{"id":240523,"date":"2022-08-01T06:17:34","date_gmt":"2022-07-31T22:17:34","guid":{"rendered":"\/\/m.iemloyee.com\/?p=240523"},"modified":"2022-07-31T21:17:49","modified_gmt":"2022-07-31T13:17:49","slug":"%e8%8b%8f%e9%bb%8e%e4%b8%96%e8%81%94%e9%82%a6%e7%90%86%e5%b7%a5%e5%ad%a6%e9%99%a2nature%ef%bc%9acpet%e4%bb%8b%e5%af%bc%e7%ad%96%e7%95%a5%e5%ae%9e%e7%8e%b0co2%e9%ab%98%e6%95%88%e9%80%89%e6%8b%a9-2","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=240523","title":{"rendered":"\u82cf\u9ece\u4e16\u8054\u90a6\u7406\u5de5\u5b66\u9662Nature\uff1aCPET\u4ecb\u5bfc\u7b56\u7565\u5b9e\u73b0CO2\u9ad8\u6548\u9009\u62e9\u6027\u8fd8\u539f"},"content":{"rendered":"<p style=\"text-align: center;\"><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-240464\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image001-3.png\" alt=\"\" width=\"1538\" height=\"917\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image001-3.png 1538w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image001-3-300x179.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image001-3-768x458.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image001-3-1024x611.png 1024w\" sizes=\"(max-width: 1538px) 100vw, 1538px\" \/>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u8fc7\u6e21\u91d1\u5c5e\u6c22\u5316\u7269(M-H)\u5bf9H<sup>+<\/sup>\/H<sub>2<\/sub>\u76f8\u4e92\u8f6c\u5316\u3001CO<sub>2<\/sub>\u8fd8\u539f\u4e3a\u7532\u9178HCOOH\u4ee5\u53ca\u6c22\u5316\u53cd\u5e94\u8d77\u7740\u6838\u5fc3\u4f5c\u7528\u3002M-H\u7684\u7b80\u6613\u5f62\u6210\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u8fd9\u4e9b\u53cd\u5e94\u7684\u80fd\u91cf\u6548\u7387\u3002\u4ee5CO<sub>2<\/sub>\u7535\u8fd8\u539f\u4e3aHCOOH\u4e3a\u4f8b\uff0c\u7528\u6e29\u548c\u7684\u8d28\u5b50\u6e90\u901a\u8fc7\u7535\u5316\u5b66\u53cd\u5e94\u751f\u6210M-H\u53ef\u4ee5\u51cf\u5c11\u7ade\u4e89\u4ea7\u7269CO\u548cH<sub>2<\/sub>\u7684\u751f\u6210\u3002\u6839\u636e\u53cd\u5e94\u673a\u7406\uff0cM-H\u7684\u7535\u5316\u5b66\u751f\u6210\u901a\u5e38\u9700\u8981\u8fd8\u539f\u91d1\u5c5e\u4e2d\u5fc3\uff0c\u4e4b\u540e\u518d\u901a\u8fc7\u7535\u5b50\u8f6c\u79fb-\u8d28\u5b50\u8f6c\u79fb(ET-PT)\u6216\u8d28\u5b50\u8f6c\u79fb-\u7535\u5b50\u8f6c\u79fb(PT-ET)\u9010\u6b65\u5b9e\u73b0\u8d28\u5b50\u548c\u7535\u5b50\u7684\u8f6c\u79fb\u3002<strong>\u5c3d\u7ba1\u4f7f\u7528\u8f83\u5f31\u7684\u9178\u6e90\u53ef\u4ee5\u5728\u9002\u5ea6\u7684\u7535\u4f4d\u4e0b\u4ea7\u751f\u5f31\u53cd\u5e94\u6027\u7684<\/strong><strong>M-H<\/strong><strong>\uff0c\u4f46\u5728<\/strong><strong>CO<sub>2<\/sub><\/strong><strong>\u8fd8\u539f\u8fc7\u7a0b\uff0c\u66f4\u5177\u53cd\u5e94\u6027\u7684<\/strong><strong>M-H<\/strong><strong>\u9700\u8981\u9ad8\u5ea6\u8fd8\u539f\u7684\u91d1\u5c5e\u4e2d\u5fc3\u6216\u4f7f\u7528\u5f3a\u9178\uff0c\u4f46\u8fd9\u4f1a\u964d\u4f4e\u80fd\u6e90\u6548\u7387\u548c\u901f\u7387<\/strong>\u3002\u76ee\u524dM-H\u4ecb\u5bfc\u7684\u7535\u50ac\u5316\u7684\u4e3b\u8981\u8fdb\u5c55\u6765\u81ea\u4e8e\u4f7f\u7528\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u6539\u8fdbET\u6b65\u9aa4\u6216\u4f7f\u7528\u8d28\u5b50\u7a7f\u68ad\u6539\u8fdbPT\u6b65\u9aa4\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p><strong>\u82cf\u9ece\u4e16\u8054\u90a6\u7406\u5de5\u5b66\u9662<\/strong><strong>Victor Mougel<\/strong><strong>\u7b49\u4eba<\/strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u7535\u5316\u5b66\u751f\u6210M-H\u7684\u66ff\u4ee3\u7b56\u7565\u3002\u5373\u5728\u4e00\u4e2a\u52a8\u529b\u5b66\u8fc7\u7a0b\u4e2d\u5c06\u7535\u5316\u5b66\u751f\u6210\u7684\u6c22\u6574\u4f53\u8f6c\u79fb\u5230\u91d1\u5c5e\u4e2d\u5fc3\uff0c\u901a\u8fc7<strong>\u534f\u540c\u8d28\u5b50<\/strong><strong>&#8211;<\/strong><strong>\u7535\u5b50\u8f6c\u79fb<\/strong><strong>(CPET)<\/strong>\u751f\u6210M-H\u5b9e\u73b0\u4e86\u66f4\u9ad8\u6548CO<sub>2<\/sub>RR\u7684\u53cd\u5e94\u901f\u7387\u4ee5\u53ca\u66f4\u4f4e\u7684\u9a71\u52a8\u529b\u3002\u4f5c\u8005\u7814\u7a76\u4e86\u4e00\u7cfb\u5217CPET\u4ecb\u8d28\u4e0eCO<sub>2<\/sub>\u7535\u8fd8\u539f\u50ac\u5316\u5242[Mn<sup>I<\/sup>(bpy)(CO)<sub>3<\/sub>Br]\u7684\u7ec4\u5408\uff0c\u63a2\u7a76\u4e86Mn-H\u751f\u6210\u6b65\u9aa4\u5bf9\u4ea7\u7269\u9009\u62e9\u6027\u6548\u7387\u7684\u5f71\u54cd\u3002\u5e76\u901a\u8fc7\u7535\u5316\u5b66\u7ea2\u5916\u5149\u8c31\uff08IRSEC\uff09\u8bc1\u660e\u4e86Mn-H\u4e2d\u95f4\u4f53\u7684\u5f62\u6210\uff0c\u786e\u5b9a\u4e86\u8fd9\u79cd\u673a\u5236\u53d1\u751f\u7684\u70ed\u529b\u5b66\u8fb9\u754c\u6761\u4ef6\u3002\u6700\u540e\u4f5c\u8005\u53d1\u73b0Fe-S\u7c07\u662fCO<sub>2<\/sub>\u7535\u8fd8\u539f\u7684\u6700\u4f73CPET\u4ecb\u8d28\uff0c\u80fd\u591f\u5f97\u5230\u6700\u5927\u5316HCOOH\u751f\u6210\u7684\u57fa\u51c6\u50ac\u5316\u7cfb\u7edf\u3002\u76f8\u5173\u6210\u679c\u4ee5<em>\u201cElectrocatalytic metal hydride generation using CPET mediators<\/em>\u201d\u53d1\u8868\u5728<strong><em>Nature<\/em><\/strong>\u4e0a\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p><strong>1.