{"id":242619,"date":"2022-10-01T06:42:54","date_gmt":"2022-09-30T22:42:54","guid":{"rendered":"\/\/m.iemloyee.com\/?p=242619"},"modified":"2022-09-30T17:43:03","modified_gmt":"2022-09-30T09:43:03","slug":"nat-mater%ef%bc%9a%e8%87%b4%e5%af%86%e7%9a%84%e6%97%a0%e6%9c%ba%e7%94%b5%e8%a7%a3%e8%b4%a8%e9%a2%97%e7%b2%92%e4%bf%83%e8%bf%9b%e5%a4%8d%e5%90%88%e7%94%b5%e8%a7%a3%e8%b4%a8%e7%9a%84%e5%af%bc%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=242619","title":{"rendered":"Nat Mater\uff1a\u81f4\u5bc6\u7684\u65e0\u673a\u7535\u89e3\u8d28\u9897\u7c92\u4fc3\u8fdb\u590d\u5408\u7535\u89e3\u8d28\u7684\u5bfc\u7535\u6027"},"content":{"rendered":"<p style=\"text-align: center;\"><strong><b>\u89e3\u8bfb<\/b><\/strong><strong><b>&#8211;<\/b><\/strong><strong><b>\u81f4\u5bc6\u7684\u65e0\u673a\u7535\u89e3\u8d28\u9897\u7c92\u4fc3\u8fdb\u590d\u5408\u7535\u89e3\u8d28\u7684\u5bfc\u7535\u6027<\/b><\/strong><\/p>\n<p>\u4f20\u7edf\u4e0a\uff0c\u6db2\u6001\u7535\u89e3\u8d28(LEs)\u7531\u4e8e\u5177\u6709\u8f83\u9ad8\u7684\u7535\u5bfc\u7387\u548c\u826f\u597d\u7684\u7535\u6781\u6da6\u6e7f\u6027\u800c\u88ab\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u4f46\u7531\u4e8e\u5176\u6613\u71c3\u6027\uff0c\u5728\u5b89\u5168\u6027\u65b9\u9762\u975e\u5e38\u4e0d\u7406\u60f3\u3002LEs\u65e0\u6cd5\u6291\u5236\u5faa\u73af\u8fc7\u7a0b\u4e2d\u5bb9\u6613\u9020\u6210\u77ed\u8def\u7684\u679d\u6676\u7684\u5f62\u6210\u3002\u56e0\u6b64\uff0c\u4eba\u4eec\u8d8a\u6765\u8d8a\u503e\u5411\u4e8e\u4f7f\u7528\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u56e0\u4e3a\u5b83\u4eec\u65e2\u53ef\u4ee5\u63d0\u9ad8\u5b89\u5168\u6027\uff0c\u53c8\u53ef\u4ee5\u6291\u5236\u679d\u6676\u7684\u5f62\u6210\u3002<\/p>\n<p>\u56fa\u6001\u7535\u89e3\u8d28\u4e3b\u8981\u5206\u4e3a\u4e24\u5927\u7c7b\uff1a\u56fa\u4f53\u805a\u5408\u7269\u7535\u89e3\u8d28(SPEs)\u548c\u9676\u74f7\u7535\u89e3\u8d28(CEs)\u3002SPEs \u5728\u5176\u67d4\u8f6f\u7684\u673a\u68b0\u6027\u80fd\u3001\u6709\u5e0c\u671b\u7684\u4f4e\u6210\u672c\u52a0\u5de5\uff08\u4f8b\u5982\uff0c\u65e0\u6eb6\u5242\u6324\u51fa\uff09\u548c\u4e0e\u7535\u6781\u7684\u7d27\u5bc6\u63a5\u89e6\u65b9\u9762\u5177\u6709\u4f18\u52bf\u3002\u7136\u800c\uff0cSPEs\u7684\u4f4e\u7535\u5bfc\u7387\u963b\u788d\u4e86\u5b83\u4eec\u5728\u5ba4\u6e29\u4e0b\u7684\u5b9e\u9645\u5e94\u7528\u3002CEs\u663e\u793a\u51fa\u66f4\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u70ed\u7a33\u5b9a\u6027\uff0c\u4f46\u5b83\u4eec\u7684\u6210\u578b\u9700\u8981\u9ad8\u6e29\u548c\/\u6216\u9ad8\u538b\uff0c\u5bfc\u81f4\u6750\u6599\u53d8\u8106\u3002\u968f\u7740\u5faa\u73af\u8fc7\u7a0b\u4e2d\u9502\u4f53\u79ef\u7684\u53d8\u5316\uff08\u9502\u7535\u9540\/\u5265\u79bb\uff09\uff0c\u7d27\u5bc6\u7684\u9502\/\u9676\u74f7\u754c\u9762\u96be\u4ee5\u5f62\u6210\u548c\u7ef4\u6301\uff0c\u4ece\u800c\u5bfc\u81f4\u5206\u5c42\u548c\u7535\u6c60\u6545\u969c\u548c\/\u6216\u679d\u6676