{"id":243094,"date":"2022-10-10T07:36:04","date_gmt":"2022-10-09T23:36:04","guid":{"rendered":"\/\/m.iemloyee.com\/?p=243094"},"modified":"2022-10-09T15:36:10","modified_gmt":"2022-10-09T07:36:10","slug":"%e6%b2%b3%e5%8c%97%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6%e5%bc%a0%e6%95%88%e6%b4%81%e7%a0%94%e7%a9%b6%e5%91%98%e5%9b%a2%e9%98%9f%ef%bc%9a%e5%90%ab%e5%8a%a8%e6%80%81%e4%ba%8c%e7%a1%ab%e9%94%ae%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=243094","title":{"rendered":"\u6cb3\u5317\u5de5\u4e1a\u5927\u5b66\u5f20\u6548\u6d01\u7814\u7a76\u5458\u56e2\u961f\uff1a\u542b\u52a8\u6001\u4e8c\u786b\u952e\u7684\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u6539\u6027\u9694\u819c\u6709\u6548\u6291\u5236\u9502\u786b\u7535\u6c60\u4e2d\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad"},"content":{"rendered":"<p>\u8fd1\u65e5\uff0c\u6cb3\u5317\u5de5\u4e1a\u5927\u5b66\u5f20\u6548\u6d01\u7814\u7a76\u5458\u56e2\u961f\u5728<em>ACS Sustainable Chemistry &amp; Engineering<\/em>\u4e0a\u53d1\u8868\u9898\u4e3a\u201c<em>Dynamic Disulfide Bonds Contained Covalent Organic Framework Modified Separator as Efficient Inhibit Polysulfide Shuttling in Li\u2212S Batteries<\/em>\u201d\u7684\u6587\u7ae0\u3002\u5408\u6210\u4e86\u5728\u78b3\u7eb3\u7c73\u7ba1\u8868\u9762\u539f\u4f4d\u751f\u957f\u7684\u4e8c\u786b\u952e\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08HUT9@CNT\uff09\u590d\u5408\u6750\u6599\uff0c\u7528\u4f5c\u9502\u786b\u7535\u6c60\u529f\u80fd\u9694\u819c\u7684\u6d82\u5c42\u3002\u901a\u8fc7\u9aa8\u67b6\u6750\u6599\u4e2d\u4e8c\u786b\u952e\u7684\u65ad\u88c2\u548c\u518d\u751f\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u6355\u83b7\u591a\u786b\u5316\u7269\uff08LiPS\uff09\u6291\u5236\u201c\u7a7f\u68ad\u6548\u5e94\u201d\uff0c\u5e76\u4fc3\u8fdbLiPSs\u8f6c\u5316\u7684\u52a8\u529b\u5b66\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-243095\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering370.png\" alt=\"\" width=\"556\" height=\"202\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering370.png 556w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering370-300x109.png 300w\" sizes=\"(max-width: 556px) 100vw, 556px\" \/><\/p>\n<p>\u7814\u7a76\u4eba\u5458\u4ee54\uff0c4-\u4e8c\u786b\u4ee3\u4e8c\u82ef\u80fa(2S-NH<sub>2<\/sub>)\u548c\u4e09\u919b\u57fa\u95f4\u82ef\u4e09\u915a(Tp)\u4e3a\u539f\u6599\u5408\u6210\u4e8c\u786b\u952e\u57fa\u5171\u4ef7\u6709\u673a\u6846\u67b6HUT9(\u56fe1)\u3002\u5e76\u4ee5\u539f\u6599\u8d28\u91cf\u5206\u6570\u768450%\u300125%\u3001<a