{"id":241523,"date":"2022-08-28T06:32:37","date_gmt":"2022-08-27T22:32:37","guid":{"rendered":"\/\/m.iemloyee.com\/?p=241523"},"modified":"2022-08-27T21:32:53","modified_gmt":"2022-08-27T13:32:53","slug":"%e6%ad%a6%e6%b1%89%e5%a4%a7%e5%ad%a6nature-catalysis%ef%bc%9a%e4%bd%8d%e7%82%b9%e9%80%89%e6%8b%a9%e6%80%a7%e8%83%ba%e5%8c%96%e5%8f%8d%e5%ba%94%e6%9e%84%e5%bb%ba%e4%b8%89%e7%ba%a7%e7%83%b7%e5%9f%ba","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=241523","title":{"rendered":"\u6b66\u6c49\u5927\u5b66Nature Catalysis\uff1a\u4f4d\u70b9\u9009\u62e9\u6027\u80fa\u5316\u53cd\u5e94\u6784\u5efa\u4e09\u7ea7\u70f7\u57fa\u70ef\u4e19\u80fa"},"content":{"rendered":"<p style=\"text-align: center;\">\u3010\u5bfc\u8bfb\u3011<\/p>\n<p>\u00a0\u70f7\u57fa\u70ef\u4e19\u80fa\u662f\u4e00\u79cd\u5177\u6709\u72ec\u7279\u751f\u7269\u548c\u836f\u7406\u6d3b\u6027\u7684\u57fa\u672c\u4e9a\u7ed3\u6784\uff0c\u5728\u6297\u771f\u83cc\u836f\u7269\u4e2d\u5e7f\u4e3a\u4eba\u77e5\uff0c\u5176\u5408\u6210\u5f15\u8d77\u4e86\u5408\u6210\u5316\u5b66\u5bb6\u3001\u836f\u5242\u5e08\u548c\u6750\u6599\u79d1\u5b66\u5bb6\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u50ac\u5316\u70ef\u4e19\u57faC-H\u6c28\u57fa\u662f\u5408\u6210\u70ef\u4e19\u57fa\u80fa\u6700\u6709\u6548\u3001\u539f\u5b50\u7ecf\u6d4e\u7684\u9014\u5f84\u4e4b\u4e00\u3002\u540c\u65f6\u7531\u4e8e\u70f7\u57fa\u70ef\u4e19\u80fa\u5e7f\u6cdb\u7528\u4e8e\u5408\u6210\u519c\u7528\u5316\u5b66\u54c1\u548c\u836f\u7269\u7684\u5404\u79cd\u7ed3\u6784\u5355\u5143\uff0c\u4eba\u4eec\u5bf9\u4f7f\u7528\u5e38\u89c1\u7684\u5316\u5b66\u539f\u6599\uff08\u70ef\u70c3\u548c\u80fa\uff09\u5f00\u53d1\u70f7\u57fa\u70ef\u4e19\u80fa\u7684\u901a\u7528\u548c\u76f4\u63a5\u8def\u7ebf\u8d8a\u6765\u8d8a\u611f\u5174\u8da3\u3002\u7136\u800c\uff0c\u8fd9\u79cd\u5076\u8054\u53cd\u5e94\u7684\u4f8b\u5b50\u4ecd\u7136\u6709\u9650\uff0c\u901a\u8fc7\u7cbe\u786e\u7684\u7ad9\u70b9\u63a7\u5236\u6765\u5b9e\u73b0\u8fd9\u4e00\u76ee\u6807\u66f4\u5177\u6311\u6218\u6027\u3002<\/p>\n<p style=\"text-align: center;\">\u3010\u6210\u679c\u63a0\u5f71\u3011<\/p>\n<p>\u8fd1\u65e5\uff0c\u6b66\u6c49\u5927\u5b66\u5316\u5b66\u4e0e\u5206\u5b50\u79d1\u5b66\u5b66\u9662\u9ad8\u7b49\u7814\u7a76\u9662 (IAS)\u96f7\u7231\u6587\u6559\u6388\u548c\u621a\u5b5d\u5929\u6559\u6388\u62a5\u544a\u4e86\u5149\u50ac\u5316\u5242\u548c\u94b4\u809f\u534f\u540c\u50ac\u5316\u7684\u4f4d\u70b9\u9009\u62e9\u6027\u80fa\u5316\u6784\u5efa\u4e09\u7ea7\u70f7\u57fa\u70ef\u4e19\u80fa\uff0c\u4ece\u800c\u6d88\u9664\u4e86\u5bf9\u6c27\u5316\u5242\u7684\u9700\u6c42\u3002\u8be5\u65b9\u6cd5\u517c\u5bb9\u4e8e\u5e7f\u6cdb\u70ef\u70c3\uff0c\u5e76\u4e14\u53ef\u4ee5\u6269\u5c55\u5230\u841c\u70ef\u7684\u4f4d\u70b9\u548c\u975e\u5bf9\u6620\u9009\u62e9\u6027\u80fa\u5316\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<strong><b>Site-selective amination towards tertiary aliphatic allylamines<\/b><\/strong>\u201d\u53d1\u8868\u5728<strong><em><b><i>Nature