{"id":241466,"date":"2022-08-24T06:41:57","date_gmt":"2022-08-23T22:41:57","guid":{"rendered":"\/\/m.iemloyee.com\/?p=241466"},"modified":"2022-08-23T15:43:19","modified_gmt":"2022-08-23T07:43:19","slug":"%e5%93%88%e5%b7%a5%e5%a4%a7%e5%bc%a0%e5%ad%a6%e4%b9%a0%e3%80%81%e7%86%8a%e5%b2%b3%e5%b9%b3%e8%af%be%e9%a2%98%e7%bb%84%ef%bc%9a%e9%80%9a%e8%bf%87%e6%94%b9%e8%bf%9b%e5%8e%8b%e5%88%b6%e5%b7%a5%e8%89%ba","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=241466","title":{"rendered":"\u54c8\u5de5\u5927\u5f20\u5b66\u4e60\u3001\u718a\u5cb3\u5e73\u8bfe\u9898\u7ec4\uff1a\u901a\u8fc7\u6539\u8fdb\u538b\u5236\u5de5\u827a\u4f18\u5316\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u8584\u7247\u4e2d\u7684\u5c40\u90e8\u79bb\u5b50\u7ed3\u6784\u5355\u5143"},"content":{"rendered":"<p>01 \u5f15\u8a00<\/p>\n<p>\u5728\u5168\u7403\u80fd\u6e90\u9700\u6c42\u4e0d\u65ad\u589e\u957f\u7684\u63a8\u52a8\u4e0b\uff0c\u5f00\u53d1\u65e2\u53ef\u9760\u53c8\u5b89\u5168\u7684\u65b0\u578b\u9ad8\u80fd\u4e8c\u6b21\u7535\u6c60\u6210\u4e3a\u80fd\u6e90\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u3002\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u662f\u76ee\u524d\u6700\u6210\u719f\u7684\u6280\u672f\u5b9e\u73b0\u65b9\u6cd5\uff0c\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5b9e\u9645\u5e94\u7528\u53ef\u4ee5\u5c06\u80fd\u91cf\u548c\u529f\u7387\u5bc6\u5ea6\u63d0\u5347\u5230\u66f4\u9ad8\u7684\u6c34\u5e73\u3002\u7136\u800c\uff0c\u7531\u4e8e\u9502\u679d\u6676\u7684\u5f62\u6210\u548c\u53ef\u71c3\u6027\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\uff0c\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5229\u7528\u5177\u6709\u6f5c\u5728\u7684\u5b89\u5168\u98ce\u9669\u3002\u800c\u56fa\u4f53\u7535\u89e3\u8d28\u66ff\u4ee3\u6db2\u4f53\u7535\u89e3\u8d28\u80fd\u591f\u663e\u8457\u6539\u5584\u7535\u6c60\u7684\u5b89\u5168\u6027\uff0c\u56e0\u4e3a\u5b83\u5177\u6709\u4e0d\u53ef\u71c3\u6027\u548c\u9ad8\u7ed3\u6784\u5f3a\u5ea6\u3002 30 \u5e74\u6765\uff0c\u968f\u7740\u56fa\u6001\u7535\u89e3\u8d28\u7814\u7a76\u7684\u4e0d\u65ad\u6df1\u5165\uff0c\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28 (SSE)\uff0c\u7279\u522b\u662f\u5177\u6709\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u786b\u4ee3\u78f7\u9178\u9502 (LPS)\u88ab\u8d8a\u6765\u8d8a\u591a\u7684\u4eba\u6240\u5173\u6ce8\u3002<\/p>\n<p>02 \u6210\u679c\u7b80\u4ecb<\/p>\n<p>\u8fd1\u65e5\uff0cChemical Engineering Journal \u53d1\u8868\u4e86\u9898\u4e3a\u201c\u901a\u8fc7\u6539\u8fdb\u538b\u5236\u5de5\u827a\u4f18\u5316\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u8584\u7247\u4e2d\u7684\u5c40\u90e8\u79bb\u5b50\u7ed3\u6784\u5355\u5143\u201d\uff08Local ionic structure unit design in sulfide solid electrolyte flakes by improving pressing process\uff09\u7684\u7814\u7a76\u8bba\u6587\uff0c\u901a\u8baf\u4f5c\u8005\u4e3a\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\u7684\u5f20\u5b66\u4e60\u6559\u6388\u548c\u718a\u5cb3\u5e73\u6559\u6388\u3002\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u535a\u58eb\u751f\u8d3e\u653f\u521a\u4e3a\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>03 \u672c\u6587\u4eae\u70b9<\/p>\n<p>\u672c\u5de5\u4f5c\u7cfb\u7edf\u7814\u7a76\u4e86\u4e0d\u540c\u538b\u7247\u5de5\u827a\u83b7\u5f97\u7684\u7535\u89e3\u8d28\u8584\u7247\u7684\u4f53\u7f3a\u9677\u3001\u5bc6\u5ea6\u548c\u7ed3\u6676\u8fc7\u7a0b\u7684\u5dee\u5f02\u3002\u5728\u9ad8\u5bc6\u5ea6\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u6837\u54c1\u4e2d\u6210\u6838\u53d7\u5230\u6291\u5236\u3002\u6b64\u5916\uff0c\u5728\u52a0\u538b\u8bbe\u5907\u6539\u8fdb\u7684\u57fa\u7840\u4e0a\uff0c\u9996\u6b21\u53d1\u73b0\u73bb\u7483\u5316\u8f6c\u53d8\u5de5\u827a\uff08\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u4e0b\u7684\u4e8c\u6b21\u70ed\u538b\uff09\u53ef\u4ee5\u663e\u7740\u6539\u5584\u5c40\u90e8\u7ed3\u6784\u79bb\u5b50\u7684\u5206\u5e03\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u73bb\u7483\u5316\u8f6c\u53d8\u540eP<sub>2<\/sub>S<sub>7<\/sub><sup>4-<\/sup>\u548cP<sub>2<\/sub>S<sub>6<\/sub><sup>4-<\/sup>\u7684\u542b\u91cf\u589e\u52a0\u4e86\u4e00\u500d\uff0c\u4ece\u800c\u5206\u522b\u63d0\u9ad8\u4e86\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u7a33\u5b9a\u6027\u3002 HP-GT\uff08\u73bb\u7483\u5316\u8f6c\u53d8\u540e\u7684\u7535\u89e3\u8d28\u8584\u7247\uff09\u5177\u6709\u6781\u9ad8\u7684\u76f8\u5bf9\u5bc6\u5ea6\uff0899\u00b11%\uff09\u3001\u4f4e\u79bb\u5b50\u6d3b\u5316\u80fd\uff0814.4 kJ\/mol\uff09\u548c\u6781\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff083.48 mS\/cm\uff09\u3002\u53e6\u4e00\u65b9\u9762\uff0cLi|HP-GT|MoS2 \u5168\u56fa\u6001\u7535\u6c60\u5728 30 \u6b21\u5faa\u73af\u540e\u4ecd\u4fdd\u6301\u7ea6 680 mAh g<sup>-1<\/sup>\u00a0\u7684\u6bd4\u653e\u7535\u5bb9\u91cf\u3002\u8be5\u5de5\u4f5c\u8bc1\u5b9e\u4e86\u4e8c\u6b21\u70ed\u538b\u540e\u7684\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u5728\u9ad8\u5b89\u5168\u6027\u3001\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u56fa\u6001\u9502\u7535\u6c60\u5e94\u7528\u4e2d\u7684\u53ef\u884c\u6027\u3002<\/p>\n<p>04 \u56fe\u6587\u5bfc\u8bfb<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-241467\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e60911.png\" alt=\"\" width=\"454\" height=\"197\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e60911.png 454w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e60911-300x130.png 300w\" sizes=\"(max-width: 454px) 100vw, 454px\" \/><\/p>\n<p>\u56fe 1 (a) LPS \u6837\u54c1\u7684 DSC \u6d4b\u8bd5\u663e\u793a\u4e86\u591a\u4e2a\u76f8\u53d8\u6e29\u5ea6\u548c\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u3002 (b) \u00a0HT-CP \uff08\u70ed\u5904\u7406\u540e\u51b7\u538b\uff09\u3001CP-HT\uff08\u51b7\u538b\u540e\u70ed\u5904\u7406\uff09\u3001HP \uff08\u70ed\u538b\u70e7\u7ed3\uff09\u548c HP-GT \u6837\u54c1\u7684\u76f8\u5bf9\u81f4\u5bc6\u5ea6\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-241468\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e601016.png\" alt=\"\" width=\"454\" height=\"402\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e601016.png 454w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e601016-300x266.png 