{"id":243351,"date":"2022-10-18T06:08:17","date_gmt":"2022-10-17T22:08:17","guid":{"rendered":"\/\/m.iemloyee.com\/?p=243351"},"modified":"2022-10-17T21:08:29","modified_gmt":"2022-10-17T13:08:29","slug":"nature-energy-%e5%8d%97%e4%ba%ac%e9%82%ae%e7%94%b5%e5%a4%a7%e5%ad%a6%e8%be%9b%e9%a2%a2%e5%9b%a2%e9%98%9f%e9%93%9c%e9%94%8c%e9%94%a1%e7%a1%ab%e8%96%84%e8%86%9c%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=243351","title":{"rendered":"Nature Energy\/\u5357\u4eac\u90ae\u7535\u5927\u5b66\u8f9b\u98a2\u56e2\u961f\u94dc\u950c\u9521\u786b\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60\u7a81\u7834\u6027\u8fdb\u5c55\uff1a\u7535\u6c60\u6548\u738713%\u521b\u65b0\u4e16\u754c\u8bb0\u5f55"},"content":{"rendered":"<p style=\"text-align: center;\"><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u950c\u9ec4\u9521\u77ff\uff08Kesterite\uff09\u7ed3\u6784\u7684\u94dc\u950c\u9521\u786b\u7852\uff08Cu<sub>2<\/sub>ZnSn(S,Se)<sub>4<\/sub>\uff0cCZTSSe\uff09\u534a\u5bfc\u4f53\u6750\u6599\u7531\u4e8e\u7ec4\u6210\u5143\u7d20\u6bd2\u6027\u4f4e\uff0c\u539f\u6599\u5730\u7403\u50a8\u91cf\u5927\uff0c\u53ef\u4ee5\u770b\u4f5c\u7531\u9ec4\u94dc\u77ff\u7ed3\u6784\u7684\u94dc\u94df\u9553\u7852\uff08Cu(In,Ga)Se<sub>2<\/sub>\uff0cCIGS\uff09\u7ecf\u5143\u7d20\u53d6\u4ee3\uff08Zn<sup>2+<\/sup>+Sn<sup>4+<\/sup> \u53d6\u4ee3In<sup>3+<\/sup>\/G<sup>3+<\/sup>\uff09\u884d\u751f\u800c\u6765\uff0c\u56e0\u6b64\u5177\u5907\u4e0eCIGS\u534a\u5bfc\u4f53\u76f8\u4f3c\u7684\u6676\u4f53\u7ed3\u6784\u548c\u5149\u7535\u5b66\u7279\u6027\uff0c\u662f\u4e00\u79cd\u5177\u6709\u5de8\u5927\u6f5c\u529b\u7684\u65b0\u578b\u7eff\u8272\u4f4e\u6210\u672c\u5149\u4f0f\u6750\u6599\u3002\u7136\u800c\uff0c\u81ea2013\u5e74\u4ee5\u6765\uff0cCZTSSe\u592a\u9633\u80fd\u7535\u6c60\u8bb0\u5f55\u8f6c\u6362\u6548\u7387\u957f\u671f\u505c\u6ede\u572812.6%\uff0c\u8fdc\u8fdc\u4f4e\u4e8eCIGS\u592a\u9633\u80fd\u7535\u6c60\u768423.35%\u3002\u9650\u5236CZTSSe\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u7684\u5173\u952e\u95ee\u9898\u662f\u5de8\u5927\u7684\u5f00\u8def\u7535\u538b\u635f\u5931\uff0cCZTSSe\u7684\u7535\u6c60\u7ed3\u6784\u4ee5p-\u578bCZTSSe\u5438\u6536\u5c42\u4e0en-\u578bCdS\u6784\u5efa\u5f02\u8d28\u7ed3\uff0c\u4f46\u4e0eCIGS\u76f8\u6bd4\uff0cCZTSSe\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd\u4e25\u91cd\u53d7\u5236\u4e8e\u7f3a\u9677\u5bfc\u81f4\u7684\u5f02\u8d28\u7ed3\u754c\u9762\u590d\u5408\uff0c\u7136\u800c\u76ee\u524d\u5bf9\u5f02\u8d28\u7ed3\u754c\u9762\u7f3a\u9677\u7684\u5f62\u6210\u673a\u5236\u5e76\u4e0d\u6e05\u695a\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u5357\u4eac\u90ae\u7535\u5927\u5b66\u6709\u673a\u7535\u5b50\u4e0e\u4fe1\u606f\u663e\u793a\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u8f9b\u98a2\u6559\u6388\u56e2\u961f\u3001\u590d\u65e6\u5927\u5b66\u8ba1\u7b97\u7269\u7406\u79d1\u5b66\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u9648\u65f6\u53cb\u56e2\u961f\u3001\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\u53ef\u518d\u751f\u80fd\u6e90\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5b5f\u5e86\u6ce2\u56e2\u961f\u5728\u94dc\u950c\u9521