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decoding=\"async\" class=\"aligncenter  wp-image-241048\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/5-6.png\" alt=\"\" width=\"656\" height=\"601\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/5-6.png 912w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/5-6-300x275.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/5-6-768x704.png 768w\" sizes=\"(max-width: 656px) 100vw, 656px\" \/><\/p>\n<p>\u56fe6\u6c22\u5316\u94b4\u50ac\u5316\u672b\u7aef\u7094\u70c3\u4eb2\u7535\u52a0\u6c22\u70ef\u4e19\u57fa\u5316\u7684\u673a\u7406\u00a9 2022 The Authors<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter  wp-image-241049\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/6-2.png\" alt=\"\" width=\"435\" height=\"389\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/6-2.png 593w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/08\/6-2-300x268.png 300w\" sizes=\"(max-width: 435px) 100vw, 435px\" \/><\/p>\n<p>\u4e94\u3001\u6210\u679c\u5c55\u793a<\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u6211\u4eec\u5c55\u793a\u4e86\u4e00\u79cd\u6709\u6548\u7684\u5408\u6210\u8def\u7ebf\u5236\u5907\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u6c22\u5316\u94b4\uff0c\u8bbe\u7f6e\u4e24\u7ec4\u5bf9\u7167\u5b9e\u9a8c\uff0c\u8c03\u6574\u7094\u70c3\u6d53\u5ea6\u3001\u70ef\u4e19\u57fa\u6eb4\u6d53\u5ea6\u3001\u50ac\u5316\u5242\u6d53\u5ea6\u3001PMHS \u6d53\u5ea6\u4ee5\u53ca\u901a\u8fc7\u5bf9\u7167\u6c18\u6807\u8bb0\u7684\u70ef\u4e19\u57fa\u6eb4\u53cd\u5e94\u3001\u6c18\u6807\u8bb0\u672b\u7aef\u7094\u70c3\u7684\u53cd\u5e94\u3001\u52a0\u6c22\u70ef\u4e19\u57fa\u5316\u53cd\u5e94\u3002\u5728\u6c18\u6807\u8bb0\u5b9e\u9a8c\u548c\u52a8\u529b\u5b66\u7814\u7a76\u7684\u57fa\u7840\u4e0a\uff0c\u521d\u6b65\u63d0\u51fa\u4e86\u03b1-\u9009\u62e9\u6027\u94b4\u70ef\u57fa\u4e2d\u95f4\u4f53\u4eb2\u7535\u70ef\u4e19\u57fa\u5316\u7684\u673a\u7406\u3002\u6c22\u5316\u94b4\u4e2d\u7684\u7269\u79cdC\uff0c\u662f\u7531\u6d3b\u6027\u7269\u8d28\u4e2d\u95f4\u4f53 (L3-H)\u2022CoBr \u4e0e LiOtBu\u548c\u6c22\u7845\u70f7\u7684\u53cd\u5e94\u83b7\u5f97\u3002\u7094\u70c3\u4e0e\u7269\u8d28 C \u914d\u4f4d\uff0c\u7136\u540e\u5c06\u672b\u7aef\u7094\u70c3\u63d2\u5165\u6c22\u5316\u94b4\u952e\uff0c\u4e3b\u8981\u63d0\u4f9b \u03b1-\u9009\u62e9\u6027\u94b4-\u70ef\u57fa\u4e2d\u95f4\u4f53 E\uff0c\u5feb\u901f\u5f02\u6784\u5316\u5e73\u8861E \u548c\u94b4\u5361\u5bbe\u4e24\u6027\u79bb\u5b50 F \u4e4b\u95f4\u7684\u5dee\u5f02\u662f\u57fa\u4e8e\u6c18\u6807\u8bb0\u5b9e\u9a8c\u7684 E \/ Z \u53d8\u5316\u3002\u6c22\u7845\u70f7\u548c\u70f7\u6c27\u5316\u7269\u53ef\u80fd\u662f\u9020\u6210\u50ac\u5316\u8fc7\u7a0b\u4e2d\u89c2\u5bdf\u5230\u7684\u533a\u57df\u9009\u62e9\u6027\u589e\u52a0\u7684\u539f\u56e0\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e<\/p>\n<p>Chen J, Ying J, Lu Z. Cobalt-catalyzed branched selective hydroallylation of terminal alkynes [J]. Nature Communications, 2022, 13(1): 4518.<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n<p>10.1038\/s41467-022-32291-3<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u5bfc\u8bfb \u00a0 \u00a0 \u00a0 \u00a0\u6c22\u80fd\u6e90\u79f0\u4e3a\u6700\u6709\u53d1\u5c55\u6f5c\u529b\u7684\u6e05\u6d01\u80fd\u6e90\u3002\u622a\u81f32020\u5e7412\u6708\u5e95\uff0c\u4e2d\u56fd\u7d2f\u8ba1\u5efa\u6210118\u5ea7\u52a0\u6c22\u7ad9(\u4e0d\u542b3\u5ea7\u5df2\u62c6\u9664\u52a0\u6c22\u7ad9)\uff0c\u5176\u4e2d\u5efa\u6210\u7684\u52a0\u6c22\u7ad9\u5df2\u6295\u5165\u8fd0\u8425&#8230;<\/p>\n","protected":false},"author":35611,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-241042","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/241042"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/35611"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=241042"}],"version-history":[{"count":5,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/241042\/revisions"}],"predecessor-version":[{"id":241152,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/241042\/revisions\/241152"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=241042"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=241042"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=241042"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}