{"id":239248,"date":"2022-07-05T06:10:02","date_gmt":"2022-07-04T22:10:02","guid":{"rendered":"\/\/m.iemloyee.com\/?p=239248"},"modified":"2022-07-04T22:12:25","modified_gmt":"2022-07-04T14:12:25","slug":"%e6%9c%80%e6%96%b0nature-catalysis%ef%bc%9a%e5%88%86%e5%ad%90%e7%ad%9b%e5%82%ac%e5%8c%96%e7%94%b2%e9%86%87%e5%92%8c%e6%b0%af%e7%94%b2%e7%83%b7%e7%9a%84%e5%82%ac%e5%8c%96%e8%b7%af%e5%be%84%e5%8f%8a","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=239248","title":{"rendered":"\u6700\u65b0Nature Catalysis\uff1a\u5206\u5b50\u7b5b\u50ac\u5316\u7532\u9187\u548c\u6c2f\u7532\u70f7\u7684\u50ac\u5316\u8def\u5f84\u53ca\u673a\u7406\u7814\u7a76"},"content":{"rendered":"<p>\u5355\u53d6\u4ee3\u7532\u70f7\uff0c\u5305\u62ec\u7532\u9187\u548c\u6c2f\u7532\u70f7\uff08\u5206\u522b\u4e3aCH<sub>3<\/sub>X\u3001X=OH\u548cCl\uff09\uff0c\u662f\u53ef\u6301\u7eed\u71c3\u6599\u548c\u5316\u5b66\u54c1\u7684\u6709\u5438\u5f15\u529b\u7684\u7ec4\u6210\u90e8\u5206\u3002\u8fd9\u4e9bC<sub>1<\/sub>\u5206\u5b50\u662f\u5408\u6210\u6c14\u8f6c\u5316\u3001\u4e8c\u6c27\u5316\u78b3\u52a0\u6c22\u548c\u5364\u7d20\u4ecb\u5bfc\u7684\u70f7\u70c3\u5b98\u80fd\u5316\u7684\u4e3b\u8981\u4ea7\u7269\uff0c\u5e76\u4e14\u53ef\u4ee5\u5728\u6cb8\u77f3\u50ac\u5316\u5242\u4e0a\u5bb9\u6613\u5730\u8f6c\u5316\u4e3a\u6709\u4ef7\u503c\u7684\u78b3\u6c22\u5316\u5408\u7269\u3002\u7406\u89e3\u7532\u9187\u548c\u6c2f\u7532\u70f7\u5728\u6cb8\u77f3\u50ac\u5316\u8f6c\u5316\u8fc7\u7a0b\u4e2d\u7684\u751f\u70c3\u8fc7\u7a0b\uff0c\u9700\u8981\u5148\u8fdb\u7684\u5149\u8c31\u624b\u6bb5\u6765\u533a\u5206\u78b3\u78b3\u952e\u5f62\u6210\u3001\u94fe\u751f\u957f\u548c\u78b3\u7269\u8d28\u6c89\u79ef\u7684\u590d\u6742\u673a\u5236\u3002\u5c3d\u7ba1\u53d6\u5f97\u4e86\u4e00\u4e9b\u8fdb\u5c55\uff0c\u4f46\u6709\u5173\u8be5\u673a\u5236\u7684\u51e0\u4e2a\u95ee\u9898\u4ecd\u7136\u5b58\u5728\u6fc0\u70c8\u4e89\u8bba\uff0c\u5305\u62ec\u81ea\u7531\u57fa\u7269\u8d28\u7684\u5b58\u5728\u548c\u4f5c\u7528\u3001\u7b2c\u4e00\u4e2aC-C\u952e\u5f62\u6210\u7684\u673a\u5236\u4ee5\u53ca\u968f\u540e\u901a\u5f80\u65e9\u671f\u82b3\u70c3\u5e93(HCP)\u7684\u8def\u5f84\u3002\u6b64\u5916\uff0c\u5178\u578b\u7684\u6eb6\u89e3-\u8403\u53d6\u5b9e\u9a8c\u548c\u5149\u8c31\u6d4b\u91cf\u5bf9\u7126\u70ad\u524d\u9a71\u4f53\u7684\u7279\u5b9a\u7ed3\u6784\u53ca\u5176\u6f14\u53d8\u6210\u6c89\u79ef\u5728\u6cb8\u77f3\u50ac\u5316\u5242\u4e2d\u7684\u78b3\u8d28\u5143\u7d20\u7684\u4e86\u89e3\u6709\u9650\u3002<\/p>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><b>[\u6210\u679c\u63a0\u5f71]<\/b><\/strong><\/p>\n<p><strong><b>\u745e\u58eb\u82cf\u9ece\u4e16\u8054\u90a6\u7406\u5de5\u5b66\u9662Guido Zichittella<\/b><\/strong><strong><b>\u3001Patrick Hemberger\u4e0e\u745e\u58eb\u4fdd\u7f57\u8c22\u52d2\u7814\u7a76\u6240Javier