Catalysis<\/i><\/b><\/em><\/strong>\u4e0a\u3002\u9ad8\u7814\u9662\u535a\u58eb\u540e\u738b\u76db\u6df3\u548c\u535a\u58eb\u7814\u7a76\u751f\u9ad8\u4e00\u9e23\u4e3a\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff0c\u6b66\u6c49\u5927\u5b66\u96f7\u7231\u6587\u6559\u6388\u548c\u621a\u5b5d\u5929\u6559\u6388\u4e3a\u8bba\u6587\u7684\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-241524 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/1-18.png\" alt=\"\" width=\"1304\" height=\"474\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/1-18.png 1304w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/1-18-300x109.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/1-18-768x279.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/1-18-1024x372.png 1024w\" sizes=\"(max-width: 1304px) 100vw, 1304px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\">\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/p>\n<p>\u901a\u8fc7\u94b4\u809f\u50ac\u5316\u5242\u7684\u6c22\u539f\u5b50\u652b\u53d6\u80fd\u529b(HAT)\uff0c\u89e3\u51b3\u4f4d\u70b9\u9009\u62e9\u6027\u96be\u4ee5\u63a7\u5236\u7684\u96be\u9898\uff1b\u5728\u8fc7\u7a0b\u4e2d\u540c\u65f6\u91ca\u653e\u6c22\u6c14\uff0c\u907f\u514d\u70ef\u4e19\u80fa\u5408\u6210\u4e2d\u5e95\u7269\u9884\u6d3b\u5316\u6b65\u9aa4\u4ee5\u53ca\u5f53\u91cf\u6c27\u5316\u5242\u7684\u4f7f\u7528\uff0c\u4f7f\u5f97\u539f\u5b50\u7ecf\u6d4e\u6027\u663e\u8457\u63d0\u9ad8\u3002<\/p>\n<p style=\"text-align: center;\">\u3010\u6570\u636e\u6982\u51b5\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-241525 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72471-5.png\" alt=\"\" width=\"1180\" height=\"831\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72471-5.png 1180w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72471-5-300x211.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72471-5-768x541.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72471-5-1024x721.png 1024w\" sizes=\"(max-width: 1180px) 100vw, 1180px\" \/><\/p>\n<p>\u56fe 1\uff1a\u70f7\u57fa\u70ef\u4e19\u80fa\u5408\u6210\u4e2d\u7684\u6311\u6218\u4e0e\u8be5\u7b56\u7565<\/p>\n<p>a\uff1a\u6280\u672f\u73b0\u72b6:\u70ef\u70c3\u5206\u5b50\u95f4\u70ef\u4e19\u57fa\u80fa\u5316\u7684\u4ee3\u8868\u6027\u5408\u6210\u65b9\u6cd5\u3002EWG\uff1a\u5438\u7535\u5b50\u96c6\u56e2\u3002b\uff1a\u7406\u60f3\u8def\u7ebf\uff1a\u70ef\u70c3\u4e0e\u70f7\u57fa\u80fa\u901a\u8fc7\u653e\u6c22\u6c14\u6c27\u5316\u5076\u8054\u83b7\u5f97\u70f7\u57fa\u70ef\u4e19\u80fa\u3002c\uff1a\u81ea\u7531\u57fa\u70ef\u4e19\u57fa\u529f\u80fd\u5316\u65b9\u6cd5\u7684\u8bf4\u660e\u3002d\uff1a\u901a\u8fc7\u94b4\u809f\u4fc3\u8fdb\u7684HAT\u4e0e\u4e8c\u7ea7\u70f7\u57fa\u70ef\u4e19\u80fa\u7684\u4f4d\u70b9\u9009\u62e9\u6027\u80fa\u5316\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-241526 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72472-6.png\" alt=\"\" width=\"1724\" height=\"2214\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72472-6.png 1724w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72472-6-234x300.png 234w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72472-6-768x986.