{"id":239382,"date":"2022-07-09T06:40:20","date_gmt":"2022-07-08T22:40:20","guid":{"rendered":"\/\/m.iemloyee.com\/?p=239382"},"modified":"2022-07-08T15:41:16","modified_gmt":"2022-07-08T07:41:16","slug":"1-8v%ef%bc%8c%e8%87%b3%e5%b0%915k%e6%ac%a1%ef%bc%9a%e9%92%99%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0-%e7%9f%bf%e8%97%8f%e4%b8%b0%e5%af%8c%e7%9a%84%e9%94%82%e7%94%b5%e6%b1%a0%e6%bd%9c%e5%9c%a8%e6%9b%bf","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=239382","title":{"rendered":"1.8V\uff0c\u81f3\u5c115k\u6b21\uff1a\u9499\u79bb\u5b50\u7535\u6c60&#8212;-\u77ff\u85cf\u4e30\u5bcc\u7684\u9502\u7535\u6c60\u6f5c\u5728\u66ff\u4ee3\u54c1"},"content":{"rendered":"<p style=\"text-align: center;\">\u3010\u5bfc\u8bfb\u3011<\/p>\n<p>\u968f\u7740\u9502\u79bb\u5b50\u7535\u6c60\u4ea7\u4e1a\u7684\u5feb\u901f\u53d1\u5c55\uff0c<strong>\u4eba\u4eec\u8d8a\u6765\u8d8a\u62c5\u5fc3\u9502\u79bb\u5b50\u539f\u6750\u6599\uff08\u5982\u94b4\u3001\u954d\u548c\u9502\uff09\u77ed\u7f3a<\/strong>\u4f1a\u9650\u5236\u73b0\u6709\u79bb\u5b50\u7535\u6c60\u7684\u751f\u4ea7<strong>\uff0c<\/strong>\u4f7f\u65e5\u76ca\u589e\u957f\u7684\u9700\u6c42\u65e0\u6cd5\u5f97\u5230\u6ee1\u8db3\u3002\u8fd9<strong>\u4fc3\u4f7f\u7814\u7a76\u4eba\u5458\u5bfb\u627e\u9502\u57fa\u7535\u5316\u5b66\u50a8\u80fd\u7cfb\u7edf\u7684\u66ff\u4ee3\u54c1<\/strong>\u3002\u5728\u6f5c\u5728\u7684\uff08\u94a0\u3001\u94be\u3001\u9541\u3001\u950c\u3001\u9499\uff09\u79bb\u5b50\u7535\u6c60\u4e2d\uff0c<strong>\u9499\u79bb\u5b50\u7535\u6c60\u8868\u73b0\u51fa\u4e86\u5de8\u5927\u7684\u6f5c\u529b<\/strong>\u3002\u4e00\u65b9\u9762<span style=\"color: #000000;\">\uff0c\u9499\u662f\u5730\u58f3\u4e2d\u7b2c\u4e94<u>\u4e30\u5bcc<\/u>\u7684\u5143\u7d20\uff0c<u>\u5168\u7403\u8d44\u6e90\u5206\u5e03\u5747\u5300<\/u>\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u9499\u79bb\u5b50\u7535\u6c60<u>\u53ef\u4ee5\u63d0\u4f9b\u6bd4\u5176\u4ed6\u57fa\u4e8e\u591a\u4ef7\u91d1\u5c5e\u79bb\u5b50\u7684\u7535\u6c60\u7cfb\u7edf\u66f4\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6<\/u>\u3002<\/span><\/p>\n<p>\u7136\u800c\uff0c\u9499\u7535\u6c60\u7684\u7814\u7a76\u548c\u5f00\u53d1\u9762\u4e34\u7740<strong>\u591a\u91cd\u6311\u6218<\/strong>\uff0c\u4e3b\u8981\u4f53\u73b0\u5728\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u9762\uff1a<\/p>\n<p>\uff081\uff09\u7f3a\u4e4f\u6709\u6548\u7684\u7535\u89e3\u8d28\u548c\u53ef\u884c\u7684\u6b63\u6781\u6750\u6599\u6765\u5b9e\u73b0\u53ef\u9006\u7684\u9499\u79bb\u5b50\u5d4c\u5165\uff1b<\/p>\n<p>\uff082\uff09\u6b64\u5916\uff0c\u9499\u7684\u5f3a\u8fd8\u539f\u80fd\u529b\u53ef\u8bf1\u5bfc\u7535\u89e3\u8d28\u5206\u89e3\uff0c\u5728\u91d1\u5c5e\u9633\u6781\u4e0a\u5f62\u6210\u79bb\u5b50\u7edd\u7f18\u5c42\uff1b<\/p>\n<p>\uff083\uff09\u5bf9\u6f5c\u5728\u9634\u6781\u8fdb\u884c\u771f\u6b63\u7684\u5168\u7535\u6c60\u6d4b\u8bd5\u5c1a\u672a\u5f97\u5230\u5b9e\u73b0\uff1b<\/p>\n<p>\u540c\u65f6\uff0c\u7531\u4e8e\u7535\u89e3\u8d28\u4e2d\u9499\u91d1\u5c5e\u5bf9\u7535\u6781\u7684\u4e25\u91cd\u949d\u5316\uff0c\u4f7f\u7528\u4f20\u7edf\u7684\u534a\u7535\u6c60\u8bbe\u7f6e\u53ef\u80fd\u5bfc\u81f4\u7535\u6781\u6027\u80fd\u88ab\u4f4e\u4f30\u3002\u56e0\u6b64\uff0c\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86\u89e3\u754c\u9762\u5316\u5b66\u548c\u8bbe\u8ba1\u5408\u9002\u7684\u9633\u6781-\u7535\u89e3\u8d28\u754c\u9762\u5bf9\u4e8e\u5b9e\u73b0\u53ef\u884c\u7684\u9499\u57fa\u7535\u6c60\u81f3\u5173\u91cd\u8981\u3002<\/p>\n<p style=\"text-align: center;\">\u3010\u6210\u679c\u63a0\u5f71\u3011<\/p>\n<p>\u8fd1\u65e5\uff0c\u5fb7\u56fd\u4e4c\u5c14\u59c6\u4ea5\u59c6\u970d\u5179\u7814\u7a76\u6240\u7684Zhirong