\u5f62\u6210\u3002\u5305\u542b\u5206\u6563\u5728\u805a\u5408\u7269\u57fa\u8d28\u4e2d\u7684\u9676\u74f7\u9897\u7c92\u7684\u590d\u5408\u7535\u89e3\u8d28\u4f3c\u4e4e\u662f\u4e00\u79cd\u6709\u5e0c\u671b\u7684\u6298\u8877\u65b9\u6848\uff0c\u5b83\u53ef\u4ee5\u7ee7\u627f\u4ee5\u4e0a\u4e24\u79cd\u7535\u89e3\u8d28\u7684\u4f18\u70b9\u3002<\/p>\n<p><strong><b>\u590d\u5408\u805a\u5408\u7269-\u9676\u74f7\u7535\u89e3\u8d28\u662f\u53ef\u80fd\u89e3\u51b3\u65b9\u6848\uff0c\u5f97\u76ca\u4e8e\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u7efc\u5408\u673a\u68b0\u6027\u80fd\u548c\u9676\u74f7\u7535\u89e3\u8d28\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u9ad8\u5bfc\u7535\u6027<\/b><\/strong>\u3002\u7136\u800c\uff0c\u5728\u5bfc\u7535\u6709\u673a\u57fa\u8d28\u4e2d\u9a71\u52a8\u5206\u6563\u7684CEs \u7535\u5bfc\u7387\u7684\u56e0\u7d20\u5c1a\u4e0d\u6e05\u695a\uff0c\u56e0\u6b64\u5bf9\u6709\u6548\u7535\u5bfc\u7387\u7684\u7269\u7406\u63cf\u8ff0\u662f\u975e\u5e38\u5fc5\u8981\u7684\u3002\u91cd\u8981\u7684\u662f\uff0c\u805a\u5408\u7269\u7535\u89e3\u8d28\u5bf9\u9676\u74f7\u9897\u7c92\u7684\u53cd\u5e94\u6027\u548c\u9897\u7c92\u5fae\u89c2\u7ed3\u6784\u7684\u5f71\u54cd\u5747\u88ab\u5ffd\u7565\u3002<\/p>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><b>[\u6210\u679c\u63a0\u5f71]<\/b><\/strong><\/p>\n<p><strong><b>\u5728\u8fd9\u9879\u7814\u7a76\u4e2d\uff0c\u6cd5\u56fd\u683c\u52d2\u8bfa\u5e03\u5c14-\u963f\u5c14\u5351\u65af\u5927\u5b66Renaud Bouchet\u8bfe\u9898\u7ec4\u4f7f\u7528\u4e0d\u540c\u7684\u6db2\u4f53\u7535\u89e3\u8d28\u5316\u5b66\u4f5c\u4e3a\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u6a21\u578b\uff0c\u5e76\u8bc4\u4f30\u4e86\u6dfb\u52a0\u5404\u79cd\u591a\u5b54\u548c\u81f4\u5bc6\u9676\u74f7\u7535\u89e3\u8d28\u5bf9\u7535\u5bfc\u7387\u7684\u5f71\u54cd\u3002<\/b><\/strong>\u6240\u6709\u7ed3\u679c\u90fd\u53ef\u4ee5\u7528\u6709\u6548\u4ecb\u8d28\u7406\u8bba\u5efa\u6a21\uff0c\u4ece\u800c\u53ef\u4ee5\u9884\u6d4b\u7535\u89e3\u8d28\u7ec4\u5408\u7684\u7535\u5bfc\u7387\u3002\u672c\u5de5\u4f5c\u660e\u786e\u5730\u786e\u5b9a\uff0c\u9ad8\u5bfc\u7535\u6027\u591a\u5b54\u9897\u7c92\u5728\u6b64\u7c7b\u7cfb\u7edf\u4e2d\u5145\u5f53\u7edd\u7f18\u4f53\uff0c\u800c\u81f4\u5bc6\u9897\u7c92\u5145\u5f53\u5bfc\u4f53\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e86\u672c\u5de5\u4f5c\u5bf9\u590d\u5408\u7535\u89e3\u8d28\u7535\u5bfc\u7387\u7684\u7406\u89e3\u3002\u76f8\u5173\u8bba\u6587\u4ee5\u9898\u4e3a\uff1a\u201c<em><i>Dense inorganic electrolyte particles as a lever to promote composite electrolyte conductivity<\/i><\/em>\u201d\u53d1\u8868\u5728<em><i>Nature Materials<\/i><\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-242620\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72471-8.png\" alt=\"\" width=\"688\" height=\"230\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72471-8.png 