P\u00e9rez-Ram\u00edre\u8bfe\u9898\u7ec4\u5408\u4f5c<\/b><\/strong><strong><b>\uff0c\u4f7f\u7528\u64cd\u4f5c\u5149\u7535\u5b50\u5149\u79bb\u5b50\u7b26\u5408(PEPICO)\u5149\u8c31<\/b><\/strong><strong><b>\u6280\u672f\uff0c\u5b9e\u73b0\u5bf9\u5c3a\u5bf8\u9ad8\u8fbeC<\/b><\/strong><strong><sub><b>14<\/b><\/sub><\/strong><strong><b>\u7684\u78b3\u6c22\u5316\u5408\u7269\u8def\u5f84\u7684\u5f02\u6784\u4f53\u9009\u62e9\u6027\u8bc6\u522b\uff0c\u4e3a\u53cd\u5e94\u4e2d\u7684\u7532\u57fa\u81ea\u7531\u57fa\u548c\u7532\u9187\u5236\u70c3\u53cd\u5e94\u4e2d\u7684\u70ef\u916e\u63d0\u4f9b\u4e86\u76f4\u63a5\u7684\u5b9e\u9a8c\u8bc1\u636e\u3002<\/b><\/strong>Operando PEPICO\u5f3a\u8c03\u4e86\u7126\u70ad\u524d\u4f53\u666e\u904d\u5b58\u5728\u7684\u5dee\u5f02\uff0c\u8fd9\u5f97\u5230\u4e86\u7535\u5b50\u987a\u78c1\u5171\u632f\u6d4b\u91cf\u7684\u652f\u6301\uff0c\u4e3a\u79ef\u7d2f\u7684\u78b3\u8d28\u7269\u8d28\u7684\u4ee3\u8868\u6027\u5206\u5b50\u7ed3\u6784\u3001\u5bc6\u5ea6\u548c\u5206\u5e03\u7684\u5dee\u5f02\u63d0\u4f9b\u4e86\u8bc1\u636e\u3002 \u6c2f\u7532\u70f7-\u70c3\u53cd\u5e94\u4e2d\u7684\u81ea\u7531\u57fa\u9a71\u52a8\u9014\u5f84\u52a0\u901f\u4e86\u6269\u5c55\u82b3\u70c3\u4f53\u7cfb\u7684\u5f62\u6210\uff0c\u5bfc\u81f4\u5feb\u901f\u5931\u6d3b\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5728\u7532\u9187\u5236\u70c3\u53cd\u5e94\u4e2d\u901a\u8fc7\u542b\u6c27\u5316\u5408\u7269\u9a71\u52a8\u7684\u9014\u5f84\u751f\u6210\u70f7\u57fa\u5316\u7269\u8d28\u53ef\u5ef6\u957f\u50ac\u5316\u5242\u5bff\u547d\u3002<strong><b>\u672c\u5de5\u4f5c<\/b><\/strong><strong><b>\u6240\u63d0\u51fa\u7684\u65b9\u6cd5\u6709\u53ef\u80fd\u4e3a\u590d\u6742\u7684\u53cd\u5e94\u7f51\u7edc\u63d0\u4f9b\u6709\u4ef7\u503c\u7684\u673a\u7406\u89c1\u89e3<\/b><\/strong>\u3002\u76f8\u5173\u8bba\u6587\u4ee5\u9898\u4e3a\uff1a\u201c<em><i>Elucidation of radical- and oxygenate-driven paths in zeolite-catalysed conversion of methanol and methyl chloride to hydrocarbons<\/i><\/em>\u201d\u53d1\u8868\u5728<em><i>Nature Catalysis<\/i><\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-239249\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72471.png\" alt=\"\" width=\"768\" height=\"298\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72471.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72471-300x116.png 300w\" sizes=\"(max-width: 768px) 100vw, 768px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>[\u6838\u5fc3\u521b\u65b0\u70b9]<\/b><\/strong><\/p>\n<ul>\n<li><b><\/b><strong><b>\u672c\u5de5\u4f5c\u4f7f\u7528\u64cd\u4f5cPEPICO\u5149\u8c31\u80fd\u591f\u5bf9\u5c3a\u5bf8\u9ad8\u8fbeC<sub>14<\/sub>\u7684\u70c3\u7c7b\u7684\u9014\u5f84\u8fdb\u884c\u5f02\u6784\u4f53\u9009\u62e9\u6027\u8bc6\u522b\uff0c\u4e3a\u7532\u9187-\u70c3\u7c7b\u53cd\u5e94\u4e2d\u7684\u7532\u57fa\u81ea\u7531\u57fa\u548c\u4e59\u70ef\u916e\u53cd\u5e94\u63d0\u4f9b\u76f4\u63a5\u7684\u5b9e\u9a8c\u8bc1\u636e<\/b><\/strong>\u3002<\/li>\n<li>\u672c\u5de5\u4f5c\u8868\u660e\uff0c\u786e\u5b9a\u6700\u7ec8\u4ea7\u751f\u542b\u78b3\u7269\u8d28\u7684C-C\u952e\u5f62\u6210\u548c\u94fe\u589e\u957f\u7684\u4e0d\u540c\u9014\u5f84\u5bf9\u4e8e\u8bbe\u8ba1CH<sub>3<\/sub>OH\u548cCH<sub>3<\/sub>Cl\u5076\u8054\u7684\u50ac\u5316\u548c\u53cd\u5e94\u5668\u7cfb\u7edf\u5177\u6709\u91cd\u8981\u7684\u5b9e\u9645\u610f\u4e49\u3002<\/li>\n<li><b><\/b><strong><b>\u672c\u5de5\u4f5c<\/b><\/strong><strong><b>\u6240\u63d0\u51fa\u7684\u65b9\u6cd5\u4e3a\u590d\u6742\u7684\u53cd\u5e94\u7f51\u7edc\u63d0\u4f9b\u6709\u4ef7\u503c\u7684\u673a\u7406<\/b><\/strong><strong><b>\uff0c\u9610\u660e\u4e86\u5206\u5b50\u7b5b\u50ac\u5316\u7532\u9187\u548c\u6c2f\u7532\u70f7\u8f6c\u5316\u4e3a\u70c3\u7684\u81ea\u7531\u57fa\u548c\u542b\u6c27\u5316\u5408\u7269\u9a71\u52a8\u8def\u5f84<\/b><\/strong>\u3002<\/li>\n<\/ul>\n<p style=\"text-align: center;\"><strong><b>[\u6570\u636e\u6982\u89c8]<\/b><\/strong><\/p>\n<ul>\n<li><b><\/b><strong><b>\u53cd\u5e94\u52a8\u529b\u5b66\u8bc4\u4f30<\/b><\/strong><\/li>\n<\/ul>\n<p>\u5728\u6b64\uff0c\u672c\u5de5\u4f5c\u5728\u76f8\u5173\u53cd\u5e94\u6761\u4ef6\u4e0b\u4f7f\u7528\u64cd\u4f5cPEPICO\u5149\u8c31\u5206\u6790\u4e86\u5728\u7532\u9187\u5236\u70c3(MTH)\u548c\u6c2f\u5316\u7269\u5236\u70c3(MCTH)\u8fc7\u7a0b\u4e2d\u4ece\u4ee3\u8868\u6027H-ZSM-5\u6cb8\u77f3\u50ac\u5316\u5242\u4e2d\u89e3\u5438\u7684\u70c3\u3002\u7ed3\u5408\u52a8\u529b\u5b66\u5206\u6790\uff0c\u6240\u91c7\u7528\u7684\u65b9\u6cd5\uff08\u56fe1\uff09\u63d0\u4f9b\u4e86\u6240\u5f62\u6210\u7269\u8d28\u7684\u9ad8\u5206\u5b50\u5206\u8fa8\u7387\uff0c\u4ece\u800c\u80fd\u591f\u5bf9\u6709\u5173\u53cd\u5e94\u673a\u5236\u7684\u51e0\u4e2a\u672a\u89e3\u51b3\u95ee\u9898\u8fdb\u884c\u5b9e\u9a8c\u9a8c\u8bc1\u3002\u901a\u8fc7\u7814\u7a76\u5728\u7b49\u6548\u6761\u4ef6\u4e0b\u6807\u79f0Si\/Al\u6bd4\u4e3a40\u7684H-ZSM-5\u6cb8\u77f3\u50ac\u5316\u5242\u4e0a\u7684\u53cd\u5e94\u7684\u7a33\u6001\u52a8\u529b\u5b66\uff0c\u672c\u5de5\u4f5c\u521d\u6b65\u4e86\u89e3\u4e86MTH\u548cMCTH\u5de5\u827a\u4e4b\u95f4\u7684\u5f02\u540c\u3002\u65f6\u95f4\u4f9d\u8d56\u6027\u53cd\u5e94\u6027\u7684\u6bd4\u8f83\u8868\u660e\uff0c\u5728MTH\u8fc7\u7a0b\u4e2d\uff0cCH<sub>3<\/sub>X\u7684\u5b8c\u5168\u8f6c\u5316\u53ef\u4ee5\u4fdd\u6301120\u5c0f\u65f6\uff08\u56fe2a\uff0cb\uff09\u3002\u5c3d\u7ba1\u5728MTH\u53cd\u5e94120\u5c0f\u65f6\u540e\u70ef\u70c3\u4ece\u5927\u7ea626%\u589e\u52a0\u523040%\uff0c\u4f46\u5728\u6295\u4ea7\u7684\u524d60\u5c0f\u65f6\u5185\u4ea7\u7269\u5206\u5e03\u51e0\u4e4e\u6ca1\u6709\u53d7\u5230\u5f71\u54cd\u3002\u672c\u5de5\