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\u5bfc\u8bfb<\/strong><\/p>\n

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\"\"<\/p>\n

\u6838\u5fc3\u4eae\u70b9<\/strong><\/p>\n

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\u56fe\u6587\u89e3\u8bfb<\/strong><\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

a \u6784\u8c61\u7075\u6d3b\u7684prentrz\u5206\u5b50\u88ab\u7528\u4f5c\u8f74\u5411\u914d\u4f53\u3002<\/p>\n

b \u7531Fe-N(\u2261C-Pd)\u914d\u4f4d\u952e\u6784\u5efa\u76842D\u7f51\u7edc\u3002\u901a\u8fc7\u5c42\u95f4\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\uff0c\u5c42\u7ed3\u6784\u7ec4\u88c5\u62103D\u6846\u67b6\u3002<\/p>\n

c lcp\u76f81<\/strong>\u00b79\/2H2<\/sub>O\u7684\u5355\u6676\u7ed3\u6784\u3002<\/p>\n

d nqp\u76f81<\/strong>\u00b74\/3H2<\/sub>O. \u7684\u5355\u6676\u7ed3\u6784\u3002<\/p>\n

\u56fe3 PXRD\u7814\u7a76\u4e86\u6c34\u7684\u5438\u9644\u7b49\u6e29\u7ebf\u53ca\u76f8\u5e94\u7684\u7ed3\u6784\u8f6c\u53d8<\/p>\n

\"\"<\/p>\n

a nqp\u3001lcp\u76f8\u53ca\u7269\u7406\u6df7\u5408\u7269\u7684\u5728433 K\u3001298k\u771f\u7a7a\u4e0b\u6837\u54c1\u7684\u7b49\u6e29\u84b8\u6c7d\u5438\u9644(\u4e0a)\u548c\u89e3\u5438(\u4e0b)\u3002<\/p>\n

b \u4e0d\u540c\u6d3b\u5316\u6761\u4ef6\u4e0b\u7684\u8fde\u7eed\u5438\u6c34-\u89e3\u5438\u5faa\u73af\u3002<\/p>\n

c \u6c34\u5438\u9644\u548c\u89e3\u5438\u7684PXRD\u8c31\u56fe\u3002<\/p>\n

\u56fe4 lcp\u76f81<\/strong>\u00b79\/2H2<\/sub>O\u548cnqp\u76f81<\/strong>\u00b74\/3H2<\/sub>O\u52a0\u70ed\u548c\u51b7\u5374\u65f6\u7684\u03c7<\/sub>M<\/sub>T\u66f2\u7ebf\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027<\/p>\n

\"\"<\/p>\n

\u56fe5\u5438\u6c34\u7ed3\u6784\u8f6c\u53d8<\/p>\n

\"\"<\/p>\n

a \u5728lcp(1<\/strong>\u00b79\/2H2<\/sub>O)\u548cnqp(1<\/strong>\u00b74\/3H2<\/sub>O)\u76f8\u4e2d\u7684\u5f39\u6027prentrz\u914d\u4f53\u7684\u6784\u8c61\u3002<\/p>\n

b prentrz\u5206\u5b50\u7684\u5c40\u90e8\u8e0f\u677f\u65cb\u8f6c\u548cFe-N\u8f74\u5411\u914d\u4f4d\u952e\u7684\u65b9\u5411\u504f\u79fb\u3002<\/p>\n

c \u914d\u4f53II\u5438\u9644\u540e\u7684\u65b9\u5411\u79fb\u4f4d\u4f7f\u901a\u9053A1’\u6269\u5f20\uff0c\u901a\u9053A2’\u5173\u95ed\uff0c\u800c\u914d\u4f53IV\u7684\u65b9\u5411\u79fb\u4f4d\u4f7f\u901a\u9053B1’\u6253\u5f00\uff0c\u901a\u9053A3’\u5173\u95ed\u3002<\/p>\n

d \u914d\u4f4d\u5c42\u8868\u73b0\u51fa\u663e\u8457\u7684\u5377\u66f2\/\u5c55\u5f00\u8fd0\u52a8\uff0c\u4ee5\u534f\u52a9Fe-N\u914d\u4f4d\u952e\u7684\u91cd\u5b9a\u5411\u3002<\/p>\n

\u56fe6 \u6c34\u5438\u9644\u7684\u80fd\u91cf\u56fe<\/p>\n

\"\"<\/p>\n

\u603b\u7ed3\u4e0e\u5c55\u671b<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u5229\u7528prentrz\u914d\u4f53\u7684\u6784\u8c61\u5f39\u6027\u548c\u4e8c\u7ef4\u914d\u4f4d\u7f51\u7edc\u7684\u6ce2\u52a8\uff0c\u5236\u5907\u4e86\u4e00\u79cd\u4e8c\u7ef4\u8f6f\u78c1\u591a\u5b54\u5355\u6676\u5316\u5408\u7269\u3002\u6c34\u5438\u9644\u5f15\u8d77\u7684\u8f74\u5411\u914d\u4f53\u7684\u4e0d\u5747\u5300\u8e0f\u677f\u65cb\u8f6c\u4f34\u968f\u7740\u4e8c\u7ef4\u5c42\u7ed3\u6784\u7684\u6298\u53e0\/\u5c55\u5f00\uff0c\u4f7f\u6676\u683c\u7ed3\u6784\u91cd\u65b0\u5212\u5206\uff0c\u8868\u73b0\u4e3a\u5b54\u9699\u6784\u578b\u7684\u91cd\u65b0\u6392\u5217\u7684\u6846\u67b6\u547c\u5438\u3002\u7531\u4e8e\u5b54\u9699\u91cd\u65b0\u6392\u5217\u7684\u540c\u65f6\u5f00\u542f\u548c\u5173\u95ed\uff0c\u5bfc\u81f4nqp – lcp\u7684\u52a8\u529b\u5b66\u8fc7\u7a0b\u7f13\u6162\uff0c\u5176\u4e2dnqp\u76f8\u9700\u8981\u957f\u65f6\u95f4\u66b4\u9732\u5728\u9971\u548c\u84b8\u6c7d\u4e2d\u624d\u80fd\u5b8c\u6210nqp – lcp\u7684\u5f00\u95e8\u5438\u9644\u3002\u6b64\u5916\uff0c\u78c1\u6027\u9aa8\u67b6\u7684\u7ed3\u6784\u8f6c\u53d8\u4e5f\u6539\u53d8\u4e86FeII<\/sup>\u78c1\u6027\u4e2d\u5fc3\u7684SCO\u6027\u8d28\u3002\u4f34\u968f\u6d3b\u5316\u6cd5\u6761\u4ef6\u4e0b\u7684\u5438\u9644\uff0c\u672c\u7814\u7a76\u63d0\u51fa\u4e86\u4e00\u79cd\u4e0e\u5438\u9644\u76f8\u5173\u7684\u5b54\u9699\u8f6c\u5316\u3002\u8fd9\u79cd\u5947\u7279\u7684\u7279\u6027\u53ef\u7528\u4e8e\u6c14\u4f53\u5438\u9644\u3001\u9a71\u52a8\u548c\u4f20\u611f\u6750\u6599\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong><\/p>\n

A spin-crossover framework endowed with pore-adjustable behavior by slow structural dynamics<\/p>\n

https:\/\/doi.org\/10.1038\/s41467-022-31274-8<\/a><\/p>\n

 <\/p>\n

\u672c\u6587\u7531junas\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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