688w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72471-8-300x100.png 300w\" sizes=\"(max-width: 688px) 100vw, 688px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><strong><b>[\u6838\u5fc3\u521b\u65b0\u70b9]<\/b><\/strong><\/p>\n<ul>\n<li><b><\/b><strong><b>\u672c\u5de5\u4f5c\u521b\u65b0\u6027\u7684<\/b><\/strong><strong><b>\u4f7f\u7528\u4e86\u590d\u5408\u7535\u89e3\u8d28\u6a21\u578b\u7cfb\u7edf\u6765\u6d4b\u91cf\u6dfb\u52a0\u9676\u74f7\u5bf9\u7535\u5bfc\u7387\u7684\u5f71\u54cd<\/b><\/strong>\u3002\u6240\u6709\u7ed3\u679c\u90fd\u53ef\u4ee5\u7528\u6709\u6548\u4ecb\u8d28\u7406\u8bba\u5efa\u6a21\uff0c\u4ece\u800c\u53ef\u4ee5\u9884\u6d4b\u7535\u89e3\u8d28\u7ec4\u5408\u7684\u7535\u5bfc\u7387\u3002<\/li>\n<li>\u672c\u5de5\u4f5c\u4f7f\u7528LEs\u4ee3\u66ffSPEs\uff0c\u56e0\u4e3a\u5728\u6d4b\u91cf\u5206\u6563\u4f53\uff08\u590d\u5408\u7535\u89e3\u8d28\uff09\u7684\u7535\u5bfc\u7387\u540e\uff0c\u53ef\u4ee5\u8ba9\u9676\u74f7\u9897\u7c92\u6c89\u6dc0\u5e76\u6d4b\u91cf\u4e0a\u6e05\u6db2\u7684\u7535\u5bfc\u7387\uff0c\u786e\u4fdd\u6dfb\u52a0\u9676\u74f7\u9897\u7c92\u540e\u7535\u5bfc\u7387\u7684\u4efb\u4f55\u53d8\u5316\u90fd\u662f\u7531\u4e8e\u9676\u74f7\u800c\u4e0d\u662f\u6db2\u76f8\u7684\u53d8\u5316\u3002<\/li>\n<li>\u672c\u5de5\u4f5c\u4f7f\u7528\u57fa\u4e8e\u9ea6\u514b\u65af\u97e6\u65b9\u7a0b(Maxwell equation)\u7684\u6709\u6548\u4ecb\u8d28\u7406\u8bba\u5bf9\u6574\u4e2a\u6570\u636e\u96c6\u8fdb\u884c\u4e86\u5b8c\u7f8e\u62df\u5408\u3002\u8be5\u6a21\u578b\u7ed9\u51fa\u4e86\u5206\u6563\u6db2\u4e2d\u9897\u7c92(\u81f4\u5bc6\u6216\u591a\u5b54\u7684\u56e2\u805a\u4f53)\u7684\u6709\u6548\u7535\u5bfc\u7387\uff0c\u80fd\u591f\u8bca\u65ad\u7531\u9676\u74f7\u7c89\u672b\u7684\u5fae\u89c2\u7ed3\u6784\u5f15\u8d77\u7684\u95ee\u9898\uff0c\u8fd8\u53ef\u4ee5\u9884\u6d4b\u805a\u5408\u7269\u548cCEs\u7684\u7ec4\u5408\u7684\u7535\u5bfc\u7387\uff0c\u53ea\u9700\u8981\u77e5\u9053\u76f8\u5e94\u7ec4\u5206\u7684\u7535\u5bfc\u7387\u548c\u9676\u74f7\u5fae\u89c2\u7ed3\u6784(\u9897\u7c92\u5b54\u9699\u7387)\u3002<\/li>\n<\/ul>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><b>[\u6570\u636e\u6982\u89c8]<\/b><\/strong><\/p>\n<ul>\n<li><b><\/b><strong><b>\u7406\u8bba\u5efa\u6a21<\/b><\/strong><\/li>\n<\/ul>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p>\u672c\u5de5\u4f5c\u901a\u8fc7\u5f15\u5165\u6709\u6548\u7684\u591a\u5b54\u7c92\u5b50\u7535\u5bfc\u7387(<em><i>\u03c3<\/i><\/em><sub>p,eff)<\/sub>\uff0c\u5bf9\u591a\u5b54\u9897\u7c92(\u7531\u5bc6\u96c6\u7684\u9897\u7c92\u805a\u96c6\u5728\u8fd9\u91cc\u5f62\u6210) (\u5b54\u9699\u7387\u4e3a<em><i>\u03b5<\/i><\/em><sub>p<\/sub>)\u7684\u5206\u6563\u65b9\u7a0b\u8fdb\u884c\u4e86\u4fee\u6b63\uff0c\u4ece\u800c\u5f97\u5230\u4e86\u591a\u5b54\u9897\u7c92\u7684\u4fee\u6b63Maxwell\u65b9\u7a0b(3)\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-242621\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72472-8.png\" alt=\"\" width=\"761\" height=\"69\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72472-8.png 