Zhao-Karger\u6559\u6388\u7b49\u7814\u7a76\u8005\u5c55\u793a\u4e86\u9499-\u9521(Ca-Sn) \u5408\u91d1\u4f5c\u4e3a\u9499\u79bb\u5b50\u7535\u6c60\u9633\u6781\u7684\u9002\u7528\u6027\u5e76\u9610\u660e\u4e86\u5176\u7535\u5316\u5b66\u6027\u80fd\u3002\u6587\u4e2d\u6f14\u793a\u7684<strong>\u9499\u79bb\u5b50\u7535\u6c60<\/strong>\uff08\u7531Ca-Sn\u5408\u91d1<strong>\u9633\u6781<\/strong>\u3001\u918c\u57fa\u805a\u5408\u7269<strong>\u9634\u6781<\/strong>\u548c\u4e0e\u9ad8\u6548\u787c\u9178\u76d0Ca[B(hfip)<sub>4<\/sub>]<sub>2<\/sub><strong>\u7535\u89e3\u8d28<\/strong>\u7ec4\u6210\uff09<strong>\u8868\u73b0\u51fa\u4e86\u4f18\u826f\u7684\u6027\u80fd<\/strong>\uff0c<strong>\u53ef\u8f93\u51fa<\/strong><strong>1.8V<\/strong><strong>\u7535\u538b\uff0c\u4e14\u5728260 mA g<sup>-1<\/sup><\/strong><strong>\u7684\u7279\u5b9a\u7535\u6d41\u4e0b\u53ef\u8fd0\u884c\u81f3\u5c115000<\/strong><strong>\u6b21\u5faa\u73af\u3002<\/strong>\u65b0\u578bCa-Sn\u5408\u91d1\u9633\u6781\u7684\u53d1\u73b0\u4e3a\u9ad8\u6027\u80fd\u9499\u79bb\u5b50\u7535\u6c60\u5f00\u8f9f\u4e86\u4e00\u6761\u6709\u5e0c\u671b\u7684\u9014\u5f84\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a<strong>\u201cCalcium-tin alloys as anodes for rechargeable non-aqueous calcium-ion batteries at room temperature\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520a<em>Nature Communication<\/em><em>s<\/em>\u4e0a\u3002<\/p>\n<p>\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/p>\n<p>\uff081\uff09\u5229\u7528X\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09\u663e\u5fae\u955c\u548c\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09\u6280\u672f\uff0c\u8868\u5f81\u4e86Ca-Sn\u5408\u91d1\u7684\u7535\u5316\u5b66\u9499\u5316\u548c\u8131\u9499\uff0c<strong>\u53d1\u73b0\u5728\u5bcc\u9499\u5408\u91d1\u7684\u521d\u59cb\u7535\u5316\u5b66\u5904\u7406\u8fc7\u7a0b\u4e2d\u5f62\u6210\u7684<\/strong><strong>Sn<\/strong><strong>\u5728\u968f\u540e\u7684\u5408\u91d1\u5316\u8fc7\u7a0b\u4e2d\u8f6c\u53d8\u4e3aCaSn<sub>3<\/sub><\/strong><strong>\uff0c\u5e76\u4e14\u8fd9\u79cd\u65b0\u76f8\u80fd\u591f\u8fdb\u884c\u53ef\u9006\u7684\u9499\u5316\/<\/strong><strong>\u8131\u9499\u3002<\/strong>\u56e0\u6b64\uff0c\u63d0\u51fa\u5c06Ca-Sn\u5408\u91d1\u4f5c\u4e3a\u9499\u79bb\u5b50\u7535\u6c60\u7684\u6f5c\u5728\u9633\u6781\uff0c\u5e76\u901a\u8fc7\u9499\u79bb\u5b50\u5168\u7535\u6c60\u539f\u578b\u8bc1\u660e\u5176\u53ef\u884c\u6027\u3002<\/p>\n<p>\uff082\uff09\u6784\u5efa\u4e00\u4e2a\u5177\u6709\u52a8\u529b\u5b66\u4e0a\u6709\u5229\u7684\u6709\u673a\u9634\u6781\uff081,4-\u805a\u84bd\u918c\uff09\u548cCa-Sn\u5408\u91d1\u9633\u6781\u7684\u5168\u7535\u6c60\uff0c\u4ee5\u89c4\u907f\u6e90\u4e8e\u9499\u91d1\u5c5e\u9633\u6781\u949d\u5316\u7684\u969c\u788d\uff0c\u5e76\u4f7f\u9633\u6781\u548c\u9634\u6781\u4e0a\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u540c\u65f6\u8fdb\u884c\u3002<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\">\u3010\u56fe\u7247\u6982\u89c8\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-239383\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig1_HTML.png\" alt=\"\" width=\"685\" height=\"1023\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig1_HTML.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig1_HTML-201x300.png 201w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p>\u56fe1. Ca-Sn\u5408\u91d1\u7684\u7279\u6027\u548c\u5e26\u6709Ca-Sn\u5408\u91d1\u9633\u6781\u7684\u7535\u6c60\u914d\u7f6e<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-239384\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig2_HTML.png\" alt=\"\" width=\"685\" height=\"356\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig2_HTML.