{"id":242183,"date":"2022-09-17T08:10:36","date_gmt":"2022-09-17T00:10:36","guid":{"rendered":"\/\/m.iemloyee.com\/?p=242183"},"modified":"2022-09-16T17:11:07","modified_gmt":"2022-09-16T09:11:07","slug":"%e6%b1%89%e9%98%b3%e5%a4%a7%e5%ad%a6nat-energy%ef%bc%9a%e5%b0%86%e9%ab%98%e4%bb%b7%e5%85%83%e7%b4%a0%e5%bc%95%e5%85%a5%e5%ae%9e%e7%94%a8%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e7%9a%84%e6%97%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=242183","title":{"rendered":"\u6c49\u9633\u5927\u5b66Nat. Energy\uff1a\u5c06\u9ad8\u4ef7\u5143\u7d20\u5f15\u5165\u5b9e\u7528\u9502\u79bb\u5b50\u7535\u6c60\u7684\u65e0\u94b4\u5c42\u72b6\u6b63\u6781"},"content":{"rendered":"<p>\u4f5c\u8005\uff1a\u91d1\u7235<\/p>\n<p><strong>\u4e00\u3001\u5bfc\u8bfb<\/strong><\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0\u9502\u7535\u6c60\u662f\u4e00\u7c7b\u7531\u9502\u91d1\u5c5e\u6216\u9502\u5408\u91d1\u4e3a\u8d1f\u6781\u6750\u6599\u3001\u4f7f\u7528\u975e\u6c34\u7535\u89e3\u8d28\u6eb6\u6db2\u7684\u7535\u6c60\u3002\u9502\u7535\u6c60\u5728\u4f20\u7edf\u9886\u57df\u4e3b\u8981\u5e94\u7528\u4e8e\u6570\u7801\u4ea7\u54c1\uff0c\u5728\u65b0\u5174\u9886\u57df\u4e3b\u8981\u7528\u4e8e\u52a8\u529b\u7535\u6c60\u3001\u50a8\u80fd\u9886\u57df\u3002\u8fd1\u5e74\u6765\uff0c\u6211\u56fd\u9502\u7535\u6c60\u4ea7\u91cf\u9010\u5e74\u589e\u957f\u3002\u672a\u6765\uff0c\u968f\u7740\u5168\u7403\u65b0\u80fd\u6e90\u4ea7\u4e1a\u7684\u53d1\u5c55\uff0c\u7535\u52a8\u8f66\u9010\u6e10\u6210\u4e3a\u9502\u7535\u6c60\u7684\u5927\u9700\u6c42\u4ea7\u4e1a\uff0c\u56e0\u6b64\u52a8\u529b\u9502\u7535\u6c60\u6210\u4e3a\u9502\u7535\u6c60\u4ea7\u4e1a\u9700\u6c42\u589e\u957f\u7684\u96c6\u4e2d\u9886\u57df\u3002<\/p>\n<p><strong>\u4e8c\u3001\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0\u968f\u7740\u94b4\u53d8\u5f97\u8d8a\u6765\u8d8a\u7a00\u7f3a\uff0c\u4ece\u5bcc\u954d\u5c42\u72b6\u6b63\u6781\u4e2d\u53bb\u9664\u94b4\u88ab\u8ba4\u4e3a\u662f\u964d\u4f4e\u5176\u6750\u6599\u6210\u672c\u548c\u9502\u79bb\u5b50\u7535\u6c60 (LIB) \u53ef\u6301\u7eed\u53d1\u5c55\u7684\u4f18\u5148\u4e8b\u9879\u3002\u5c06 1 mol% Mo \u5f15\u5165 Li(Ni<sub>0.9<\/sub>Mn<sub>0.1<\/sub> )O<sub>2<\/sub>\u53ef\u5728 4.4V \u4e0b\u63d0\u4f9b 234 mAh g <sup>-1<\/sup>\u3002\u5177\u6709 Li(Ni<sub>0.89<\/sub>Mn<sub>0.1<\/sub>Mo<sub>0.01<\/sub> )O<sub>2<\/sub> (Mo- NM90) \u9634\u6781\u901a\u8fc7\u6539\u6027\u7535\u89e3\u8d28\u5faa\u73af\u7a33\u5b9a\u6027\u5f97\u5230\u589e\u5f3a\uff1b\u5728 1,000 \u6b21\u5faa\u73af\u540e\u4fdd\u6301 86% \u7684\u521d\u59cb\u5bb9\u91cf\uff0c\u540c\u65f6\u63d0\u4f9b 880 Wh kg<sub>cathode<\/sub><sup>-1<\/sup>. \u901a\u8fc7 Mo \u63ba\u6742\u5b9e\u73b0\u7684\u6676\u7c92\u7ec6\u5316\u901a\u8fc7\u65ad\u88c2\u589e\u97e7\u548c\u6d88\u9664\u5c40\u90e8\u6210\u5206\u4e0d\u5747\u5300\u6027\u6d88\u9664\u4e86\u6676\u683c\u7a81\u7136\u6536\u7f29\u9020\u6210\u7684\u6709\u5bb3\u5e94\u53d8\u3002Mo<sup>6+<\/sup>\u7684\u5b58\u5728\u5f15\u8d77\u7684\u589e\u5f3a\u7684\u9633\u79bb\u5b50\u6392\u5e8f\uff0c\u4e5f\u901a\u8fc7\u67f1\u6548\u5e94\u7a33\u5b9a\u4e86\u8131\u9502\u7ed3\u6784\u3002Mo-NM90\u6b63\u6781\u