761w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72472-8-300x27.png 300w\" sizes=\"(max-width: 761px) 100vw, 761px\" \/><\/p>\n<p>\u91cd\u8981\u7684\u662f\uff0c<em><i>\u03c3<\/i><\/em><sub>p,eff<\/sub>\u5305\u542b\u6765\u81ea\u56fa\u76f8\uff08\u6676\u7c92\u548c\u6676\u754c\uff09\u548c\u5b58\u5728\u4e8e\u805a\u96c6\u4f53\u5b54\u9699\u5185\u7684\u8fde\u7eed\u76f8\u7684\u8d21\u732e\uff0c\u4ee5\u53ca\u6cbf\u6676\u7c92\u8868\u9762\u7684\u4efb\u4f55\u7535\u5bfc\u7387(\u56fe1)\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u9ea6\u514b\u65af\u97e6\u65b9\u7a0b\u5e94\u7528\u4e8e\u4e00\u7cfb\u5217\u5206\u6563\u5728\u4e0d\u540c\u8fde\u7eed LE \u76f8\u4e2d\u7684\u5bfc\u7535\u9676\u74f7\u9897\u7c92\uff0c\u4ee5\u5bf9\u590d\u5408\u7535\u89e3\u8d28\u7684\u4e0d\u540c\u7ec4\u5408\u8fdb\u884c\u57fa\u51c6\u6d4b\u8bd5\u3002\u901a\u8fc7\u7b80\u5355\u5730\u6d4b\u91cf\u6bcf\u6b21\u6dfb\u52a0\u9676\u74f7\u540eLEs\u7684\u7535\u5bfc\u7387\u548cLE-CE\u590d\u5408\u6750\u6599\u7684\u6709\u6548\u7535\u5bfc\u7387(<em><i>\u03c3<\/i><\/em><sub>eff<\/sub>)\uff0c\u53ea\u8981<em><i>\u03b5<\/i><\/em><sub>p<\/sub>\u5df2\u77e5\uff0c\u5c31\u53ef\u4ee5\u8ba1\u7b97\u51fa\u5206\u6563\u9676\u74f7\u76f8\u7684\u6709\u6548\u7535\u5bfc\u7387\u3002<\/p>\n<p>\u56fe2\u663e\u793a\u4e86\u590d\u5408\u6750\u6599\u572840\u00b0C\u4e0b\u7684\u5f52\u4e00\u5316\u7535\u5bfc\u7387\uff0c\u5373\u6709\u6548\u7535\u5bfc\u7387(<em><i>\u03c3<\/i><\/em><sub>eff<\/sub>)\u9664\u4ee5LE\u7684\u7535\u5bfc\u7387(<em><i>\u03c3<\/i><\/em><sup>0<\/sup>)\u4e0e<em><i>\u03b5<\/i><\/em><sub>LE<\/sub>\u3002\u6240\u6709\u590d\u5408\u6750\u6599\u7684\u884c\u4e3a\u65b9\u5f0f\u76f8\u540c\uff1a\u5411LE\u6dfb\u52a0\u591a\u5b54CE\u4f1a\u5bfc\u81f4<em><i>\u03c3<\/i><\/em><sub>eff<\/sub>\/<em><i>\u03c3<\/i><\/em><sup>0<\/sup>&lt;1\uff0c\u5373\u6709\u6548\u7535\u5bfc\u7387\u968f\u7740\u9676\u74f7\u7684\u6dfb\u52a0\u800c\u964d\u4f4e\u3002<strong><b>\u672c\u5de5\u4f5c\u53d1\u73b0\u65e0\u8bba\u7c89\u672b\u548c\u7535\u89e3\u8d28\u7684\u6027\u8d28\u5982\u4f55\uff0c\u7ed3\u679c\u90fd\u662f\u76f8\u4f3c\u7684\uff1a\u4e24\u4e2a\u4e0d\u540c\u7684LEs\u4e2d\u7684\u76f8\u540c\u7c89\u672b\u4ea7\u751f\u76f8\u540c\u7684\u7ed3\u679c\u3002\u8fd9\u4e9b\u7ed3\u679c\u975e\u5e38\u666e\u904d\uff0c\u9002\u7528\u4e8e\u6240\u6709\u805a\u5408\u7269\u7535\u89e3\u8d28<\/b><\/strong>\u3002<\/p>\n<p>\u901a\u8fc7\u5b9e\u9a8c\u89c2\u5bdf\uff0c\u672c\u5de5\u4f5c\u53d1\u73b0\u5728\u9897\u7c92\u6c89\u964d\u540e\u6d4b\u91cf\u7684LE(<em><i>\u03c3<\/i><\/em><sup>0<\/sup>)\u7684\u7535\u5bfc\u7387\u751a\u81f3\u6bd4<em><i>\u03c3<\/i><\/em><sub>eff<\/sub>\u589e\u52a0\u66f4\u591a\uff0c\u8fd9\u8868\u660e\u590d\u5408\u6750\u6599\u7684\u7535\u5bfc\u7387\u589e\u76ca\u53ef\u4ee5\u5f52\u56e0\u4e8eLE\u7535\u5bfc\u7387