{"id":242985,"date":"2022-10-11T06:31:29","date_gmt":"2022-10-10T22:31:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=242985"},"modified":"2022-10-10T16:32:04","modified_gmt":"2022-10-10T08:32:04","slug":"cu-boulder%e5%bc%a0%e4%bc%9f%e6%95%99%e6%8e%88nat-chem-%ef%bc%9a%e5%ae%9e%e7%8e%b0%e7%83%ad%e5%9b%ba%e6%80%a7%e8%81%9a%e5%90%88%e7%89%a9%e5%8f%af%e5%9b%9e%e6%94%b6%ef%bc%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=242985","title":{"rendered":"CU-Boulder\u5f20\u4f1f\u6559\u6388Nat. Chem.\uff1a\u5b9e\u73b0\u70ed\u56fa\u6027\u805a\u5408\u7269\u53ef\u56de\u6536\uff01"},"content":{"rendered":"<p><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u5851\u6599\u5df2\u7ecf\u6210\u4e3a\u6211\u4eec\u65e5\u5e38\u751f\u6d3b\u4e2d\u4e0d\u53ef\u7f3a\u5c11\u7684\u4e00\u90e8\u5206\u3002\u968f\u7740\u5bf9\u5851\u6599\u7684\u9700\u6c42\u4e0d\u65ad\u589e\u52a0\uff0c\u5851\u6599\u5bf9\u73af\u5883\u7684\u8d1f\u9762\u5f71\u54cd\u4ee5\u53ca\u5851\u6599\u56de\u6536\u7684\u6311\u6218\uff0c\u90fd\u4f7f\u4eba\u4eec\u62c5\u5fc3\u5851\u6599\u5bf9\u73af\u5883\u548c\u4eba\u7c7b\u7684\u5065\u5eb7\u6709\u5bb3\u3002\u56e0\u6b64\uff0c\u805a\u5408\u7269\u7684\u5316\u5b66\u56de\u6536\u5bf9\u4e8e\u63d0\u9ad8\u5851\u6599\u5faa\u73af\u7ecf\u6d4e\u548c\u73af\u5883\u53ef\u6301\u7eed\u6027\u81f3\u5173\u91cd\u8981\u3002\u5316\u5b66\u56de\u6536\u663e\u793a\u51fa\u5de8\u5927\u7684\u6f5c\u529b\uff0c\u56e0\u4e3a\u5b83\u80fd\u591f\u5c06\u805a\u5408\u7269\u964d\u89e3\u4e3a\u5176\u524d\u4f53\uff0c\u53ef\u4ee5\u7528\u4f5c\u7c7b\u4f3c\u77f3\u6cb9\u57fa\u5316\u5b66\u54c1\u7684\u539f\u6599\u3002\u4f20\u7edf\u7684\u70ed\u56fa\u6027\u805a\u5408\u7269\u901a\u5e38\u88ab\u8ba4\u4e3a\u662f\u96be\u4ee5\u6216\u4e0d\u53ef\u80fd\u56de\u6536\u7684\u6c38\u4e45\u4ea4\u8054\u6750\u6599\u3002\u4e3a\u4e86\u89e3\u51b3\u5b83\u4eec\u7684\u53ef\u56de\u6536\u6027\u95ee\u9898\uff0c\u901a\u8fc7\u5c06\u53ef\u88c2\u89e3\u6216\u52a8\u6001\u5171\u4ef7\u952e\u5f15\u5165\u5355\u4f53\u6216\u4f5c\u4e3a\u4ea4\u8054\u5242\uff0c\u8bb8\u591a\u65b0\u7684\u70ed\u56fa\u6027\u805a\u5408\u7269\u88ab\u521b\u9020\u51fa\u6765\u3002\u5404\u79cd\u5316\u5b66\u53cd\u5e94\uff0c\u5982\u53ef\u9006\u4e9a\u80fa\u952e\u3001\u916f\u4ea4\u6362\u3001\u787c\u9178\u916f\u952e\u3001\u6c28\u57fa\u7532\u9178\u4e59\u916f\u952e\u548c\u7845\u919a\u952e\uff0c\u90fd\u88ab\u63a2\u7d22\u4e3a\u5236\u5907\u8fd9\u4e9b\u6750\u6599\u7684\u53ef\u88c2\u89e3\u5355\u5143\u3002\u7136\u800c\uff0c\u4e13\u6ce8\u4e8e\u5b9e\u73b0\u73b0\u6709\u70ed\u56fa\u6027\u7684\u53ef\u56de\u6536\u6027\u548c\u5ef6\u5c55\u6027\u4ee5\u5b9e\u73b0\u5faa\u73af\u7ecf\u6d4e\u7684\u7814\u7a76\u4ecd\u7136\u5f88\u5c11\u3002\u5c3d\u7ba1\u5f00\u53d1\u65b0\u805a\u5408\u7269\u4f5c\u4e3a\u201c\u7eff\u8272\u201d\u66ff\u4ee3\u54c1\u5f88\u91cd\u8981\uff0c\u4f46\u4ece\u4e0d\u540c\u89d2\u5ea6\u91