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig2_HTML-300x156.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p>\u56fe2. Ca\u01c0\u01c014PAQ\u548cCaxSn\u01c0\u01c014PAQ\u7535\u6c60\u572825\u2103\u4e0b\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-239385\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig3_HTML.png\" alt=\"\" width=\"685\" height=\"490\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig3_HTML.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig3_HTML-300x215.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p>\u56fe3. \u901a\u8fc7\u539f\u4f4dXRD\u6d4b\u91cf\u5bf9\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u7684Ca-Sn\u5408\u91d1\u9633\u6781\u8fdb\u884c\u76f8\u5206\u6790<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-239386\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig4_HTML.png\" alt=\"\" width=\"685\" height=\"493\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig4_HTML.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig4_HTML-300x216.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p>\u56fe4. \u4e0d\u540c\u7535\u5316\u5b66\u72b6\u6001\u4e0b\u7684Ca-Sn\u5408\u91d1\u9633\u6781\u7684\u5fae\u89c2\u7ed3\u6784\u548c\u7ed3\u6676\u5b66\u5206\u6790<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-239387\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig5_HTML.png\" alt=\"\" width=\"685\" height=\"941\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig5_HTML.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig5_HTML-218x300.png 218w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p>\u56fe5. CaSn<sub>3<\/sub>\u5408\u91d1\u7684\u6676\u4f53\u5b66\u548c\u7535\u5316\u5b66\u7279\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-239388\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig6_HTML.png\" alt=\"\" width=\"685\" height=\"472\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig6_HTML.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig6_HTML-300x207.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p>\u56fe6. \u7535\u5316\u5b66\u8fc7\u7a0b\u4e2dCaSn3\u9633\u6781\u7684\u76f8\u548c\u5f62\u6001\u5206\u6790<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-239389\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig7_HTML.png\" alt=\"\" width=\"685\" height=\"536\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig7_HTML.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/41467_2022_31261_Fig7_HTML-300x235.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p>\u56fe7. \u57fa\u4e8eCa-Sn\u5408\u91d1\u9633\u6781\u7684\u7535\u6c60\u572825\u2103\u65f6\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n<p style=\"text-align: center;\">\u3010\u6210\u679c\u542f\u793a\u3011<\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u5f00\u53d1\u4e86\u4e00\u79cd\u7531\u918c\u57fa\u805a\u5408\u7269\u9634\u6781\u548cCa-Sn\u5408\u91d1\u9633\u6781\u4e0e\u9ad8\u6548\u787c\u9178\u76d0Ca[B(hfip)<sub>4<\/sub>]<sub>2<\/sub>\u7535\u89e3\u8d28\u7ec4\u5408\u800c\u6210\u7684\u9499\u5168\u7535\u6c60\u3002\u8fd9\u4e2a\u5b8c\u6574\u7684\u7535\u6c60\u539f\u578b\u8868\u73b0\u51fa\u7ea61.8V\u7684\u7535\u6c60\u7535\u538b\uff0c\u5e76\u4e14\u53ef\u4ee5\u5728260mA 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href=\"https:\/\/www.nature.com\/articles\/s41467-022-31261-z\">https:\/\/www.nature.com\/articles\/s41467-022-31261-z<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5bfc\u8bfb\u3011 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