href=\"mailto:12.5%\u63ba\u6742\u4e0d\u540c\u6bd4\u4f8b\u7684\u78b3\u7eb3\u7c73\u7ba1\u5408\u62102-HUT9@CNT\u30014-HUT9@CNT\u30018-HUT9@CNT\">12.5%\u63ba\u6742\u4e0d\u540c\u6bd4\u4f8b\u7684\u78b3\u7eb3\u7c73\u7ba1\u5408\u62102-HUT9@CNT\u30014-HUT9@CNT\u30018-HUT9@CNT<\/a>\u3002\u7ea2\u5916(\u56fe2a)\u548c\u56fa\u4f53\u6838\u78c1(\u56fe2b)\u8868\u660e\u4e86\u6750\u6599\u7684\u6210\u529f\u5236\u5907\u3002\u7136\u540e\uff0c\u7ed3\u5408\u5b9e\u9a8cXRD\u548c\u6a21\u62dfXRD(\u56fe2c\uff0cd)\u786e\u5b9a\u4e86HUT9\u5177\u6709AA\u5806\u79ef\u7ed3\u6784(\u56fe2e)\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-243096\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering646.png\" alt=\"\" width=\"554\" height=\"295\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering646.png 554w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering646-300x160.png 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p>\u56fe1:HUT9\u7684\u5236\u5907\u8fc7\u7a0b\u53caHUT9@CNT\u6539\u6027\u9694\u819c\u5728\u9502\u786b\u7535\u6c60\u4e2d\u7684\u5de5\u4f5c\u539f\u7406\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-243097\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering686.png\" alt=\"\" width=\"550\" height=\"264\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering686.png 550w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering686-300x144.png 300w\" sizes=\"(max-width: 550px) 100vw, 550px\" \/><\/p>\n<p>\u56fe2:(a) Tp\u30012S-NH<sub>2<\/sub>\u548cHUT9\u7684FT-IR\u5149\u8c31\uff1b(b) HUT9\u7684\u56fa\u4f53<sup>13<\/sup>C NMR\u8c31\uff1b(c-d) HUT9\u7684\u5b9e\u9a8c\u548c\u6a21\u62dfPXRD\u8c31\u56fe\uff1b(e-f) HUT9\u7684AA\u3001AB\u5806\u79ef\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-243098\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering783.png\" alt=\"\" width=\"550\" height=\"282\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering783.png 550w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering783-300x154.png 300w\" sizes=\"(max-width: 550px) 100vw, 550px\" \/><\/p>\n<p>\u56fe3:(a)\u6539\u6027\u9694\u819c\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u548c\u5e93\u4ed1\u6548\u7387\uff1b(b)\u4e0d\u540c\u500d\u7387\u4e0b2-HUT9@CNT\u7684\u7535\u6c60\u5145\u653e\u7535\u66f2\uff1b(c) 2-HUT9@CNT\u30014-HUT9@CNT\u3001HUT9\u548cCNT\u6539\u6027\u7535\u6c60\u57280.2 C\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1b(d) 2-HUT9@CNT\u30014-HUT9@CNT\u548cCNT\u6539\u6027\u7535\u6c60\u57281\u00a0C\u4e0b\u7684\u957f\u671f\u5faa\u73af\u6027\u80fd\uff1b(e) 