{"id":241111,"date":"2022-08-15T06:39:14","date_gmt":"2022-08-14T22:39:14","guid":{"rendered":"\/\/m.iemloyee.com\/?p=241111"},"modified":"2022-08-14T22:43:57","modified_gmt":"2022-08-14T14:43:57","slug":"%e4%ba%8b%e5%85%b3%e6%89%8b%e6%80%a7%ef%bc%81nature-communications%ef%bc%9a%e4%bd%8d%e9%98%bb%e5%bc%82%e6%9e%84%e4%bd%93%e4%b8%8d%e5%af%b9%e7%a7%b0%e7%bb%93%e6%9e%84%e7%9a%84%e6%9e%84%e8%b1%a1","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=241111","title":{"rendered":"\u4e8b\u5173\u624b\u6027\uff01Nature communications\uff1a\u4f4d\u963b\u5f02\u6784\u4f53\u4e0d\u5bf9\u79f0\u7ed3\u6784\u7684\u6784\u8c61\u5bf9\u6620\u4f53\u9274\u522b"},"content":{"rendered":"

01<\/strong>\u3001\u5bfc\u8bfb<\/strong><\/p>\n

\u6211\u4eec\u77e5\u9053\uff0c\u6784\u8c61\u662f\u539f\u5b50\u56f4\u7ed5\u5355\u952e\u65cb\u8f6c\u5f62\u6210\u7684\u7a7a\u95f4\u6392\u5217\u3002\u4f46\u5728\u5927\u591a\u6570\u60c5\u51b5\u4e0b\u65e0\u6cd5\u5206\u79bb\u7eaf\u6784\u8c61\uff0c\u56e0\u4e3a\u5206\u5b50\u5728\u6240\u6709\u53ef\u80fd\u7684\u6784\u8c61\u4e2d\u4e0d\u65ad\u65cb\u8f6c\u3002\u6709\u8da3\u7684\u662f\uff0c\u5f53\u56f4\u7ed5\u5355\u952e\u7684\u65cb\u8f6c\u53d7\u5230\u9650\u5236\u65f6\uff0c\u4e00\u7c7b\u79f0\u4e3a\u987a\u53cd\u5f02\u6784\u4f53\u7684\u7279\u6b8a\u6784\u8c61\u5c31\u53ef\u4ee5\u5206\u79bb\u51fa\u4e0d\u540c\u7684\u5316\u5b66\u7269\u8d28\u3002\u5355\u952e\u7684\u6784\u8c61\u548c\u65cb\u8f6c\u5bf9\u5206\u5b50\u529f\u80fd\u548c\u5316\u5b66\u8f6c\u5316\u81f3\u5173\u91cd\u8981\uff0c\u5728\u5b9e\u9645\u5316\u5b66\u5e94\u7528\u4e2d\uff0c\u4f8b\u5982\u5728\u9176\u50ac\u5316\u4e2d\u6784\u8c61\u52a8\u529b\u5b66\u5c31\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002\u7136\u800c\uff0c\u5728\u4e0d\u5bf9\u79f0\u50ac\u5316\u4e2d\uff0c\u4f17\u6240\u5468\u77e5\uff0c\u975e\u9176\u6027\u624b\u6027\u50ac\u5316\u5242\u7684\u7ed3\u6784\u521a\u6027\u901a\u5e38\u662f\u5b9e\u73b0\u9ad8\u6c34\u5e73\u4e0d\u5bf9\u79f0\u8bf1\u5bfc\u7684\u5fc5\u8981\u6761\u4ef6\uff0c\u4f46\u5bf9\u624b\u6027\u50ac\u5316\u5242\u7684\u5206\u5b50\u7075\u6d3b\u6027\u548c\u6784\u8c61\u52a8\u529b\u5b66\u7684\u7814\u7a76\u8f83\u5c11\uff0c\u624b\u6027\u50ac\u5316\u5242\u7684\u6784\u8c61\u5206\u79bb\u96be\u5ea6\u8f83\u5927\u662f\u963b\u788d\u5176\u7814\u7a76\u7684\u4e3b\u8981\u539f\u56e0\uff0c\u56e0\u6b64\u63ed\u793a\u5176\u6784\u8c61\u4e0e\u5bf9\u6620\u4f53\u5206\u79bb\u4e4b\u95f4\u7684\u5173\u7cfb\u5177\u6709\u5f88\u5927\u7684\u6311\u6218\u6027\u3002\u8f74\u5411\u624b\u6027\u5206\u5b50\u4e0d\u4ec5\u5728\u81ea\u7136\u754c\u4e2d\u975e\u5e38\u4e30\u5bcc\uff0c\u800c\u4e14\u5728\u8bb8\u591a\u79d1\u5b66\u9886\u57df\u53d6\u5f97\u4e86\u5de8\u5927\u7684\u6210\u529f\uff0c\u5982\u6750\u6599\u79d1\u5b66\u548c\u4e0d\u5bf9\u79f0\u5408\u6210\u9886\u57df\u30021,1′-\u8054\u4e8c\u8418\u915a (BINOL)\u30011,1′-\u8054-2-\u8418\u80fa\uff08BINAM\uff09\u30012-\u6c28\u57fa-2\u2019-\u7f9f\u57fa-1,1′-\u8054\u8418\uff08NOBIN\uff09\u662f\u6700\u7a81\u51fa\u548c\u6700\u6709\u4ef7\u503c\u7684\u8f74\u5411\u624b\u6027\u5206\u5b50\u3002\u5bf9\u6620\u4f53\u7eaf\u7684(R)-\u548c(S)-BINOL\u53ca\u5176\u4e00\u4e9b\u884d\u751f\u7269\u5982\u4eca\u5df2\u5728\u5e02\u573a\u4e0a\u51fa\u552e\uff0c\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5c3d\u7ba1\u5728\u8fc7\u53bb\u4e09\u5341\u5e74\u4e2d\u5bf9\u5176\u5408\u6210\u8fdb\u884c\u4e86\u5927\u91cf\u52aa\u529b\uff0c\u4f46\u5177\u6709\u4e0d\u540c\u53d6\u4ee3\u6a21\u5f0f\u7684\u5bf9\u6620\u4f53\u7eaf\u7684BINAMs\u548cNOBINs\u4ecd\u7136\u5f88\u96be\u83b7\u5f97\uff0c\u56e0\u6b64\u8feb\u5207\u9700\u8981\u65b0\u7684\u7814\u7a76\u89e3\u51b3\u4e0a\u8ff0\u95ee\u9898\u3002<\/p>\n

