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\u4e00 \u00a0<\/strong>\u5bfc\u8bfb<\/strong><\/p>\n

\u201c\u5355\u6676\u5230\u5355\u6676\u7684\u8f6c\u53d8\u201d\u6307\u7684\u662f\u901a\u8fc7\u4e00\u7cfb\u5217\u65b9\u6cd5\u6539\u53d8\u539f\u5b50\u7279\u6027\u548c\/\u6216\u6750\u6599\u7ed3\u6784\uff0c\u540c\u65f6\u4fdd\u6301\u957f\u7a0b\u7ed3\u6676\u6027\u80fd\u3002\u8fd9\u79cd\u540e\u5408\u6210\u65b9\u6cd5\u53ef\u4ee5\u63d0\u4f9b\u6b63\u5e38\u5408\u6210\u8def\u5f84\u65e0\u6cd5\u5b9e\u73b0\u7684\u65b0\u6027\u80fd\uff0c\u6bd4\u5982\u5149\u3001\u78c1\u3001\u7ed3\u6784\u53ca\u673a\u68b0\u7279\u6027\u3002\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u662f\u4e00\u79cd\u53ef\u5b9e\u73b0\u5355\u6676\u5230\u5355\u6676\u8f6c\u53d8\u7684\u6709\u8da3\u6750\u6599\uff0c\u5176\u591a\u5b54\u7279\u6027\u6709\u5229\u4e8e\u901a\u8fc7\u7269\u7406\u6355\u83b7\u3001\u4e0e\u91d1\u5c5e\u8282\u70b9\u7684\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u800c\u5728\u5185\u8154\u4e2d\u4ea4\u6362\u6eb6\u5242\u3001\u91d1\u5c5e\u79bb\u5b50\u7b49\u5ba2\u4f53\u3002\u800c\u4e14\uff0cMOFs\u7ed3\u6784\u7684\u52a8\u6001\u53d8\u5316\u5df2\u7ecf\u88ab\u8bc1\u5b9e\u53ef\u4ee5\u5b9e\u73b0\uff0c\u8be5\u8fc7\u7a0b\u6d89\u53ca\u6574\u4e2a\u6846\u67b6\u7684\u7075\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u4e4b\u95f4\u7684\u826f\u597d\u5e73\u8861\u3002\u76ee\u524d\uff0c\u901a\u8fc7\u8fc7\u6e21\u91d1\u5c5e\u548c\u542b\u6709\u7fa7\u9178\u914d\u4f4d\u4f4d\u70b9\u7684\u8054\u63a5\u6865\u7ec4\u5408\uff0c\u5df2\u7ecf\u5b9e\u73b0\u4e86\u91d1\u5c5e\u79bb\u5b50\u8f6c\u6362\uff0c\u5176\u6240\u7528\u8054\u63a5\u6865\u901a\u5e38\u4e3a\u786c\u914d\u4f53\u3002\u7136\u800c\uff0c\u8fd9\u79cd\u4ea4\u6362\u8fc7\u7a0b\u5728\u57fa\u4e8e\u91d1\u5c5e-\u5421\u5576\u914d\u4f4d\u7684MOF\u4e2d\u975e\u5e38\u5c11\u89c1\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u8be5\u79cd\u914d\u4f53\u573a\u5f3a\u9002\u4e2d\uff0c\u8fd9\u79cd\u7c7b\u578b\u7684MOFs\u5df2\u77e5\u53ef\u4ee5\u8fdb\u884c\u914d\u4f53\u4ea4\u6362\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u6750\u6599\u662f\u5426\u80fd\u591f\u5728MOFs\u9aa8\u67b6\u5b8c\u6574\u7684\u60c5\u51b5\u4e0b\u8fdb\u884c\u5b9a\u91cf\u7684\u91d1\u5c5e\u9633\u79bb\u5b50\u4ea4\u6362\u5e76\u4e0d\u6e05\u695a\u3002\u7531\u4e8e\u914d\u4f53\u4e0d\u7a33\u5b9a\uff0c\u8fdb\u884c\u91d1\u5c5e\u9633\u79bb\u5b50\u4ea4\u6362\u65f6\uff0c\u6676\u4f53\u7ed3\u6784\u53ef\u80fd\u5d29\u584c\u3002<\/p>\n