2-HUT9@CNT\u7535\u6c60\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n<p>\u901a\u8fc7\u7b80\u5355\u9ad8\u6548\u7684\u7684\u6d82\u8986\u6cd5\u628a2-HUT9@CNT\u30014-HUT9@CNT\u3001HUT9\u6750\u6599\u6d82\u8986\u5230PP\u9694\u819c\u8868\u9762\uff0c\u5c06\u4e0d\u540c\u6539\u6027\u9694\u819c\u7ec4\u88c5\u5230\u7535\u6c60\u4e2d\u8fdb\u884c\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\uff0c\u4ee5\u63a2\u7a76\u6750\u6599\u5bf9LiPSs\u7684\u5438\u9644\u548c\u6355\u6349\u80fd\u529b\u3002\u500d\u7387(\u56fe3a)\u3001\u77ed\u5faa\u73af(\u56fe3c)\u3001\u957f\u5faa\u73af(\u56fe3d)\u90fd\u663e\u793a2-HUT9@CNT\u6539\u6027\u9694\u819c\u5bf9\u7a7f\u68ad\u6548\u5e94\u7684\u6291\u5236\u4f5c\u7528\u66f4\u660e\u663e\uff0c\u8fd9\u53ef\u80fd\u56e0\u4e3a2-HUT9@CNT\u5728\u78b3\u7eb3\u7c73\u7ba1\u8868\u9762\u5177\u6709\u6700\u591a\u7684\u4e8c\u786b\u548c\u7fb0\u57fa\u6d3b\u6027\u4f4d\u70b9\u3002\u7fb0\u57fa\u548c\u4e8c\u786b\u952e\u7684\u5316\u5b66\u5438\u9644\u540c\u65f6\u4fc3\u8fdb\u4e86\u591a\u786b\u5316\u7269\u7684\u8f6c\u5316\u8fc7\u7a0b\uff0c\u7f13\u89e3\u4e86\u52a8\u529b\u5b66\u7f13\u6162\u7684\u95ee\u9898\u3002\u56e0\u6b64\uff0c\u4f7f\u75282-HUT9@CNT\u6539\u6027\u9694\u819c\u7684\u7535\u6c60\u5177\u6709\u6700\u4f73\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-243099\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering1218.png\" alt=\"\" width=\"397\" height=\"318\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering1218.png 397w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering1218-300x240.png 300w\" sizes=\"(max-width: 397px) 100vw, 397px\" \/><\/p>\n<p>\u56fe4:(a) 2-HUT9@CNT\u30014-HUT9@CNT\u548cCNT\u9694\u819c\u6539\u6027\u7535\u6c60\u7684CV\u66f2\u7ebf\uff1b(b)\u626b\u63cf\u901f\u7387\u4e3a0.1 mV s<sup>\u2212<\/sup><sup>1<\/sup>\u65f6\uff0c2-HUT9@CNT\u30014-HUT9@CNT\u548cCNT\u9694\u819c\u6539\u6027\u7535\u6c60\u6c27\u5316\u8fc7\u7a0b\u7684LSV\u6d4b\u8bd5\uff1b(c) 2-HUT9@CNT\u30014-HUT9@CNT\u548cCNT\u9694\u819c\u6539\u6027\u7535\u6c60\u7684Tafel\u56fe\uff1b(d)\u4e0d\u540c\u5bf9\u79f0\u7535\u6c60\u7684CV\u66f2\u7ebf\u3002<\/p>\n<p>\u6b64\u5916\uff0c\u5229\u7528\u7ebf\u6027\u5faa\u73af\u4f0f\u5b89\u6cd5(LSV)\u8bc4\u4ef7\u4e862-HUT9@CNT\u30014-HUT9@CNT\u5bf9\u56fa\u6db2\u8f6c\u5316\u52a8\u529b\u5b66\u7684\u5f71\u54cd\u3002\u5982\u56fe4b\uff0c2-HUT9@CNT\u6539\u6027\u9694\u819c\u7535\u6c60\u7684\u521d\u59cb\u7535\u4f4d\u9ad8\u4e8e4-HUT9@CNT\u548cCNT\uff0c\u5e76\u4e14\u968f\u7740\u7535\u6d41\u5bc6\u5ea6\u7684\u589e\u52a0\uff0c2-HUT9@CNT\u5728\u964d\u4f4e\u8fc7\u7535\u4f4d\u65b9\u9762\u7684\u52a8\u529b\u5b66\u4f18\u52bf\u4ecd\u7136\u5b58\u5728\u3002\u5e76\u4e14\uff0c2-HUT9@CNT\u7684Tafel\u659c\u7387\u6700\u5c0f(\u56fe4c)\uff0c\u8