{"id":242887,"date":"2022-10-09T08:04:00","date_gmt":"2022-10-09T00:04:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=242887"},"modified":"2022-10-08T17:04:06","modified_gmt":"2022-10-08T09:04:06","slug":"nat-rev-chem%ef%bc%9a%e5%be%b7%e5%9b%bd%e9%9b%b7%e6%a0%b9%e6%96%af%e5%a0%a1%e5%a4%a7%e5%ad%a6burkhard-konig%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84%e9%ab%98%e8%83%bd%e9%87%8f%e6%95%88","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=242887","title":{"rendered":"Nat.\u00a0Rev.Chem\uff1a\u5fb7\u56fd\u96f7\u6839\u65af\u5821\u5927\u5b66Burkhard 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K\u00f6nig\u6559\u6388\u8bfe\u9898\u7ec4\u91cd\u70b9\u4ecb\u7ecd\u4e86\u5438\u80fd\u5149\u50ac\u5316\u7684\u53ef\u884c\u6027\u7684\u8303\u4f8b\uff0c\u6bd4\u8f83\u4e86\u51e0\u4e2a\u6700\u8fd1\u62a5\u9053\u7684\u6709\u673a\u5149\u50ac\u5316\u53cd\u5e94\u7684\u8ba1\u7b97\u81ea\u7531\u80fd\u5206\u5e03\uff08298.15K\uff09\u3002\u901a\u8fc7\u9009\u62e9\u8ba1\u7b97\u672a\u6eb6\u5242\u5316\u7684\u80fd\u91cf\u503c\uff0c\u5bf9\u4e00\u822c\u8f6c\u5316\u800c\u4e0d\u662f\u7279\u5b9a\u50ac\u5316\u7cfb\u7edf\u8fdb\u884c\u0394G\u8bc4\u4f30\u3002\u4f7f\u7528\u8fd9\u4e9b\u8ba1\u7b97\u7ed3\u679c\u4f5c\u4e3a\u7c97\u7565\u7684\u6307\u5bfc\uff0c\u4f5c\u8005\u56de\u987e\u4e86\u5438\u80fd\u5149\u50ac\u5316\u7684\u53cd\u5e94\u8bbe\u8ba1\u548c\u7c7b\u522b\uff0c\u8ba8\u8bba\u4e86\u5b83\u4eec\u5728\u66f4\u5927\u8303\u56f4\u5185\u7684\u6f5c\u5728\u5e94\u7528\uff0c\u5e76\u63d0\u51fa\u4e86\u5bf9\u8fd9\u4e2a\u65b0\u5174\u8bdd\u9898\u7684\u5c55\u671b\u3002<\/p>\n<p>\u76f8\u5173\u6210\u679c\u4ee5<strong>\u201cEnergy- and atom-efficientchemical synthesis with endergonicphotocatalysis\u201d<\/strong>\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520a<em>Nature Reviews Chemistry<\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-242888\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image001-1.png\" alt=\"\" width=\"813\" height=\"344\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image001-1.png 813w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image001-1-300x127.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image001-1-768x325.png 768w\" sizes=\"(max-width: 813px) 100vw, 813px\" \/><\/p>\n<p><strong>\u4e09\u3001\u6838\u5fc3\u521b\u65b0<\/strong><\/p>\n<p>\u5438\u80fd\u5149\u50ac\u5316\u662f\u5229\u7528\u5149\u6765\u8fdb\u884c\u5728\u70ed\u529b\u5b66\u4e0a\u4e0d\u5229\u7684\u50ac\u5316\u53cd\u5e94\u3002\u867d\u7136\u5149\u50ac\u5316\u5df2\u6210\u4e3a\u4fc3\u8fdb\u5316\u5b66\u8f6c\u5316\u7684\u6709\u529b\u5de5\u5177\uff0c\u4f46\u8fd9\u4e9b\u8fc7\u7a0b\u7684\u5149\u80fd\u6548\u7387\u5e76\u672a\u5f15\u8d77\u592a\u591a\u91cd\u89c6\u3002\u653e\u80fd\u5149\u50ac\u5316\u4e0d