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72472-6-797x1024.png 797w\" sizes=\"(max-width: 1724px) 100vw, 1724px\" \/><\/p>\n<p>\u56fe 2\uff1a\u70ef\u70c3\u5e95\u7269\u62d3\u5c55\uff1a\u4e0d\u540c\u70ef\u4e19\u4f4d\u9009\u62e9\u6027\u6bd4\u8f83<\/p>\n<p>a\uff0c\u4e00\u7ea7\u4e0e\u4e09\u7ea7\u70ef\u4e19\u4f4dC-H\u952e\u540c\u65f6\u5b58\u5728\uff0c\u4ec5\u65ad\u88c2\u4e00\u7ea7\u70ef\u4e19\u4f4dC-H\u952e\u3002b\uff0c\u4e00\u7ea7\u4e0e\u4e8c\u7ea7\u70ef\u4e19\u4f4dC-H\u952e\u540c\u65f6\u5b58\u5728\uff0c\u4f18\u5148\u65ad\u88c2\u4e00\u7ea7\u70ef\u4e19\u4f4dC-H\u952e\u3002\u53cd\u5e94\u6761\u4ef6\uff1a\u80fa(0.2\u2009mmol)\u3001\u70ef\u70c3(0.5\u2009ml\u62161.2\u2009mmol)\u3001[Ir(dFCF<sub>3<\/sub>ppy)<sub>2<\/sub>dtbpy)]PF<sub>6<\/sub>(1\u2009mol%)\u548cCo-I(2.5\u2009mol%)\u5728\u7532\u82ef(6\u2009ml)\u4e2d\u7684\u6eb6\u6db2\u5728N<sub>2<\/sub>\u4e0b\u6405\u62cc\u5e76\u572825\u00b0C\u4e0b\u75283\u2009W\u84dd\u8272LED\u7167\u5c049\u2009h\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-241527 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72473-6.png\" alt=\"\" width=\"1042\" height=\"790\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72473-6.png 1042w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72473-6-300x227.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72473-6-768x582.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72473-6-1024x776.png 1024w\" sizes=\"(max-width: 1042px) 100vw, 1042px\" \/><\/p>\n<p>\u56fe 3\uff1a\u53d6\u4ee3\u70ef\u70c3\u7684\u9644\u52a0\u8303\u56f4\u548c\u9650\u5236\u3002<\/p>\n<p>\u53cd\u5e94\u6761\u4ef6:\u80fa(0.2mmol)\uff0c\u672a\u6d3b\u5316\u70ef\u70c3(0.5 ml)\u6216\u82b3\u57fa\u70ef\u70c3(1.2 mmol)\uff0c [Ir(dFCF<sub>3<\/sub>ppy)<sub>2<\/sub>dtbpy)]PF<sub>6<\/sub>\u00a0(1 mol%)\u548cCo-I (2.5 mol%)\u7684\u7532\u82ef(6 ml)\u6eb6\u6db2\u5728N<sub>2<\/sub>\u4e0b\u6405\u62cc\uff0c\u5e76\u75283 W\u84dd\u8272LED\u572825\u2103\u4e0b\u7167\u5c049\u5c0f\u65f6\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-241528 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72474-5.png\" alt=\"\" width=\"696\" height=\"842\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72474-5.png 696w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72474-5-248x300.png 248w\" sizes=\"(max-width: 696px) 100vw, 696px\" \/><\/p>\n<p>\u56fe 4\uff1a\u70f7\u57fa\u70ef\u4e19\u80fa\u7684\u9002\u7528\u8303\u56f4\u3002<\/p>\n<p>\u53cd\u5e94\u6761\u4ef6:\u80fa(0.2 mmol)\u3001\u70ef\u70c3(0.5 ml)\u3001\u94f1\u50ac\u5316\u5242(1 mol%)\u548cCo-I (2.5 mol%)\u7684\u7532\u82ef(6 ml)\u6eb6\u6db2\u5728N<sub>2<\/sub>\u4e0b\u6405\u62cc\uff0c\u7136\u540e\u75283 