{"id":240123,"date":"2022-07-22T06:31:55","date_gmt":"2022-07-21T22:31:55","guid":{"rendered":"\/\/m.iemloyee.com\/?p=240123"},"modified":"2022-07-21T14:32:10","modified_gmt":"2022-07-21T06:32:10","slug":"%e9%95%bf%e6%98%a5%e5%ba%94%e5%8c%96%e6%89%80advanced-science%ef%bc%9a%e7%a7%bb%e8%8a%b1%e6%8e%a5%e6%9c%a8%ef%bc%8c%e9%80%a0%e5%b0%b1%e5%bf%ab%e5%85%85%e5%ae%bd%e6%b8%a9%e9%94%82%e7%a6%bb%e5%ad%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=240123","title":{"rendered":"\u957f\u6625\u5e94\u5316\u6240Advanced Science\uff1a\u79fb\u82b1\u63a5\u6728\uff0c\u9020\u5c31\u5feb\u5145\u5bbd\u6e29\u9502\u79bb\u5b50\u7535\u6c60\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762"},"content":{"rendered":"<p style=\"text-align: center;\"><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u53ef\u5145\u7535\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\u5728\u521d\u59cb\u5faa\u73af\u4e2d\uff0c\u7535\u89e3\u8d28\u5206\u89e3\u5728\u7535\u6781\u8868\u9762\u5f62\u6210\u4e86\u56fa\u6001\u7535\u89e3\u8d28\u4e2d\u95f4\u76f8(SEI)\uff0c\u8fd9\u79cd\u5f62\u6210\u7684SEI\u53ef\u4ee5\u4fdd\u62a4\u7535\u6781\u5e76\u51cf\u7f13\u8fdb\u4e00\u6b65\u7684\u7535\u89e3\u8d28\u5206\u89e3\uff0c\u4ece\u800c\u5b9e\u73b0\u66f4\u597d\u7684\u7535\u6781\u7a33\u5b9a\u6027\u548c\u66f4\u9ad8\u7684\u7535\u6c60\u6027\u80fd\u3002\u76ee\u524d\u8bb8\u591a\u65b9\u6cd5\u88ab\u5e7f\u6cdb\u5f00\u53d1\u7528\u6765\u63a7\u5236SEI\u7684\u6210\u5206\u548c\u7ed3\u6784\uff0c\u4ee5\u8ffd\u6c42\u66f4\u597d\u7684\u6027\u80fd\uff0c\u5305\u62ec\u7535\u6781\u6d82\u5c42\u548c\u7535\u89e3\u8d28\u5de5\u7a0b\u3002\u5176\u4e2d\uff0c\u7535\u89e3\u8d28\u5de5\u7a0b\u5df2\u6210\u4e3a\u5b9e\u9645\u5e94\u7528\u4e2d\u8c03\u6574SEI\u7684\u6700\u6709\u6548\u7b56\u7565\u3002\u901a\u8fc7\u5728\u9502\u79bb\u5b50\u7535\u6c60(LIBs)\u7684\u9633\u6781\u548c\u9634\u6781\u4e0a\u8bbe\u8ba1\u72ec\u7279\u7684SEI\u6216CEI\uff0c\u53ef\u4ee5\u663e\u7740\u63d0\u9ad8LIBs\u7684\u7a33\u5b9a\u6027\u548c\u53ef\u9760\u6027\u3002\u6b64\u5916\uff0c\u540c\u6837\u7684\u7b56\u7565\u4e5f\u53ef\u4ee5\u5728\u9502\u7535\u6c60\u4e2d\u7684\u9502\u91d1\u5c5e\u4ee5\u53ca\u5176\u4ed6\u7c7b\u578b\u7684\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\u7535\u6781\u4e0a\u4f7f\u7528\u3002\u7136\u800c\uff0c\u7531\u4e8e\u7535\u89e3\u8d28\u5206\u89e3\u53d6\u51b3\u4e8e\u7535\u89e3\u8d28\u6210\u5206\u548c\u7535\u6781\u7279\u6027\uff0c\u5206\u89e3\u8fc7\u7a0b\u9075\u5faa\u4e0d\u540c\u7684\u539f\u7406\uff0c<strong>\u89e3\u91ca<\/strong><strong>SEI<\/strong><strong>\u7684\u5f62\u6210\u673a\u5236\u53ca\u5176\u5bf9\u4e0d\u540c\u7535\u89e3\u8d28\u7684\u5f71\u54cd\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218<\/strong>\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p><strong>\u957f\u6625\u5e94\u7528\u5316\u5b