\u80fd\u5145\u5206\u5229\u7528\u5149\u80fd\u8f93\u5165\uff0c\u4ea7\u751f\u4f4e\u80fd\u4ea7\u54c1\u548c\u70ed\u91cf\uff0c\u800c\u5438\u80fd\u5149\u50ac\u5316\u7ed3\u5408\u4e86\u4e00\u90e8\u5206\u5149\u5b50\u80fd\u91cf\u8fdb\u5165\u53cd\u5e94\uff0c\u4ea7\u751f\u4ea7\u7269\u7684\u81ea\u7531\u80fd\u9ad8\u4e8e\u53cd\u5e94\u7269\u3002\u8fd9\u6837\u7684\u8fc7\u7a0b\u53ef\u4ee5\u5b9e\u73b0\u4ece\u7a33\u5b9a\u7684\u6750\u6599\u4e2d\u50ac\u5316\u3001\u539f\u5b50\u7ecf\u6d4e\u5730\u5408\u6210\u53cd\u5e94\u6027\u5316\u5408\u7269\u3002\u5728\u73af\u5883\u53cb\u597d\u6027\u548c\u78b3\u4e2d\u548c\u65b9\u9762\uff0c\u5438\u80fd\u5149\u50ac\u5316\u5728\u5927\u89c4\u6a21\u5de5\u4e1a\u5236\u9020\u65b9\u9762\u4e5f\u6709\u5e7f\u6cdb\u7528\u9014\uff0c\u5728\u8fd9\u4e9b\u5de5\u4e1a\u5236\u9020\u4e2d\uff0c\u4eba\u4eec\u5bfb\u6c42\u66f4\u597d\u7684\u80fd\u6e90\u6548\u7387\u3001\u66f4\u5c11\u7684\u6d6a\u8d39\u548c\u9644\u52a0\u4ef7\u503c\u3002\u56e0\u6b64\uff0c\u62a5\u544a\u5728\u8fd9\u91cc\u8bc4\u4f30\u4e86\u51e0\u7c7b\u62a5\u544a\u7684\u5149\u50ac\u5316\u8f6c\u5316\u7684\u70ed\u5316\u5b66\uff0c\u4ee5\u5c55\u793a\u5438\u80fd\u5149\u50ac\u5316\u7684\u5f53\u524d\u8fdb\u5c55\u5e76\u6307\u51fa\u5b83\u4eec\u7684\u5de5\u4e1a\u6f5c\u529b\u3002<\/p>\n<p>\u5149\u5b50\u4f5c\u4e3a\u6e05\u6d01\u7684\u9ad8\u80fd\u8bd5\u5242\uff0c\u5728\u5b9e\u8df5\u4e2d\u6bd4\u4f20\u7edf\u7684\u70ed\u65b9\u6cd5\u548c\u5316\u5b66\u8bd5\u5242\u66f4\u5177\u4f18\u52bf\uff0c\u63d0\u4f9b\u66f4\u6709\u9488\u5bf9\u6027\u7684\u80fd\u91cf\u8f93\u5165\uff0c\u7eaf\u5316\u8fc7\u7a0b\u4e2d\u7684\u6d6a\u8d39\u66f4\u5c11\uff0c\u5408\u6210\u8ba1\u5212\u4e2d\u7684\u9884\u529f\u80fd\u5316\u6b65\u9aa4\u66f4\u5c11\u3002\u8bda\u7136\uff0c\u8bbe\u8ba1\u4e00\u4e2a\u5149\u50ac\u5316\u5faa\u73af\u4ecd\u7136\u5177\u6709\u6311\u6218\u6027\uff0c\u5728\u8be5\u5faa\u73af\u4e2d\uff0c\u6d89\u53ca\u77ac\u6001\u7269\u8d28\u7684\u534f\u540c\u6c27\u5316\u548c\u8fd8\u539f\uff08\u6216\u5176\u4ed6\u591a\u50ac\u5316\u5242\u5e8f\u5217\uff09\u5fc5\u987b\u6b63\u786e\u65f6\u5e8f\u4ee5\u6210\u529f\u8f6c\u6362\u50ac\u5316\u5242\uff0c\u800c\u5bf9\u8fd9\u4e00\u9886\u57df\u7684\u66f4\u591a\u66f4\u6df1\u5165\u7406\u89e3\u7684\u7814\u7a76\u5c06\u662f\u6709\u76ca\u7684\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56db\u3001\u6570\u636e\u6982\u89c8<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-242889\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image003-1.png\" alt=\"\" width=\"679\" height=\"549\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image003-1.png 679w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image003-1-300x243.png 300w\" sizes=\"(max-width: 679px) 100vw, 679px\" \/><\/p>\n<p>\u56fe1 \u53cd\u5e94\u7684\u5178\u578b\u81ea\u7531\u80fd\u5206\u5e03\u56fe\u3002a)(\u70ed)\u5316\u5b66\u53cd\u5e94\u81ea\u7531\u80fd\u8c31\u7684\u4e24\u79cd\u53ef\u80fd\u60c5\u51b5:\u653e\u80fd(\u5de6)\u548c\u5438\u80fd\u80fd(\u53f3)\u3002b)\u901a\u8fc7\u63d0\u9ad8\u9006\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u52bf\u5792\u6765\u9632\u6b62\u4ea7\u7269\u9006\u53cd\u5e94\u7684\u5185\u751f\u5149\u50ac\u5316\u53cd\u5e94\u7684\u81ea\u7531\u80fd\u8c31\u3002\u00a9 2022 The Authors<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-242890\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image005-1.png\" alt=\"\" width=\"583\" height=\"608\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image005-1.png 583w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image005-1-288x300.png 288w\" sizes=\"(max-width: 583px) 100vw, 583px\" \/><\/p>\n<p>\u56fe2 \u8131\u4e59\u9170\u5316\u548c\u5f00\u73af\u5f02\u6784\u5316\u3002a\uff09\u5149\u654f\u8131\u4e59\u9170\u5316\u7684\u7b49\u4f4d\u57fa\u56e0\uff0cbach\u53d1\u8868\u3002 b\uff09\u5149\u50ac\u5316\u73af\u5c3f\u7d20\u8131\u4e59\u9170\u5316\uff0c Knowles\u53d1\u8868\u3002c\uff09\u9187\u7684\u5149\u50ac\u5316\u5f02\u6784\u5316\u751f\u6210\u919b\u548c\u916e\uff0cKnowles\u53d1\u8868\u3002\u00a9 2022 The Authors<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-242891\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image007.png\" alt=\"\" width=\"568\" height=\"567\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image007.png 568w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image007-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image007-300x300.png 300w\" sizes=\"(max-width: 568px) 100vw, 568px\" \/><\/p>\n<p>\u56fe3 \u70ef\u70c3\u5f02\u6784\u5316\u53cd\u5e94\u3002a\uff09\u5149\u654f\u4f5c\u7528\uff0cWeaver\u548cGilmour\u62a5\u9053\u3002b\uff09\u914d\u4f4d\u6fc0\u6d3b\u5438\u6536\u7ea2\u79fb\uff0c Poisson\u62a5\u9053\u3002\u5bf9\u4e8e\u6240\u793a\u7684\u53cd\u5e94\uff0c\u636e\u62a5\u9053\uff0c\u53cd\u5e94\u7269\u540c\u5206\u5f02\u6784\u4f53\u7684\u80fd\u91cf\u90fd\u9ad8\u4e8e\u4ea7\u7269\u540c\u5206\u5f02\u6784\u4f53\uff0c\u56e0\u6b64\u6240\u6709\u7684\u53cd\u5e94\u90fd\u662f\u5438\u80fd\u7684\u3002\u00a9 2022 The Authors<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-242892\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image009.png\" alt=\"\" width=\"870\" height=\"588\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image009.png 870w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image009-300x203.