u4f5c\u53d1\u73b0\u5fae\u5b54\u4f53\u79ef\u548c\u7126\u70ad\u542b\u91cf\u4e4b\u95f4\u5b58\u5728\u7ebf\u6027\u8d1f\u76f8\u5173\uff08\u56fe2d\uff09\u3002\u8fd9\u8868\u660e\u5c3d\u7ba1\u6c89\u79ef\u901f\u7387\u4e0d\u540c\uff0c\u4f46\u78b3\u8d28\u7269\u8d28\u5728\u5b54\u9699\u7f51\u7edc\u4e2d\u7684\u6f14\u5316\u548c\u79ef\u7d2f\u76f8\u4f3c\uff0c\u8fd9\u4e0eEPR\u7684\u7ed3\u679c\u4e00\u81f4\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-239251\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72472.png\" alt=\"\" width=\"659\" height=\"483\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72472.png 659w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72472-300x220.png 300w\" sizes=\"(max-width: 659px) 100vw, 659px\" \/><\/p>\n<p>\u56fe1. \u78b3\u6c22\u5316\u5408\u7269\u50ac\u5316\u751f\u6210\u548c\u6f14\u5316\u7684\u6620\u5c04\u65b9\u6cd5\u00a9 2022 Springer Nature Limited<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-239252\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72473.png\" alt=\"\" width=\"385\" height=\"620\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72473.png 385w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72473-186x300.png 186w\" sizes=\"(max-width: 385px) 100vw, 385px\" \/><\/p>\n<p>\u56fe2. \u6cb8\u77f3\u50ac\u5316\u5242\u7684\u6bd4\u8f83\u6027\u80fd\u00a9 2022 Springer Nature Limited<\/p>\n<ul>\n<li><b><\/b><strong><b>\u70c3\u5f62\u6210\u9014\u5f84<\/b><\/strong><\/li>\n<\/ul>\n<p>Operando PEPICO\u5206\u6790\u4f7f\u672c\u5de5\u4f5c\u80fd\u591f\u8be6\u7ec6\u4e86\u89e3\u5728\u76f8\u5173\u6761\u4ef6\uff08T\u2264773\u2009K\uff0cP\u22640.5\u2009bar\uff09\u4e0bH-ZSM-5\u53cd\u5e94\u4e2d\u5f62\u6210\u7684\u4e2d\u95f4\u4f53\u548c\u4ea7\u7269\uff0c\u663e\u793a\u8303\u56f4\u5e7f\u6cdb\u7684\u70c3\u7c7b\uff08C<sub>1<\/sub>-C<sub>14<\/sub>\uff09\u5728MTH\u548cMCTH\u8fc7\u7a0b\u4e2d\u4ee5\u53ca\u4ec5\u5728MTH\u53cd\u5e94\u4e2d\u7684\u6c27\u5408\u7269\uff08C<sub>1<\/sub>-C<sub>4<\/sub>\uff09(\u56fe3-5)\u3002<strong><b>\u5b9e\u9a8c\u8bc1\u5b9e\u4e86\u5728MTH \u548cMCTH\u53cd\u5e94\u4e2d\u90fd\u5b58\u5728CH<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>\u2022\u7269\u8d28\u3002\u5728\u63a5\u8fd1\u73af\u5883\u538b\u529b\u4e0b\u68c0\u6d4b\u5230 CH<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>\u2022\u81ea\u7531\u57fa\u8868\u660e\uff0c\u8fd9\u4e9b\u7269\u8d28\u5728\u5b9e\u9645\u6761\u4ef6\u4e0b\u662f\u53cd\u5e94\u6027\u4e2d\u95f4\u4f53\uff0c\u800c\u4e0d\u4ec5\u4ec5\u662f\u6765\u81ea\u8868\u9762\u7532\u6c27\u57fa\u7269\u8d28\u6216\u4ec5\u4ec5\u662f\u65c1\u89c2\u8005\u7684\u5c11\u91cf\u89e3\u5438\u526f\u4ea7\u7269<\/b><\/strong>\u3002\u5728MTH\u8fc7\u7a0b\u7684\u65e9\u671f\u9636\u6bb5\u901a\u8fc7CH<sub>3<\/sub>OH\u8131\u6c34\u751f\u6210(CH<sub>3<\/sub>)<sub>2<\/sub>O\uff0c\u800cCH<sub>3<\/sub>CHO\u53ef\u80fd\u8fde\u7eed\u53c2\u4e0e\u4e86\u7b2c\u4e00\u4e2aC-C\u952e\u7684\u5f62\u6210\u3002 \u76f8\u6bd4\u4e4b\u4e0b\uff0cCH<sub>2<\/sub>O\u7684\u5f62\u6210\u968f\u6e29\u5ea6\u6301\u7eed\u4e0a\u5347\u5728MTH\u53cd\u5e94\u7684\u4f4e\u538b\u5b9e\u9a8c\u4e2d\u89c2\u5bdf\u5230\u76f8\u540c\u7684\u8d8b\u52bf\uff0c\u5c3d\u7ba1\u4ea7\u751f\u7684CH<sub>2<\/sub>O\u7684\u91cf\u8981\u9ad8\u5f97\u591a\u3002\u8fd9\u8868\u660eCH<sub>2<\/sub>O\u4e3b\u8981\u53c2\u4e0e\u70c3\u7c7b\u6f14\u5316\u7684\u7b2c\u4e00\u6b65\uff0c\u800c\u4e0d\u662f\u53c2\u4e0e\u7126\u70ad\u524d\u4f53\u7684\u751f\u6210\u3002<\/p>\n<p>\u57fa\u4e8e\u8fd9\u4e9b\u53d1\u73b0\uff0c\u4e24\u6761\u4e3b\u8981\u7684\u53cd\u5e94\u9014\u5f84\u4f3c\u4e4e\u662f\u7b2c\u4e00\u4e2aC-C\u952e\u5f62\u6210\u548c\u968f\u540e\u7684C<sub>5<\/sub>\u5316\u5408\u7269\u94fe\u589e\u957f\u7684\u539f\u56e0\u3002\u7b2c\u4e00\u4e2a\u9014\u5f84\u6d89\u53ca\u542b\u6c27\u5316\u5408\u7269\u7684\u6f14\u5316\uff0c\u4f8b\u5982(CH<sub>3<\/sub>)<sub>2<\/sub>O\u548c CH<sub>3<\/sub>CHO\uff0c\u5e76\u4e14\u4ec5\u4e0eMTH\u5de5\u827a\u76f8\u5173\uff08\u56fe4a\uff09\uff0c\u800c\u7b2c\u4e8c\u4e2a\u5305\u62ec\u70ef\u70c3\u5e76\u4e14\u5728MTH\u548cMCTH\u5de5\u827a\u4e2d\u90fd\u51fa\u73b0\uff08\u56fe4b\uff09\u3002\u5728\u7b2c\u4e8c\u79cd\u9014\u5f84\u4e2d\uff0cCH<sub>3<\/sub>X\u53ef\u4ee5\u89e3\u79bb\u5438\u9644\u5f62\u6210CH<sub>3<\/sub>\u2022\u81ea\u7531\u57fa\u548c\u914d\u4f4d\u79bb\u53bb\u57fa\u56e2X*=Cl*\u6216OH*\uff08\u56fe4b\uff09\u3002\u7136\u540e\u901a\u8fc7\u4e24\u4e2aCH<sub>3<\/sub>\u2022\u81ea\u7531\u57fa\u5728\u8131\u6c22\u65f6\u53cd\u5e94\u751f\u6210C<sub>2<\/sub>H<sub>4<\/sub>\uff0c\u4ea7\u751f\u7b2c\u4e00\u4e2aC-C\u952e\uff0c\u7c7b\u4f3c\u4e8e\u5efa\u8bae\u7684\u8868\u9762\u7532\u6c27\u57fa\u7269\u8d28\u76f4\u63a5\u5076\u8054\u5f62\u6210\u8fd9\u79cd\u70ef\u70c3\u3002\u6709\u8da3\u7684\u662f\uff0c\u53d1\u73b0\u5f02\u6784\u5316\u548c\u975e\u4f2f\u70ef\u70c3\u7684\u4fe1\u53f7\u66f4\u5f3a\uff0c\u8fd9\u4e0e\u5b83\u4eec\u4e0e\u4f2f\u70ef\u70c3\u76f8\u6bd4\u5177\u6709\u66f4\u9ad8\u7684\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\u662f\u4e00\u81f4\u7684\u3002CH<sub>4<\/sub>\u662f\u901a\u8fc7CH<sub>3<\/sub>\u2022\u7684\u6c22\u5316\u5f62\u6210\u7684\uff0c\u800cCH<sub>3<\/sub>\u2022\u81ea\u7531\u57fa-\u81ea\u7531\u57fa\u53cd\u5e94\u4ea7\u751fC<sub>2<\/sub>H<sub>6<\/sub>\uff0c\u8fd9\u4e24\u79cd\u4ea7\u7269\u90fd\u662fMTH\u548cMCTH\u8fc7\u7a0b\u7684\u4ea7\u7269\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-239253\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72474.png\" alt=\"\" width=\"765\" height=\"499\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72474.png 