\u786b\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60\u9886\u57df\u7814\u7a76\u53d6\u5f97\u7a81\u7834\u6027\u8fdb\u5c55\uff0c\u901a\u8fc7\u4f4e\u6e29\u70ed\u5904\u7406\u5b9e\u73b0\u4e86\u5916\u5ef6\u5f02\u8d28\u7ed3\u754c\u9762\uff0c\u663e\u8457\u51cf\u4f4e\u4e86\u5f02\u8d28\u754c\u9762\u590d\u5408\uff0c\u63d0\u9ad8\u4e86\u7535\u6c60\u5f00\u8def\u7535\u538b\u548c\u586b\u5145\u56e0\u5b50\uff0c\u7535\u6c60\u6548\u7387\u7ecf\u7f8e\u56fd\u56fd\u5bb6\u53ef\u518d\u751f\u80fd\u6e90\u5b9e\u9a8c\u5ba4\uff08NREL\uff09\u8ba4\u8bc1\u8fbe\u523013.0%\uff0c\u521b\u9020\u4e86\u94dc\u950c\u9521\u786b\u7535\u6c60\u65b0\u7684\u4e16\u754c\u7eaa\u5f55\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cElemental de-mixing-induced epitaxial kesterite\/CdS interface enabling 13%-efficiency kesterite solar cells\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature Energy\u671f\u520a\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-243352 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/1665475839125.png\" alt=\"\" width=\"1203\" height=\"619\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/1665475839125.png 1203w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/1665475839125-300x154.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/1665475839125-768x395.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/1665475839125-1024x527.png 1024w\" sizes=\"(max-width: 1203px) 100vw, 1203px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>\u901a\u8fc7\u7cfb\u7edf\u7814\u7a76\u94dc\u950c\u9521\u786b\u7535\u6c60\u5f02\u8d28\u7ed3\u754c\u9762\u7684\u6784\u5efa\u8fc7\u7a0b\uff0c\u9996\u6b21\u63ed\u793a\u4e86\u94dc\u950c\u9521\u786b\u5f02\u8d28\u7ed3\u754c\u9762\u7f3a\u9677\u5f62\u6210\u53ca\u4f4e\u6e29\u52a0\u70ed\u5b9e\u73b0\u5916\u5ef6\u578b\u5f02\u8d28\u7ed3\u754c\u9762\u7684\u673a\u5236\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-243353 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/1-11.png\" alt=\"\" width=\"645\" height=\"846\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/1-11.png 645w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/1-11-229x300.png 229w\" sizes=\"(max-width: 645px) 100vw, 645px\" \/><\/p>\n<p>\u56fe\u4e00\uff1a\u94dc\u950c\u9521\u786b\u7535\u6c60\u5236\u5907\u8fc7\u7a0b\u53ca\u4f4e\u6e29\u5f02\u8d28\u7ed3\u70ed\u5904\u7406\u5bf9\u7535\u6c60\u5149\u4f0f\u6027\u80fd\u7684\u5f71\u54cd\u3002\u00a9 2022 Springer Nature<\/p>\n<p>a\uff0cACZTSSe\u592a\u9633\u80fd\u7535\u6c60\u5236\u9020\u5de5\u827a\u7684\u793a\u610f\u56fe\u3002\u4ece\u5de6\u5230\u53f3\uff1a\u524d\u4f53\u6eb6\u6db2\u7ecf\u65cb\u6d82\u5236\u5907\u524d\u4f53\u819c (ACZTS)\uff0c ACZTS\u901a\u8fc7\u7852\u5316\u5230\u5438\u6536\u819c(ACZTSSe)\uff0c\u901a\u8fc7CBD\u6c89\u79efCdS\u7f13\u51b2\u5c42\uff0c\u7136\u540e\u5728\u70ed\u677f\u4e0a\u8fdb\u884c\u5f02\u8d28\u7ed3\u70ed\u5904\u7406\uff0c\u901a\u8fc7\u6e85\u5c04\u6c89\u79ef\u7a97\u53e3\u5c42 (i-ZnO\u548cITO\uff09\u3002 b\uff0c\u5668\u4ef6\u7684\u6a2a\u622a\u9762 SEM \u56fe\u50cf\u3002\u5668\u4ef6\u7ed3\u6784\u81ea\u4e0b\u800c\u4e0a\u4e3a\u94a0\u9499\u73bb\u7483\uff08SLG\uff09\/Mo\/MoSe<sub>2<\/sub>\/ACZTSSe\/CdS\/i-ZnO\/ITO\u3002c\uff0c\u672a\u7ecf\uff08Ref\uff09\u548c\u7ecf\u8fc7\u5f02\u8d28\u7ed3\u70ed\u5904\u7406\uff08JHT\uff09\u7684ACZTSSe\u592a\u9633\u80fd\u7535\u6c60\u7684J-V\u66f2\u7ebf\u3002 d\uff0cRef\u548cJHT\u592a\u9633\u80fd\u7535\u6c60\u7684\u5668\u4ef6\u53c2\u6570\u7edf\u8ba1\u7bb1\u7ebf\u56fe\u3002\u7bb1\u7ebf\u56fe\u8868\u793a\u4e2d\u4f4d\u6570\uff08\u4e2d\u5fc3\u7ebf\uff09\u3001\u5e73\u5747\u503c\uff08\u70b9\uff09\u3001\u7b2c 25 \u4f4d\uff08\u6846\u7684\u5e95\u8fb9\uff09\u3001\u7b2c 75 \u4f4d\uff08\u6846\u7684\u9876\u8fb9\uff09\u3001\u7b2c 95 \u4f4d\uff08\u4e0a\u987b\u7ebf\uff09\u548c\u7b2c 5 \u4f4d\uff08\u4e0b\u987b\u7ebf\uff09\u767e\u5206\u4f4d\u6570\u3002\u6bcf\u7ec4\u7684\u6837\u672c\u91cf\u4e3a 20\u3002 e,f\uff0cNREL\u8ba4\u8bc1\u7684 12.96% \u6548\u7387 ACZTSSe \u592a\u9633\u80fd\u7535\u6c60\u7684 J-V (e) \u548c EQE (f) \u66f2\u7ebf\u3002 f\u4e2d\u7684\u6a59\u8272\u66f2\u7ebf\u662f\u6765\u81eaEQE\u7684\u79ef\u5206\u7535\u6d41 J<sub>SC<\/sub>\uff08J<sub>integrated<\/sub>\uff09\u3002 ACZTSSe \u7684\u5e26\u9699 (E<sub>g<\/sub>) \u7531 EQE \u7684\u62d0\u70b9\uff08\u865a\u7ebf\uff09\u4f30\u8ba1\uff0c\u8be5\u62d0\u70b9\u7531 EQE\u5bf9\u6ce2\u957f (\u03bb) \u7684\u4e00\u9636\u5bfc\u6570\uff08\u7d2b\u8272\u66f2\u7ebf\uff09\u786e\u5b9a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-243354 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/2-11.png\" alt=\"\" width=\"591\" height=\"825\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/2-11.png 591w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/2-11-215x300.png 215w\" sizes=\"(max-width: 591px) 100vw, 591px\" \/><\/p>\n<p>\u56fe\u4e8c\uff1aACZTSSe\u548cCISSe\u7535\u6c60\u8f7d\u6d41\u5b50\u590d\u5408\u7279\u6027\u5206\u6790\u3002\u00a9 2022 Springer Nature<\/p>\n<p>a\uff0cb\uff0cRef\u548cJHT\u592a\u9633\u80fd\u7535\u6c60\u7684TPV\uff08a\uff09\u548cTPC\uff08b\uff09\u66f2\u7ebf\u3002\u901a\u8fc7\u66f2\u7ebf\u7684\u5355\u6307\u6570\u62df\u5408\u8ba1\u7b97\u8870\u51cf\u5bff\u547d\uff08\u03c4<sub>TPV<\/sub> \u548c \u03c4<sub>TPC<\/sub>\uff09\u3002 c,d\uff0cRef \u548c JHT \u592a\u9633\u80fd\u7535\u6c60\u7684\u504f\u7f6e\u7535\u538b\u76f8\u5173 \u03b7<sub>ext<\/sub> (c) \u548c \u03b7<sub>C<\/sub> (d)\u3002 \u03b7<sub>C<\/sub> \u7531 \u03c4<sub>TPC<\/sub> \u548c \u03c4<sub>TPV<\/sub> \u5728\u504f\u7f6e\u7535\u538b\u4e0b\u4ece d \u4e2d\u7684\u7b49\u5f0f\u5f97\u51fa\u3002 e\uff0c\u4f7f\u7528 C-V\uff08\u5c01\u95ed\u6807\u8bb0\uff09\u548c DLCP\uff08\u5f00\u653e\u6807\u8bb0\uff09\u6d4b\u91cf\u7684 Ref\uff08\u84dd\u8272\uff09\u548c JHT\uff08\u6a59\u8272\uff09\u5668\u4ef6\u7684\u8f7d\u6d41\u5b50\u5bc6\u5ea6\u5206\u5e03\u3002\u53cc\u7bad\u5934\u7ebf\u8868\u793a\u754c\u9762\u9677\u9631\u5bc6\u5ea6\uff08NIT\uff09\u3002 X\u662f\u8017\u5c3d\u5bbd\u5ea6\u3002\u5e95\u90e8\u7684\u7bad\u5934\u6307\u5411\u8017\u5c3d\u5bbd\u5ea6 (X<sub>d<\/sub>)\uff0c\u5176\u4e2d\u65bd\u52a0\u7684\u7535\u538b\u4e3a0 V\u3002<em>f<\/em> \u662f\u7528\u4e8eC-V\u548cDLCP\u6d4b\u91cf\u7684\u8c03\u5236\u9891\u7387\u3002 \u03b5<sub>r<\/sub>\u662f\u5438\u6536\u4f53\u7684\u76f8\u5bf9\u4ecb\u7535\u5e38\u6570\u3002 