W\u84dd\u8272LED\u572825\u2103\u4e0b\u7167\u5c049\u5c0f\u65f6\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-241529 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72475-6.png\" alt=\"\" width=\"694\" height=\"846\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72475-6.png 694w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72475-6-246x300.png 246w\" sizes=\"(max-width: 694px) 100vw, 694px\" \/><\/p>\n<p>\u56fe 5\uff1a\u70ef\u70c3\u5f53\u91cf\u548c\u94b4\u809f\u7684\u5f71\u54cd\u3002<\/p>\n<p>a\uff0c\u80fa\u5316\u4ea7\u7387\u4e0e\u70ef\u70c3\u5f53\u91cf\u7684\u5173\u7cfb\uff0c\u6240\u6709\u4ea7\u7387\u5747\u7531\u6c14\u76f8\u8272\u8c31\u6cd5\u6d4b\u5b9a\u3002\u4ee5CH<sub>4<\/sub>\u4e3a\u5185\u6807\u6d4b\u5b9aH<sub>2<\/sub>\u4ea7\u7387\u3002b\u3001ARCs\u7684\u4e24\u79cd\u53ef\u80fd\u8f6c\u5316\u8def\u7ebf\uff1a\u53bb\u8d28\u5b50\u5316\u548c\u70ef\u70c3\u80fa\u5316\u3002c, HAT\u5bf9\u4e0d\u540c\u94b4\u809f\u7684\u9009\u62e9\u6027\u3002\u53cd\u5e94\u6761\u4ef6:\u5417\u5549 (0.2 mmol)\uff0c\u70ef\u70c3(0.5 ml)\uff0c [Ir(dFCF3ppy)2dtbpy)]PF6 (1 mol%)\u548c\u94b4\u809f(2.5 mol%)\u7684\u7532\u82ef(6 ml)\u6eb6\u6db2\u5728N<sub>2<\/sub>\u4e0b\u6405\u62cc\uff0c\u75283 W\u84dd\u8272led\u572825\u2103\u4e0b\u7167\u5c049\u5c0f\u65f6<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-241530 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72476-3.png\" alt=\"\" width=\"689\" height=\"848\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72476-3.png 689w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72476-3-244x300.png 244w\" sizes=\"(max-width: 689px) 100vw, 689px\" \/><\/p>\n<p>\u56fe 6\uff1a\u673a\u7406\u7814\u7a76\u548cDFT\u8ba1\u7b97\u3002<\/p>\n<p>a\uff0c\u94b4\u7684XAFS\u3002b\uff0cEPR\u5b9e\u9a8c\u3002c\uff0cDFT\u8ba1\u7b97\u3002\u6240\u6709\u80fd\u91cf\u5747\u5728 M06\/6-311\u2009+\u2009G(d,p)\u2013SDD\/SMD(toluene)\/\/B3LYP-D3(BJ)\/6-31\u2009G(d)\u2013LANL2DZ\u7406\u8bba\u6c34\u5e73\u4e0b\u8ba1\u7b97\u3002 XANES\uff1a\u8fd1\u8fb9\u7f18\u7ed3\u6784\u7684\u5f52\u4e00\u5316X\u5c04\u7ebf\u5438\u6536\u3002 EXAFS\uff1a\u5085\u91cc\u53f6\u53d8\u6362\u6269\u5c55X\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u3002DMPO\uff1a5,5-\u4e8c\u7532\u57fa-1-\u5421\u54af\u5549 N-\u6c27\u5316\u7269\u3002 DMPO-C\uff1a\u78b3\u81ea\u7531\u57fa\u52a0\u6210\u540e\u7684DMPO\u884d\u751f\u7269\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-241531 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72477-2.png\" alt=\"\" width=\"1043\" height=\"708\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72477-2.png 1043w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72477-2-300x204.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72477-2-768x521.