\u7684\u589e\u52a0\u3002\u8fd9\u4e00\u7ed3\u679c\u53ef\u4ee5\u89e3\u91ca\u6587\u732e\u4e2d\u89c2\u5bdf\u5230\u7684\u975e\u5355\u8c03\u884c\u4e3a\uff1a<strong><b>\u6700\u521d\u6dfb\u52a0\u9676\u74f7\u4f1a\u7531\u4e8e\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u964d\u89e3\u3001\u9676\u74f7\u8868\u9762\u6742\u8d28\u7684\u6eb6\u89e3\u3001H<\/b><\/strong><strong><sup><b>+<\/b><\/sup><\/strong><strong><b>\/Li<\/b><\/strong><strong><sup><b>+<\/b><\/sup><\/strong><strong><b>\u4ea4\u6362\u7b49\u5bfc\u81f4\u7535\u5bfc\u7387\u589e\u52a0\uff0c\u800c\u8fdb\u4e00\u6b65\u6dfb\u52a0\u5219\u4f1a\u7531\u4e8e\u6dfb\u52a0\u591a\u5b54\u9676\u74f7\u9897\u7c92\u5bfc\u81f4\u7535\u5bfc\u7387\u964d\u4f4e<\/b><\/strong>(\u56fe2)\u3002\u56e0\u6b64\uff0c\u56fe2\u4e2d\u663e\u793a\u7684\u7ed3\u679c\u5747\u6839\u636e\u6dfb\u52a0\u9676\u74f7\u540e\u503e\u6790\u7684LE\u6d4b\u91cf\u7684<em><i>\u03c3<\/i><\/em><sup>0<\/sup>\u8fdb\u884c\u6821\u51c6\uff0c\u4ece\u800c\u4f7f\u6574\u4e2a\u7ec4\u5408\u5177\u6709\u5747\u5300\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-242622\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72473-9.png\" alt=\"\" width=\"747\" height=\"450\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72473-9.png 747w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72473-9-300x181.png 300w\" sizes=\"(max-width: 747px) 100vw, 747px\" \/><\/p>\n<p>\u56fe1. \u5f71\u54cd\u590d\u5408\u7535\u89e3\u8d28\u6709\u6548\u7535\u5bfc\u7387\u7684\u53ef\u80fd\u56e0\u7d20\u00a9 2022 Springer Nature Limited<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-242623\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72474-7.png\" alt=\"\" width=\"783\" height=\"496\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72474-7.png 783w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72474-7-300x190.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72474-7-768x486.png 768w\" sizes=\"(max-width: 783px) 100vw, 783px\" \/><\/p>\n<p>\u56fe2. \u591a\u5b54\u9897\u7c92\u590d\u5408\u6750\u6599\u7684\u7535\u5bfc\u7387\u00a9 2022 Springer Nature Limited<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><b><\/b><strong><b>\u591a\u5b54\u9897\u7c92\u590d\u5408\u6750\u6599\u7684\u7535\u5bfc\u7387<\/b><\/strong><\/li>\n<\/ul>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p>\u4e3a\u4e86\u8fdb\u4e00\u6b65\u7406\u89e3\u8fd9\u4e9b\u591a\u5b54\u4f53\u7cfb\uff0c\u672c\u5de5\u4f5c\u7528\u4fee\u6b63\u7684\u9ea6\u514b\u65af\u97e6\u65b9\u7a0b(3)\u6765\u62df\u5408\u5206\u6563\u4f53\u7684\u5b9e\u9a8c\u6709\u6548\u7535\u5bfc\u7387\uff0c\u4f7f\u7528\u9897\u7c92\u5b54\u9699\u7387\u03b5p\u5e76\u8c03\u6574\u552f\u4e00\u672a\u77e5\u91cf\uff0c\u5373\u591a\u5b54\u9897\u7c92\u7684\u6709\u6548\u7535\u5bfc\u7387(<em><i>\u03c3<\/i><\/em><sub>p,eff<\/sub>)\u3002\u6240\u6709\u62df\u5408\u90fd\u975e\u5e38\u597d\uff0c\u76f8\u5173\u