66\u7814\u7a76\u6240\u660e\u519b\u7814\u7a76\u5458<\/strong>\u7b49\u4eba\u901a\u8fc7\u5207\u6362\u7535\u89e3\u8d28\u5f15\u5165\u4e86\u4e00\u79cd\u5168\u65b0\u7684\u7b56\u7565\u6765\u8c03\u6574SEI\u7684\u6027\u80fd\uff0c\u9996\u5148\u5728\u4e00\u79cd\u7279\u5b9a\u7684\u7535\u89e3\u8d28\u4e2d\u8d4b\u4e88\u7535\u6781\u7279\u5b9a\u7684SEI\uff0c\u7136\u540e\u5c06\u5176\u8f6c\u79fb\u5230\u53e6\u4e00\u79cd\u66f4\u901a\u7528\u7684\u7535\u89e3\u8d28\u4e2d\uff0c\u7535\u6c60\u53ef\u4ee5\u663e\u793a\u51fa\u66f4\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u4f5c\u4e3a\u8303\u4f8b\uff0c\u4f5c\u8005\u53d1\u73b0\u53ef\u4ee5\u5728\u919a\u7c7b\u7535\u89e3\u8d28\u4e2d\u7684\u77f3\u58a8\u9633\u6781\u4e0a\u53ef\u4ee5\u5f97\u5230\u66f4\u8584\u7684SEI(\u77f3\u58a8@SEI)\uff0c\u7136\u540e\u5c06\u83b7\u5f97\u7684\u77f3\u58a8@S\u200b\u200bEI\u5e94\u7528\u4e8e\u5546\u4e1a\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\uff0c\u7ed3\u679c\u53d1\u73b0\u6539\u6027\u7684\u77f3\u58a8\u9633\u6781\u80fd\u591f\u8f7b\u677e\u6784\u5efa\u5feb\u901f\u5145\u7535\u7684LIBs\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u6784\u5efa\u4e86\u4e00\u79cd\u754c\u9762\u6a21\u578b\u6765\u8bc1\u660e\u4ece\u919a\u57fa\u5230\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\u7684\u7535\u89e3\u8d28\u5206\u89e3\u8def\u5f84\u7684\u5dee\u5f02\uff0c\u4ece\u800c\u9610\u660e\u4e86LIBs\u83b7\u5f97\u66f4\u9ad8\u500d\u7387\u6027\u80fd\u7684\u539f\u56e0\u3002\u76f8\u5173\u6210\u679c\u4ee5<em>\u201cSwitching Electrolyte Interfacial Model to Engineer Solid Electrolyte Interface for Fast Charging and Wide-Temperature Lithium-Ion Batteries<\/em>\u201d\u53d1\u8868\u5728<em>Advanced Science<\/em>\u4e0a\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p><strong>1.<\/strong><strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u901a\u8fc7\u5207\u6362\u7535\u89e3\u8d28\u754c\u9762\u6a21\u578b\u6765\u8c03\u6574<\/strong><strong>SEI<\/strong><strong>\u6027\u80fd\u7684\u521b\u65b0\u6982\u5ff5\uff0c<\/strong><\/p>\n<p><strong>2.<\/strong><strong>\u63d0\u51fa\u4e86\u4e00\u4e2a\u5206\u5b50\u754c\u9762\u6a21\u578b\u6765\u9610\u660e<\/strong><strong>SEI<\/strong><strong>\u7684\u5f62\u6210\u673a\u5236\u3002<\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-240124\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/1-7.png\" alt=\"\" width=\"1336\" height=\"813\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/1-7.png 1336w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/1-7-300x183.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/1-7-768x467.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/1-7-1024x623.png 1024w\" sizes=\"(max-width: 1336px) 100vw, 1336px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1.