{"id":240419,"date":"2022-07-29T08:33:13","date_gmt":"2022-07-29T00:33:13","guid":{"rendered":"\/\/m.iemloyee.com\/?p=240419"},"modified":"2022-07-29T08:33:13","modified_gmt":"2022-07-29T00:33:13","slug":"%e5%8f%88%e5%8f%8c%e5%8f%92%e5%8f%95%e6%98%af%e9%92%99%e9%92%9b%e7%9f%bf%ef%bc%8c%e4%b8%ad%e7%a7%91%e9%99%a2%e5%8d%8a%e5%af%bc%e4%bd%93%e7%a0%94%e7%a9%b6%e6%89%80%e6%b8%b8%e7%bb%8f%e7%a2%a7%e7%a0%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=240419","title":{"rendered":"\u53c8\u53cc\u53d2\u53d5\u662f\u9499\u949b\u77ff\uff0c\u4e2d\u79d1\u9662\u534a\u5bfc\u4f53\u7814\u7a76\u6240\u6e38\u7ecf\u78a7\u7814\u7a76\u5458\u4eca\u65e5Science"},"content":{"rendered":"

\u3010\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u805a\u7126\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u53d1\u5c55\uff0c\u5176\u529f\u7387\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u4e00\u76f4\u662f\u5168\u4e16\u754c\u7814\u7a76\u8005\u5173\u6ce8\u7684\u7126\u70b9\u3002\u5176\u4e2d\uff0c\u6709\u51e0\u79cd\u7b56\u7565\u53ef\u4ee5\u63d0\u9ad8\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSC\uff09\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387\uff0c\u4f8b\u5982\u751f\u957f\u5177\u6709\u9ad8\u7ed3\u6676\u5ea6\u7684\u8584\u819c\u3001\u63ba\u6742\u9634\u79bb\u5b50\u3001\u9633\u79bb\u5b50\u6216\u4e24\u8005<\/b><\/strong>\u3001<\/b><\/strong>\u8bbe\u8ba1\u7535\u8377\u4f20\u8f93\u5c42\uff0c\u4ee5\u53ca\u901a\u7528\u949d\u5316\u5c42<\/b><\/strong>\u7684<\/b><\/strong>\u4f7f\u7528<\/b><\/strong>\u3002\u4ee5\u524d\u7684\u62a5\u544a\u8868\u660e\uff0cPbI2<\/sub>\u7684\u7b2c\u4e8c\u9636\u6bb5\u5bf9\u4e8e\u83b7\u5f97\u9ad8\u6027\u80fd\u6c34\u5e73\u81f3\u5173\u91cd\u8981\u3002\u8fc7\u91cfPbI2<\/sub>\u65e0\u8bba\u662f\u5728\u9499\u949b\u77ff\u8584\u819c\u7684\u672c\u4f53\u4e2d\u8fd8\u662f\u5728\u6676\u754c\u5904\uff0c\u90fd\u5177\u6709\u7531I\u578b\u80fd\u5e26\u6392\u5217\u5f62\u6210\u7684\u949d\u5316\u6548\u5e94\u3002\u7136\u800c\uff0c\u8fc7\u91cf\u7684PbI<\/b><\/strong>2<\/b><\/sub><\/strong>\u8fc7\u4e8e\u6d3b\u8dc3\uff0c\u4f1a\u5bfc\u81f4\u5668\u4ef6\u7684\u4e0d\u7a33\u5b9a\u548c\u7535\u6d41\u5bc6\u5ea6\u7535\u538b\uff08\u00a0J-V\uff09 \u7279\u6027\u7684\u5927\u6ede\u540e<\/b><\/strong>\u3002\u8fd9\u4e24\u4e2a\u56e0\u7d20\u90fd\u53ef\u4ee5\u5f52\u56e0\u4e8ePbI2<\/sub>\u7684\u5149\u5206\u89e3\u548c\u589e\u5f3a\u7684\u79bb\u5b50\u8fc1\u79fb\u3002\u8c03\u63a7\u9499\u949b\u77ff\u8584\u819c\u4e2d\u8fc7\u91cf\u7684\u4e0d\u7a33\u5b9aPbI2<\/sub>\u4ee5\u5b9e\u73b0\u9ad8\u6548\u7387\u81f3\u5173\u91cd\u8981\u3002\u6700\u8fd1\uff0c\u7814\u7a76\u8005\u5f00\u53d1\u4e86\u4e00\u79cd\u914d\u4f53\u8c03\u8282\u65b9\u6cd5\u6765\u7ba1\u7406\u8fc7\u91cf\u7684PbI2<\/sub>\u5e76\u6210\u529f\u63d0\u9ad8\u4e86PCE\uff08\u9ad8\u8fbe22%\uff09\u548c\u7a33\u5b9a\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u63a0\u5f71\u3011<\/b><\/strong><\/p>\n