<\/strong><strong>\u63d0\u51fa\u4e86\u534f\u540c\u8d28\u5b50<\/strong><strong>&#8211;<\/strong><strong>\u7535\u5b50\u8f6c\u79fb<\/strong><strong>(CPET)<\/strong><strong>\u7535\u50ac\u5316\u751f\u6210<\/strong><strong>M-H<\/strong><strong>\u4e2d\u95f4\u4ea7\u7269<\/strong><strong>\u7684\u6982\u5ff5<\/strong><\/p>\n<p><strong>2.<\/strong><strong>\u7814\u7a76\u4e86<\/strong><strong>CPET<\/strong><strong>\u4ecb\u5bfc\u7684<\/strong><strong>M-H<\/strong><strong>\u751f\u6210\u7684\u70ed\u529b\u5b66\u8fb9\u754c\u6761\u4ef6<\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-240465\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image003-6.png\" alt=\"\" width=\"1262\" height=\"1252\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image003-6.png 1262w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image003-6-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image003-6-300x298.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image003-6-768x762.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image003-6-1024x1016.png 1024w\" sizes=\"(max-width: 1262px) 100vw, 1262px\" \/>\u56fe<\/strong><strong>1.<\/strong> CPET\u4ecb\u5bfc\u7684\u91d1\u5c5e\u6c22\u5316\u7269\u7684\u5f62\u6210 <strong>\u00a9 2022 Springer Nature<\/strong><\/p>\n<p>\u7edd\u5927\u591a\u6570\u7528\u4e8eCO<sub>2<\/sub>RR\u7684\u7535\u50ac\u5316\u5242\u4fc3\u8fdbCO<sub>2<\/sub>\u7684\u53cc\u7535\u5b50\u8fd8\u539f\u4e3aCO\u6216HCOOH\uff0cHCOOH\u7684\u8fd8\u539f\u901a\u5e38\u9700\u8981\u5f62\u6210M-H\u4e2d\u95f4\u4f53\uff0c\u800cCO\u7684\u5f62\u6210\u901a\u5e38\u9700\u8981CO<sub>2<\/sub>\u4e0e\u91d1\u5c5e\u4e2d\u5fc3\u7684\u76f4\u63a5\u76f8\u4e92\u4f5c\u7528\u5e76\u6392\u9664M-H\u5f62\u6210\u3002<strong>\u56fe<\/strong><strong>1<\/strong>b\u5c55\u793a\u4e86Mn<sup>I<\/sup>-cat\u5728\u7535\u50ac\u5316\u548c\u5149\u50ac\u5316CO<sub>2<\/sub>RR\u4e2d\u7684\u8fc7\u7a0b\u3002\u53ef\u4ee5\u53d1\u73b0\u5176\u5728\u7535\u5316\u5b66\u6761\u4ef6\u4e0b\u4ea7\u751fCO\uff0c\u800c\u5728\u5149\u5316\u5b66\u6761\u4ef6\u4e0b\u4e3b\u8981\u4ea7\u7269\u4e3aHCOOH\u3002\u8fd9\u79cd\u9009\u62e9\u6027\u7684\u53d8\u5316\u4e0e\u50ac\u5316\u8fc7\u7a0b\u4e2d\u6d89\u53ca\u7684\u53cd\u5e94\u9014\u5f84\u76f4\u63a5\u76f8\u5173\u3002\u6700\u8fd1\u7684\u7814\u7a76\u8868\u660e\u5408\u6210\u7684Fe-S\u7c07\u662f\u80fd\u591f\u5728\u5316\u5b66\u8ba1\u91cf\u53cd\u5e94\u4e2d\u63d0\u4f9b\u6216\u63a5\u53d7H\u539f\u5b50\u3002\u6b64\u5916\uff0c\u5b83\u4eec\u7684\u91cd\u7ec4\u80fd\u4f4e\uff0c\u8fd9\u662f\u9176\u50ac\u5316\u7cfb\u7edf\u4e2d\u9ad8\u6548\u7535\u5b50\u8f6c\u79fb\u7684\u5173\u952e\uff0c\u5f53\u7528\u4f5cCPET\u4ecb\u5bfc\u65f6\uff0c\u5b83\u4eec\u53ef\u4ee5\u9ad