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72477-2-1024x695.png 1024w\" sizes=\"(max-width: 1043px) 100vw, 1043px\" \/><\/p>\n<p>\u56fe 7\uff1a\u5e94\u7528\u548c\u7b56\u7565\u6269\u5c55\u3002<\/p>\n<p>a\uff0c\u5728\u519c\u836f\u5408\u6210\u4e2d\u7684\u5e94\u7528\u3002b\uff0c\u8fdc\u7a0bC-H\u53bb\u9971\u548c\u7b56\u7565\u5b9e\u73b0\u5929\u7136\u841c\u70ef\u7684\u4f4d\u70b9\u548c\u975e\u5bf9\u6620\u9009\u62e9\u6027\u80fa\u5316\u3002 <sup>a<\/sup>\u80fa\u5316\u6761\u4ef6\uff1a\u80fa(0.2\u2009mmol)\u30012-\u7532\u57fa\u4e19\u70ef(1\u2009ml, 2.4\u2009M \u7684THF\u6eb6\u6db2)\u3001[Ir(dFCF<sub>3<\/sub>ppy)<sub>2<\/sub>dtbpy)] PF<sub>6<\/sub>\u00a0(1\u2009mol%) \u548c Co-I (2.5\u2009mol%) \u5728\u5c06\u8131\u6c14\u7684\u7532\u82ef(6\u2009ml)\u5728 N<sub>2<\/sub>\u4e0b\u6405\u62cc\uff0c\u5e76\u572825\u2009\u00b0C\u4e0b\u75283\u2009W\u84dd\u8272LED\u7167\u5c049\u2009h\u3002<sup>b<\/sup>\u8fdc\u7a0b\u53bb\u9971\u548c\u6761\u4ef6\uff1a\u4f7f\u7528\u80fa (0.2\u2009mmol)\u3001\u848e\u70ef (1\u2009ml, 6.6\u2009mmol, 33\u2009\u5f53\u91cf)\u3001[Ir(dFCF<sub>3<\/sub>ppy)<sub>2<\/sub>dtbpy)]PF<sub>6 <\/sub>(1\u2009mol%) \u548cCo-IV(5\u2009mol%) \u7684\u6eb6\u6db2)\u3002<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\">\u3010\u6210\u679c\u542f\u793a\u3011<\/p>\n<p>\u603b\u8a00\u4e4b\u672c\u6587\u5b9e\u73b0\u4e86\u70f7\u57fa\u70ef\u4e19\u80fa\u7684\u7cbe\u786e\u5408\u6210\uff0c\u5229\u7528\u6c2e\u81ea\u7531\u57fa\u9633\u79bb\u5b50\u5bf9\u70ef\u70c3\u7684\u53cd\u9a6c\u6c0f\u52a0\u6210\u548c\u94b4\u809f\u50ac\u5316\u7684HAT\u8fc7\u7a0b\uff0c\u53ef\u4ee5\u4f7f\u70f7\u57fa\u80fa\u548c\u70ef\u70c3\u76f4\u63a5\u5076\u8054\uff0c\u5e76\u4ea7\u751fH<sub>2<\/sub>\u3002\u8fd9\u4e00\u8fc7\u7a0b\u7684\u7279\u70b9\u662f\u9009\u62e9\u6027\u70ef\u70c3\u8f6c\u4f4d\uff0c\u4e0e\u5176\u4ed6\u70ef\u4e19\u57faC-H\u952e\u5b98\u80fd\u56e2\u5316\u76f8\u6bd4\uff0c\u8be5\u7b56\u7565\u5177\u6709\u4e0d\u540c\u5bfb\u5e38\u7684\u504f\u597d\uff0c\u94b4\u809fHAT\u4fc3\u8fdb\u4e86\u4f4d\u963b\u66f4\u5c0f\u7684\u70ef\u4e19\u57faC-H\u952e\u4f18\u5148\u65ad\u88c2\u3002\u8fd9\u79cd\u65b9\u6cd5\u89e3\u51b3\u4e86\u672a\u6fc0\u6d3b\u70ef\u70c3\u4e0e\u70f7\u57fa\u70ef\u4e19\u80fa\u5408\u6210\u7684\u957f\u671f\u6311\u6218\uff0c\u5e76\u4e3a\u70ef\u70c3\u70ef\u4e19\u4f4d\u9009\u62e9\u6027\u8f6c\u5316\u63d0\u4f9b\u4e86\u65b0\u601d\u60f3\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1aWang, S., Gao, Y., Liu, Z. et al. Site-selective amination towards tertiary aliphatic allylamines. <em><i>Nat<\/i><\/em><em><i>.<\/i><\/em><em><i>\u00a0Catal. <\/i><\/em>5, 642\u2013651 (2022). <a href=\"https:\/\/doi\"><u>https:\/\/doi<\/u><\/a>.org\/10.1038\/s41929-022-00818-y<\/p>\n<p>&nbsp;<\/p>\n<p>1.