\u4eca\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u534a\u5bfc\u4f53\u7814\u7a76\u6240\u6e38\u7ecf\u78a7\u7814\u7a76\u5458\u56e2\u961f<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u901a\u8fc7RbCl\u63ba\u6742\u5c06PbI2<\/sub>\u8f6c\u5316\u4e3a\u975e\u6d3b\u6027(PbI2<\/sub>)2<\/sub>RbCl\u5316\u5408\u7269\uff08PIRC\uff09\uff0c\u4ece\u800c\u6709\u6548\u5730\u7a33\u5b9a\u4e86\u9499\u949b\u77ff\u76f8\u3002\u57fa\u4e8e\u8fd9\u4e00\u7b56\u7565\uff0c\u4f5c\u8005\u83b7\u5f97\u4e86FAPbI<\/b><\/strong>3<\/b><\/sub><\/strong>\uff08FA\uff0c\u7532\u9170\u80fa\uff09\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c6025.6%\u7684\u8ba4\u8bc1PCE\u3002\u8bbe\u5907\u5b58\u50a81000\u5c0f\u65f6\u540e\u4fdd\u6301\u5176\u539f\u59cbPCE\u503c\u768496%\uff0c\u572885<\/b><\/strong>\u2103<\/b><\/strong>\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c500\u5c0f\u65f6\u70ed\u7a33\u5b9a\u6027\u6d4b\u8bd5\u540e\u4fdd\u630180%<\/b><\/strong>\u3002\u5177\u4f53\u6765\u8bf4\uff0c\u901a\u8fc7\u4ee5\u524d\u62a5\u544a\u4e2d\u4f7f\u7528\u7684\u6539\u8fdb\u7684\u4e24\u6b65\u6cd5\u6c89\u79ef\u4e86\u7eafFAPbI3<\/sub>\uff0c\u9996\u5148\u5728\u886c\u5e95\u4e0a\u751f\u957fPbI2<\/sub>\u6676\u79cd\u5c42\uff0c\u540c\u65f6\u5c06\u6709\u673a\u76d0\u7532\u8112\u7898\u5316\uff08FAI\uff09\u6eb6\u6db2\u6c89\u79ef\u5728PbI2<\/sub>\u4e0a\u4ee5\u901a\u8fc7\u9000\u706b\u6269\u6563\u548c\u5f62\u6210\u9499\u949b\u77ff\u3002\u6b64\u5916\uff0c\u4e3a\u4e86\u6539\u5584\u9499\u949b\u77ff\u7ed3\u6676\uff0c\u5c06\u7532\u57fa\u6c2f\u5316\u94f5\uff08MACl\uff09\u6dfb\u52a0\u5230FAI\u6eb6\u6db2\u3002\u4e0e\u4e4b\u524d\u7684\u62a5\u9053\u76f8\u6bd4\uff0c\u4e3a\u4e86\u5c3d\u53ef\u80fd\u63d0\u9ad8\u9499\u949b\u77ff\u7684\u70ed\u7a33\u5b9a\u6027\u5e76\u964d\u4f4e\u5e26\u9699\uff0c\u672c\u7814\u7a76\u672a\u4f7f\u7528\u4f20\u7edf\u7684\u6709\u673a\u76d0\u7532\u57fa\u7898\u5316\u94f5\uff08MAI\uff09\u6216\u7532\u57fa\u6eb4\u5316\u94f5\uff0c\u4e14\u786e\u8ba45%\u6469\u5c14\u6bd4\u7684RbCl\u63ba\u6742\u662f\u5668\u4ef6\u6027\u80fd\u7684\u6700\u4f73\u6761\u4ef6<\/b><\/strong>\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cInactive (PbI<\/i><\/b><\/em><\/strong>2<\/i><\/b><\/sub><\/em><\/strong>)<\/i><\/b><\/em><\/strong>2<\/i><\/b><\/sub><\/em><\/strong>RbCl stabilizes perovskite films for efficient solar cells<\/i><\/b><\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Science<\/i><\/b><\/em><\/strong>\u4e0a\u3002\"\"<\/p>\n

\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/b><\/strong><\/p>\n

1.\u7528\u6c2f\u5316\u94f7\uff08RbCl\uff09\u63ba\u6742\u53ef\u4ee5\u4ea7\u751f\u88ab\u52a8\u975e\u6d3b\u6027(PbI2<\/sub>)2<\/sub>RbCl\u76f8\uff0c\u7a33\u5b9a\u9499\u949b\u77ff\u76f8\u5e76\u964d\u4f4e\u5176\u5e26\u9699\uff1b<\/p>\n

2.\u5668\u4ef6\u80fd\u591f\u8868\u73b0\u51fa25.6%\u7684\u8ba4\u8bc1\u6548\u7387\uff0c\u5e76\u572885\u2103\u4e0b\u8fd0\u884c500\u5c0f\u65f6\u540e\u4fdd\u6301\u8be5\u6548\u7387\u768480%\u3002<\/p>\n