80fd\u591f\u4ee5\u8f83\u4f4e\u7684\u6750\u6599\u6210\u672c\u63d0\u4f9b\u9ad8\u5bb9\u91cf\u548c\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u9002\u5408\u7535\u52a8\u6c7d\u8f66\u7684\u957f\u5bff\u547d\u4f7f\u7528\uff0c\u8fdb\u4e00\u6b65\u5b9e\u73b0\u4e86\u5546\u4e1a\u4e0a\u53ef\u884c\u7684LIBs\u65e0\u94b4\u6b63\u6781\u3002<\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0\u6765\u81ea\u97e9\u56fd\u9996\u5c14\u6c49\u9633\u5927\u5b66\u80fd\u6e90\u5de5\u7a0b\u7cfb\u548c\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\uff0c\u4f5c\u8005\u4e3aGeon-Tae Park\u200a, Been Namkoong, Su-Bin Kim\u7b49\uff0c\u4ee5\u9898\u76ee\u4e3a\uff1a\u201cIntroducing high-valence elements into cobalt-free layered cathodes for practical lithium-ion batteries\u201d\uff0c\u53d1\u8868\u5728Nature Energy\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-242184\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/0-4.png\" alt=\"\" width=\"1260\" height=\"506\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/0-4.png 1260w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/0-4-300x120.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/0-4-768x308.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/0-4-1024x411.png 1024w\" sizes=\"(max-width: 1260px) 100vw, 1260px\" \/><\/p>\n<p><strong>\u4e09\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0\u5728\u8fd9\u9879\u7814\u7a76\u4e2d\uff0c\u7740\u91cd\u5206\u6790 Co \u5728\u5178\u578b\u7684\u65e0 Co\u3001\u5bcc\u954d\u5c42\u72b6 NM90 \u9634\u6781\u4e2d\u7684\u4f5c\u7528\u3002 \u63d0\u51fa\u4e86\u4e00\u79cd\u5c06NM90\u6b63\u6781\u7684\u8131\u9502\u7ed3\u6784\u7a33\u5b9a\u57284.4V\u7684\u65b9\u6cd5\u3002\u5373\u5728\u6b63\u6781\u4e2d\u5f15\u5165\u7b2c\u4e09\u5143\u7d20\u5e76\u7ed3\u5408\u7535\u89e3\u8d28\u7684\u6539\u6027\u3002\u4e3a\u4e86\u7cfb\u7edf\u7406\u89e3\u63ba\u6742\u4e0d\u540c\u6c27\u5316\u6570\u7684\u65e0\u94b4 NM90 \u9634\u6781\uff0c\u6d4b\u8bd5\u4e86\u4e00\u7cfb\u5217\u63ba\u6742\u5143\u7d20\uff08Co<sup>3+<\/sup>\u3001Al<sup>3+<\/sup>\u3001Ti<sup>4+<\/sup>\u3001Nb<sup>5+<\/sup>\u3001Ta<sup>5+<\/sup>\u3001W<sup>6+<\/sup> \u548c Mo<sup>6+<\/sup>\uff09\u3002<\/p>\n<p><strong>\u56db\u3001\u6570\u636e\u6982\u8bba<\/strong><\/p>\n<p>\u56fe1.\u672a\u63ba\u6742\u548c\u63ba\u6742 NM90 \u9634\u6781\u7684\u534a\u7535\u6c60\u5177\u6709\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u00a92022 Nature Energy<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-242185\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/1-11.png\" alt=\"\" width=\"1118\" height=\"847\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/1-11.png 1118w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/1-11-300x227.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/1-11-768x582.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/1-11-1024x776.png 1024w\" sizes=\"(max-width: 1118px) 100vw, 1118px\" \/><\/p>\n<p>\u56fe2. \u672a\u63ba\u6742\u548c\u63ba\u6742 NM90 \u9634\u6781\u7684\u521d\u7ea7\u7c92\u5b50\u5f62\u6001\u6bd4\u8f83\u3002\u00a92022 Nature Energy<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-242186\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/2-9.png\" alt=\"\" width=\"1012\" height=\"546\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/2-9.png 1012w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/2-9-300x162.