cd\u65b0\u5ba1\u89c6\u4f20\u7edf\u6750\u6599\u4e5f\u5341\u5206\u5173\u952e\uff0c\u5e76\u4e14\u53ef\u4ee5\u6307\u5bfc\u53ef\u6301\u7eed\u6750\u6599\u5f00\u53d1\u3002<\/p>\n<p><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>2022\u5e749\u670826\u65e5\uff0c<strong>\u7f8e\u56fd\u79d1\u7f57\u62c9\u591a\u5927\u5b66\u535a\u5c14\u5fb7\u5206\u6821\u5f20\u4f1f\u6559\u6388\u56e2\u961f<\/strong>\u7814\u7a76\u8868\u660e\uff0c\u901a\u8fc7\u6fc0\u6d3b\u201c\u4f11\u7720\u201d\u5171\u4ef7\u952e\uff0c\u4f20\u7edf\u7684\u70ed\u56fa\u6027\u805a\u6c30\u9178\u916f\u53ef\u4ee5\u964d\u89e3\u4e3a\u539f\u59cb\u5355\u4f53\uff0c\u8fbe\u5230\u5faa\u73af\u4f7f\u7528\u7684\u76ee\u7684\u3002\u901a\u8fc7\u9006\u5408\u6210\u5206\u6790\uff0c\u4f5c\u8005\u5c06\u5408\u6210\u8def\u7ebf\u4ece\u901a\u8fc7\u6c30\u9178\u916f\u4e0d\u53ef\u9006\u4e09\u805a\u5f62\u6210\u4f20\u7edf\u7684C-N\u952e\u8f6c\u5411\u901a\u8fc7\u9187\u4eb2\u6838\u5242\u5bf9\u70f7\u6c27\u57fa\u53d6\u4ee3\u7684\u4e09\u55ea\u884d\u751f\u7269\u7684\u53ef\u9006\u4eb2\u6838\u82b3\u9999\u53d6\u4ee3\u5f62\u6210C-O\u952e\u3002\u65b0\u7684\u53ef\u9006\u5408\u6210\u8def\u7ebf\u4f7f\u4ee5\u524d\u65e0\u6cd5\u5408\u6210\u7684\u70f7\u57fa\u805a\u6c30\u9178\u916f\u70ed\u56fa\u6027\u805a\u5408\u7269\u5f97\u4ee5\u5408\u6210\uff0c\u8be5\u70ed\u56fa\u6027\u5851\u6599\u5177\u6709\u4f18\u5f02\u7684\u8584\u819c\u6027\u80fd\u3001\u4f18\u5f02\u7684\u8010\u5316\u5b66\u8150\u8680\u6027\u3001\u95ed\u73af\u53ef\u56de\u6536\u6027\u548c\u518d\u52a0\u5de5\u6027\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u201c\u770b\u4f3c\u4f11\u7720\u201d\u7684\u52a8\u6001\u952e\u53ef\u4ee5\u88ab\u6fc0\u6d3b\u5e76\u7528\u4e8e\u6784\u5efa\u5b8c\u5168\u53ef\u56de\u6536\u7684\u70ed\u56fa\u6027\u805a\u5408\u7269\uff0c\u5355\u4f53\u8303\u56f4\u66f4\u5e7f\uff0c\u53ef\u6301\u7eed\u6027\u66f4\u5f3a\u3002\u8be5\u8bba\u6587\u4ee5\u9898\u4e3a\u201c<strong>Recyclable and malleable thermosets enabled by activating dormant dynamic linkages\u201d<\/strong>\u53d1\u8868\u5728\u77e5\u540d\u671f\u520a<strong>Nature Chemistry<\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-242986\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/0.png\" alt=\"\" width=\"600\" height=\"273\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/0.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/0-300x137.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/p>\n<p>1\u3001\u901a\u8fc7\u9006\u5408\u6210\u5206\u6790\uff0c\u5c06\u6c30\u9178\u916f\u6811\u8102\u5408\u6210\u8def\u7ebf\u4ece\u4f20\u7edf\u7684\u901a\u8fc7\u6c30\u9178\u916f\u4e0d\u53ef\u9006\u5730\u4e09\u805a\u5316\uff0c\u8f6c\u53d8\u4e3a\u4e8c\u9187\u4eb2\u6838\u8bd5\u5242\u901a\u8fc7\u53ef\u9006\u4eb2\u6838\u82b3\u9999\u65cf\u53d6\u4ee3\u53cd\u5e94\u4e0e\u70f7\u6c27\u57fa\u53d6\u4ee3\u4e09\u55ea\u884d\u751f\u7269