<\/strong> \u5728\u7535\u6781\u4e0a\u6784\u5efa\u4eba\u5de5SEI\u793a\u610f\u56fe\u3002(a)\u539f\u59cb\u77f3\u58a8\u7535\u6781\u3002(b)\u5728\u7535\u89e3\u8d28A\u4e2d\u7684\u77f3\u58a8\u7535\u6781\u4e0a\u9884\u5148\u5f62\u6210\u8584\u7684SEI\uff0c\u7136\u540e(c)\u8fd9\u79cd\u8584\u7684SEI\u6d82\u5c42\u77f3\u58a8\u7535\u6781\u5728\u7535\u89e3\u8d28B\u4e2d\u8868\u73b0\u51fa\u9ad8\u500d\u7387\u80fd\u529b\u3002(d)\u5728\u7535\u89e3\u8d28B\u4e2d\u7684\u539f\u59cb\u77f3\u58a8\u7535\u6781\u4e0a\u5f62\u6210\u4e86\u539a\u7684SEI\u3002<strong>\u00a9 (2022) The Authors<\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1<\/strong>\u4e2d\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u901a\u8fc7\u5207\u6362\u7535\u89e3\u8d28\u754c\u9762\u6a21\u578b\u6765\u8c03\u6574SEI\u7279\u6027\u7684\u65b0\u6982\u5ff5\uff0c\u7535\u6781\u9996\u5148\u5728\u4e00\u79cd\u7279\u5b9a\u7684\u7535\u89e3\u8d28\u4e2d\u5faa\u73af\u5f62\u6210\u72ec\u7279\u7684SEI\uff0c\u7136\u540e\u5c06\u8fd9\u79cdSEI\u6d82\u5c42\u7535\u6781\u7528\u4e8e\u53e6\u4e00\u79cd\u76ee\u6807\u7535\u89e3\u8d28\u4e2d\uff0c\u80fd\u591f\u83b7\u5f97\u66f4\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u8fd9\u4e2a\u6982\u5ff5\u7684\u57fa\u672c\u539f\u7406\u5728\u4e8e\u4e0d\u540c\u7684\u7535\u89e3\u8d28\u4e2d\u5206\u89e3\u53ef\u4ee5\u5f62\u6210\u4e0d\u540c\u7684SEI\uff0c\u5f97\u5230\u4e0d\u540c\u7684\u7535\u89e3\u8d28\u754c\u9762\u6a21\u578b\uff0c\u4e5f\u5c31\u5177\u6709\u7279\u5b9a\u7684\u5185\u5728\u7279\u6027\uff0c\u5176\u56fa\u6709\u7279\u6027\u5bf9\u7535\u6c60\u6027\u80fd\u4f1a\u4ea7\u751f\u7279\u5b9a\u7684\u5f71\u54cd\u3002\u56e0\u6b64\uff0c\u8fd9\u79cd\u7b56\u7565\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u5c06\u4e0d\u540c\u7535\u89e3\u8d28\u7684\u4e0d\u540c\u4f18\u52bf\u7ed3\u5408\u5230\u4e00\u4e2a\u7535\u6c60\u7cfb\u7edf\u4e2d\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-240130\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/2-6.png\" alt=\"\" width=\"1336\" height=\"626\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/2-6.png 1336w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/2-6-300x141.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/2-6-768x360.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/2-6-1024x480.png 1024w\" sizes=\"(max-width: 1336px) 100vw, 1336px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2.<\/strong> \u77f3\u58a8\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002(a)\u500d\u7387\u6027\u80fd\u548c(b\uff0cc)\u7535\u538b\u4e0e\u5bb9\u91cf\u66f2\u7ebf\u6bd4\u8f83\uff0c(d\uff0ce)CV\uff0c\u548c(f)GITT\u66f2\u7ebf\u5728\u919a\u57fa\u7535\u89e3\u8d28\u4e0e\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\u4e2d\u8fd0\u884c\u7684\u77f3\u58a8\u7535\u6781\u7684\u6bd4\u8f83\u3002<strong>\u00a9 (2022) The