 <\/p>\n

\u4e8c <\/strong>\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n

 <\/p>\n

\u6700\u8fd1\uff0c\u9b4f\u8328\u66fc\u79d1\u5b66\u7814\u7a76\u6240\u7684Dan Oron\u7b49\u4eba\u57fa\u4e8e\u56db\u9762\u4f53\u5421\u5576\u914d\u4f53\u548c\u9530\u5408\u6210\u4e86Mn\u57faMOFs\uff0c\u5c06\u5176\u4e0e\u91d1\u5c5e\u6c2f\u5316\u7269\u76d0\uff08MCl2<\/sub>, M=Fe2+<\/sup>, Co2+<\/sup>, Ni2+<\/sup>, Cu2+<\/sup>, Zn2+<\/sup>\uff09\u7684\u7532\u9187\u6eb6\u6db2\u6df7\u5408\u540e\u53d1\u751f\u4e86\u91d1\u5c5e\u9633\u79bb\u5b50\u4ea4\u6362\uff0c\u751f\u6210\u4e86\u65b0\u7684\u91d1\u5c5e\u57faMOFs\uff0c\u5176\u5177\u6709\u4e24\u4e2a\u4e0d\u540c\u7684\u7eb3\u7c73\u901a\u9053\uff0c\u4f46\u662f\u4fdd\u7559\u4e86\u539f\u6765\u7684Mn\u57faMOFs\u76f8\u540c\u7684\u7ed3\u6676\u5f62\u6001\u548c\u5c3a\u5bf8\u3002\u5206\u6790\u8868\u660e\uff0cMn\u4e2d\u5fc3\u4e0e\u4e0a\u8ff0\u91d1\u5c5e\u76d0\u8fdb\u884c\u4e86\u5b9a\u91cf\u4ea4\u6362(>99.4%)\u3002<\/p>\n

\u6b64\u5916\uff0c\u8be5\u79cdMofs\u8fd8\u53ef\u4ee5\u8fdb\u884c\u4eceMn2+<\/sup>\u5230Co2+<\/sup>\u5230Cu2+<\/sup>\u7684\u8fde\u7eed\u4ea4\u6362\uff0c\u4ecd\u65e7\u4fdd\u6301\u4e86\u539f\u59cb\u7684\u7ed3\u6676\u5f62\u6001\u548c\u6676\u578b\u5806\u79ef\u3002\u7531\u4e8e\u6676\u4f53\u7ed3\u6784\u3001\u51e0\u4f55\u5f62\u72b6\u548c\u5c3a\u5bf8\u76f8\u4f3c\uff0c\u53ef\u4ee5\u76f4\u63a5\u5bf9\u4e0d\u540c\u91d1\u5c5e\u79bb\u5b50\u7684MOFs\u8fdb\u884c\u6574\u4f53\u548c\u5355\u6676\u5c3a\u5ea6\u6027\u80fd\u6bd4\u8f83\uff0c\u5305\u62ec\u5149\u5b66\u6027\u80fd\u548c\u78c1\u6027\u80fd\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201c<\/strong>Directing the Morphology, Packing, and Properties of Chiral Metal\u2013 Organic Frameworks by Cation Exchange<\/strong>\u201d<\/strong>\u53d1\u8868\u5728\u56fd\u9645\u671f\u520aAngewandte Chemie International Edition<\/strong><\/em>\u4e0a\u3002<\/p>\n