\u805a\u5408\u3002<\/p>\n<p>2\u3001\u5f97\u5230\u7684\u70ed\u56fa\u6027\u805a\u5408\u7269\u5177\u6709\u4f18\u5f02\u7684\u8584\u819c\u6027\u80fd\u3001\u4f18\u5f02\u7684\u8010\u5316\u5b66\u8150\u8680\u6027\u3001\u95ed\u73af\u53ef\u56de\u6536\u6027\u548c\u518d\u52a0\u5de5\u6027\u3002<\/p>\n<p><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><strong>\u56fe\u4e00\u3001\u805a\u5408\u7269\u5408\u6210\u793a\u610f\u56fe<\/strong><strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-242987\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/1-1.png\" alt=\"\" width=\"600\" height=\"192\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/1-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/1-1-300x96.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u53ef\u4ee5\u901a\u8fc7\u5364\u4ee3\u82b3\u57fa\u548c\u672b\u7aef\u7094\u70c3\uff08\u84dd\u8272\uff09\u4e4b\u95f4\u7684\u4ea4\u53c9\u5076\u8054\u6216\u7094\u70c3\u590d\u5206\u89e3\u805a\u5408\uff08\u7ea2\u8272\uff09\u6765\u5236\u5907PPE\u3002<\/p>\n<p>\uff08b\uff09PCNs\u53ef\u4ee5\u901a\u8fc7\u6c30\u9178\u916f\uff08\u84dd\u8272\uff09\u7684[2\u2009+\u20092+\u20092]\u73af\u4e09\u805a\u53cd\u5e94\u6216\u70f7\u6c27\u57fa\u4e09\u55ea\u4e0e\u9187\uff08\u7ea2\u8272\uff09\u4e4b\u95f4\u7684\u52a8\u6001S<sub>N<\/sub>Ar\u53cd\u5e94\u5236\u5907\u3002<\/p>\n<p><strong>\u56fe\u4e8c\u3001\u6c30\u9178\u916f\u4ea4\u6362\u4e2d\u7684<\/strong>S<sub>N<\/sub>Ar<strong>\u53cd\u5e94<\/strong><strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-242988\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/2-1.png\" alt=\"\" width=\"600\" height=\"725\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/2-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/2-1-248x300.png 248w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u5f53\u52a0\u51656 mol%\u7684TBD\u65f6\uff0cTETA\u4e0e\u7532\u9187\u53d1\u751f\u4ea4\u6362\u53cd\u5e94\uff0c\u5e76\u572860 \u2103\u4e0b40\u5c0f\u65f6\u5185\u8fbe\u5230\u5e73\u8861\u3002<\/p>\n<p>\uff08b\uff09\u901a\u8fc7\u7ed8\u5236TETA\u7684\u76f8\u5bf9\u6d53\u5ea6\u4e0e\u65f6\u95f4\u7684\u5173\u7cfb\uff0c\u83b7\u5f97\u4e86\u4e0d\u540c\u6e29\u5ea6\u4e0bS<sub>N<\/sub>Ar\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u66f2\u7ebf\u3002<\/p>\n<p>\uff08c\uff09\u5c0f\u5206\u5b50\u6a21\u578b\u53cd\u5e94\u5b9e\u9a8c\u901f\u7387\u5e38\u6570\uff08<em>k<sub>exp<\/sub><\/em>\uff09\u548c\u6e29\u5ea6\uff08T\uff09\u7684Arrhenius\u56fe\u53ca\u5176\u7ebf\u6027\u62df\u5408\u3002\u8ba1\u7b97\u5f97\u5230\u7684\u6d3b\u5316\u80fd\u4e3a62.5 kJ\/mol\u3002<\/p>\n<p><strong>\u56fe\u4e09\u3001\u805a\u6c30\u9178\u916f\uff08<\/strong><strong>PCNs<\/strong><strong>\uff09\u7684\u5236\u5907\u53ca\u8868\u5f81<\/strong><strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-242989\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/3-1.png\" alt=\"\" width=\"600\" height=\"481\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/3-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/3-1-300x241.