{"id":242017,"date":"2022-09-09T09:02:23","date_gmt":"2022-09-09T01:02:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=242017"},"modified":"2022-09-08T17:48:34","modified_gmt":"2022-09-08T09:48:34","slug":"%e8%8b%8f%e5%b7%9e%e5%a4%a7%e5%ad%a6%e9%98%bf%e5%be%b7%e8%8e%b1%e5%be%b7%e5%a4%a7%e5%ad%a6nat-commun%ef%bc%9aco2-rr%e8%bf%87%e7%a8%8b%e4%b8%ad%e7%9a%84%e9%86%87%e5%90%88%e6%88%90%e6%96%b0%e7%ad%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=242017","title":{"rendered":"\u82cf\u5dde\u5927\u5b66&\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66Nat Commun\uff1aCO2 RR\u8fc7\u7a0b\u4e2d\u7684\u9187\u5408\u6210\u65b0\u7b56\u7565"},"content":{"rendered":"

\u5bfc\u8bfb<\/strong><\/p>\n

\u7531\u53ef\u518d\u751f\u80fd\u6e90\u9a71\u52a8\u7684\u7535\u5316\u5b66 CO2<\/sub> \u8fd8\u539f\u53cd\u5e94\u751f\u4ea7\u9ad8\u9644\u52a0\u503c\u7684\u5316\u5b66\u71c3\u6599\u548c\u539f\u6599\uff0c\u662f\u5b9e\u73b0\u4eba\u7c7b\u7684\u78b3\u4e2d\u548c\u76ee\u6807\u7684\u4e00\u5927\u8fdb\u6b65\u3002\u94dc\u548c\u94dc\u57fa\u5316\u5408\u7269\u7531\u4e8e\u5176\u5408\u9002\u7684\u4e2d\u95f4\u4f53\u7ed3\u5408\u80fd\u91cf\u5b66\u5141\u8bb8\u4e32\u8054\u53cd\u5e94\u7ea7\u8054\u88ab\u8ba4\u4e3a\u5728\u751f\u4ea7\u6df1\u5ea6\u8fd8\u539f\u7684\u591a\u7535\u5b50\u4ea7\u54c1\u65b9\u9762\u975e\u5e38\u6709\u6548\uff1b\u4e59\u9187\u548c\u6b63\u4e19\u9187\u5177\u6709\u5f88\u9ad8\u7684\u5de5\u4e1a\u548c\u7ecf\u6d4e\u4f18\u52bf\uff0c\u4f46\u5176\u9634\u6781\u8868\u9762\u7684\u9ad8\u5ea6\u8fd8\u539f\u73af\u5883\uff0c\u4f7f\u5f97\u542b\u6c27\u4e2d\u95f4\u4f53\u96be\u4ee5\u505c\u7559\uff0c\u8d85\u51fa\u4e86 C-C \u8026\u5408\u7684\u7535\u4f4d\uff0c\u4f7f\u5f97\u5176\u5f88\u96be\u4ee5\u9ad8\u4ea7\u7387\u548c\u9009\u62e9\u6027\u83b7\u5f97\u3002<\/p>\n

\u6210\u679c\u80cc\u666f<\/strong><\/p>\n

\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e00\u96be\u9898\uff0c\u82cf\u5dde\u5927\u5b66\u5f6d\u626c\u6559\u6388\u548c\u9093\u662d\u6559\u6388\u8054\u5408\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u989c\u5a07\u6559\u6388\u4e3a\u5171\u540c\u901a\u8baf\u4f5c\u8005\u5728\u201cNATURE COMMUNICATIONS<\/em><\/strong>\u201d\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cElectrocatalytic CO2<\/sub>\u00a0reduction to alcohols by modulating the molecular geometry and Cu coordination in bicentric copper complexes\u201d\u7684\u6587\u7ae0\uff0c\u4ed6\u4eec\u9009\u62e9\u4e86\u4e09\u4e2a\u57fa\u4e8e\u6269\u5c55\u548c\u6c1f\u5316\u535f\u5549\u7ed3\u6784\u4f46\u4e0d\u540c\u7684\u5206\u5b50\u548c\u914d\u4f4d\u51e0\u4f55\u5f62\u72b6\u7684\u53cc\u4e2d\u5fc3\u94dc\u914d\u5408\u7269\u6765\u8bf4\u660e\u591a\u76f8\u5206\u5b50\u50ac\u5316\u5242\u5728 CO2<\/sub>RR \u4e2d\u7684\u7ed3\u6784\u6027\u80fd\u76f8\u5173\u6027\u3002\u5728\u5b9e\u9a8c\u548c\u7406\u8bba\u4e2d\u53d1\u73b0\uff0c\u539f\u4f4d\u751f\u6210\u7684\u94dc\u7c07\u548c\u90e8\u5206\u8fd8\u539f\u7684\u5206\u5b50\u5e95\u7269\u5728\u534f\u540c\u751f\u4ea7\u542b\u6c27\u5316\u5408\u7269\u65b9\u9762\u5177\u6709\u5f88\u5f3a\u7684\u534f\u540c\u4f5c\u7528\uff0c\u901a\u8fc7\u8c03\u8282\u53cc\u4e2d\u5fc3\u94dc\u914d\u5408\u7269\u4e2d\u7684\u5206\u5b50\u51e0\u4f55\u5f62\u72b6\u548c\u94dc\u914d\u4f4d\u53ef\u4ee5\u5b9e\u73b0\u4e59\u9187\u548c\u6b63\u4e19\u9187\u7684\u9ad8\u8f6c\u5316\u7387\uff0c\u94dc\u7c07\u548c\u90e8\u5206\u8fd8\u539f\u7684\u542b\u6c27\u516d\u6c22\u535f\u5549\u914d\u4f53\u7684\u6df7\u5408\u7ed3\u6784\u5728\u5c06 CO2<\/sub> \u8f6c\u5316\u4e3a\u9187\u65b9\u9762\u53ef\u4ee5\u5b9e\u73b0\u9ad8\u8fbe 32.5% \u7684\u4e59\u9187\u548c 18.3% \u7684\u6b63\u4e19\u9187\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u3002<\/p>\n