Authors<\/strong><\/p>\n<p><strong>\u5982\u56fe<\/strong><strong>2<\/strong>\u6240\u793a\uff0c\u4f5c\u8005\u53d1\u73b0\u77f3\u58a8\u7535\u6781\u5728\u919a\u57fa\u548c\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\u4e2d\u7684\u50a8\u9502\u80fd\u529b\u663e\u7740\u4e0d\u540c\u3002\u77f3\u58a8\u7535\u6781\u5728\u919a\u57fa\u7535\u89e3\u8d28\u4e2d\u80fd\u591f\u63d0\u4f9b\u66f4\u9ad8\u7684\u5bb9\u91cf\u3002\u7136\u800c\uff0c\u7531\u4e8eLi<sup>+<\/sup>\u6eb6\u5242\u5171\u63d2\u5165\u5f15\u8d77\u7684\u77f3\u58a8\u5265\u79bb\uff0c\u5927\u591a\u6570\u919a\u57fa\u7535\u89e3\u8d28\u4e0e\u77f3\u58a8\u4e0d\u76f8\u5bb9\uff0c\u8fd9\u662f\u7b2c\u4e00\u6b21\u62a5\u9053\u919a\u57fa\u7535\u89e3\u8d28\u5177\u6709\u5982\u6b64\u9ad8\u7684\u500d\u7387\u6027\u80fd\u3002\u6b64\u5916\uff0c\u6839\u636e\u4e0d\u540c\u500d\u7387\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\u6bd4\u8f83\u53d1\u73b0\u7535\u6781\u5728\u919a\u57fa\u7535\u89e3\u8d28\u4e2d\u6781\u5316\u8981\u660e\u663e\u51cf\u5c0f\u3002\u5faa\u73af\u4f0f\u5b89(CV)\u66f2\u7ebf\u66f4\u5b8c\u7f8e\u7684\u91cd\u53e0\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e86\u77f3\u58a8\u7535\u6781\u5728\u919a\u57fa\u7535\u89e3\u8d28\u4e2d\u5177\u6709\u66f4\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u919a\u57fa\u7535\u89e3\u8d28\u4e2d\u66f4\u4f18\u5f02\u7684\u6027\u80fd\u53ef\u80fd\u662f\u7531\u4e8e\u77f3\u58a8\u7535\u6781\u4e0a\u5f62\u6210\u7684\u66f4\u8584\u7684SEI\u5177\u6709\u66f4\u9ad8\u7684Li<sup>+<\/sup>\u4f20\u8f93\u80fd\u529b\u3002\u6052\u7535\u6d41\u95f4\u6b47\u6ef4\u5b9a\u6280\u672f(GITT)\u53d1\u73b0\u77f3\u58a8\u7535\u6781\u5185\u7684\u5e73\u5747\u9502\u79bb\u5b50\u6269\u6563\u7cfb\u6570\u5728\u919a\u57fa\u7535\u89e3\u8d28\u4e2d\u8981\u9ad8\u4e8e\u5546\u7528\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\uff0c\u8bc1\u5b9e\u4e86\u8fd9\u4e00\u731c\u60f3\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-240131\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/3-6.png\" alt=\"\" width=\"1336\" height=\"799\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/3-6.png 1336w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/3-6-300x179.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/3-6-768x459.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/3-6-1024x612.png 1024w\" sizes=\"(max-width: 1336px) 100vw, 1336px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3.