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09TETA\u5355\u4f53\u65e2\u53ef\u4ee5\u901a\u8fc7\u5e38\u89c4\u4e09\u805a\u5316\u5236\u5907\u7684\u65e7\u82b3\u57faPCN\u89e3\u805a\u5f97\u5230\uff0c\u4e5f\u53ef\u4ee5\u7531\u5e02\u552e\u4e09\u805a\u6c2f\u6c30\u5408\u6210\u3002<\/p>\n<p>\uff08b\uff09PCNs\u7684\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\u3002<\/p>\n<p>\uff08c\uff09\u901a\u8fc7PCNs\u7684\u52a8\u6001\u529b\u5b66\u5206\u6790\u83b7\u5f97\u7684\u635f\u8017\u6bd4\u2014\u6e29\u5ea6\u66f2\u7ebf\u3002<\/p>\n<p>\uff08d\uff09PCNs\u7684\u51dd\u80f6\u5206\u7387\u6d4b\u8bd5\u3002<\/p>\n<p>\uff08e\uff09PCN-A6\u5728\u4e0d\u540c\u6eb6\u6db2\u5904\u740648 h\u7684FTIR\u5149\u8c31\u5bf9\u6bd4\u3002<\/p>\n<p>\uff08f\uff09PCN-A6\u7684\u900f\u660e\u819c\u53ef\u4ee5\u4f5c\u4e3a\u4e00\u79cd\u8010\u5316\u5b66\u8150\u8680\u7684\u8584\u819c\u3002<\/p>\n<p><strong>\u56fe\u56db\u3001<\/strong><strong>PCNs<\/strong><strong>\u7684\u5316\u5b66\u56de\u6536<\/strong><strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-242990\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/4-1.png\" alt=\"\" width=\"600\" height=\"498\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/4-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/4-1-300x249.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09PCNs\u7684\u95ed\u73af\u56de\u6536\u8fc7\u7a0b\u3002<\/p>\n<p>\uff08b\uff09\u7167\u7247\u663e\u793a\u4ece\u542b\u6709\u9ad8\u5bc6\u5ea6\u805a\u4e59\u70ef\u3001\u805a\u4e19\u70ef\u548c\u805a\u82ef\u4e59\u70ef\u7684\u5851\u6599\u5e9f\u7269\u4e2d\u9009\u62e9\u6027\u56de\u6536PCN-A6\u7684\u8fc7\u7a0b\u3002<\/p>\n<p>\uff08c\uff09\u56de\u6536\u4e0e\u65b0\u5408\u6210TETA\u7684<sup>1<\/sup>H NMR\u5bf9\u6bd4\u3002<\/p>\n<p>\uff08d\uff09\u539f\u59cbPCNs\u548c\u56de\u6536PCNs\u7684\u529b\u5b66\u6027\u80fd\u5bf9\u6bd4\u3002<\/p>\n<p>\uff08e\uff09\u56de\u6536\u7684PCNs\u8868\u73b0\u51fa\u4e0e\u539f\u59cbPCNs\u51e0\u4e4e\u76f8\u540c\u7684\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u3002<\/p>\n<p><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u7efc\u8ff0\u6240\u8ff0\uff0c\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u9006\u5408\u6210\u5206\u6790\uff0c\u5c06\u4e00\u79cd\u65b0\u7684\u5316\u5b66\u65b9\u6cd5\uff08\u52a8\u6001S<sub>N<\/sub>Ar\uff09\u5f15\u5165\u5230\u4f20\u7edf\u7684\u70ed\u56fa\u6027\u805a\u6c30\u8132\u9178\u916f\u5408\u6210\u4e2d\uff0c\u4ece\u800c\u5f00\u53d1\u51fa\u4e00\u7c7b\u5b8c\u5168\u53ef\u56de\u6536\u7684PCNs\u3002\u8fd9\u79cd\u5177\u6709\u5ec9\u4ef7\u53ef\u8c03\u5355\u4f53\u3001\u9ad8\u5316\u5b66\u8010\u6027\u548c\u95ed\u73af\u53ef\u56de\