8\u6548\u518d\u751f\u3002\u6700\u540e\uff0cFe-S\u7c07\u53ef\u4ee5\u4e3aCPET\u63d0\u4f9b\u591a\u4f4d\u70b9\uff0c\u5176\u4e2d\u8d28\u5b50\u5316\u53d1\u751f\u5728\u786b\u57fa\uff0c\u800c\u8fd8\u539f\u53d1\u751f\u5728Fe\u4e2d\u5fc3\u3002\u57fa\u4e8e\u6b64\uff0c\u4f5c\u8005\u4f7f\u7528Fe-S\u7c07\u4f5c\u4e3aCPET\u4ecb\u8d28\uff0c\u4ee5Mn<sup>I<\/sup>-cat\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u5bf9CO<sub>2<\/sub>RR\u8fdb\u884c\u7814\u7a76\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-240466\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image005-3.png\" alt=\"\" width=\"1817\" height=\"1009\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image005-3.png 1817w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image005-3-300x167.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image005-3-768x426.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image005-3-1024x569.png 1024w\" sizes=\"(max-width: 1817px) 100vw, 1817px\" \/>\u56fe<\/strong><strong>2.<\/strong> CPET\u4ecb\u5bfc\u7684Mn<sup>I<\/sup>-cat\u7684CO2RR\u6d3b\u6027\u76f8\u5173\u4e2d\u95f4\u4f53\u7684\u50ac\u5316\u6d3b\u6027\u548cIRSEC\u5149\u8c31 <strong>\u00a92022 Springer Nature<\/strong><\/p>\n<p>\u5728\u6c29\u6c14\u73af\u5883\u4e0b\uff0cMn<sup>I<\/sup>-cat\u548cFe-S\u7c07(1:1)\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u4e0e\u5176\u5404\u4e2a\u7ec4\u5206\u7684CV\u603b\u548c\u76f8\u540c\uff0c\u4e0d\u540c\u5cf0\u4f4d\u5bf9\u5e94\u4e8e\u53d1\u751f\u5728-1.34\u2009V\u3001-1.65\u2009V\u548c-1.89\u2009V\u7684\u8fde\u7eed\u4e09\u4e2a1e<sup>\u2212<\/sup>\u8fd8\u539f\u53cd\u5e94\u3002\u53e6\u5916\uff0c\u5728\u4f7f\u75282,2,2-\u4e09\u6c1f\u4e59\u9187(TFE)\u4f5c\u4e3a\u8d28\u5b50\u6e90\u65f6\uff0c\u7535\u5316\u5b66\u53cd\u5e94\u53d1\u751f\u660e\u663e\u53d8\u5316\u3002\u4ece<strong>\u56fe<\/strong><strong>2<\/strong>a\u4e2d\u53ef\u4ee5\u770b\u51faMn<sup>I<\/sup>-cat\u548cFe-S\u76841:1\u6df7\u5408\u7269\u7684CV\u76f8\u5bf9\u4e8e\u6bcf\u4e2a\u590d\u5408\u7269\u7684CV\u8868\u73b0\u51fa\u4e24\u4e2a\u663e\u7740\u53d8\u5316\uff1a\u5728-2.05\u2009V\u5904\u7684\u7535\u6d41\u5927\u7ea6\u670950%\u7684\u589e\u5f3a\uff0c\u540c\u65f6\u5728-1.85\u2009V\u5904\u51fa\u73b0\u4e86\u65b0\u7684\u50ac\u5316\u7279\u5f81\u5cf0\u3002\u589e\u52a0Fe-S\u7684\u6d53\u5ea6\u4e0d\u4f1a\u5f71\u54cd-2.05\u2009V\u5cf0\u7684\u7535\u6d41\uff0c\u4f46\u4f1a\u5bfc\u81f4-1.85\u2009V\u5904\u7684\u50ac\u5316\u7535\u6d41\u8fdb\u4e00\u6b65\u589e\u52a0\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c-1.85\u2009V\u7684\u65