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image009-768x519.png 768w\" sizes=\"(max-width: 870px) 100vw, 870px\" \/><\/p>\n<p>\u56fe4\u00a0 \u8131\u82b3\u6784\u5316\u548c\u73af\u52a0\u6210\u53cd\u5e94\u3002a\uff09\u901a\u8fc7\u82ef\u4e59\u70ef\u57faC=C\u952e\u7684\u5149\u654f\u5316\u6784\u5efa\u53bb\u82b3\u6784\u5316\u7684\u590d\u5408\u7269\u7ed3\u6784\u7684\uff0c Glorius\u53d1\u8868\u3002b\uff09\u82ef\u4e59\u70efC=C\u952e\u76f4\u63a5\u6fc0\u53d1\u82ef\u7ea7\u8054\u8131\u82b3\u6784\u53cd\u5e94\uff0cBaumann\u53d1\u8868\u3002c\uff09\u5432\u54daC=C\u952e\u7684\u5149\u654f\u5316\u8131\u82b3\uff0c\u968f\u540e\u7684[4+2]\u73af\u52a0\u6210\uff0cYou\u53d1\u8868\u3002d\uff09\u5432\u54da\u901a\u8fc7[2+2]\u73af\u52a0\u6210\u8131\u82b3\u6784\uff0c 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\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image011-300x233.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image011-768x596.png 768w\" sizes=\"(max-width: 871px) 100vw, 871px\" \/><\/p>\n<p>\u56fe5 \u8131\u6c22\u548c\u8131\u6c22\u4ea4\u53c9\u8026\u5408\u3002a\uff09\u4f7f\u7528\u5341\u94a8\u9178\u76d0\u5149\u50ac\u5316\u5242\u548c\u94b4\u809f\u9178\u76d0\u50ac\u5316\u5242\u8131\u6c22\u70f7\u70c3\u548c\u9187\uff0c\u7531Sorensen\u53d1\u8868\u3002b\uff09\u5728\u7b49\u94ec\u9178\u76d0\u4e0a\u7531\u5149\u6c27\u5316\u8fd8\u539f\u548c\u94b4\u809f\u9178HAT\u5b9e\u73b0\u7684\u8131\u6c22\u4ea4\u53c9\u8026\u5408\uff0cL.-Z\u53d1\u8868\u3002Wu (\u4ece\u70ef\u9187)\u3002c\uff09\u8131\u6c22C(<em>sp<\/em><sup>2<\/sup>) -Het\u4ea4\u53c9\u8026\u5408\uff0cL.-Z. Wu\u548cTung\u53d1\u8868\u3002d\uff09\u8131\u6c22C(<em>sp<\/em><sup>2<\/sup>) -O\u4ea4\u53c9\u8026\u5408\uff0cLei\u53d1\u8868\u3002e\uff09\u919b\u4e0a\u7684\u5149\u6c27\u5316\u8fd8\u539f\u548c\u954d\u8fd8\u539f\u6d88\u9664\u4f7f\u8131\u6c22\u4ea4\u53c9\u8026\u5408\uff0cMurakami\u53d1\u8868\u3002f\uff09\u5341\u94a8\u9178\u76d0\u548c\u94b4\u809f\u5149- HAT\u5728\u70f7\u70c3\u548c\u919b\u4e0a\u7684\u8131\u6c22\u4ea4\u53c9\u5076\u8054\uff0cJ. Wu\u53d1\u8868\u3002\u00a9 2022 The Authors<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-242894\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image013.png\" alt=\"\" width=\"863\" height=\"499\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image013.png 863w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image013-300x173.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/10\/image013-768x444.png 768w\" sizes=\"(max-width: 863px) 100vw, 863px\" \/><\/p>\n<p>\u56fe6 \u57fa\u56e2\u8f6c\u79fb\u53cd\u5e94\u3002a\uff09\u901a\u8fc7\u916e\u4e8c\u57faC-H\u7fa7\u57fa\u5316\uff0cMurakami\u53d1\u8868\u3002b\uff09\u901a\u8fc7CO<sub>2<\/sub>\u81ea\u7531\u57fa\u9634\u79bb\u5b50C-H\u7fa7\u5316\uff0c\u53d1\u8868\u4e8eJamison\u3002c\uff09\u901a\u8fc7\u82c4\u9634\u79bb\u5b50C-H\u7fa7\u57fa\u5316\uff0c\u7531K\u00f6nig\u53d1\u8868\u3002d\uff09\u5341\u94a8\u9178\u916f\u78fa\u9170\u5316C-H, 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