765w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72474-300x196.png 300w\" sizes=\"(max-width: 765px) 100vw, 765px\" \/><\/p>\n<p>\u56fe3. \u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u6f14\u5316\u00a9 2022 Springer Nature Limited<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-239254\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72475.png\" alt=\"\" width=\"493\" height=\"594\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72475.png 493w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72475-249x300.png 249w\" sizes=\"(max-width: 493px) 100vw, 493px\" \/><\/p>\n<p>\u56fe4. \u50ac\u5316C<sub>1<\/sub>\u5076\u8054\u7684\u53cd\u5e94\u9014\u5f84\u00a9 2022 Springer Nature Limited<\/p>\n<ul>\n<li><b><\/b><strong><b>\u7126\u70ad\u7684\u4ea7\u751f\u548c\u6f14\u53d8<\/b><\/strong><\/li>\n<\/ul>\n<p><strong><b>\u78b3\u9aa8\u67b6\u7684\u8fdb\u4e00\u6b65\u751f\u957f\u5bfc\u81f4\u91cd\u78b3\u7269\u8d28\u7684\u5f62\u6210\u5e76\u6700\u7ec8\u5bfc\u81f4\u5b83\u4eec\u5728\u6cb8\u77f3\u5b54\u7f51\u7edc\u4e2d\u4ee5\u7126\u70ad\u7684\u5f62\u5f0f\u6c89\u79ef<\/b><\/strong>\u3002\u901a\u8fc7\u64cd\u4f5cPEPICO\uff0c\u57280.5\u2009bar\u7684MTH\u548cMCTH\u8fc7\u7a0b\u4e2d\u90fd\u89c2\u5bdf\u5230\u4e86\u4e00\u7cfb\u5217C<sub>10<\/sub>+\u70c3\uff08\u56fe5a\uff09\u3002\u8fd9\u4e9b\u7269\u8d28\u5728\u4f4e\u538b\u5b9e\u9a8c\u4e2d\u51e0\u4e4e\u6ca1\u6709\u88ab\u89c2\u5bdf\u5230\uff0c\u8868\u660e\u94fe\u4f20\u64ad\u548c\u7f29\u5408\u53cd\u5e94\u901f\u7387\u964d\u4f4e\u3002\u672c\u5de5\u4f5c\u786e\u5b9a\u4e86\u8418\u7684\u4e24\u79cd\u9014\u5f84\uff0c\u8418\u88ab\u8ba4\u4e3a\u662f\u8f83\u91cd\u7684\u78b3\u8d28\u7269\u8d28\u7684\u4e3b\u8981\u524d\u4f53\uff08\u56fe5b\uff09\u3002\u7279\u522b\u662f\uff0c\u5728MTH\u548cMCTH\u8fc7\u7a0b\u4e4b\u540e\u90fd\u68c0\u6d4b\u5230\u4e0e\u8418\u76f8\u5173\u7684\u5149\u79bb\u5b50\uff0c\u800c\u831a\u548c\u84bd\u4e5f\u53ef\u4ee5\u5728MCTH\u53cd\u5e94\u540e\u88ab\u786e\u5b9a\u91ca\u653e\u3002\u8fd9\u4e0eMCTH\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u5bb9\u6613\u751f\u6210\u831a\u4ee5\u53ca\u957f\u671f\u6d4b\u8bd5\u4e2d\u6295\u4ea7\u524d60\u5c0f\u65f6\u5185\u8f83\u9ad8\u7684\u7126\u70ad\u79ef\u7d2f\u7387\u662f\u4e00\u81f4\u7684\u3002\u867d\u7136\u5b64\u7acb\u7684\u987a\u78c1\u7126\u901a\u5e38\u4f1a\u4ea7\u751f\u9ad8\u65af\u7ebf\u5f62\uff0c\u4f46\u7d27\u5bc6\u5806\u79ef\u7684\u81ea\u65cb\u7684\u78c1\u76f8\u4e92\u4f5c\u7528\u901a\u5e38\u4f1a\u4ea7\u751f\u6d1b\u4f26\u5179\u578b\u7ebf\u5bbd\u3002 \u56e0\u6b64\uff0cMCTH\u53cd\u5e94\u5bfc\u81f4\u5728\u53cd\u5e94\u7684\u524d5\u5c0f\u65f6\u5185\u5f62\u6210\u9ad8\u5bc6\u5ea6\u7684\u78b3\u8d28\u5316\u5408\u7269\uff0c\u800c\u8fd9\u4e9b\u7269\u8d28\u7684\u5bc6\u5ea6\u5728MTH\u53cd\u5e94\u4e2d\u589e\u957f\u7f13\u6162\uff08\u56fe5d\uff09\uff0c\u8fd9\u4e0eCH<sub>3<\/sub>Cl\u4ea7\u751fBTX\u7684\u8f83\u9ad8\u8d8b\u52bf\u4e00\u81f4\u3002<strong><b>\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u4e4b\u524d\u5728H-ZSM-554\u4e0a\u7684\u4e59\u9187\u5076\u8054\u4e2d\u89c2\u5bdf\u5230\u4e86\u4e59\u57fa\u8418\uff0c\u8fd9\u8868\u660e\u7126\u70ad\u524d\u4f53\u7684\u4ea7\u751f\u53ef\u80fd\u53d7\u5230\u6cb8\u77f3\u9aa8\u67b6\u7684\u5f3a\u70c8\u5f71\u54cd\u3002\u5bf9\u76f8\u5e94H:C\u6bd4\u7387\u7684\u4f30\u8ba1\u8868\u660e\uff0c\u5728MTH\u8fc7\u7a0b\u4e2d\u5f62\u6210\u4e86\u5177\u6709\u8f83\u9ad8\u70f7\u57fa\u5316\u7a0b\u5ea6\u7684\u7269\u8d28<\/b><\/strong>\uff08\u56fe5h\uff09\u3002\u4e59\u70ef\u916e\u9a71\u52a8\u7684\u94fe\u589e\u957f\u8def\u7ebf\u7684\u5b58\u5728\u5bfc\u81f4\u7ebf\u6027\u5316\u5408\u7269\u7684\u5f62\u6210\u3002\u8fd9\u4e0e\u901a\u8fc7 CW EPR\u548cTGA\u89c2\u5bdf\u5230\u7684\u8f83\u6162\u7684\u78b3\u8d28\u7269\u8d28\u751f\u6210\u521d\u59cb\u901f\u7387\u4e00\u8d77\uff0c\u53ef\u4ee5\u89e3\u91ca\u4e3a\u4ec0\u4e48\u4e0eMCTH\u53cd\u5e94\u76f8\u6bd4\uff0c\u5728MTH\u8fc7\u7a0b\u4e2d\u5f62\u6210\u9ad8\u5ea6\u82b3\u9999\u65cf\u5316\u5408\u7269\u7684\u8d8b\u52bf\u964d\u4f4e\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-239255\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72476.png\" alt=\"\" width=\"561\" height=\"629\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72476.png 561w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/07\/\u56fe\u72476-268x300.png 268w\" sizes=\"(max-width: 561px) 100vw, 561px\" \/><\/p>\n<p>\u56fe5. \u51dd\u805a\u7126\u70ad\u7684\u751f\u6210\u4e0e\u6f14\u5316\u00a9 2022 Springer Nature Limited<\/p>\n<p style=\"text-align: center;\"><strong><b>[\u6210\u679c\u542f\u793a]<\/b><\/strong><\/p>\n<p><strong><b>\u603b\u4e4b\uff0c<\/b><\/strong><strong><b>\u672c<\/b><\/strong><strong><b>\u5de5\u4f5c<\/b><\/strong><strong><b>\u5229\u7528\u64cd\u4f5cPEPICO\u5149\u8c31\u7814\u7a76\u4e86CH<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>OH\u548cCH<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>Cl\u5728\u6cb8\u77f3\u50ac\u5316\u5076\u8054\u53cd\u5e94\u4e2dC-C\u952e\u5f62\u6210\u548c\u94fe\u4f20\u64ad\u7684\u673a\u7406\uff0c\u5176\u72ec\u7279\u7684\u7075\u654f\u5ea6\u4f7f<\/b><\/strong><strong><b>\u672c\u5de5\u4f5c<\/b><\/strong><strong><b>\u80fd\u591f\u5b9a\u91cf\u548c\u9009\u62e9\u6027\u5730\u63cf\u8ff0MTH\u548cMCTH\u53cd\u5e94\u521d\u671f\u4e2d\u95f4\u4f53\u7684\u751f\u6210<\/b><\/strong>\u3002\u64cd\u4f5cPEPICO\u5149\u8c31\u8fd8\u5bf9MTH\u548cMCTH\u4e2d\u8418\u53ca\u5176\u7532\u57fa\u5316\u7c7b\u4f3c\u7269\u7b49\u7126\u70ad\u524d\u9a71\u4f53\u7684\u751f\u6210\u673a\u7406\u63d0\u4f9b\u4e86\u89c1\u89e3\u3002\