\u56e2\u961f\u4ecb\u7ecd\uff1b<\/p>\n<p>\u96f7\u7231\u6587\u6559\u6388\u6df1\u8015\u7eff\u8272\u6c27\u5316\u5076\u8054\u5341\u4e94\u8f7d\uff0c\u4ee5\u53d1\u5c55\u7eff\u8272\u548c\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u73b0\u4ee3\u6709\u673a\u5408\u6210\u5316\u5b66\u4f5c\u4e3a\u6838\u5fc3\u601d\u60f3\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u65e0\u727a\u7272\u6027\u6c27\u5316\u5242\u5b9e\u73b0\u8131\u6c22\u53cd\u5e94\u7684\u901a\u7528\u7b56\u7565\uff1a\u653e\u6c22\u6c14\u6c27\u5316\u4ea4\u53c9\u5076\u8054\uff0c\u6b64\u7b56\u7565\u6452\u5f03\u4e86\u4f20\u7edf\u65b9\u6cd5\u4e2d\u5f53\u91cf\u6c27\u5316\u5242\u7684\u4f7f\u7528\uff0c\u907f\u514d\u4e86\u4ece\u539f\u6599\u5230\u4ea7\u7269\u8f6c\u5316\u8fc7\u7a0b\u4e2d\u6c27\u5316\u5242\u7684\u5e72\u6270\u3002\u5229\u7528\u7eff\u8272\u7535\u80fd\u9a71\u52a8\u5316\u5b66\u53cd\u5e94\uff0c\u8be5\u7b56\u7565\u53ef\u5e94\u7528\u4e8e\u5927\u89c4\u6a21\u7eff\u6c22\u5236\u5907\u3001\u6709\u673a\u81a6\u4e0e\u786b\u5316\u5b66\u54c1\u7b49\u9ad8\u503c\u5316\u5de5\u54c1\u7684\u9ad8\u6548\u751f\u4ea7\u3002\u653e\u6c22\u6c14\u6c27\u5316\u4ea4\u53c9\u5076\u8054\u4e3a\u4f20\u7edf\u5316\u5b66\u54c1\u7684\u5408\u6210\u63d0\u4f9b\u4e00\u6761\u7eff\u8272\u9014\u5f84\uff0c\u4e5f\u4e3a\u7eff\u8272\u80fd\u6e90\u8f6c\u5316\u63d0\u4f9b\u4e86\u65b0\u7684\u5e94\u7528\u7b56\u7565\u3002\u8fc4\u4eca\u4e3a\u6b62\u53d1\u8868\u8bba\u6587450\u4f59\u7bc7\uff0c\u5728<em>J<\/em><em>ACS<\/em><em>(32<\/em><em>\u7bc7<\/em><em>)<\/em><em>\u3001ACIE<\/em><em>(48<\/em><em>\u7bc7<\/em><em>)<\/em><em>\u3001Nature Catal. <\/em><strong><em>(2<\/em><\/strong><em>\u7bc7<\/em><strong><em>)\u3001<\/em><\/strong><em>Nat. Commun.<\/em><em>\u00a0<\/em><em>(16<\/em><em>\u7bc7<\/em><em>)<\/em><em>\u3001<\/em><em>C<\/em><em>hem<\/em><em>(<\/em><em>2)<\/em><em>\u00a0\u3001<\/em><em>C<\/em><em>hem. Rev.<\/em><strong><em>(4<\/em><\/strong><em>\u7bc7<\/em><strong><em>)<\/em><\/strong><em>\u3001<\/em><em>C<\/em><em>hem. Soc. Rev.<\/em><strong><em>(3<\/em><\/strong><em>\u7bc7<\/em><strong><em>)<\/em><\/strong><em>\u3001<\/em><em>A<\/em><em>cc. <\/em><em>C<\/em><em>hem. Res.<\/em>(2<em>\u7bc7<\/em>)\u7b49\u5f71\u54cd\u56e0\u5b50\u5927\u4e8e12 \u7684\u6742\u5fd7\u4e0a\u53d1\u8868\u7814\u7a76\u8bba\u6587<strong><b>1<\/b><\/strong><strong><b>3<\/b><\/strong><strong><b>0\u4f59\u7bc7<\/b><\/strong>\uff0c\u603b\u88ab\u5f15\u7528\u8d8529000\u4f59\u6b21\uff0cH \u56e0\u5b50\u4e3a96\u30022016-2022\u5e74\u8fde\u7eed\u5165\u9009Thomson Reuters\u548cElsevier\u7684\u5168\u7403\u201c\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u201d\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>2.\u56e2\u961f\u5728\u8be5\u9886\u57df\u7684\u5de5\u4f5c\u6c47\u603b<\/p>\n<p>\u56e2\u961f\u5229\u7528\u5149\/\u7535\u8d4b\u80fd\u7eff\u8272\u7269\u8d28\u8f6c\u5316\uff0c\u5b9e\u73b0\u4e86\u591a\u79cd\u9ad8\u503c\u5316\u5408\u7269\u7684\u5408\u6210\uff0c\u53d6\u5f97\u4e86\u7cfb\u5217\u91cd\u8981\u79d1\u5b66\u8fdb\u5c55\uff0c\u53ef\u4ee5\u53c2\u8003\u56e2\u961f\u7efc\u8ff0\uff1aElectrochemical Oxidative Cross-Coupling with Hydrogen Evolution Reactions \uff08Acc. Chem. Res. 2019, 52, 12, 3309\u20133324\uff09\uff1bRecent Advances in Oxidative R<sup>1<\/sup>-H\/R<sup>2<\/sup>-H Cross-Coupling with Hydrogen Evolution via Photo-\/Electrochemistry \uff08Chem. Rev. 2019, 119, 12, 6769\u20136787\uff09\uff1bRecent advances in electrochemical oxidative cross-coupling with hydrogen evolution involving radicals \uff08Chem. Soc. Rev., 2021,50, 10058-10086\uff09.