56e0\u5b50\u03c7<sup>2<\/sup>&gt;0.99\u3002\u4f7f\u7528LE\u5728\u4e0d\u540cLiTFSI\u6d53\u5ea6\u4e0b\u83b7\u5f97\u7684\u03c3p,eff\u7ed3\u679c\u503c\u663e\u793a\u5728\u56fe3\u4e2d\uff0c\u4ee5\u53ca\u76f8\u5e94\u503e\u6790LE\u7684\u6d4b\u91cf<em><i>\u03c3<\/i><\/em><sup>0<\/sup>\u503c\u548c\u9884\u671fCE\u503c\u3002\u4ece\u56fe3\u53ef\u4ee5\u5f97\u51fa\u4e09\u4e2a\u5173\u952e\u89c2\u5bdf\u7ed3\u679c\uff1a(1)<em><i>\u03c3<\/i><\/em><sub>p,eff<\/sub>\u00a0\u59cb\u7ec8\u5c0f\u4e8e<em><i>\u03c3<\/i><\/em><sup>0<\/sup>\uff0c(2)<em><i>\u03c3<\/i><\/em><sub>p,eff<\/sub>\u5b8c\u5168\u72ec\u7acb\u4e8eCE\u7535\u5bfc\u7387\u7684\u9884\u671f\u503c\u548c(3)\u03c3<sub>p,eff <\/sub>\u548c\u03c30\u662f\u6210\u6bd4\u4f8b\u7684\u3002\u5916\u63a8\u8868\u660e\uff0c\u4e0d\u53ef\u80fd\u5236\u5907\u5177\u6709\u6bd4SPE\u66f4\u9ad8\u7535\u5bfc\u7387\u7684\u591a\u5b54\u9897\u7c92\u7684\u590d\u5408\u7535\u89e3\u8d28\uff0c\u8fd9\u5bf9\u8fd9\u4e9b\u9897\u7c92\u5728\u590d\u5408\u7535\u89e3\u8d28\u4e2d\u7684\u4f7f\u7528\u5177\u6709\u4e25\u91cd\u5f71\u54cd\u3002<\/p>\n<p>\u4e3a\u4e86\u4e86\u89e3\u591a\u5b54\u9897\u7c92\u7684\u6709\u6548\u7535\u5bfc\u7387\uff0c<em><i>\u03c3<\/i><\/em><sub>p,eff<\/sub>\/<em><i>\u03c3<\/i><\/em><sup>0<\/sup>\u4e0e\u03b5p\u7684\u5173\u7cfb\u5982\u56fe4\u6240\u793a\u3002\u5728\u56fe4\u4e2d\uff0c\u9676\u74f7\u9897\u7c92\u7684\u6709\u6548\u7535\u5bfc\u7387(<em><i>\u03c3<\/i><\/em><sub>p,eff<\/sub>)\u53e0\u52a0\u5728\u975e\u5bfc\u7535\u9897\u7c92\u5206\u6563\u4f53\u7684\u9884\u6d4b\u66f2\u6298\u5ea6\u4e0a\uff0c\u8868\u660e<em><i>\u03c3<\/i><\/em><sub>p,eff<\/sub>\u5b8c\u5168\u662f\u7531\u4e8eLE\u7684\u7535\u5bfc\u7387\u5b58\u5728\u4e8e\u5b54\u9699\u4e2d\u9676\u74f7\u9897\u7c92\uff0c\u4ee5\u53caCE\u58c1\u7684\u7535\u5bfc\u7387\uff08\u5373\u9676\u74f7\u6750\u6599\u672c\u8eab\u3001\u6676\u7c92\u548c\u6676\u754c\uff09\u7684\u8868\u89c2\u7535\u5bfc\u7387\u4e3a\u96f6\u3002\u8fd9\u4e2a\u7ed3\u679c\u53ef\u4ee5\u901a\u8fc7\u8003\u8651\u5728\u4e00\u4e2a\u805a\u5408\u4f53\u4e2d\u89e3\u91ca\uff0c\u6676\u7c92-\u6676\u7c92\u76f8\u4e92\u4f5c\u7528\u662f\u70b9\u63a5\u89e6\uff0c\u56e0\u6b64\u4e0e\u5927\u90e8\u5206\u6750\u6599\u76f8\u6bd4\u5177\u6709\u9ad8\u7535\u963b\u3002<\/p>\n<p>\u4e00\u822c\u6765\u8bf4\uff0c\u7814\u7a76\u5c0f\u7ec4\u5df2\u7ecf\u7814\u7a76\u4e86\u7528\u4e8e\u590d\u5408\u7535\u89e3\u8d28\u7684\u7eb3\u7c73\u7ed3\u6784\u6750\u6599\u7684\u6548\u679c\uff0c\u8fd9\u63a8\u52a8\u4e86\u4f9b\u5e94\u5546\u51cf\u5c11\u9676\u74f7\u9897\u7c92\u7684\u7c92\u5ea6\uff0c\u4ece\u800c\u4ea7\u751f\u5f3a\u805a\u96c6\u7684\u9897\u7c92\u3002\u56e0\u6b64\uff0c\u5f88\u96be\u627e\u5230\u7531\u81f4\u5bc6\u3001\u5b64\u7acb\u7684\u9897\u7c92\u7ec4\u6210\u7684CE\u7c89\u672b\u7684\u5546\u4e1a\u6837\u54c1\uff0c\u672c\u5de5\u4f5c\u6240\u77e5\u552f\u4e00\u7684\u4f8b\u5b50\u662fLATP-Tosh\u7684\u7c89\u672b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-242624\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72475-7.png\" alt=\"\" width=\"717\" height=\"460\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72475-7.png 