fdb\u4e00\u6b65\u8bf4\u660e2-HUT9@CNT\u5bf9LiPSs\u7684\u6355\u83b7\u548c\u8f6c\u5316\u6548\u679c\u6700\u597d\u3002\u7528\u78b3\u5e03\u8d1f\u8f7d2-HUT9@CNT\u548c4-HUT9@CNT\u540e\u7ec4\u88c5\u6210\u5bf9\u79f0\u7535\u6c60\u8fdb\u884cCV\u6d4b\u8bd5\uff0c\u4ee5\u7814\u7a76\u4e0d\u540c\u6750\u6599\u5bf9LiPSs\u7684\u8f6c\u5316\u80fd\u529b(\u56fe4d)\u3002\u672a\u6dfb\u52a0Li<sub>2<\/sub>S<sub>6<\/sub>\u6eb6\u6db2\u7684\u7a7a\u767d\u78b3\u5e03\u5bf9\u79f0\u7535\u6c60\u7684CV\u66f2\u7ebf\u662f\u76f4\u7ebf\u7684\uff0c\u8bf4\u660e\u7535\u6d41\u54cd\u5e94\u6765\u81ea\u4e8eLi<sub>2<\/sub>S<sub>6<\/sub>\u7684\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u3002\u4e0eCNT\u7535\u6c60\u76f8\u6bd4\uff0c2-HUT9@CNT\u548c4-HUT9@CNT\u7535\u6c60\u5177\u6709\u66f4\u9ad8\u7684\u5cf0\u503c\u7535\u6d41\uff0c\u8bf4\u660e\u4e24\u79cd\u6750\u6599\u7684\u5f15\u5165\u53ef\u4ee5\u6539\u5584\u6eb6\u89e3\u7684LiPSs\u7684\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u3002\u540c\u65f6\uff0c2-HUT9@CNT\u7535\u6c60\u5177\u6709\u6700\u5c0f\u7684\u6781\u5316\u7535\u4f4d\uff0c\u8868\u660e\u5b83\u53ef\u4ee5\u964d\u4f4eLiPSs\u7684\u8f6c\u5316\u8fc7\u7535\u4f4d\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-243100\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering1817.png\" alt=\"\" width=\"461\" height=\"359\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering1817.png 461w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering1817-300x234.png 300w\" sizes=\"(max-width: 461px) 100vw, 461px\" \/><\/p>\n<p>\u56fe5:CNT (a)\u548cHUT9 (b)\u7684\u9759\u7535\u52bf\u548c\u5bf9\u5e94\u7684\u5206\u5b50\u6781\u6027\u6307\u6570;(c) CNT\u548cHUT9\u5438\u9644LiPSs\u7684\u7ed3\u5408\u80fd;(d) CNT\u548cHUT9\u886c\u5e95\u653e\u7535\u8fc7\u7a0b\u4e2dS8\u5230Li<sub>2<\/sub>S\u7684\u76f8\u5bf9\u81ea\u7531\u80fd\u3002<\/p>\n<p>\u9759\u7535\u52bf\u6709\u52a9\u4e8e\u89e3\u91caLiPSs\u5bf9CNT\u548cHUT9\u7684\u5438\u9644\u3002\u663e\u7136\uff0cHUT9\u4e2d\u7684\u6c27\u539f\u5b50(\u56fe5b)\u7684\u8d1f\u7535\u4f4d\u9ad8\u4e8eCNT\u4e2d\u7684\u78b3\u539f\u5b50(\u56fe5a)\uff0c\u8bf4\u660eHUT9\u5bf9LiPSs\u7684\u5438\u9644\u6027\u80fd\u66f4\u4f18\u8d8a\u3002\u6b64\u5916\uff0cHUT9\u5438\u9644LiPSs\u7684\u7ed3\u5408\u80fd(\u56fe5c)\u9ad8\u4e8eCNT\uff0c\u8bf4\u660eHUT9\u5bf9LiPSs\u5177\u6709\u66f4\u5f3a\u7684\u951a\u5b9a\u4f5c\u7528\uff0c\u6291\u5236\u4e86\u5145\u7535\u8fc7\u7a0b\u4e2d\u7684\u7a7f\u68ad\u6548\u5e94\u3002\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u4eceS<sub>8<\/sub>\u5230Li<sub>2<\/sub>S\u7684\u66f4\u5feb\u7684\u52a8\u529b\u5b66\u53ef\u4ee5\u5e26\u6765\u66f4\u9ad8\u7684\u786b\u5229\u7528\u7387\uff0c\u4ece\u800c\u63d0\u9ad8\u7535\u6c60\u7684\u6027\u80fd\uff0c\u5982\u7535\u6c60\u5bb9\u91cf\u3002\u5982\u56fe5d\u6240\u793a\uff0cHUT9\u886c\u5e95\u4e0aS<sub>8<\/sub>\u4e0eLi<sub>2<\/sub>S\u7684\u76f8\u5bf9\u81ea\u7531\u80fd\u5dee(-15.43 