\"\"<\/p>\n

\u5173\u952e\u521b\u65b0<\/strong><\/p>\n

1\u3001\u8bc1\u660e\u4e86\u94dc\u7c07\u548c\u90e8\u5206\u8fd8\u539f\u7684\u542b\u6c27\u516d\u6c22\u535f\u5549\u914d\u4f53\u7684\u6df7\u5408\u7ed3\u6784\u5728\u5c06 CO2<\/sub> \u8f6c\u5316\u4e3a\u9187\u65b9\u9762\u975e\u5e38\u6709\u6548\u3002<\/p>\n

2\u3001\u5f3a\u8c03\u4e86\u5229\u7528\u7ed3\u6784\u4f9d\u8d56\u6027\u7535\u5316\u5b66\u7279\u6027\u6765\u5f15\u5bfc CO2<\/sub> \u8fd8\u539f\u9014\u5f84\uff0c\u4ee5\u53ca\u901a\u8fc7\u6784\u5efa\u6709\u673a\/\u65e0\u673a Cu \u6742\u5316\u7269\u6765\u9776\u5411\u9187\u5408\u6210\u7684\u6f5c\u5728\u901a\u7528\u7b56\u7565\u3002<\/p>\n

3\u3001\u5c06CO2<\/sub>\u7535\u50ac\u5316\u8fd8\u539f\u6210\u5177\u6709\u9ad8\u7ecf\u6d4e\u4ef7\u503c\u7684\u9187\u4e3a\u5b9e\u73b0CO2<\/sub>\u8d44\u6e90\u5316\u5229\u7528\u63d0\u4f9b\u4e86\u4e00\u6761\u6709\u5e0c\u671b\u7684\u9014\u5f84\u3002<\/p>\n

\u6838\u5fc3\u6570\u636e\u89e3\u8bfb<\/strong>\"\"<\/strong>\u56fe 1\uff1a\u53cc\u4e2d\u5fc3\u81a8\u80c0\u535f\u5549\u590d\u5408\u7269\u7684\u7ed3\u6784\u548c\u8868\u5f81\u3002@NATURE COMMUNICATIONS<\/p>\n

a-c Hex-2Cu-O (a)\u3001Hex-2Cu-2O (b) \u548c Oct-2Cu (c) \u7684\u5206\u5b50\u7ed3\u6784\u548c\u7a7a\u95f4\u51e0\u4f55\u5f62\u72b6\u3002\u00a0 d Hex-2Cu-O\u3001Hex-2Cu-2O \u548c Oct-2Cu \u7684\u7d2b\u5916-\u53ef\u89c1\u5149\u8c31\u3002\u00a0 e XANES Cu K-edge \u548c f\u53c2\u8003Cu-TPP \u548c Cu \u7b94\u7684 Hex-2Cu-O\u3001Hex-2Cu-2O \u548c Oct-2Cu FT-EXAFS \u5149\u8c31\u3002\"\"\u56fe 2\uff1a\u7535\u50ac\u5316 CO2<\/sub>RR \u6027\u80fd\u3002@NATURE COMMUNICATIONS<\/p>\n