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/2-9-768x414.png 768w\" sizes=\"(max-width: 1012px) 100vw, 1012px\" \/><\/p>\n<p>\u56fe3. NM90\u9634\u6781\u7684\u7ed3\u6784\u4e0d\u7a33\u5b9a\u6027\u8868\u5f81\u3002\u00a92022 Nature Energy<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-242187\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/3-8.png\" alt=\"\" width=\"1342\" height=\"542\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/3-8.png 1342w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/3-8-300x121.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/3-8-768x310.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/3-8-1024x414.png 1024w\" sizes=\"(max-width: 1342px) 100vw, 1342px\" \/><\/p>\n<p>\u56fe4. \u65e0Co Mo-NM90 \u6b63\u6781\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u00a92022 Nature Energy<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-242188\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/4-8.png\" alt=\"\" width=\"920\" height=\"686\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/4-8.png 920w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/4-8-300x224.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/4-8-768x573.png 768w\" sizes=\"(max-width: 920px) 100vw, 920px\" \/><\/p>\n<p>\u56fe5. \u5177\u6709\u672a\u63ba\u6742\u548c\u63ba\u6742\u65e0Co NM90 \u9634\u6781\u7684\u5168\u7535\u6c60\u957f\u671f\u5faa\u73af\u6027\u80fd\u6bd4\u8f83\u4ee5\u53ca\u6027\u80fd\u6d4b\u8bd5\u540e\u7684\u8bc4\u4f30\u5206\u6790\u00a92022 Nature Energy<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-242189\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/5-4.png\" alt=\"\" width=\"728\" height=\"866\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/5-4.png 728w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/09\/5-4-252x300.png 252w\" sizes=\"(max-width: 728px) 100vw, 728px\" \/><\/p>\n<p><strong>\u4e94\u3001\u6210\u679c\u5c55\u793a<\/strong><\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0\u672c\u7814\u7a76\u8868\u660e\uff0c\u5c06Mo\u5f15\u5165NM90 \u6b63\u6781\u5e76\u4f34\u968f\u5c06\u4e0a\u9650\u622a\u6b62\u7535\u538b\u63d0\u9ad8\u5230 4.4V\uff08\u76f8\u5bf9\u4e8e Li+\/Li\uff09\uff0c\u6709\u52a9\u4e8e\u5b9e\u73b0\u534a\u7535\u6c60\u7684\u5236\u4f5c\uff0c\u63d0\u4f9bLi(Ni<sub>x<\/sub>Co<sub>y<\/sub>Mn<sub>1<\/sub><sub>\u2212<\/sub><sub>x<\/sub><sub>\u2212<\/sub><sub>y<\/sub>)O<sub>2<\/sub>(NCM)\u4e0eNi\u542b\u91cf\u76f8\u4f3c\u7684\u5bb9\u91cf\u3002\u6b64\u5916\uff0cMo-NM90 \u5168\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u5f97\u5230\u63d0\u5347\uff0c\u662f\u901a\u8fc7\u6539\u8fdb\u7535\u89e3\u8d28\u4f7f\u5176\u4e0e 4.3V \u7684\u5de5\u4f5c\u622a\u6b62\u7535\u538b\uff08\u76f8\u5bf9\u4e8e\u77f3\u58a8\uff09\u517c\u5bb9\uff0c\u4ece\u800c\u6210\u529f\u63d0\u9ad8\u4e86\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u6240\u63d0\u51fa\u7684 