02<\/strong>\u3001\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n

\u5728\u6b64\uff0c\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u5316\u5b66\u4e0e\u5206\u5b50\u5de5\u7a0b\u5b66\u9662\u8d75\u6885\u6b23\u526f\u6559\u6388\u548c\u5f20\u5fd7\u9e4f\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u7531\u975e\u624b\u6027\u50ac\u5316\u6d3b\u6027\u5355\u5143\uff08N,N-\u53cc\u9f7f-1,10-\u83f2\u7f57\u5549\uff09\u548c\u8f74\u5411\u624b\u60271,1′-\u8054-2-\u8418\u915a(BINOL)\u5355\u5143\u901a\u8fc7C-O\u5355\u952e\u8fde\u63a5\u800c\u6210\u7684\u624b\u6027\u50ac\u5316\u4f53\u7cfb\u3002\u901a\u8fc7\u5355\u6676x\u5c04\u7ebf\u884d\u5c04\u786e\u5b9a\u4e86C-O\u952e\u65cb\u8f6c\u8bf1\u5bfc\u7684\u4e24\u79cd\u50ac\u5316\u5242\u6784\u8c61\uff0c\u53d1\u73b0\u5b83\u4eec\u5206\u522b\u751f\u6210\u4e86\u9ad8\u5ea6\u91cd\u8981\u7684\u8f74\u5411\u624b\u60271,1′-\u8054-2-\u8418\u80fa(BINAM)\u548c2-\u6c28\u57fa-2′-\u7f9f\u57fa-1,1′-\u8054\u8418(NOBIN)\u884d\u751f\u7269\uff0c\u4ea7\u7387\u9ad8\u8fbe98%\uff0c\u5177\u6709\u4f18\u826f\u7684\u5bf9\u6620\u9009\u62e9\u6027(\u9ad8\u8fbe98:2 e.r)\u548c\u76f8\u53cd\u7684\u7edd\u5bf9\u6784\u578b\u3002\u8fd9\u4e00\u7ed3\u679c\u5f3a\u8c03\u4e86\u4e0d\u5bf9\u79f0\u50ac\u5316\u4e2d\u624b\u6027\u50ac\u5316\u5242\u6784\u8c61\u52a8\u529b\u5b66\u7684\u91cd\u8981\u6027\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cConformational enantiodiscrimination forasymmetric construction of atropisomers<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature Communications<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\" <\/p>\n