\u3010\u6570\u636e\u6982\u89c8\u3011<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>\u4e00<\/b><\/strong>\u3001\u9499\u949b\u77ff\u4e0a\u7b2c\u4e8c\u76f8<\/b><\/strong>(PbI<\/b><\/strong>2<\/b><\/sub><\/strong>)<\/b><\/strong>2<\/b><\/sub><\/strong>RbCl<\/b><\/strong>\u7684\u5fae\u89c2\u7ed3\u6784\u548c\u5f62\u8c8c\u3002<\/b><\/strong>\"\"<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>\u4e8c\u3001\u63a7\u5236\u548cPIRC\u9499\u949b\u77ff\u8584\u819c\u7684\u6027\u8d28\uff0c\u5305\u62ec\u79bb\u5b50\u4f20\u8f93\u3001\u6210\u5206\u548c\u5149\u81f4\u53d1\u5149<\/b><\/strong>\u3002<\/b><\/strong>\"\"<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>\u4e09<\/b><\/strong>\u3001\u5668\u4ef6\u7279\u6027\u548c\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/b><\/strong>\"\"<\/p>\n

\u3010<\/b><\/strong>\u6210\u679c\u542f\u793a<\/b><\/strong>\u3011<\/b><\/strong><\/p>\n

\u603b\u800c\u8a00\u4e4b\uff0c\u672c\u6587\u5c55\u793a\u7684PCE\u4ece24.6%\u4e0a\u5347\u81f325.6%\uff0c\u57fa\u4e8ePIRC\u7684\u5668\u4ef6\u51e0\u4e4e\u6ca1\u6709\u6ede\u540e\uff0c\u800c\u63a7\u5236\u5668\u4ef6\u5219\u8868\u73b0\u51fa\u660e\u663e\u7684\u6ede\u540e\uff0c\u4e14\u5728\u5b9e\u9a8c\u5ba4\u6d4b\u8bd5\u7684\u4f18\u5316\u540e\u6700\u9ad8PCE \u4e3a26.1%\uff0c\u8be5\u5668\u4ef6\u8fd8\u8868\u73b0\u51fa25.7%\u7684\u6548\u7387\u548c1200\u79d2\u7684\u7a33\u5b9a\u8f93\u51fa\uff0cPCE\u5206\u5e03\u7684\u7edf\u8ba1\u6570\u636e\u8bc1\u5b9e\u4e86\u7ed3\u679c\u7684\u53ef\u91cd\u590d\u6027\u3002\u5728500\u5c0f\u65f6\u7684\u8fde\u7eed\u52a0\u70ed\u4e0b\uff0c\u5668\u4ef6\u4fdd\u630180%\u7684\u521d\u59cb\u6027\u80fd\uff0c\u800c\u5bf9\u7167\u5668\u4ef6\u4ec5\u4fdd\u7559\u5176\u521d\u59cbPCE\u768450%\u3002\u672c\u7814\u7a76\u63d0\u51fa\u7684PIRC\u65b9\u6cd5\u53ef\u4ee5\u63d0\u9ad8\u7a33\u5b9a\u6027\u548c\u5668\u4ef6\u6548\u7387\uff0c\u8fd9\u5c06\u4e3a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u53d1\u5c55\u63d0\u4f9b\u65b0\u7684\u65b9\u5411\uff1b\u4e5f\u6709\u53ef\u80fd\u7528\u4e8e\u5176\u4ed6\u5149\u7535\u5668\u4ef6\uff0c\u4f8b\u5982\u53d1\u5149\u4e8c\u6781\u7ba1\u548c\u5149\u7535\u63a2\u6d4b\u5668\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/b><\/strong>Inactive (PbI<\/i><\/b><\/u><\/em><\/strong>2<\/i><\/b><\/sub><\/u><\/em><\/strong>)<\/i><\/b><\/u><\/em><\/strong>2<\/i><\/b><\/sub><\/u><\/em><\/strong>RbCl stabilizes perovskite films for efficient solar cells<\/i><\/b><\/u><\/em><\/strong><\/a>\u201d<\/b><\/strong>\uff08<\/b><\/strong>Science<\/i><\/b><\/em><\/strong>\uff0c<\/b><\/strong>202<\/b><\/strong>2<\/b><\/strong>\uff0c<\/b><\/strong>10.1126\/science.abp8873<\/b><\/strong>\uff09<\/b><\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4ebaCYM\u7f16\u8bd1\u4f9b\u7a3f\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu \u3002<\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5bfc\u8bfb\u3011 \u805a\u7126\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u53d1\u5c55\uff0c\u5176\u529f\u7387\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u4e00\u76f4\u662f\u5168\u4e16\u754c\u7814\u7a76\u8005\u5173\u6ce8\u7684\u7126\u70b9\u3002\u5176\u4e2d\uff0c\u6709\u51e0\u79cd\u7b56\u7565\u53ef\u4ee5\u63d0\u9ad8\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSC\uff09\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387\uff0c\u4f8b…<\/p>\n","protected":false},"author":9629,"featured_media":240420,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[155],"class_list":["post-240419","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-science"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/240419"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/9629"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=240419"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/240419\/revisions"}],"predecessor-version":[{"id":240424,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/240419\/revisions\/240424"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/240420"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=240419"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=240419"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=240419"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}