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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n 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\u4ec5\u4ec5\u65f6\u9694\u56db\u4e2a\u6708\uff0c\u5170\u5dde\u5927\u5b66\u738b\u80b2\u534e\u6559\u6388\u3001<\/strong>Takatoshi Seto<\/strong>\u6559\u6388\u3001\u4e2d\u56fd\u5730\u8d28\u5927\u5b66<\/strong>(<\/strong>\u5317\u4eac<\/strong>)<\/strong>\u6750\u6599\u5b66\u9662\u5ed6\u7acb\u5175\u6559\u6388\u3001\u6885\u4e50\u592b\u6559\u6388\u548c\u53a6\u95e8\u5927\u5b66\u5e84\u9038\u7199\u526f\u6559\u6388\u7b49\u5b66\u8005<\/strong>\u518d\u6b21\u5f00\u5c55\u79d1\u7814\u5408\u4f5c\uff0c\u5c06\u76f8\u5173\u8bba\u6587<\/strong>Activators Lattice Migration Strategy<\/strong> Customized for Tunable Luminescence of Ce3+ <\/sup>Doped \u03b2<\/em>-Ca3<\/sub>(PO4<\/sub>)2 <\/sub><\/strong>\u518d\u6b21<\/strong>\u53d1\u8868\u4e8e\u56fd\u9645\u8457\u540d\u671f\u520a<\/strong> Chemical Engineering Journal (<\/strong>\u4e2d\u79d1\u9662\u4e00\u533a\uff0c<\/strong>TOP, <\/strong>\u5f71\u54cd\u56e0\u5b50<\/strong>:13.273)<\/strong>\u3002\u4e2d\u56fd\u5730\u8d28\u5927\u5b66<\/strong>(<\/strong>\u5317\u4eac<\/strong>)&<\/strong>\u53a6\u95e8\u5927\u5b66\u8054\u5408\u57f9\u517b\u535a\u58eb\u751f\u6f58\u946b\u4e3a\u7b2c\u4e00\u4f5c\u8005\u3002<\/strong>doi:https:\/\/doi.org\/10.1016\/j.cej.2022.137271<\/strong><\/p>\n 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\u56fe<\/strong>2 (a) <\/strong>\u03b2<\/strong>-TCP<\/strong>\u7684\u539f\u59cb\u6676\u4f53\u7ed3\u6784\u56fe\u548c\u4e94\u79cd\u4e0d\u540c\u9633\u79bb\u5b50<\/strong>(M)<\/em><\/strong>\u7684\u914d\u4f4d\u3002<\/strong>(b)-(c)<\/strong>\u6839\u636e<\/strong>DFT<\/strong>\u8ba1\u7b97\u5f97\u5230\u7684\u80fd\u5e26\u7ed3\u6784\u548c\u80fd\u5e26\u6001\u5bc6\u5ea6\u8c31<\/strong><\/p>\n \u56fe<\/strong>3 (a)-(f)TCSP<\/strong>\u7684<\/strong>Rietveld<\/strong>\u7ec6\u5316\u7ed3\u679c\u3002<\/strong>(g) TCSP:Ce<\/strong>\u7684<\/strong>XRPD<\/strong>\u3002<\/strong>(h) <\/strong>\u7ebf\u6027\u4f53\u79ef\u4f9d\u8d56\u6027<\/strong>V(x)<\/strong>\u3002<\/strong>(i) TCSP:Ce<\/strong>\u7684<\/strong>DRS<\/strong>\u5149\u8c31\u548c\u8ba1\u7b97\u7684\u5149\u5b66\u5e26\u9699\u3002<\/strong>(j) TCSP:Ce(x=0<\/strong>\u548c<\/strong>1.5)<\/strong>\u548c\u6807\u6837<\/strong>CeO2<\/sub>\/CePO4<\/sub><\/strong>\u7684<\/strong>Ce