b0\u50ac\u5316\u8fc7\u7a0b\u4e0e\u7531Fe-S\u548cMn<sup>I<\/sup>-cat\u7684\u534f\u540c\u7ec4\u5408\u4ea7\u751f\u7684\u65b0\u50ac\u5316\u7269\u8d28\u7684\u4ea7\u751f\u6709\u5173\u3002\u4e3a\u4e86\u63a2\u7a76\u8fd9\u79cd\u65b0\u7684\u50ac\u5316\u673a\u7406\uff0c\u4f5c\u8005\u8fdb\u884c\u4e86\u4e00\u7cfb\u521790\u5206\u949f\u7684\u53d7\u63a7\u7535\u4f4d\u7535\u89e3(CPE)\u5b9e\u9a8c\u3002\u53d1\u73b0\u5728-1.85\u2009V\u7684CPE\u4ea7\u7269\u9009\u62e9\u6027\u548c\u5f62\u6210\u901f\u7387\u5b8c\u5168\u8f6c\u53d8\u3002\u968f\u7740Fe-S\u6d53\u5ea6\u7684\u589e\u52a0\uff0c\u4ee51:2\u7684\u6bd4\u7387\u8fbe\u5230\u6700\u5927\u5e73\u53f0\uff0c\u56e0\u6b641:2 Mn<sup>I<\/sup>-cat\/Fe-S\u50ac\u5316\u5242\u7ec4\u5408\u662f\u5c06CO<sub>2<\/sub>\u8fd8\u539f\u4e3aHCOOH\u7684\u6700\u4f73\u5206\u5b50\u7535\u50ac\u5316\u7cfb\u7edf\u4e4b\u4e00\u3002CO\u5230HCOOH\u7684\u9009\u62e9\u6027\u53d8\u5316\u8868\u660e\u5728Fe-S\u5b58\u5728\u4e0b\u5f62\u6210\u4e86Mn-H\u4e2d\u95f4\u4f53\uff0c\u4f5c\u8005\u901a\u8fc7IRSEC\u8c31\u7814\u7a76\u4e86\u4e2d\u95f4\u4f53\u7684\u751f\u6210\uff0c\u7ed3\u679c\u8868\u660e\u57281,990\u548c 1,892\u2009cm<sup>-1<\/sup>\u5904\uff0c\u4ee5\u53ca\u57281,764\u2009cm<sup>-1<\/sup>\u5904\u5b58\u5728\u5f31\u632f\u52a8\u5cf0\uff0c\u5bf9\u5e94\u4e8eMn<sup>I<\/sup>-H\u4e2dMn(I)\u7684\u7279\u5f81\u632f\u52a8\u5cf0\u7684\u51fa\u73b0\u3002\u5728\u6ca1\u6709Fe-S\u6216TFE\u7684\u60c5\u51b5\u4e0b\uff0c\u6ca1\u6709\u89c2\u5bdf\u5230\u4e0eMn<sup>I<\/sup>-H\u76f8\u5173\u7684\u632f\u52a8\u3002\u8fd9\u8868\u660e\u5728Fe-S\u7684\u5b58\u5728\u4fc3\u8fdbMn<sup>I<\/sup>-H\u7684\u5f62\u6210\u3002Mn<sup>I<\/sup>-cat\/Fe-S(1:1)\u6eb6\u6db2\u7684<sup>1<\/sup>H NMR\u6ce2\u8c31\u4e2d\uff0c\u5728-3.12\u2009ppm\u7684\u6c22\u5316\u7269\u5171\u632f\u7684\u51fa\u73b0\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u4e86Mn<sup>I<\/sup>-H\u7684\u5f62\u6210\u3002\u5f53\u4f7f\u7528TFED\u4ee3\u66ffTFE\u65f6\uff0c<sup>1<\/sup>H NMR\u5149\u8c31\u4e2d\u7684Mn<sup>I<\/sup>-H\u548cHCOOH\u4fe1\u53f7\u6d88\u5931\u3002\u5728\u76f8\u540c\u6761\u4ef6\u4e0b\uff0c\u5728\u6ca1\u6709Fe-S\u7684\u60c5\u51b5\u4e0b\uff0c\u6ca1\u6709\u89c2\u5bdf\u5230\u4e0eMn<sup>I<\/sup>-H\u76f8\u5173\u7684\u4fe1\u53f7\u3002\u8fd9\u8868\u660eFe-S\u548cMn<sup>I<\/sup>-cat\u7684\u534f\u540c\u7ec4\u5408\u4fc3\u8fdb\u4e86Mn<sup>I<\/sup>-H\u7684\u751f\u6210\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-240467\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image007-4.png\" alt=\"\" width=\"1269\" height=\"1305\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image007-4.