 <\/p>\n

\u4e09 <\/strong>\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n

\u57fa\u4e8e\u91d1\u5c5e-\u56db\u9762\u4f53\u5421\u5576\u914d\u4f4d\u7684MOFs\uff0c\u5728\u4fdd\u6301MOFs\u9aa8\u67b6\u5b8c\u6574\u7684\u60c5\u51b5\u4e0b\u5b9e\u73b0\u4e86\u5b9a\u91cf\u7684\u91d1\u5c5e\u9633\u79bb\u5b50\u4ea4\u6362\uff0c\u540c\u65f6\u4fdd\u7559\u5176\u7ed3\u6676\u5ea6\u548c\u6676\u4f53\u5f62\u6001\u3002<\/p>\n

 <\/p>\n

\u56db <\/strong>\u6570\u636e\u6982\u89c8<\/strong><\/p>\n

\u00a0\"\"<\/p>\n

\u53cd\u5e94\u8def\u7ebf1<\/strong> \u56db\u9762\u4f53\u5421\u5576\u914d\u4f53AdDB\u4e0e\u4e0d\u540c\u7684\u4e00\u7ea7\u8fc7\u5ea6\u91d1\u5c5e\u76d0\u901a\u8fc7\u6eb6\u5242\u5206\u5c42\u53cd\u5e94\uff08\u4e0a\u9762\u4e00\u884c\uff09\u3002\u4ece\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\uff08Mn-AdDB\uff09\u8fdb\u884c\u9633\u79bb\u5b50\u4ea4\u6362\uff0c\u4fdd\u6301\u4e86\u5f62\u6001\u7684\u5747\u4e00\u6027\uff08\u4e0b\u9762\u4e00\u884c\uff09\u00a92022 The Authors<\/p>\n

\"\"<\/p>\n

\u56fe1<\/strong> \u00a0Mn-AdDB\u7684\u5149\u5b66\u663e\u5fae\u955c\u56fe\u8c31\uff08\u5de6\uff09\u548cSEM\u56fe\u8c31\uff08\u53f3\uff09\u00a92022 The Authors<\/p>\n

\"\"<\/p>\n

\u56fe2 <\/strong>Mn-AdDB\u548c\u901a\u8fc7\u91d1\u5c5e\u9633\u79bb\u5b50\u4ea4\u6362\u5f62\u6210\u7684\u4e94\u79cd\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff08M2+<\/sup>\uff1dFe2+<\/sup>\u3001Co2+<\/sup>\u3001Ni2+<\/sup>\u3001Cu2+<\/sup>\u3001Zn2+<\/sup>\uff09\u7684\u5355\u6676X\u5c04\u7ebf\u884d\u5c04\u6570\u636e \u00a92022 The Authors<\/p>\n

\"\"<\/p>\n

\u56fe3 <\/strong>SEM\u56fe\u50cf \u4e0a\u9762\u4e00\u884c\uff1a\u56db\u9762\u4f53\u5421\u5576\u914d\u4f53AdDB\u548c\u91d1\u5c5e\u4e8c\u6c2f\u5316\u7269\u76d0\u901a\u8fc7\u6eb6\u5242\u5206\u5c42\u53cd\u5e94\u5f97\u5230\u7684\u7ed3\u6784\uff1b\u4e0b\u9762\u4e00\u884c\uff1a\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6Mn-AdDB\u4e0e\u91d1\u5c5e\u76d0\u7684\u7532\u9187\u6eb6\u6db2\u53cd\u5e94\u540e\u5f97\u5230\u7684\u7ed3\u6784\uff0cMCl2<\/sub>, M=Fe2+<\/sup>, Co2+<\/sup>, Ni2+<\/sup>, Cu2+<\/sup>, Zn2+<\/sup>. \u6bd4\u4f8b\u5c3a=2 \u03bcm. \u00a92022 The Authors<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe4<\/strong> \u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u6700\u5f00\u59cb\u7684\u989c\u8272\uff08\u5de6\u4fa7\u7ba1\uff09\uff1b\u4ee5\u53caMn-AdDB\u4e0e\u542b\u91d1\u5c5e\u76d0\u7684\u7684\u7532\u9187\u6eb6\u6db2\u63a5\u89e6\u540e\u7684\u989c\u8272\uff08MCl2<\/sub>, M= Fe2+<\/sup>, Co2+<\/sup>, Ni2+<\/sup>, Cu2+<\/sup>, Zn2+<\/sup>\uff09. \u00a92022 The Authors<\/p>\n