L3<\/strong>\u8fb9<\/strong>XANES<\/strong>\u5149\u8c31\u3002<\/strong>(k) <\/strong>\u7531<\/strong>350<\/strong>\u548c<\/strong>370nm<\/strong>\u53d1\u5c04\u76d1\u6d4b\u7684\u6fc0\u53d1\u5149\u8c31\u53ca\u5728<\/strong>290<\/strong>\u548c<\/strong>310 nm<\/strong>\u6fc0\u53d1\u4e0b<\/strong>TCSP:Ce(x=0<\/strong>\uff0c<\/strong>TCP:Ce)<\/strong>\u7684\u53d1\u5c04\u5149\u8c31\u3002<\/strong><\/p>\n \u56fe<\/strong>5<\/strong>\uff1a<\/strong>(a) Ca<\/strong>\u3001<\/strong>Sr<\/strong>\u548c<\/strong>Ca+Sr<\/strong>\u7684\u539f\u5b50\u5360\u6709\u7387\u3002<\/strong>(b)<\/strong>\u4e94\u79cd<\/strong>M-O<\/strong>\u548c\u4e09\u79cd<\/strong>P-O<\/strong>\u9633\u79bb\u5b50\u7684\u5e73\u5747\u952e\u957f\u3002<\/strong>(c) <\/strong>\u9633\u79bb\u5b50\u4f4d\u70b9<\/strong>M(1)-M(5)<\/strong>\u7684\u5e73\u5747\u952e\u957f<\/strong>(Rav<\/sub><\/em>)<\/strong>\u548c\u591a\u9762\u4f53\u7578\u53d8<\/strong>(Dpq<\/sub><\/em>)<\/strong>\uff0c<\/strong>Sr(x<\/em>)=0-3<\/strong>\u3002<\/strong>(d) Ce3+<\/sup><\/strong>\u6676\u683c\u8fc1\u79fb\u968f<\/strong>Sr(x<\/em>)<\/strong>\u53d8\u5316\u7684\u793a\u610f\u56fe\u3002<\/strong><\/p>\n \u00a0 \u56fe<\/strong>6 (a) TCSP<\/strong>\uff1a<\/strong>Ce(x=0<\/strong>\u548c<\/strong>1.5)<\/strong>\u548c\u6807\u6837<\/strong>CeO2<\/sub><\/strong>\u548c<\/strong>CePO4<\/sub><\/strong>\u4e2d<\/strong>Ce<\/strong>\u5468\u56f4\u7684<\/strong>R<\/strong>\u7a7a\u95f4<\/strong>EXAFS<\/strong>\u7684\u5c40\u57df\u7ed3\u6784\u5206\u6790\u3002<\/strong>(b) Sr(x<\/em>)=0<\/strong>\u3001<\/strong>1.5<\/strong>\u4e2d\u4e94\u79cd\u4e0d\u540c<\/strong>Ce3+<\/sup><\/strong>\u6676\u4f4d\u5f62\u6210\u80fd<\/strong>E<\/em><\/strong>\u7684\u8ba1\u7b97\u3002<\/strong>(d) TCSP:Ce<\/strong>\u4e2d<\/strong>Ce3+<\/sup><\/strong>\u7684\u80fd\u5e26\u53d8\u5316\u56fe\u3002<\/strong><\/p>\n \u56fe<\/strong>7 (a) <\/strong>\u7528<\/strong>366nm<\/strong>\u53d1\u5c04\u76d1\u6d4b<\/strong>TCSP:Ce<\/strong>\u7684\u6fc0\u53d1\u5149\u8c31\u3002<\/strong>(b) TCSP:Ce<\/strong>\u5728<\/strong>310 nm<\/strong>\u6fc0\u53d1\u4e0b\u7684\u53d1\u5c04\u5149\u8c31\u3002<\/strong>(c) TCSP:Ce(x=1.5)<\/strong>\u5728<\/strong>77 K<\/strong>\u4e0b\u7684\u4f4e\u6e29\u53d1\u5c04\u5149\u8c31\u548c\u9ad8\u65af\u62df\u5408\u5cf0\u3002<\/strong>(d) Ce3+<\/sup><\/strong>\u79bb\u5b50<\/strong>5d-4f<\/strong>\u8dc3\u8fc1\u7684\u53d1\u5149\u673a\u7406\u56fe\u3002<\/strong>(e) <\/strong>\u5728<\/strong>366 