u6536\u6027\u7684\u70f7\u57fa\u805a\u6c30\u9178\u916f\u53ef\u4ee5\u5728\u5851\u6599\u548c\u76f8\u5173\u884c\u4e1a\u4e2d\u6709\u5f88\u5927\u7684\u5e94\u7528\uff0c\u4e5f\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u73af\u5883\u53ef\u6301\u7eed\u6027\u3002\u7814\u7a76\u4eba\u5458\u8ba4\u4e3a\uff0c\u9006\u5408\u6210\u5206\u6790\u4f5c\u4e3a\u6709\u673a\u5408\u6210\u4e2d\u7684\u4e00\u79cd\u6709\u6548\u548c\u5e38\u89c4\u505a\u6cd5\uff0c\u4e5f\u53ef\u4ee5\u542f\u53d1\u73b0\u6709\u6216\u65b0\u578b\u805a\u5408\u7269\u6750\u6599\u7684\u8bbe\u8ba1\u548c\u5408\u6210\uff0c\u4ee5\u63ed\u793a\u524d\u6240\u672a\u6709\u7684\u7279\u5f81\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41557-022-01046-4\" target=\"_blank\" rel=\"noopener\">Recyclable and malleable thermosets enabled by activating dormant dynamic linkages<\/a> (<em>Nat. Chem. <\/em><strong>2022<\/strong>, DOI: 10.1038\/s41557-022-01046-4)<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56e2\u961f\u7b80\u4ecb\uff1a<\/strong><\/p>\n<p>\u5f20\u4f1f\u8bfe\u9898\u7ec4\u957f\u671f\u4ece\u4e8b\u52a8\u6001\u5171\u4ef7\u5316\u5b66(Dynamic Covalent Chemistry, DCvC)\u7684\u63a2\u7d22\u4e0e\u76f8\u5173\u5e94\u7528\u7814\u7a76\uff0c\u5728\u7094\u70c3\u590d\u5206\u89e3(alkyne metathesis)\u3001\u6709\u673a\u5206\u5b50\u7b3c\u3001\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u3001\u5171\u4ef7\u9002\u5e94\u7f51\u7edc\uff08CANs\uff09\u4ee5\u53ca\u53ef\u56de\u6536\u70ed\u56fa\u6027\u9ad8\u5206\u5b50\u6750\u6599\u7b49\u7814\u7a76\u9886\u57df\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u8fdb\u5c55\u3002\u8fd1\u5e74\u6765\uff0c\u5728\u53ef\u56de\u6536\u4e0e\u53ef\u5851\u9ad8\u5206\u5b50\u6750\u6599\u65b9\u5411\uff0c\u56e2\u961f\u4ee5\u9996\u521b\u7684\u805a\u4e9a\u80fa\u4e3a\u5e73\u53f0\uff0c\u5728\u78b3\u7ea4\u7ef4\u5f3a\u5316\u590d\u5408\u6750\u6599\uff08CFRCs\uff09\u3001\u7535\u5b50\u76ae\u80a4\uff08electronic skin\uff09\u3001\u751f\u7269\u8d28\u590d\u5408\u6750\u6599\u3001\u9ad8\u7535\u5bfc\u7387\u590d\u5408\u6750\u6599\u30013D\u6253\u5370\u53ca\u6c14\u51dd\u80f6\u7b49\u7814\u7a76\u65b9\u5411\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u6210\u679c\u3002\u5e76\u5728\u8fd1\u671f\u7814\u53d1\u4e86\u53ef\u9006\u52a8\u6001\u82b3\u9999\u4eb2\u6838\u53d6\u4ee3\u53cd\u5e94(Dynamic S<sub>N<\/sub>Ar)\uff0c\u8fdb\u800c\u6210\u529f\u5b9e\u73b0\u4e86\u53ef\u56de\u6536\u4e0e\u53ef\u5851\u7684\u805a\u6c30\u9178\u916f\u7684\u5f00\u53d1\u3002<\/p>\n<p><strong>\u76f8\u5173\u5de5\u4f5c\uff1a<\/strong><\/p>\n<p>1\u3001Taynton, P.; Yu, K.; Shoemaker, R.; Jin, Y.; Qi, H. J.; Zhang, W. &#8220;Heat or Water Driven Malleability in a Highly-Recyclable Covalent Network Polymer&#8221; Adv. Mater. 