eV)\u5c0f\u4e8eCNT\u886c\u5e95\u4e0a\u7684\u76f8\u5bf9\u81ea\u7531\u80fd\u5dee(-14.76 eV)\uff0c\u8bf4\u660e\u4eceS<sub>8<\/sub>\u5230Li<sub>2<\/sub>S, HUT9\u5177\u6709\u66f4\u4f18\u5f02\u7684\u52a8\u529b\u5b66\u6027\u80fd\u3002\u603b\u4e4b\uff0cHUT9\u53ef\u4ee5\u9632\u6b62\u957f\u94fe\u591a\u786b\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\u7684\u6269\u6563\uff0c\u4fc3\u8fdb\u653e\u7535\u8fc7\u7a0b\u4e2d\u52a8\u529b\u5b66\u7531S<sub>8<\/sub>\u5411Li<sub>2<\/sub>S<sub>8<\/sub>\u8fc7\u6e21\uff0c\u4ece\u800c\u8fbe\u5230\u6291\u5236\u7a7f\u68ad\u6548\u5e94\uff0c\u63d0\u9ad8\u7535\u6c60\u6027\u80fd\u7684\u76ee\u7684\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-243101\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering2274.png\" alt=\"\" width=\"540\" height=\"377\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering2274.png 540w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/\u5f20\u6548\u6d01\u2014\u2014\u516c\u4f17\u53f7\u6295\u7a3f-Sustainable-ChemistryEngineering2274-300x209.png 300w\" sizes=\"(max-width: 540px) 100vw, 540px\" \/><\/p>\n<p>\u56fe6:\u5728298.15 K\u4e0b\uff0cPhSSPh-Li<sub>2<\/sub>S<sub>4<\/sub>\u3001PhSSPh-Li<sub>2<\/sub>S<sub>6<\/sub>\u548cPhSSPh-Li<sub>2<\/sub>S<sub>8<\/sub>\u5728200 ps\u5206\u5b50\u6a21\u62df\u8fc7\u7a0b\u4e2d\u7684\u5f84\u5411\u5206\u5e03\u51fd\u6570(a)\u548c\u5747\u65b9\u6839\u504f\u5dee(b);\u00a0\u5728298.15 K\u4e0b\u8fdb\u884c200 ps\u5206\u5b50\u6a21\u62df\u65f6\uff0cPhSSPh-Li<sub>2<\/sub>S<sub>4<\/sub>\u00a0(c) PhSSPh-Li<sub>2<\/sub>S<sub>6<\/sub>\u00a0(d)\u548cPhSSPh-Li<sub>2<\/sub>S<sub>8<\/sub>\u00a0(e)\u7684\u521d\u59cb\u548c\u6700\u7ec8\u7ed3\u6784\u3002(\u6ce8\u610f\uff0c\u7ebf\u5f0f\u7ed3\u6784\u548c\u7403\u68d2\u7ed3\u6784\u5206\u522b\u8868\u793a\u521d\u59cb\u7ed3\u6784\u548c\u6700\u7ec8\u7ed3\u6784)<\/p>\n<p>HUT9\u4e2d\u7684\u52a8\u6001S-S\u952e\u5728\u4e0eLiPSs\u7684\u53cd\u5e94\u4e2d\u4e5f\u8d77\u7740\u91cd\u8981\u4f5c\u7528\u3002\u4e3a\u4e86\u8bc1\u660e\u8fd9\u4e00\u70b9\uff0c\u5bf9\u4e09\u4e2a\u4f53\u7cfbPhSSPh-Li<sub>2<\/sub>S<sub>4<\/sub>\u3001PhSSPh-Li<sub>2<\/sub>S<sub>6<\/sub>\u548cPhSSPh-Li<sub>2<\/sub>S<sub>8<\/sub>\u8fdb\u884c\u4e86\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u3002\u6211\u4eec\u4f7f\u7528RDF\u548cRMSD\u5206\u6790\u7cfb\u7edf\u7684\u7279\u6027\u3002\u5982\u56fe6a\u6240\u793a\uff0c\u5728r = 2 \u00c5\u548cr = 4 \u00c5 ~ 6 \u00c5\u4e2d\u51fa\u73b0\u4e86\u4e24\u4e2a\u660e\u663e\u7684g(r)\u6700\u5927\u503c\uff0c\u5206\u522b\u8868\u793a\u5728PhS\u00b7\u7684S\u548cLiPSs\u7684S\u4e4b\u95f4\u5f62\u6210\u4e86\u65b0\u7684S-S\u952e(S-S\u952e\u7684\u952e\u957f\u8303\u56f4\u4e3a1.6 \u00c5 ~ 3 \u00c5)\uff0c\u591a\u786b\u5316\u7269\u88ab\u88c2\u89e3\u6210\u957f\u94fe\u786b(\u56fe6c-e)\u3002\u540c\u65f6\uff0c\u5728200ps\u7684\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u4e2d\uff0c\u4e09\u4e2a\u4f53\u7cfb(\u56fe6b)\u7684RMSD\u90fd\u5f88\u5927\uff0c\u8bf4\u660eS-S\u952e\u4e0eLiPSs\u4e4b\u95f4\u7684\u53cd\u5e94\u5df2\u7ecf\u4f7f\u4e09\u4e2a\u4f53\u7cfb\u7684\u7ed3\u6784\u53d1\u751f\u4e86\u5267\u70c8\u7684\u53d8\u5316\u3002\u5728200ps\u7684\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u4e2d\uff0c\u5c06\u6700\u7ec8\u7ed3\u6784\u4e0e\u521d\u59cb\u7ed3\u6784\u8fdb\u884c\u6bd4\u5bf9(\u56fe6c-e)\uff0c\u53ef\u4ee5\u6e05\u695a\u5730\u770b\u5230\u4e0a\u8ff0\u73b0\u8c61(\u65b0\u7684S-S\u952e\u7684\u5f62\u6210\u3001LiPSs\u7684\u7834\u88c2\u3001\u521d\u59cb\u6001\u4e0e\u6700\u7ec8\u6001\u4e4b\u95f4\u5de8\u5927\u7684\u7ed3\u6784\u5dee\u5f02)\uff0c\u8bf4\u660eS-S\u52a8\u6001\u952e\u4e0eLiPSs\u4e4b\u95f4\u76f4\u63a5\u5b58\u5728\u5f88\u5f3a\u7684\u6548\u5e94\u3002\u56e0\u6b64\uff0c\u672c\u7814\u7a76\u5229\u7528HUT9\u6539\u6027\u5546\u7528PP\u9694\u819c\u662f\u5f00\u53d1\u9ad8\u6027\u80fd\u9502\u786b\u7535\u6c60\u7684\u4e00\u6761\u5f88\u6709\u524d\u9014\u7684\u9014\u5f84\u3002<\/p>\n<p>\u539f\u6587\u8fde\u63a5\uff1ahttps:\/\/doi.org\/10.1021\/acssuschemeng.2c03498<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u8fd1\u65e5\uff0c\u6cb3\u5317\u5de5\u4e1a\u5927\u5b66\u5f20\u6548\u6d01\u7814\u7a76\u5458\u56e2\u961f\u5728ACS Sustainable Chemistry &amp; Engineering\u4e0a\u53d1\u8868\u9898\u4e3a\u201cDynamic Disul&#8230;<\/p>\n","protected":false},"author":35234,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-243094","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/243094"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/35234"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=243094"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/243094\/revisions"}],"predecessor-version":[{"id":243103,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/243094\/revisions\/243103"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=243094"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=243094"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=243094"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}