<\/strong> SEI\u7684\u5728\u4e0d\u540c\u7535\u89e3\u8d28\u4e2d\u7684\u7279\u5f81\u7814\u7a76\u3002(a\uff0cb)\u9502|\u77f3\u58a8\u534a\u7535\u6c60\u653e\u7535\u7684\u539f\u4f4dEIS\uff0c\u5faa\u73af\u540e\u7684\u77f3\u58a8\u7535\u6781\u5728\u919a\u57fa(c\uff0ce)\u548c\u78b3\u9178\u76d0\u57fa(d\uff0cf)\u7535\u89e3\u8d28\u7684SEM\u548cTEM\u56fe\u50cf\u3002<strong>\u00a9 (2022) The Authors<\/strong><\/p>\n<p>\u4f5c\u8005\u4e3a\u4e86\u89e3\u91ca\u4e0d\u540c\u77f3\u58a8\u7535\u6781\u5bf9\u5e94\u7684\u6027\u80fd\u7684\u4e0d\u540c\uff0c\u5728<strong>\u56fe<\/strong><strong>3<\/strong>\u4e2d\u901a\u8fc7\u539f\u4f4d\u7535\u5316\u5b66\u963b\u6297\u8c31(EIS)\u7814\u7a76\u4e86\u77f3\u58a8\u7535\u6781\u4e0a\u5f62\u6210\u7684SEI\u7684\u5dee\u5f02\u3002<strong>\u56fe<\/strong><strong>3<\/strong>a\u3001b\u663e\u793a\u4e86\u4f7f\u7528\u4e0d\u540c\u7535\u89e3\u8d28\u7cfb\u7edf\u83b7\u5f97\u7684\u5948\u594e\u65af\u7279\u56fe\u7684\u4fef\u89c6\u56fe\uff0c\u4ece\u7ea2\u8272\u5230\u84dd\u8272\uff0c\u659c\u7387\u503c\u7531\u6b63\u53d8\u4e3a\u8d1f\uff0c\u5bf9\u5e94\u534a\u5706\u7684\u5de6\u8fb9\u5230\u53f3\u8fb9\uff0c\u66f4\u5bbd\u7684\u68af\u5ea6\u4ee3\u8868\u534a\u5706\u7684\u534a\u5f84\u8d8a\u5927\uff0c\u8868\u793a\u963b\u6297\u8d8a\u9ad8\u3002\u919a\u57fa\u7535\u89e3\u8d28\u7cfb\u7edf\u4e2d\u7684\u77f3\u58a8\u7535\u6781\u8868\u73b0\u51fa\u6bd4\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\u7cfb\u7edf\u4f4e\u7684\u963b\u6297\uff0c\u6b64\u5916\uff0cSEM\u548cTEM\u56fe\u50cf\u8bc1\u5b9e\u4e86\u5728\u919a\u57fa\u7535\u89e3\u8d28\u4e2d\u7684\u77f3\u58a8\u7535\u6781\u4e0a\u5f62\u6210\u7684\u66f4\u5149\u6ed1\u3001\u66f4\u8584\u7684SEI\u3002\u66f4\u8584\u7684SEI\u63d0\u4f9b\u66f4\u77ed\u7684Li<sup>+<\/sup>\u4f20\u8f93\u8def\u5f84\uff0c\u6709\u52a9\u4e8e\u77f3\u58a8\u7535\u6781\u5728\u919a\u57fa\u7535\u89e3\u8d28\u4e2d\u7684\u9ad8\u500d\u7387\u80fd\u529b\u3002\u4f5c\u8005\u53d1\u73b0\u4e0d\u540c\u7684\u6027\u80fd\u4e3b\u8981\u662f\u7531\u4e0d\u540c\u7684SEI\u5c5e\u6027\u5f15\u8d77\u7684\u3002<\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-240125\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/4-6.png\" alt=\"\" width=\"1336\" height=\"830\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/4-6.png 1336w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/4-6-300x186.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/4-6-768x477.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/4-6-1024x636.png 1024w\" sizes=\"(max-width: 1336px) 100vw, 1336px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>4.<\/strong> \u5207\u6362\u7535\u89e3\u8d28\u754c\u9762\u6a21\u578b\u7684\u4f18\u52bf\u7814\u7a76\u3002(a)\u5207\u6362\u7535\u89e3\u8d28\u793a\u610f\u56fe\u548c(b)\u5207\u6362\u5b9e\u9a8c\u7684\u8fc7\u7a0b\u3002\u77f3\u58a8@S\u200b\u200bEI\u5728(c)\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\u4e2d\u548c(d)\u919a\u7c7b\u7535\u89e3\u8d28\u4e2d\u7684\u500d\u7387\u80fd\u529b\u6bd4\u8f83\u3002(e)\u901a\u8fc7\u5207\u6362\u7535\u89e3\u8d28\u83b7\u5f97\u7684\u77f3\u58a8\u7535\u6781\u7684\u500d\u7387\u6027\u80fd\u4e0e\u4e4b\u524d\u62a5\u9053\u7684\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\u7684\u6bd4\u8f83\u3002<strong>\u00a9 (2022) The Authors<\/strong><\/p>\n<p>\u4e3a\u4e86\u8bc1\u5b9e\u63d0\u51fa\u7684\u6982\u5ff5\uff0c\u4f5c\u8005\u5728<strong>\u56fe<\/strong><strong>4<\/strong>\u4e2d\u65b0\u8bbe\u8ba1\u4e86\u7535\u89e3\u8d28\u4ea4\u6362\u5b9e\u9a8c\u3002SEI\u662f\u77f3\u58a8\u7535\u6781\u5728\u919a\u57fa\u6216\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\u4e2d\u5faa\u73af\u591a\u6b21\u540e\u9884\u5148\u5f62\u6210\u7684(\u77f3\u58a8@SEI)\uff0c\u53d6\u51fa\u77f3\u58a8@SEI\uff0c\u7136\u540e\u4f7f\u7528\u53e6\u4e00\u79cd\u7535\u89e3\u8d28\u91cd\u65b0\u7ec4\u88c5\u5230\u65b0\u7535\u6c60\u4e2d\u3002\u7ed3\u679c\u8868\u660e\uff0c\u77f3\u58a8\u5728\u919a\u57fa\u7535\u89e3\u8d28\u4e2d\u9884\u5148\u5f62\u6210\u7684SEI\u6709\u5229\u4e8e\u5728\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\u4e2d\u83b7\u5f97\u9ad8\u500d\u7387\u6027\u80fd\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u53d1\u73b0\u5f53\u77f3\u58a8@SEI\u7535\u6781\u5728\u65b0\u7535\u6c60\u4e2d\u91cd\u65b0\u7ec4\u88c5\u65f6\uff0c\u5373\u4ece\u919a\u57fa\u7535\u89e3\u8d28\u5230\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\uff0c\u9996\u6b21\u5e93\u4ed1\u6548\u7387\u53ef\u4ee5\u4ece82.3%\u63d0\u9ad8\u523088.6%\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u5728\u5207\u6362\u5b9e\u9a8c\u8fc7\u7a0b\u4e2d\uff0c\u9884\u5148\u5f62\u6210\u7684\u8584SEI\u53ef\u4ee5\u5f88\u597d\u5730\u4fdd\u6301\uff0c\u5e76\u4e14\u8fd9\u79cdSEI\u53ef\u4ee5\u6709\u6548\u5730\u6291\u5236\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\u5728\u77f3\u58a8\u4e0a\u7684\u5206\u89e3\uff0c\u4ece\u800c\u4f7f\u65b0\u578b\u7535\u6c60\u5177\u6709\u9ad8\u500d\u7387\u6027\u80fd\u3002<\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-240126\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/5-6.png\" alt=\"\" width=\"1336\" height=\"896\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/5-6.png 1336w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/5-6-300x201.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/5-6-768x515.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/5-6-1024x687.png 1024w\" sizes=\"(max-width: 1336px) 100vw, 1336px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>5. <\/strong>\u5207\u6362SEI\u7684\u5f62\u6210\u673a\u5236\u3002\u5728\u919a\u57fa\u7535\u89e3\u8d28\u4e0e\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\u4e2d\u5f62\u6210\u7684SEI\u7684(a-c)XPS\u5149\u8c31\u6bd4\u8f83\u3002(d)\u919a\u57fa\u7535\u89e3\u8d28\u4e2d\u5f62\u6210\u7684SEI\u5b58\u5728N 1s\u548cS 2p\u3002(e)\u919a\u57fa\u7535\u89e3\u8d28\u548c(f)\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\u4e2d\u77f3\u58a8\u7535\u6781\u4e0a\u7684\u7535\u89e3\u8d28\u5206\u89e3\u884c\u4e3a\u548cSEI\u5f62\u6210\u8fc7\u7a0b\u793a\u610f\u56fe\u3002(g)SEI\u5f62\u6210\u8fc7\u7a0b\u4e2d\u4e0d\u540c\u7ed3\u6784\u7684LUMO\u548cHOMO\u80fd\u91cf\u3002(h)\u5728\u919a\u57fa\u7535\u89e3\u8d28\u4e2d\u9884\u5148\u5f62\u6210\u7684SEI\u793a\u610f\u56fe\u3002<strong>\u00a9 (2022) The Authors<\/strong><\/p>\n<p>\u4f5c\u8005\u5728<strong>\u56fe<\/strong><strong>5<\/strong>\u4e2d\u5bf9SEI\u7684\u5f62\u6210\u673a\u5236\u8fdb\u884c\u4e86\u5b9e\u9a8c\u548c\u7406\u8ba1\u7b97\u7814\u7a76\uff0c\u5206\u6790\u4e86\u8fd9\u4e24\u79cd\u7535\u89e3\u8d28\u7684SEI\u7684\u7ec4\u6210\u548c\u7ed3\u6784\u3002\u901a\u8fc7XPS\u5206\u6790\u6bd4\u8f83Li 1s\u548cC 1s\u7ed3\u679c\u8868\u660e\u919a\u57fa\u7535\u89e3\u8d28\u7684\u5206\u89e3\u53d7\u5230\u9650\u5236\uff0c\u4ece\u800c\u80fd\u591f\u5f62\u6210\u66f4\u8584\u7684SEI\u5c42\u3002\u5e76\u4e14\u4f5c\u8005\u4ece\u919a\u57fa\u7535\u89e3\u8d28\u7684SEI\u4e2d\u68c0\u6d4b\u5230N\u548cS\u57fa\u7269\u8d28\uff0c\u8fd9\u6709\u52a9\u4e8e\u5f62\u6210\u66f4\u575a\u56fa\u7684SEI\uff0c\u5e76\u6709\u52a9\u4e8e\u901a\u8fc7\u5171\u4ef7\u952e\u66f4\u5feb\u5730\u4f20\u8f93 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Liu, G., et.al, Switching Electrolyte Interfacial Model to Engineer Solid Electrolyte Interface for Fast Charging and Wide-Temperature Lithium-Ion Batteries. Adv. Sci. 2022, 2201893. https:\/\/doi.org\/10.1002\/advs.202201893<\/p>\n<p>\u672c\u6587\u7531MichstaBe\u5b59\u56fd\u6587\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u53ef\u5145\u7535\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\u5728\u521d\u59cb\u5faa\u73af\u4e2d\uff0c\u7535\u89e3\u8d28\u5206\u89e3\u5728\u7535\u6781\u8868\u9762\u5f62\u6210\u4e86\u56fa\u6001\u7535\u89e3\u8d28\u4e2d\u95f4\u76f8(SEI)\uff0c\u8fd9\u79cd\u5f62\u6210\u7684SEI\u53ef\u4ee5\u4fdd\u62a4\u7535\u6781\u5e76\u51cf\u7f13\u8fdb\u4e00\u6b65\u7684\u7535\u89e3\u8d28\u5206\u89e3\uff0c\u4ece\u800c\u5b9e&#8230;<\/p>\n","protected":false},"author":34745,"featured_media":240128,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[4011,4890,3397,2609],"class_list":["post-240123","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji","tag-libs","tag-4890","tag-3397","tag-2609"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/240123"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/34745"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=240123"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/240123\/revisions"}],"predecessor-version":[{"id":240147,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/240123\/revisions\/240147"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/240128"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=240123"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=240123"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=240123"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}