2014, 26, 3938\u20133942<\/p>\n<p>2\u3001Taynton, P.; Ni, H.; Zhu, C.; Yu, K.; Loob, S.; Jin, Y.; Qi, J.; Zhang, W. &#8220;Repairable Woven Carbon Fiber Composites with Full Recyclability Enabled by Malleable Polyimine Networks&#8221; Adv. Mater. 2016, 28, 2904\u20132909<\/p>\n<p>3\u3001Zou, Z.; Zhu, C.; Li, Y.; Lei, X.; Zhang, W.; Xiao, J. &#8221; Rehealable, fully recyclable and malleable electronic skin enabled by dynamic covalent thermoset nanocomposite&#8221; . Sci. Adv. 2018;4: eaaq0508<\/p>\n<p>4\u3001Jin, Y.; Lei, Z.; Taynton, P.; Huang, S.; Zhang, W., Malleable and Recyclable Thermosets: The Next Generation of Plastics. Matter, 2019, 1, 1456<\/p>\n<p>5\u3001Shi, C.; Zou, Z.; Lei, Z.; Zhu, P.; Zhang, W.; Xiao, J., &#8220;Heterogeneous integration of rigid, soft, and liquid materials for self-healable, recyclable, and reconfigurable wearable electronics&#8221; Sci. Adv. 2020, 6 (45), eabd0202<\/p>\n<p>6\u3001Su, Z.; Huang, S.; Wang, Y.; Ling, H.; Yang, X.; Jin, Y.; Wang, X.; Zhang, W., Robust, high-barrier, and fully recyclable cellulose-based plastic replacement enabled by dynamic imine polymer. J. Mater. Chem. A, 2020, 8, 14082-14090<\/p>\n<p>7\u3001\u00a0Luo, S.; Ma, Y.; Wei, X.; Jin, Y.; Qiu, L.; Zhang, W. \u201cMalleable and Recyclable Vitrimer-Graphene Aerogel Composite with High Electrical Conductivity\u201d ACS Appl. Electron. Mater. 2021, 3, 1178<\/p>\n<p>8\u3001Lei, Z.; Chen, H.; Luo, C.; Rong, Y.; Hu, Y.; Jin, Y.; Long, R.; Yu, K.; Zhang, W. \u201cRecyclable and Malleable Thermosets Enabled by Activating Dormant Dynamic Linkages\u201d, Nat. Chem. 2022, 14, in press.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u5851\u6599\u5df2\u7ecf\u6210\u4e3a\u6211\u4eec\u65e5\u5e38\u751f\u6d3b\u4e2d\u4e0d\u53ef\u7f3a\u5c11\u7684\u4e00\u90e8\u5206\u3002\u968f\u7740\u5bf9\u5851\u6599\u7684\u9700\u6c42\u4e0d\u65ad\u589e\u52a0\uff0c\u5851\u6599\u5bf9\u73af\u5883\u7684\u8d1f\u9762\u5f71\u54cd\u4ee5\u53ca\u5851\u6599\u56de\u6536\u7684\u6311\u6218\uff0c\u90fd\u4f7f\u4eba\u4eec\u62c5\u5fc3\u5851\u6599\u5bf9\u73af\u5883\u548c\u4eba\u7c7b\u7684\u5065\u5eb7\u6709&#8230;<\/p>\n","protected":false},"author":1004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[4941],"class_list":["post-242985","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-4941"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/242985"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1004"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=242985"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/242985\/revisions"}],"predecessor-version":[{"id":243153,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/242985\/revisions\/243153"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=242985"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=242985"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=242985"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}