f\uff0cV<sub>OC<\/sub>\u4e0e\u6e29\u5ea6 (V<sub>OC<\/sub>\u2013T)\u7684\u66f2\u7ebf\u56fe\u4ee5\u53caRef\uff08\u84dd\u8272\uff09\u548cJHT\uff08\u6a59\u8272\uff09\u5668\u4ef6\u7684\u91cd\u7ec4E<sub>a<\/sub>\u7684\u7ebf\u6027\u62df\u5408\u3002 g\uff0cRef\u548cJHT ACZTSSe\/CdS\u548cCISSe\/CdS\u8584\u819c\u7684\u62c9\u66fc\u5149\u8c31\u3002\u865a\u7ebf\u8868\u793a\u5316\u5408\u7269\u7684\u62c9\u66fc\u4f4d\u79fb\u3002 h\uff0cRef\u548cJHT CISSe \u5668\u4ef6\u7684E<sub>a<\/sub>\u7684 V<sub>OC<\/sub>-T\u56fe\u548c\u7ebf\u6027\u62df\u5408\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-243355 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/3-11.png\" alt=\"\" width=\"748\" height=\"697\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/3-11.png 748w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/3-11-300x280.png 300w\" sizes=\"(max-width: 748px) 100vw, 748px\" \/><\/p>\n<p>\u56fe\u4e09\uff1a\u4f4e\u6e29\u70ed\u5904\u7406\u524d\u540eACZTSSe\/CdS\u5f02\u8d28\u7ed3\u754c\u9762\u6027\u8d28\u5206\u6790\u3002\u00a9 2022 Springer Nature<\/p>\n<p>a\uff0cb\uff0cEDX\u5143\u7d20\u5206\u5e03\u548c Ref (a) \u548c JHT (b)\u9ad8\u5206\u8fa8\u6697\u573a\u900f\u5c04\u7535\u955c\u56fe\u50cf\u3002 a \u4e2d\u7684\u84dd\u8272\u65b9\u5757\u548c d \u4e2d\u7684\u6a59\u8272\u65b9\u5757\u8868\u793a\u6267\u884cEDX\u7ebf\u626b\u63cf\u7684\u4f4d\u7f6e\uff0c\u7bad\u5934\u6307\u793a\u626b\u63cf\u65b9\u5411\u3002 c\u3001d\uff0c\u5206\u522b\u5728a\u548c b\u4e2d\u7a81\u51fa\u663e\u793a\u7684\u533a\u57df\u5185\u6d4b\u91cf\u7684 Ref (c) \u548c JHT (d) 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Y., Zhu, Q., Li, B. et al. Elemental de-mixing-induced epitaxial kesterite\/CdS interface enabling 13%-efficiency kesterite solar cells. <em>Nat Energy<\/em> (2022). <a href=\"https:\/\/doi.org\/10.1038\/s41560-022-01132-4\">https:\/\/doi.org\/10.1038\/s41560-022-01132-4<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u950c\u9ec4\u9521\u77ff\uff08Kesterite\uff09\u7ed3\u6784\u7684\u94dc\u950c\u9521\u786b\u7852\uff08Cu2ZnSn(S,Se)4\uff0cCZTSSe\uff09\u534a\u5bfc\u4f53\u6750\u6599\u7531\u4e8e\u7ec4\u6210\u5143\u7d20\u6bd2\u6027\u4f4e\uff0c\u539f\u6599\u5730\u7403\u50a8\u91cf\u5927\uff0c\u53ef\u4ee5\u770b\u4f5c&#8230;<\/p>\n","protected":false},"author":39059,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[4950,78,4949],"class_list":["post-243351","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-nature-energy","tag-photovoltaic","tag-4949"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/243351"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/39059"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=243351"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/243351\/revisions"}],"predecessor-version":[{"id":243407,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/243351\/revisions\/243407"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=243351"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=243351"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=243351"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}