300w\" sizes=\"(max-width: 454px) 100vw, 454px\" \/><\/p>\n<p>\u56fe2 \u4e0d\u540c\u538b\u7247\u5de5\u827aLPS\u8584\u7247\u7684Raman (a, c)\u548cMAS NMR (b, d)\u56fe\u663e\u793a\u9634\u79bb\u5b50\u542b\u91cf<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-241469\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e601069.png\" alt=\"\" width=\"454\" height=\"203\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e601069.png 454w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e601069-300x134.png 300w\" sizes=\"(max-width: 454px) 100vw, 454px\" \/><\/p>\n<p>\u56fe3 (a) thio-LISICON \u2161\u6676\u76f8\u793a\u610f\u56fe\u548c(b) \u4e0d\u540c\u538b\u7247\u5de5\u827aLPS\u8584\u7247\u7684XPS\u56fe\u8c31<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-241470\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e601120.png\" alt=\"\" width=\"454\" height=\"519\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e601120.png 454w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e601120-262x300.png 262w\" sizes=\"(max-width: 454px) 100vw, 454px\" \/><\/p>\n<p>\u56fe 4 (a) HT-CP\u3001CP-HT\u3001HP \u548c HP-GT \u8584\u7247\u7684 Arrhenius \u56fe\uff1b (b) HP-GT \u7684\u5faa\u73af\u4f0f\u5b89\u6cd5 (CV)\uff1b (c) \u674e |HP-GT| \u9502\u7535\u6c60\uff0c0.1 mA cm-2\uff1b (d) MoS2|HP|Li \u548c MoS2|HP-GT|Li \u7535\u6c60\u5728 0.1 C \u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1b (e) MoS2|HP-GT|Li\u7535\u6c60\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-241471\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e601303.png\" alt=\"\" width=\"454\" height=\"265\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e601303.png 454w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/\u6750\u6599\u4eba\u6295\u7a3f-\u54c8\u5de5\u5927\u5f20\u5b66\u4e601303-300x175.png 300w\" sizes=\"(max-width: 454px) 100vw, 454px\" \/><\/p>\n<p>\u56fe5 HP-GT\uff08a\uff0cb\uff09\u548cHP\uff08d\uff0ce\uff09\u5faa\u73af\u540e\u7535\u6c60\u7684\u6a2a\u622a\u9762SEM\u548cEDX\u56fe\u50cf\u3002 \u6b64\u5916\uff0c\u4e0e HP \u548c HP-GT \u63a5\u89e6\u7684\u9502\u91d1\u5c5e\u7684 S (c) \u548c P (d) XPS \u5206\u6790\u3002<\/p>\n<p>05 \u603b\u7ed3\u4e0e\u5c55\u671b<\/p>\n<p>\u603b\u4e4b\uff0c\u901a\u8fc7\u5728\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u4e0b\u7684\u7b2c\u4e8c\u6b21\u70ed\u538b\u6210\u529f\u5730\u8bbe\u8ba1\u548c\u5236\u5907\u4e86\u4f18\u8d28\u7684 LPS \u8584\u7247\u3002\u8be5\u5de5\u827a\u7684\u4f18\u70b9\u96c6\u4e2d\u5728\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u9762\uff1a\uff081\uff09\u70ed\u538b\u5de5\u827a\u6709\u5229\u4e8e\u51cf\u5c11\u4f53\u79ef\u7f3a\u9677\u548c\u589e\u52a0LPS\u8584\u7247\u7684\u76f8\u5bf9\u81f4\u5bc6\u5ea6\u3002\u540c\u65f6\uff0c\u8f83\u9ad8\u7684\u76f8\u5bf9\u5bc6\u5ea6\u4f1a\u963b\u788d\u6676\u76f8\u7684\u5f62\u6210\uff0c\u589e\u52a0\u73bb\u7483\u76f8\u7684\u542b\u91cf\u3002 (2) \u901a\u8fc7\u5bf9\u6bd4\u73bb\u7483\u5316\u8f6c\u53d8\u524d\u540e\u7684 SEM \u56fe\u50cf\uff0c\u53d1\u73b0\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u4e0b\u7684\u4e8c\u6b21\u70ed\u538b\u5904\u7406\u5bfc\u81f4\u4e86\u5fae\u88c2\u7eb9\u7684\u81ea\u6108\u8fc7\u7a0b\uff0c\u4ece\u800c\u8fdb\u4e00\u6b65\u63d0\u9ad8\u4e86\u76f8\u5bf9\u5bc6\u5ea6 (99\u00b11% ) LPS \u8584\u7247\u3002 (3)\u6b64\u5916\uff0c\u73bb\u7483\u5316\u8f6c\u53d8\u5904\u7406\u53ef\u4ee5\u63d0\u9ad8LPS\u8584\u7247\u4e2dP<sub>2<\/sub>S<sub>7<\/sub><sup>4-<\/sup>\u548cP<sub>2<\/sub>S<sub>6<\/sub><sup>4-<\/sup>\u7684\u542b\u91cf\uff0c\u4ece\u800c\u663e\u7740\u63d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0cHP-GT \u8584\u7247\u5728\u5ba4\u6e29\u4e0b\u8868\u73b0\u51fa3.48 mS\/cm\u7684\u9ad8\u9502\u79bb\u5b50\u7535\u5bfc\u7387\u548c14.4 kJ\/mol\u7684\u4f4e\u79bb\u5b50\u6d3b\u5316\u80fd\u3002\u6b64\u5916\uff0c\u57fa\u4e8e HP-GT \u7247\u6750\u7684 Li-MoS2 \u56fa\u6001\u7535\u6c60\u663e\u793a\u51fa\u66f4\u9ad8\u7684\u53ef\u9006\u521d\u59cb\u5bb9\u91cf\uff08810 mAh\/g\uff09\u548c\u66f4\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0830 \u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u9ad8\u8fbe 84%\uff09\u3002\u8be5\u5de5\u4f5c\u8bc1\u5b9e\u4e86\u4e8c\u6b21\u70ed\u538b\u540e\u7684\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u5728\u9ad8\u5b89\u5168\u6027\u3001\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u56fa\u6001\u9502\u7535\u6c60\u5e94\u7528\u4e2d\u7684\u53ef\u884c\u6027\u3002\u6240\u63d0\u51fa\u7684\u538b\u7247\u5de5\u827a\u9002\u7528\u4e8e\u5176\u4ed6\u7c7b\u578b\u7684\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u4e3a\u4e0b\u4e00\u4ee3\u50a8\u80fd\u88c5\u7f6e\u63d0\u4f9b\u4e86\u6f5c\u529b\u548c\u524d\u666f\u3002<\/p>\n<p>\u539f\u6587<\/p>\n<p>Jia Zhenggang, Zhang Xuexi, Qian Mingfang, et al. Local ionic structure unit design in sulfide solid electrolyte flakes by improving pressing process[J]. Chem Eng J, 2022, 435: 134663. DOI: 10.1016\/j.cej.2022.134663<\/p>\n","protected":false},"excerpt":{"rendered":"<p>01 \u5f15\u8a00 \u5728\u5168\u7403\u80fd\u6e90\u9700\u6c42\u4e0d\u65ad\u589e\u957f\u7684\u63a8\u52a8\u4e0b\uff0c\u5f00\u53d1\u65e2\u53ef\u9760\u53c8\u5b89\u5168\u7684\u65b0\u578b\u9ad8\u80fd\u4e8c\u6b21\u7535\u6c60\u6210\u4e3a\u80fd\u6e90\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u3002\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u662f\u76ee\u524d\u6700\u6210\u719f\u7684\u6280\u672f\u5b9e\u73b0\u65b9\u6cd5\uff0c\u9502\u91d1\u5c5e\u8d1f&#8230;<\/p>\n","protected":false},"author":35234,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-241466","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/241466"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/35234"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=241466"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/241466\/revisions"}],"predecessor-version":[{"id":241472,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/241466\/revisions\/241472"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=241466"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=241466"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=241466"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}