<\/p>\n<p>&nbsp;<\/p>\n<p>3.\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350\uff1b<\/p>\n<p>\u6700\u8fd1\u5341\u5929\uff0c\u8fde\u53d1\u56db\u6587\uff08Nature\u00a0Catalysis, JACS, ACIE \u53ca\u00a0Nature\u00a0Communications\uff09<\/p>\n<p>&nbsp;<\/p>\n<p>7\u670821\u65e5\u5149\u7535\u534f\u540c\u50ac\u5316JACS\uff1a<\/p>\n<p>Electrophotochemical Ce-Catalyzed Ring-Opening Functionalization of Cycloalkanols under Redox-Neutral Condition: Scope and Mechanism.\u00a0<\/p>\n<p>\u6587\u7ae0\u94fe\u63a5\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/full\/10.1021\/jacs.2c05520\"><u>https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.2c05520<\/u><\/a><\/p>\n<p><u>7<\/u><u>\u67082<\/u><u>6<\/u><u>\u65e5\u7535\u5316\u5b66\u7269\u8d28\u8f6c\u5316A<\/u><u>CIE<\/u><u>\uff1a<\/u><\/p>\n<p>Synthesis of Cyclopentene Derivatives via Electrochemically Induced Intermolecular Selective (3+2) Annulation<\/p>\n<p>\u6587\u7ae0\u94fe\u63a5<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202207059\"><u>https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202207059<\/u><\/a><\/p>\n<p>&nbsp;<\/p>\n<p>7\u670830\u65e5\u7535\u5316\u5b66\u7269\u8d28\u8f6c\u5316Nature\u00a0Communications<\/p>\n<p>1,2-Amino oxygenation of alkenes with hydrogen evolution reaction<\/p>\n<p>\u6587\u7ae0\u94fe\u63a5<a href=\"https:\/\/www.nature.com\/articles\/s41467-022-32084-8\"><u>https:\/\/www.nature.com\/articles\/s41467-022-32084-8<\/u><\/a><\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5bfc\u8bfb\u3011 \u00a0\u70f7\u57fa\u70ef\u4e19\u80fa\u662f\u4e00\u79cd\u5177\u6709\u72ec\u7279\u751f\u7269\u548c\u836f\u7406\u6d3b\u6027\u7684\u57fa\u672c\u4e9a\u7ed3\u6784\uff0c\u5728\u6297\u771f\u83cc\u836f\u7269\u4e2d\u5e7f\u4e3a\u4eba\u77e5\uff0c\u5176\u5408\u6210\u5f15\u8d77\u4e86\u5408\u6210\u5316\u5b66\u5bb6\u3001\u836f\u5242\u5e08\u548c\u6750\u6599\u79d1\u5b66\u5bb6\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u50ac\u5316\u70ef\u4e19\u57faC-H\u6c28&#8230;<\/p>\n","protected":false},"author":34544,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-241523","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/241523"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/34544"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=241523"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/241523\/revisions"}],"predecessor-version":[{"id":241600,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/241523\/revisions\/241600"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=241523"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=241523"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=241523"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}