Mo-NM90 \u7684\u8d85\u7ec6\u7ed3\u6784\u901a\u8fc7\u65ad\u88c2\u589e\u97e7\u548c\u6d88\u9664\u5c40\u90e8\u6210\u5206\u4e0d\u5747\u5300\u6027\u6765\u6291\u5236\u5fae\u88c2\u7eb9\u7684\u5f62\u6210\u3002 Mo<sup>6+<\/sup> \u7684\u5b58\u5728\u589e\u5f3a\u7684\u9633\u79bb\u5b50\u6392\u5e8f\u4e5f\u7a33\u5b9a\u4e86\u8131\u9502\u7ed3\u6784\u3002\u7531\u4e8e\u63d0\u53d6\u4e0d\u5747\u5300\uff0c\u8be5\u7ed3\u6784\u6700\u5bb9\u6613\u53d7\u5230\u653b\u51fbLi<sup>+<\/sup> \u79bb\u5b50\u3002\u5728\u5168\u7535\u6c60\u4e2d\uff0c10%\u7684\u6c1f\u4ee3\u78b3\u9178\u4e9a\u4e59\u916f\uff08EF91\uff09\u7535\u89e3\u8d28\u901a\u8fc7\u4fc3\u8fdb\u5bcc LiF \u5c42\u7684\u5f62\u6210\u548c\u6291\u5236\u6750\u6599\u6eb6\u89e3\u6765\u4fdd\u62a4\u9634\u6781\u8868\u9762\uff0c\u4ece\u800c\u4f7f\u7535\u6c60\u80fd\u591f\u5728 4.3V \u7684\u622a\u6b62\u7535\u538b\uff08\u76f8\u5bf9\u4e8e\u77f3\u58a8\uff09\u4e0b\u5b9e\u73b0\u957f\u671f\u5faa\u73af\u3002\u8bc1\u5b9e\u4e86 Mo-NM90 \u5168\u7535\u6c60\u7684\u957f\u671f\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u4ee5\u786e\u4fdd\u6240\u63d0\u51fa\u7684 Mo-NM90 \u9002\u7528\u4e8e\u7535\u52a8\u6c7d\u8f66\u7684 LIB\u3002\u8be5\u7814\u7a76\u63d0\u4f9b\u4e86\u5bf9\u94b4\u5728\u5bcc\u954d\u5c42\u72b6\u9634\u6781\u4e2d\u7684\u4f5c\u7528\u7684\u57fa\u672c\u89c1\u89e3\uff0c\u5e76\u4f7f\u8be5\u9886\u57df\u66f4\u63a5\u8fd1\u4e8e\u5b9e\u73b0\u5546\u4e1a\u4e0a\u53ef\u884c\u7684\u65e0\u94b4\u3001\u5bcc\u954d\u5c42\u72b6\u9634\u6781\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e<\/p>\n<p>Park, GT., Namkoong, B., Kim, SB. et al. Introducing high-valence elements into cobalt-free layered cathodes for practical lithium-ion batteries. Nat Energy (2022).<\/p>\n<p>\u6587\u732e\u94fe\u63a5<\/p>\n<p>https:\/\/www.nature.com\/articles\/s41560-022-01106-6<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4f5c\u8005\uff1a\u91d1\u7235 \u4e00\u3001\u5bfc\u8bfb \u00a0 \u00a0 \u00a0 \u00a0\u9502\u7535\u6c60\u662f\u4e00\u7c7b\u7531\u9502\u91d1\u5c5e\u6216\u9502\u5408\u91d1\u4e3a\u8d1f\u6781\u6750\u6599\u3001\u4f7f\u7528\u975e\u6c34\u7535\u89e3\u8d28\u6eb6\u6db2\u7684\u7535\u6c60\u3002\u9502\u7535\u6c60\u5728\u4f20\u7edf\u9886\u57df\u4e3b\u8981\u5e94\u7528\u4e8e\u6570\u7801\u4ea7\u54c1\uff0c\u5728\u65b0\u5174\u9886\u57df\u4e3b\u8981\u7528\u4e8e\u52a8\u529b&#8230;<\/p>\n","protected":false},"author":35611,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-242183","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/242183"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/35611"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=242183"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/242183\/revisions"}],"predecessor-version":[{"id":242354,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/242183\/revisions\/242354"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=242183"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=242183"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=242183"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}