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image007-4-292x300.png 292w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image007-4-768x790.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image007-4-996x1024.png 996w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/>\u56fe<\/strong><strong>3.<\/strong> \u50ac\u5316CPET\u4ecb\u5bfc\u7684\u91d1\u5c5e\u6c22\u5316\u7269\u5f62\u6210\u7684\u70ed\u529b\u5b66\u548c\u52a8\u529b\u5b66\u6d4b\u8bd5 <strong>\u00a9 2022 Springer Nature<\/strong><\/p>\n<p>\u4e3a\u4e86\u63a2\u7a76CPET\u4ecb\u5bfc\u7684\u91d1\u5c5e\u6c22\u5316\u7269\u751f\u6210\u7684\u70ed\u529b\u5b66\u548c\u52a8\u529b\u5b66\u6761\u4ef6\u3002\u5728<strong>\u56fe<\/strong><strong>3<\/strong>\u4e2d\uff0c\u4f5c\u8005\u8003\u8651\u4e86\u4e24\u4e2aCPET\u6b65\u9aa4\uff1a(1)\u5177\u6709\u7535\u5b50\u548c\u8d28\u5b50\u7684med-H\u7269\u8d28\u7684\u518d\u751f\uff1b(2)\u8868\u89c2\u6c22\u539f\u5b50\u5411\u5355\u4e00\u8fd8\u539f\u91d1\u5c5e\u4f4d\u70b9[M<sup>(n-1)+<\/sup>]\u7684\u6574\u4f53\u8f6c\u79fb\u3002\u8fd9\u4e24\u4e2a\u6b65\u9aa4\u90fd\u53ef\u4ee5\u7528Marcus\u5f62\u5f0f\u6765\u89e3\u91ca\uff0c\u4f5c\u8005\u9884\u8ba1\u53cd\u5e94\u901f\u7387(k<sub>CPET<\/sub>)\u548c\u70ed\u529b\u5b66\u9a71\u52a8\u529b(\u0394G\u00b0<sub>CPET<\/sub>)\u4e4b\u95f4\u5b58\u5728\u5bf9\u79f0\u4f9d\u8d56\u6027\uff0c\u4ece\u800c\u5bfc\u81f4\u8f83\u4f4e\u7684\u6d3b\u5316\u52bf\u5792\u3002\u9996\u5148\uff0cCPET\u4ecb\u8d28\u7684\u6709\u6548\u518d\u751f\u6210\u9700\u8981\u6700\u5c0f\u5316\u7684\u9a71\u52a8\u529b\u0394G\u00b0<sub>1<\/sub>\u548c\u91cd\u7ec4\u80fd\u03bb1\u4fc3\u8fdbmed\u2192med-H\u7684\u8f6c\u5316\u3002\u9009\u62e9CPET\u7ed3\u6784\u548c\u6781\u6027\u53d8\u5316\u6700\u5c0f\u7684\u4ecb\u8d28\u662f\u964d\u4f4e\u03bb1\u7684\u5408\u7406\u9009\u62e9\u3002\u5176\u6b21\uff0c\u4ece\u70ed\u529b\u5b66\u89d2\u5ea6\u6765\u770b\uff0c\u5bf9\u4e8e\u4ecemed-H\u5230\u8fd8\u539f\u91d1\u5c5e\u914d\u5408\u7269M\u53d1\u751f\u7684CPET\u8fc7\u7a0b\uff0cmed-H\u7684BDFE\u5e94\u8be5\u4f4e\u4e8e\u5f62\u6210\u7684M-H\u7684BDFE\u3002\u540c\u65f6\u4e3a\u4e86\u964d\u4f4e\u76f8\u5173\u7684\u52a8\u80fd\u52bf\u5792\uff0c\u8fd9\u4e9b\u503c\u5e94\u8be5\u63a5\u8fd1\u3002\u6700\u540e\uff0c\u4e3a\u4e86\u786e\u4fdd\u4ece\u8d28\u5b50\u6e90\u5230\u4ecb\u8d28\u7684\u6709\u6548\u8d28\u5b50\u8f6c\u79fb\uff0c\u5e94\u8be5\u6ee1\u8db3\u5173\u7cfbp<em>K<\/em><sub>a<\/sub> <sup>proton source<\/sup>\u2264\u2009p<em>K<\/em><sub>a<\/sub><sup>med-H<\/sup>\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-240468\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image009-3.png\" alt=\"\" width=\"1668\" height=\"1081\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image009-3.png 1668w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image009-3-300x194.