03<\/strong>\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n

1\u3001\u4ee5(R)-BINOL\u4e3a\u624b\u6027\u5355\u5143\uff0c\u4ee5N,N-\u53cc\u9f7f1,10-\u83f2\u7f57\u5549\u4e3a\u624b\u6027\u87af\u5408\u5355\u5143\u3002\u901a\u8fc7\u5728\u83f2\u7f57\u5549\u5355\u5143\u7684C2\u78b3\u548c\u624b\u6027\u5355\u5143\u4e00\u4e2a\u915a\u7f9f\u57fa\u7684\u6c27\u4e4b\u95f4\u5f62\u6210C-O\u952e\uff0c\u5236\u5907\u4e86\u4e00\u4e2a\u65b0\u7684\u914d\u4f53\uff0c\u8be5\u914d\u4f53\u5177\u6709\u8f74\u5411\u624b\u6027\u3001\u4f18\u5f02\u7684\u914d\u4f4d\u80fd\u529b\u548c\u6784\u8c61\u7075\u6d3b\u6027\u3002<\/p>\n

2\u3001\u9009\u53d6\u5076\u6c2e\u8418\u4e0eN-\u82c4\u57fa-2-\u8418\u80fa\u4e0d\u5bf9\u79f0\u4ea4\u53c9\u5076\u8054\u751f\u6210BINAM\u884d\u751f\u7269\u4f5c\u4e3a\u53cd\u5e94\u6765\u8bc4\u4ef7\u4e0d\u540c\u7684\u5c4f\u853d\u914d\u4f53\uff0c\u5e76\u4ee5\u94dc\u4f5c\u4e3a\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u94dc\u4ece\u672a\u88ab\u62a5\u9053\u50ac\u5316\u8be5\u53cd\u5e94\u3002<\/p>\n

3\u3001\u7b5b\u9009\u83f2\u7f57\u5549\u5355\u5143C9\u4f4d\u7f6e\u4e0a\u7684\u53d6\u4ee3\u57fa\u6765\u5bfb\u627e\u5408\u9002\u7684\u5c4f\u853d\u914d\u4f53\u540e\uff0c\u5728\u6700\u4f18\u5c4f\u853d\u914d\u4f53\u6761\u4ef6\u4e0b\uff0c\u751f\u6210\u4e86\u9ad8\u5ea6\u91cd\u8981\u7684\u8f74\u5411\u624b\u60271,1′-\u8054\u8418-2,2′-\u4e8c\u80fa(BINAM)\u548c2-\u6c28\u57fa-2′-\u7f9f\u57fa-1,1’\u8054\u8418(NOBIN)\u884d\u751f\u7269\uff0c\u6709\u7740\u6781\u4f73\u7684\u6536\u7387\u548c\u5bf9\u6620\u9009\u62e9\u6027\u3002<\/p>\n

4\u3001\u53cd\u5e94\u4ea7\u7269\u7684\u7edd\u5bf9\u6784\u578b\u662f\u7531\u50ac\u5316\u5242\u7684\u6784\u8c61\u51b3\u5b9a\u7684\uff0c\u800c\u4e0d\u662fBINOL\u7684\u7edd\u5bf9\u6784\u578b\uff0c\u8fd9\u662f\u4e00\u4e2a\u65b0\u7684\u53d1\u73b0\u3002<\/p>\n

04<\/strong>\u3001\u6570\u636e\u6982\u89c8<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1<\/strong>\u3001\u5173\u4e8e\u5355\u952e\u7684\u65cb\u8f6c\u548c\u6784\u8c61\u5bf9\u6620\u5224\u522b\uff1b<\/strong>\u00a9 The Author(s) 2022<\/strong><\/p>\n

\uff08a\uff09\u3001\u4e59\u70f7\u4e2d\u7684\u78b3-\u78b3\u952e\u65cb\u8f6c;<\/p>\n

