uff08c-e\uff09Li<sub>2<\/sub>S\u6210\u6838\u6d4b\u8bd5\uff0c\uff08f\uff09Li-S\u7535\u6c60\u57280.1 mV S<sup>-1<\/sup>\u4e0b\u7684CV\u66f2\u7ebf\uff0c\uff08g\uff09Tafel\u66f2\u7ebf\uff0c\uff08h\uff09\u5faa\u73af\u524d\u548c600\u6b21\u5faa\u73af\u540e\u9634\u6781\u7684\u963b\u6297\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-244215\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72477-5.png\" alt=\"\" width=\"1283\" height=\"1038\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72477-5.png 1283w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72477-5-300x243.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72477-5-768x621.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/11\/\u56fe\u72477-5-1024x828.png 1024w\" sizes=\"(max-width: 1283px) 100vw, 1283px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56fe<\/strong><strong>4<\/strong><strong>\u3001<\/strong><strong>CTVHs\/S<\/strong><strong>\u3001<\/strong><strong>TiO<\/strong><strong><sub>2<\/sub>\/S<\/strong><strong>\u548c<\/strong><strong>V<sub>2<\/sub>O<sub>5<\/sub>\/S<\/strong><strong>\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n<p>\uff08a\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u500d\u7387\u6027\u80fd\u56fe\uff0c\uff08b\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff0c\uff08c\uff09\u57280.2 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of Power Sources\u7b49\u671f\u520a\u53d1\u8868\u5b66\u672f\u8bba\u658730\u4f59\u7bc7\uff0c\u5176\u4e2d ESI \u9ad8\u88ab\u5f15\u8bba\u6587 3 \u7bc7\u3002\u7533\u8bf7\u6216\u6388\u6743\u56fd\u5bb6\u53d1\u660e\u4e13\u522920\u4f59\u9879\uff0c\u5e76\u83b7\u8fbd\u5b81\u7701\u81ea\u7136\u79d1\u5b66\u5b66\u672f\u6210\u679c\u5956\u4e09\u7b49\u59561\u9879\uff0c\u9526\u5dde\u5e02\u81ea\u7136\u79d1\u5b66\u5b66\u672f\u6210\u679c\u5956\u4e00\u7b49\u59561\u9879\uff0c\u51fa\u7248\u5b66\u672f\u4e13\u84572\u90e8\u3002<\/p>\n<p><strong>\u738b\u5766<\/strong>\uff0c\u6e24\u6d77\u5927\u5b662019\u7ea7\u7855\u58eb\u7814\u7a76\u751f\uff0c\u73b0\u4e3a\u5317\u4eac\u7406\u5de5\u5927\u5b66\u5316\u5b66\u5de5\u7a0b\u4e0e\u6280\u672f\u4e13\u4e1a2022\u7ea7\u535a\u58eb\u7814\u7a76\u751f\u3002\u5728Composites Part B-Engineering\u7b49\u671f\u520a\u53d1\u8868SCI\u8bba\u65876\u7bc7\uff0c\u5176\u4e2dESI\u9ad8\u88ab\u5f15\u8bba\u65872\u7bc7\u3002\u7533\u8bf7\u53d1\u660e\u4e13\u52296\u9879\uff0c\u5176\u4e2d\u5df2\u6388\u67434\u9879\uff0c\u5305\u62ec1\u9879\u6fb3\u5927\u5229\u4e9a\u4e13\u5229\u3002\u4e3b\u6301\u7814\u7a76\u751f\u521b\u65b0\u57fa\u91d1\u9879\u76ee1\u9879\uff0c\u53c2\u4e0e\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\u9879\u76ee1\u9879\u53ca\u7701\u90e8\u7ea7\u9879\u76ee2\u9879\u3002<\/p>\n<p><strong>\u6587\u7ae0\u4fe1\u606f\uff1a<\/strong>A cocklebur-like sulfur host with the TiO<sub>2<\/sub>-VO<sub>x<\/sub> heterostructure efficiently implementing one-step adsorption-diffusion-conversion towards long-life Li\u2013S batteries, <em>Composites Part B-Engineering<\/em>, 2023:249.110410.<\/p>\n<p>\u94fe\u63a5\uff1ahttps:\/\/authors.elsevier.com\/c\/1g5vv4rCEkkd0N\uff082023\u5e741\u67086\u65e5\u4e4b\u524d\u901a\u8fc7\u6b64\u94fe\u63a5\u53ef\u514d\u8d39\u4e0b\u8f7d\u5168\u6587\uff0c\u65e0\u9700\u6ce8\u518c\uff09<\/p>\n<p>\u4f9b\u7a3f\u4eba\uff1a\u738b\u5766<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 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