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image009-3-768x498.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/image009-3-1024x664.png 1024w\" sizes=\"(max-width: 1668px) 100vw, 1668px\" \/>\u56fe<\/strong><strong>4.<\/strong>\u5728\u5404\u79cdCPET\u4ecb\u8d28\u5b58\u5728\u4e0bMn<sup>I<\/sup>-cat\u7684CO<sub>2<\/sub>RR\u6d3b\u6027 <strong>\u00a9 2022 Springer Nature<\/strong><\/p>\n<p>\u5f53Mn<sup>I<\/sup>-cat\u7528\u4e8e\u5149\u5316\u5b66CO<sub>2<\/sub>RR\u65f6\uff0c\u4f5c\u8005\u901a\u8fc7BDFE\u548c\u6c34\u5408\u5ea6\u503c\u63a2\u7a76\u4e86\u50ac\u5316\u5242\u5bf9HCOOH\u751f\u6210\u7684\u9009\u62e9\u6027\u3002\u7531\u5149\u654f\u5242\u548c\u8d28\u5b50\u6e90\u5236\u6210\u7684\u590d\u5408\u7cfb\u7edf\u7684BDFE\u5728\u5149\u6fc0\u53d1\u4e0b\u7684\u5178\u578b\u964d\u4f4e\u503c\u4f4e\u4e8e40\u2009kcal\u2009mol<sup>-1<\/sup>\uff0c\u8fd9\u53ef\u4ee5\u89e6\u53d1Mn<sup>I<\/sup>-H\u548cHCOOH\u7684\u751f\u6210\u3002\u6b64\u5916\uff0c\u5728\u5404\u79cdCPET\u4ecb\u8d28\u5b58\u5728\u4e0b\u7684\u7535\u50ac\u5316\u6d4b\u8bd5\u663e\u793a\u5b83\u4eec\u5728Mn<sup>I<\/sup>-cat\u50ac\u5316\u6d3b\u6027\u4e2d\u7684\u4f5c\u7528\u7684\u51e0\u4e2a\u5173\u952e\u7279\u5f81\u3002\u9996\u5148\uff0c\u5728CPET\u4ecb\u8d28(\u5982H<sub>2<\/sub>Q)\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\uff0c\u4e5f\u89c2\u5bdf\u5230Mn<sup>I<\/sup>-cat\u7684CO<sub>2<\/sub>RR\u6d3b\u6027\u663e\u7740\u589e\u5f3a\uff0c\u4f46\u662f\u9009\u62e9\u6027\u6ca1\u6709\u53d8\u5316\u3002\u4f5c\u8005\u5c06\u8fd9\u79cd\u5feb\u901f\u7684\u901f\u7387\u63d0\u9ad8\u5f52\u56e0\u4e8eH<sub>2<\/sub>Q\u7684BDFE\u503c\u8fc7\u9ad8\uff0c\u65e0\u6cd5\u751f\u6210Mn<sup>I<\/sup>-H\u4e2d\u95f4\u4f53\uff0c\u4f46H<sub>2<\/sub>Q\u4ecd\u5145\u5f53CPET\u4ecb\u8d28\u4ee5\u63d0\u9ad8CO<sub>2<\/sub>RR\u53cd\u5e94\u901f\u7387\u3002\u5bf9\u518d\u751f\u6b65\u9aa4\u8fdb\u884c\u4e86\u8be6\u7ec6\u5206\u6790\uff0c\u53d1\u73b0\u8f83\u4f4e\u7684TON\u662f\u7531\u4e8e\u8d28\u5b50\u6e90\u8f6c\u79fb\u8d28\u5b50\u5bf9\u4ecb\u8d28\u548c\u6c27\u5316\u4ecb\u8d28\u7684\u5feb\u901f\u8fd8\u539f\u3002\u5176\u6b21\uff0c\u4f7f\u7528Fe-S\u4f5c\u4e3a\u4ecb\u8d28\u50ac\u5316CO<sub>2<\/sub>RR\u83b7\u5f97\u7684HCOOH\u7684\u6027\u80fd\u660e\u663e\u4f18\u4e8e\u4f7f\u7528Ru-NH\u548cDTH