a-c Hex-2Cu-O (a)\u3001Hex-2Cu-2O (b) \u548c Oct-2Cu (c) \u4e0d\u540c\u7535\u4f4d\u4e0b\u5404\u79cd\u8fd8\u539f\u4ea7\u7269\u7684 FE\u3002\u00a0 d Hex-2Cu-O \u5728 -1.2\u2009V \u5904\u7684\u8ba1\u65f6\u7535\u6d41 i-t \u66f2\u7ebf\u968f\u4e59\u9187\u548c\u6b63\u4e19\u9187 FEs \u7684\u6f14\u53d8\u3002 \u8bef\u5dee\u68d2\u4ee3\u8868\u4e09\u4e2a\u72ec\u7acb\u6d4b\u91cf\u7684\u6807\u51c6\u504f\u5dee\u3002\"\"\u56fe3: \u5f02\u4f4d\u900f\u5c04\u7535\u955c\u56fe\u50cf\u548cXAS\u8fd0\u7b97\u3002@NATURE COMMUNICATIONS<\/p>\n

a Hex-2Cu-O\/KB\uff081:10 \u7a00\u91ca\uff09\u7684\u4ee3\u8868\u6027 HAADF-STEM \u56fe\u50cf\u663e\u793a\u5b58\u5728\u7528\u7ea2\u8272\u5706\u5708\u6807\u8bb0\u7684\u5b64\u7acb\u94dc\u5bf9\u3002\u00a0 b \u5728\u53cc\u539f\u5b50\u94dc\u5bf9\u4e4b\u4e00\u4e0a\u7ed8\u5236\u7684\u7ebf\u626b\u63cf\u5f3a\u5ea6\u5206\u5e03\u3002\u00a0 c, d Hex-2Cu-O\/KB \u5728 \u20131.2\u2009V \u4e0b\u7535\u89e3 10\u2009h \u540e\u7684\u9ad8\u5206\u8fa8\u7387 TEM (c) \u548c Cs-TEM (d) \u56fe\u50cf\u3002\u6bd4\u4f8b\u5c3a\uff0c2\u2009nm (a), 50\u2009nm (c) \u548c 2\u2009nm (d)\u3002\u00a0 e-j \u7535\u50ac\u5316 CO2<\/sub>RR \u6761\u4ef6\u4e0b\u7684\u539f\u4f4d XAS \u6d4b\u91cf\uff1aHex-2Cu-O\u3001Hex-2Cu-2O \u548cOct-2Cu \u7684 Cu K-edge XANES \u5149\u8c31 (e-g) \u548c\u5085\u91cc\u53f6\u53d8\u6362 Cu K-edge EXAFS \u5149\u8c31 (h-j)<\/p>\n

\"\"\u56fe 4\uff1aHex-2Cu-O \u751f\u4ea7\u4e59\u9187\u7684\u673a\u7406\u7814\u7a76\u3002@NATURE COMMUNICATIONS<\/p>\n

a\uff0cb CO2<\/sub>RR \u4ea7\u7269\u5206\u5e03\u548c\u76f8\u5e94\u7684 FEs \u5728\u4e59\u9187\u6d78\u6ce1\u53bb\u9664\u6709\u673a\u76f8\u540e\u4fdd\u7559\u5728\u7535\u6781\u4e0a\u7684 a \u94dc\u7c07\u548c b \u56de\u94f8\u6eb6\u8d28\u540e\u7684\u94dc\u7c07\/\u6269\u5c55\u535f\u5549\u7684\u6df7\u5408\u7269\u3002\u00a0 c ATR-SEIRAS \u5149\u8c31\u662f\u901a\u8fc7\u5728 CO2 <\/sub>\u9971\u548c\u7684 0.1\u2009M KHCO3<\/sub> \u4e2d\u5c06\u65bd\u52a0\u7684\u7535\u4f4d\u4ece -0.5 \u964d\u4f4e\u5230 -1.3\u2009V \u5f97\u5230\u7684\u3002\u00a0 d \u6db2\u4f53\u4ea7\u7269\u7684 1<\/sup>H-NMR \u5149\u8c31\u548c e \u7531\u540c\u4f4d\u7d20 13<\/sup>CO2<\/sub>RR \u5728-1.2\u2009V \u4e0b\u4ea7\u751f\u7684\u6c14\u4f53\u4ea7\u7269\u7684 GC-MS \u5149\u8c31\u3002f \u63d0\u51fa\u7684\u5728\u91cd\u7ec4 Hex-2Cu-O \u4e0a\u751f\u4ea7\u9187\u7684 C-C \u8026\u5408\u548c\u6c27\u5316\u673a\u5236\u3002 \u989c\u8272\u4ee3\u7801\uff1aCu\uff0c\u6a59\u8272\uff1b\u00a0 C\u3001\u7070\u8272\uff08Hex-2Cu-O\uff09\u3001\u6d77\u519b\u84dd\uff08KB\uff09\u548c\u7eff\u8272\uff08\u53cd\u5e94\u4e2d\u95f4\u4f53\uff09\uff1b\u00a0 O\u3001\u6d0b\u7ea2\u8272\uff08Hex-2Cu-O\uff09\u548c\u7ea2\u8272\uff08\u53cd\u5e94\u4e2d\u95f4\u4f53\uff09\uff1b\u00a0 H\uff0c\u7c89\u7ea2\u8272\uff08Hex-2Cu-O\uff09\u3002 \u8bef\u5dee\u68d2\u4ee3\u8868\u4e09\u4e2a\u72ec\u7acb\u6d4b\u91cf\u7684\u6807\u51c6\u504f\u5dee\u3002\"\"\u56fe 5\uff1a\u63ed\u793a\u591a\u78b3\u9187\u5f62\u6210\u673a\u5236\u7684 DFT \u8ba1\u7b97\u3002@NATURE COMMUNICATIONS<\/p>\n