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\uff08c\uff09\u3001\u56f4\u7ed5\u9501\u5b9a\u5728\u4e8c\u5143\u91d1\u5c5e\u7edc\u5408\u7269\u548c\u4e8c\u7f9f\u57fa\u78f7\u9178\u4e2d\u7684C\u2013C\u5355\u952e\u65cb\u8f6c\uff1b<\/p>\n

\uff08d\uff09\u3001\u4e0d\u5bf9\u79f0\u6784\u8c61\u5bf9\u6620\u4f53\u8bc6\u522b\u624b\u6027\u50ac\u5316\u4f53\u7cfb\u7684\u8bbe\u8ba1\uff1b<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2<\/strong>\u3001\u5076\u6c2e\u8418\u4e0e<\/strong>2-<\/strong>\u8418\u80fa\u4e0d\u5bf9\u79f0\u4ea4\u53c9\u5076\u8054\u7684\u6784\u8c61\u5bf9\u6620\u4f53\u9274\u522b\uff1b<\/strong>\u00a9 The Author(s) 2022<\/strong><\/p>\n

\uff08a\uff09\u3001\u5c4f\u853d\u7b5b\u9009\uff0848h\uff09;<\/p>\n

\uff08b\uff09\u3001\u7f9f\u57fa\u7684\u5f71\u54cd\uff0848h\uff09\uff1b<\/p>\n

\uff08c\uff09\u3001\u5e95\u7269\u8303\u56f4(60h)\uff1b<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3<\/strong>\u3001\u5076\u6c2e\u8418\u4e0e<\/strong>2-<\/strong>\u8418\u915a\u4e0d\u5bf9\u79f0\u4ea4\u53c9\u5076\u8054\u7684\u6784\u8c61\u5bf9\u6620\u4f53\u9274\u522b\uff1b<\/strong>\u00a9 The Author(s) 2022<\/strong><\/p>\n

\uff08a\uff09\u3001\u6784\u8c61\u5e73\u8861\u5bf9\u5bf9\u6620\u4f53\u9274\u522b\u7684\u5f71\u54cd\uff1b<\/p>\n

\uff08b\uff09\u3001\u5e95\u7269\u8303\u56f4\uff1b<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4<\/strong>\u3001\u5355\u6676<\/strong>X<\/strong>\u5c04\u7ebf\u884d\u5c04\u6cd5\u6d4b\u5b9a\u6784\u8c61\uff1b<\/strong>\u00a9 The Author(s) 2022<\/strong><\/p>\n

\uff08a\uff09\u3001\u7531L8\u3001Cu(MeCN)4<\/sub>PF6<\/sub>\u548c2-(\u84bd-9-\u57fa)-9-\u6c2f-1,10-\u83f2\u7f57\u5549(L15)\u5236\u5907\u4e86\u94dc\u914d\u5408\u7269Cu-1\uff1b<\/p>\n

\uff08b\uff09\u3001\u7531L13\u548cCuCl\u5236\u5907\u7684\u94dc\u7edc\u5408\u7269Cu-2\uff1b<\/p>\n

05<\/strong>\u3001\u6210\u679c\u542f\u793a<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Conformational enantiodiscrimination forasymmetric construction of atropisomers<\/strong>\uff08<\/strong>NatureCommunications<\/strong>\uff0c<\/strong>2022<\/strong>\uff0c<\/strong>https:\/\/doi.org\/10.1038\/s41467-022-32432-8<\/strong>\uff09<\/strong><\/p>\n

06<\/strong>\u3001\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong><\/p>\n

\"\"<\/p>\n

\u8d75\u6885\u6b23<\/strong><\/p>\n

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\u7814\u7a76\u65b9\u5411\uff1a\u6709\u673a\u5316\u5b66<\/strong><\/p>\n

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\uff082\uff09 \u5177\u6709\u751f\u7269\u6d3b\u6027\u7684\u624b\u6027\u6742\u73af\u5316\u5408\u7269\u7684\u65b0\u5408\u6210\u65b9\u6cd5;<\/p>\n

\uff083\uff09 \u529f\u80fd\u6750\u6599\u7684\u5408\u6210\u53ca\u5e94\u7528\uff1b<\/p>\n

\"\"<\/p>\n

\u5f20\u5fd7\u9e4f<\/strong><\/p>\n

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\u7814\u7a76\u65b9\u5411\uff1a\u6709\u673a\u5316\u5b66<\/strong><\/p>\n

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