u786e\u5b9a\u78b3\u7269\u8d28\u751f\u6210\u7684C-C\u952e\u5f62\u6210\u548c\u94fe\u6269\u5c55\u7684\u4e0d\u540c\u9014\u5f84\uff0c\u5bf9\u4e8e\u8bbe\u8ba1CH<sub>3<\/sub>OH\u548cCH<sub>3<\/sub>Cl\u8026\u5408\u7684\u50ac\u5316\u548c\u53cd\u5e94\u5668\u7cfb\u7edf\u5177\u6709\u91cd\u8981\u7684\u5b9e\u9645\u610f\u4e49\u3002\u4eca\u540e\uff0c\u8fd9\u4e9b\u6280\u672f\u4e3a\u6df1\u5165\u4e86\u89e3\u70c3\u7c7b\u8f6c\u5316\u4e2d\u7684\u5176\u4ed6\u957f\u671f\u5b58\u5728\u7684\u95ee\u9898\u63d0\u4f9b\u4e86\u4e00\u4e2a\u6709\u4ef7\u503c\u7684\u5e73\u53f0\uff0c\u4f8b\u5982\u786e\u8ba4\u4fc3\u8fdb\u5242\u6216\u53cd\u5e94\u7269\u79bb\u5f00\u57fa\u56e2\u7684\u5f71\u54cd\uff0c\u533a\u5206\u4ec5\u4ec5\u662f\u65c1\u89c2\u8005\u548c\u771f\u6b63\u7684\u53cd\u5e94\u4e2d\u95f4\u4f53\uff0c\u5e76\u53ef\u5e94\u7528\u4e8e\u51e0\u4e4e\u6240\u6709\u7684\u70c3\u7c7b\u529f\u80fd\u5316\u8fc7\u7a0b\u3002<\/p>\n<p>\u7b2c\u4e00\u4f5c\u8005\uff1aAlessia Cesarini\u3001Sharon Mitchell\u3001Guido Zichittella<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1aGuido Zichittella\u3001Patrick Hemberger\u3001Javier P\u00e9rez-Ram\u00edre<\/p>\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u745e\u58eb\u82cf\u9ece\u4e16\u8054\u90a6\u7406\u5de5\u5b66\u9662\u3001\u745e\u58eb\u4fdd\u7f57\u8c22\u52d2\u7814\u7a76\u6240<\/p>\n<p>\u8bba\u6587doi\uff1a<\/p>\n<p>https:\/\/doi.org\/10.1038\/s41929-022-00808-0<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5355\u53d6\u4ee3\u7532\u70f7\uff0c\u5305\u62ec\u7532\u9187\u548c\u6c2f\u7532\u70f7\uff08\u5206\u522b\u4e3aCH3X\u3001X=OH\u548cCl\uff09\uff0c\u662f\u53ef\u6301\u7eed\u71c3\u6599\u548c\u5316\u5b66\u54c1\u7684\u6709\u5438\u5f15\u529b\u7684\u7ec4\u6210\u90e8\u5206\u3002\u8fd9\u4e9bC1\u5206\u5b50\u662f\u5408\u6210\u6c14\u8f6c\u5316\u3001\u4e8c\u6c27\u5316\u78b3\u52a0\u6c22\u548c\u5364\u7d20\u4ecb\u5bfc\u7684\u70f7\u70c3&#8230;<\/p>\n","protected":false},"author":34419,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,4,2],"tags":[2490,4879],"class_list":["post-239248","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-ganhuo","category-keji","tag-2490","tag-4879"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/239248"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/34419"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=239248"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/239248\/revisions"}],"predecessor-version":[{"id":239266,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/239248\/revisions\/239266"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=239248"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=239248"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=239248"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}