nm(\u03bbex=310 nm)<\/strong>\u4e0b\u76d1\u6d4b<\/strong>TCSP:Ce<\/strong>\u8367\u5149\u7c89\u4e2d<\/strong>Ce3+<\/sup><\/strong>\u7684\u8870\u51cf\u66f2\u7ebf\u3002<\/strong>(f) <\/strong>\u53d1\u5c04\u5f3a\u5ea6\u548c\u6ce2\u957f\u968f<\/strong>Sr<\/strong>\u6d53\u5ea6<\/strong>x<\/em><\/strong>\u7684\u589e\u52a0\u548c<\/strong>TCSP:Ce<\/strong>\u7684\u5f52\u4e00\u5316\u53d1\u5c04\u5149\u8c31<\/strong>(<\/strong>\u91cd\u590d<\/strong>3<\/strong>\u6b21<\/strong>)<\/strong>\u7684\u53d8\u5316<\/strong><\/p>\n \u56fe<\/strong>S6 <\/strong>\u9632\u4f2a\u5e94\u7528\u3002\u5c06\u7814\u5236\u7684\u8367\u5149\u7c89\u5236\u6210\u8367\u5149\u6cb9\u58a8\u7528\u4e8e\u4e1d\u7f51\u5370\u5237\u3002\u6253\u5370\u4fe1\u606f\uff08\u4f8b\u5982\uff0c\u52a8\u6001\u9632\u75ab\u4e8c\u7ef4\u7801\uff09\u5728\u65e5\u5149\u4e0b\u4e0d\u53ef\u89c1\uff0c\u5728<\/strong>UVB<\/strong>\u5149\u4e0b\u53ef\u8bfb\u3002<\/strong><\/p>\n \u7b2c\u4e00\u4f5c\u8005<\/strong><\/p>\n \u6f58\u946b<\/strong>\uff0c\u4e2d\u56fd\u5730\u8d28\u5927\u5b66(\u5317\u4eac)\u5b9d\u77f3\u53ca\u6750\u6599\u5de5\u827a\u5b66\/\u5de5\u5546\u7ba1\u7406\u53cc\u5b66\u4f4d\u5b66\u58eb\u3001\u5b9d\u77f3\u5b66\u7855\u58eb\u3001\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5728\u8bfb\u535a\u58eb\u751f(\u53a6\u95e8\u5927\u5b66\u8054\u5408\u57f9\u517b)\u3002\u82f1\u56fd\u7687\u5bb6\u5b9d\u77f3\u5b66\u4f1a\u4f1a\u5458\u53ca\u6ce8\u518c\u9274\u5b9a\u5e08\u3002\u53c2\u4e0e\u591a\u9879\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u7814\u7a76\uff0c\u7533\u8bf74\u9879\u56fd\u5bb6\u53d1\u660e\u4e13\u5229\u3002\u66fe\u83b7\u5168\u56fd\u5927\u5b66\u751f\u79d1\u6280\u521b\u65b0\u5927\u8d5b\u4e00\u7b49\u5956\u3001\u591a\u6b21\u5b66\u672f\u7814\u8ba8\u4f1a\u62a5\u544a\u4f18\u79c0\u5956\u53ca\u4f18\u79c0\u79d1\u7814\u6fc0\u52b1\u5956\u3001\u5168\u56fd\u897f\u90e8\u8ba1\u5212\u4f18\u79c0\u652f\u6559\u6559\u5e08\u3001\u5e02\u4f18\u79c0\u56e2\u5e72\u90e8\u3001\u5e02\u4e09\u597d\u5b66\u751f\u3001\u4e2d\u592e\u56fd\u5bb6\u673a\u5173\u4f18\u79c0\u5b9e\u4e60\u751f\u7b49\u8363\u8a89\u3002\u73b0\u4e3b\u8981\u4ece\u4e8b\u5149\u81f4\/\u529b\u81f4\u53d1\u5149\u6750\u6599\u7684\u673a\u7406\u3001\u6784\u6548\u5173\u7cfb\u3001\u6027\u80fd\u8c03\u63a7\u53ca\u76f8\u5173\u5149\u7535\u5b50\u5b66\u3001\u77ff\u7269\u6676\u4f53\u5b66\u7684\u7814\u7a76\u3002<\/p>\n
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