<sub>2<\/sub>Q\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u8fd9\u9879\u7814\u7a76\u4e3a\u5408\u7406\u9009\u62e9\u80fd\u591f\u50ac\u5316\u91d1\u5c5e\u6c22\u5316\u7269\u4e2d\u95f4\u4f53\u5f62\u6210\u7684CPET\u4ecb\u8d28\u63d0\u4f9b\u4e86\u6982\u5ff5\u6027\u7684\u9a8c\u8bc1\uff0c\u5e76\u901a\u8fc7\u5b9e\u9a8c\u8bc1\u660eFe-S\u7c07\u62e5\u6709\u4f4e\u91cd\u7ec4\u80fd\u548c\u5728\u914d\u4f53\u6846\u67b6\u4e0a\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u7684\u7b80\u5355\u8c03\u8282\u80fd\u529b\uff0c\u662f\u5f53\u524d\u50ac\u5316\u7cfb\u7edf\u975e\u5e38\u6709\u6548\u7684CPET\u4ecb\u8d28\u3002\u534f\u540c\u8d28\u5b50\u7535\u5b50\u8f6c\u79fb\u7b56\u7565(CPET)\u5728\u7535\u50ac\u5316\u751f\u6210M-H\u7684\u63d0\u51fa\u4e3a\u6d89\u53caM-H\u7684\u5e7f\u6cdb\u50ac\u5316\u53cd\u5e94\u63d0\u4f9b\u4e86\u6307\u5bfc\u3002<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>: Dey, S., Masero, F., Brack, E. et al. Electrocatalytic metal hydride generation using CPET mediators. <em>Nature<\/em> 607, 499\u2013506 (2022). https:\/\/doi.org\/10.1038\/s41586-022-04874-z<\/p>\n<p>\u672c\u6587\u7531MichstaBe\u5b59\u56fd\u6587\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u8fc7\u6e21\u91d1\u5c5e\u6c22\u5316\u7269(M-H)\u5bf9H+\/H2\u76f8\u4e92\u8f6c\u5316\u3001CO2\u8fd8\u539f\u4e3a\u7532\u9178HCOOH\u4ee5\u53ca\u6c22\u5316\u53cd\u5e94\u8d77\u7740\u6838\u5fc3\u4f5c\u7528\u3002M-H\u7684\u7b80\u6613\u5f62\u6210\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u8fd9\u4e9b\u53cd\u5e94\u7684\u80fd\u91cf\u6548\u7387&#8230;<\/p>\n","protected":false},"author":34745,"featured_media":240464,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2,67],"tags":[3633,4901,4898,4902],"class_list":["post-240523","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji","category-zhoubao","tag-co2-","tag-4901","tag-4898","tag-4902"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/240523"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/34745"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=240523"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/240523\/revisions"}],"predecessor-version":[{"id":240530,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/240523\/revisions\/240530"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/240464"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=240523"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=240523"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=240523"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}