a R-Hex-2Cu-O\/G\u4e0a2*CO\u5438\u9644\u548c*OCCOH\u5f62\u6210\u81ea\u7531\u80fd\u4e4b\u95f4\u7684\u7ebf\u6027\u6bd4\u4f8b\u5173\u7cfb\u3002b \u5206\u6790 R-Hex-2Cu-2O\/G \u4e0a\u5404\u4e2a\u4f4d\u70b9\u7684 CO\uff08\u0394E*CO\uff09\u548c H\uff08\u0394E*H\uff09\u7684\u5438\u9644\u80fd\u3002 \u5782\u76f4\u548c\u6c34\u5e73\u9ed1\u7ebf\u5206\u522b\u4ee3\u8868 *H\u2009\u2194\u2009\u00bd H2<\/sub> \u548c *CO\u2009\u2194\u2009CO \u7684\u5e73\u8861\u72b6\u6001\uff08\u5373 \u0394G\u2009=\u20090\uff09\u3002 c \u5728 R-Hex-2Cu-O\/G \u4e0a\u786e\u5b9a\u7684 0\u2009V vs RHE \u8fd8\u539f\u9014\u5f84\u3002 \u53c2\u8003\u80fd\u7ea7\u8bbe\u7f6e\u4e3a\u88f8\u9732\u8868\u9762\u3002 \u5173\u952e\u5206\u53c9\u4e2d\u95f4\u4f53\u7684\u81ea\u7531\u80fd\u53d8\u5316 (\u0394G) \u503c\u5728 eV \u4e2d\u6ce8\u91ca\u3002\u00a0 d \u6cbf\u4e59\u9187\u9014\u5f84\u7684\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u539f\u5b50\u7ed3\u6784\u3002\u00a0 0\u2009V vs RHE \u7684\u6bcf\u4e00\u6b65\u7684 \u0394G \u90fd\u7528 eV \u6ce8\u91ca\u3002 \u7eff\u8272\u548c\u7ea2\u8272\u503c\u5206\u522b\u8868\u793a\u91ca\u653e\u548c\u5438\u6536\u80fd\u91cf\u8fc7\u7a0b\u3002 \u84dd\u8272\u5b9e\u5fc3\u7bad\u5934\u6307\u7684\u662f PCET \u6b65\u9aa4\u3002 \u989c\u8272\u4ee3\u7801\uff1aCu\uff0c\u6a59\u8272\uff1b\u00a0 C\u3001\u68d5\u8272\uff08Hex-2Cu-O\uff09\u3001\u6d77\u519b\u84dd\uff08\u77f3\u58a8\u70ef\uff09\u548c\u7eff\u8272\uff08\u53cd\u5e94\u4e2d\u95f4\u4f53\uff09\uff1b\u00a0 O\u3001\u7ea2\u8272\uff08Hex-2Cu-O\uff09\u548c\u7d2b\u8272\uff08\u53cd\u5e94\u4e2d\u95f4\u4f53\uff09\uff1b\u00a0 H\uff0c\u7c89\u7ea2\u8272\uff08Hex-2Cu-O\uff09\u548c\u84dd\u8272\uff08\u53cd\u5e94\u4e2d\u95f4\u4f53\uff09\u3002\u00a0 e R-Hex-2Cu-O\/G \u5728 0\u2009V \u548c \u20131.3\u2009V \u4e0e RHE \u4e0b*HOCCOH \u5f62\u6210\u7684\u80fd\u5792\u3002<\/p>\n

\u7ed3\u8bba<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n

https:\/\/www.nature.com\/articles\/s41467-022-32740-z<\/p>\n","protected":false},"excerpt":{"rendered":"

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