717w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72475-7-300x192.png 300w\" sizes=\"(max-width: 717px) 100vw, 717px\" \/><\/p>\n<p>\u56fe3. \u591a\u5b54\u7c92\u5b50\u7684\u6709\u6548\u7535\u5bfc\u7387\u00a9 2022 Springer Nature Limited<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-242625\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72476-3.png\" alt=\"\" width=\"502\" height=\"418\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72476-3.png 502w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72476-3-300x250.png 300w\" sizes=\"(max-width: 502px) 100vw, 502px\" \/><\/p>\n<p>\u56fe4. \u5c06\u805a\u96c6\u7684CE\u9897\u7c92\u7684\u7535\u5bfc\u7387\u5efa\u6a21\u4e3a\u975e\u5bfc\u7535\u7684\u00a9 2022 Springer Nature Limited<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><b><\/b><strong><b>\u5177\u6709\u81f4\u5bc6\u9897\u7c92\u7684\u590d\u5408\u6750\u6599\u7684\u7535\u5bfc\u7387<\/b><\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p>\u5305\u542b\u5206\u6563\u5728\u4e0d\u540c\u76d0\u6d53\u5ea6\u7684PEG-240\u4e2d\u7684\u65e0\u5b54LATP-Tosh\u7684\u590d\u5408\u6750\u6599\u7684\u5f52\u4e00\u5316\u7535\u5bfc\u7387\u4e0e<em><i>\u03b5<\/i><\/em><sub>LE<\/sub>\u7684\u5173\u7cfb\u5982\u56fe5a\u6240\u793a\u3002\u590d\u5408\u7535\u89e3\u8d28\u572810\u2009mM LiTFSI\u4e0b\u7684\u7535\u5bfc\u7387\u9ad8\u4e8e\u521d\u59cbLE\u3002\u6709\u6548\u7535\u5bfc\u7387\u4ee5\u5355\u8c03\u7684\u65b9\u5f0f\u589e\u52a0\uff0c\u6d4b\u91cf\u5230\u9ad8\u8fbe32\u2009vol%CE\uff08\u5373<em><i>\u03b5<\/i><\/em><sub>LE<\/sub>=0.68\uff09\u3002 \u7c92\u5b50\u6c89\u964d\u540e\u6ca1\u6709\u89c2\u5bdf\u5230<em><i>\u03c3<\/i><\/em><sup>0<\/sup>\u6216\u989c\u8272\u7684\u53d8\u5316\u3002<\/p>\n<p>\u4e3a\u4e86\u786e\u5b9a\u8fd9\u4e9b\u4f53\u7cfb\u4e2d\u9676\u74f7\u9897\u7c92\u7684\u7535\u5bfc\u7387\uff0c\u5b9e\u9a8c\u7ed3\u679c\u7528\u9ea6\u514b\u65af\u97e6\u65b9\u7a0b\u8fdb\u884c\u62df\u5408\uff0c\u8be5\u65b9\u7a0b\u9002\u7528\u4e8e\u6ca1\u6709\u9897\u7c92\u5b54\u9699\u7387(<em><i>\u03b5<\/i><\/em><sub>p<\/sub>=0)\u7684\u60c5\u51b5\uff0c<em><i>\u03c3<\/i><\/em><sub>p<\/sub>\u662f\u552f\u4e00\u53d8\u91cf\u3002\u62df\u5408\u7684\u7ed3\u679c\u5982\u56fe5a\u6240\u793a\uff0c\u4e0e\u5b9e\u9a8c\u6570\u636e\u975e\u5e38\u543b\u5408\uff0c\u751a\u81f3\u9ad8\u8fbe32\u2009vol% CE\u3002\u5728\u4e0d\u540c\u76d0\u6d53\u5ea6\u4e0b\u5f97\u5230\u7684<em><i>\u03c3<\/i><\/em><sub>p<\/sub>\u503c\u663e\u793a\u5728\u56fe5b\u4e2d\uff0c\u4ee5\u53ca\u6d4b\u91cf\u7684LE\u76f8\u7684\u7535\u5bfc\u7387\u548c\u9884\u671f\u7684CE\u7535\u5bfc\u7387\u3002<\/p>\n<p>\u5bf9\u4e8e\u76d0\u6d53\u5ea6\u4e3a100\u2009mM\u6216\u4ee5\u4e0a\u7684LE PEG-240 (\u56fe5a)\uff0c<em><i>\u03c3<\/i><\/em><sub>eff\/<\/sub><em><i>\u03c3<\/i><\/em><sup>0<\/sup>&lt;1\u7684\u503c\u53ef\u4ee5\u7b80\u5355\u5730\u89e3\u91ca\u4e3aLE\u7684\u7535\u5bfc\u7387\u9ad8\u4e8eLATP 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srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72477-3.png 674w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72477-3-300x242.png 300w\" sizes=\"(max-width: 674px) 100vw, 674px\" \/><\/p>\n<p>\u56fe5. \u542b\u6709\u81f4\u5bc6\u9897\u7c92\u7684\u590d\u5408\u6750\u6599\u7684\u7535\u5bfc\u7387\u00a9 2022 Springer Nature Limited<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-242627\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72478-2.png\" alt=\"\" width=\"436\" height=\"375\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72478-2.png 436w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/\u56fe\u72478-2-300x258.png 300w\" sizes=\"(max-width: 436px) 100vw, 436px\" \/><\/p>\n<p>\u9644\u56fe7. \u590d\u5408\u7535\u89e3\u8d28\u7535\u5bfc\u7387\u6781\u9650\u7684\u9884\u6d4b\u00a9 2022 Springer Nature Limited<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p>\u7b2c\u4e00\u4f5c\u8005\uff1aJames A. Isaac<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1aRenaud Bouchet<\/p>\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u6cd5\u56fd\u683c\u52d2\u8bfa\u5e03\u5c14-\u963f\u5c14\u5351\u65af\u5927\u5b66<\/p>\n<p>\u8bba\u6587doi\uff1a<\/p>\n<p>https:\/\/doi.org\/10.1038\/s41563-022-01343-w<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u89e3\u8bfb&#8211;\u81f4\u5bc6\u7684\u65e0\u673a\u7535\u89e3\u8d28\u9897\u7c92\u4fc3\u8fdb\u590d\u5408\u7535\u89e3\u8d28\u7684\u5bfc\u7535\u6027 \u4f20\u7edf\u4e0a\uff0c\u6db2\u6001\u7535\u89e3\u8d28(LEs)\u7531\u4e8e\u5177\u6709\u8f83\u9ad8\u7684\u7535\u5bfc\u7387\u548c\u826f\u597d\u7684\u7535\u6781\u6da6\u6e7f\u6027\u800c\u88ab\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u4f46\u7531\u4e8e\u5176\u6613\u71c3&#8230;<\/p>\n","protected":false},"author":34419,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,4,2],"tags":[3135,2613,4929],"class_list":["post-242619","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-ganhuo","category-keji","tag-3135","tag-2613","tag-4929"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/242619"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/34419"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=242619"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/242619\/revisions"}],"predecessor-version":[{"id":242853,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/242619\/revisions\/242853"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=242619"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=242619"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=242619"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}