\"\"<\/p>\n

\u56fe5<\/strong> A) Mn-AdDB\u8fdb\u884c\u663e\u5fae\u5207\u7247\uff0c\u6d82\u8986\u8584\u5c42\u91d1\u5c5e\u94f1\uff0c\u7136\u540e\u8fdb\u884cEDS\u626b\u63cf\u7684\u8fc7\u7a0b\uff1bB) \u6676\u4f53\u4e2d\u9530\u4e0e\u94dc\u7684\u76f8\u5bf9\u91cf\u968f\u65f6\u95f4\u53d8\u5316\u7684\u66f2\u7ebf\u56fe;C) \u6676\u4f53\u5185\u91d1\u5c5e\u9633\u79bb\u5b50\u542b\u91cf\u968f\u65f6\u95f4\u53d8\u5316\u7684EDS\u5143\u7d20\u5f3a\u5ea6\u56fe\u00a92022 The Authors<\/p>\n

\"\"<\/p>\n

\u56fe6 <\/strong>\u00a0Mn-AdDB\u5230Co-AdDB\u518d\u5230Cu-AdDB\u7684\u8fde\u7eed\u9633\u79bb\u5b50\u4ea4\u6362\u7684\u5149\u5b66\u663e\u5fae\u955c\u56fe\u8c31\u3002\u00a92022 The Authors<\/p>\n

\u63d2\u56fe\u663e\u793a\u4e86\u5355\u6676X\u5c04\u7ebf\u884d\u5c04\uff08SCXRD\uff09\u5206\u6790\u7684\u91d1\u5c5e\u914d\u4f4d\u8282\u70b9\uff0c\u9ec4\u8272\u662fMn\uff0c\u7c89\u8272\u662fCo\uff0c\u7eff\u8272\u662fCu\uff0c\u84dd\u8272\u662fCl\uff0c\u7d2b\u8272\u662fN\uff0c\u7070\u8272\u662fC\uff0c\u6bd4\u4f8b\u5c3a\u662f50\u03bcm<\/p>\n

\"\"<\/p>\n

\u56fe7 <\/strong>\u00a0Mn-AdDB, Fe-AdDB, Co-AdDB, Ni-AdDB, Cu-AdDB, Zn-AdDB\u548cAdDB\u7684\u5149\u5b66\u548c\u78c1\u6027\u80fd\u00a92022 The Authors<\/p>\n

 <\/p>\n

\u4e94 <\/strong>\u6210\u679c\u542f\u793a<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aDirecting the Morphology, Packing, and Properties of Chiral Metal\u2013Organic Frameworks by Cation Exchange** – Nasi – 2022 – Angewandte Chemie – Wiley Online Library<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00 \u00a0\u5bfc\u8bfb \u201c\u5355\u6676\u5230\u5355\u6676\u7684\u8f6c\u53d8\u201d\u6307\u7684\u662f\u901a\u8fc7\u4e00\u7cfb\u5217\u65b9\u6cd5\u6539\u53d8\u539f\u5b50\u7279\u6027\u548c\/\u6216\u6750\u6599\u7ed3\u6784\uff0c\u540c\u65f6\u4fdd\u6301\u957f\u7a0b\u7ed3\u6676\u6027\u80fd\u3002\u8fd9\u79cd\u540e\u5408\u6210\u65b9\u6cd5\u53ef\u4ee5\u63d0\u4f9b\u6b63\u5e38\u5408\u6210\u8def\u5f84\u65e0\u6cd5\u5b9e\u73b0\u7684\u65b0\u6027\u80fd\uff0c\u6bd4\u5982\u5149…<\/p>\n","protected":false},"author":39305,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-242037","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/242037"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/39305"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=242037"}],"version-history":[{"count":5,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/242037\/revisions"}],"predecessor-version":[{"id":242083,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/242037\/revisions\/242083"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=242037"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=242037"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=242037"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}