{"id":237213,"date":"2022-05-15T06:16:01","date_gmt":"2022-05-14T22:16:01","guid":{"rendered":"\/\/m.iemloyee.com\/?p=237213"},"modified":"2022-05-14T21:16:24","modified_gmt":"2022-05-14T13:16:24","slug":"%e7%8e%af%e5%b7%b1%e7%83%b7%e5%90%88%e6%88%90%e9%a2%86%e5%9f%9f%e5%8f%96%e5%be%97%e6%96%b0%e7%aa%81%e7%a0%b4%ef%bc%8c%e9%a6%96%e6%ac%a1%e7%99%bb%e4%b8%8ascience","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=237213","title":{"rendered":"\u73af\u5df1\u70f7\u5408\u6210\u9886\u57df\u53d6\u5f97\u65b0\u7a81\u7834\uff0c\u9996\u6b21\u767b\u4e0aScience"},"content":{"rendered":"<p style=\"text-align: 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\u8fd9\u79cd\u65b9\u6cd5\u7684\u5408\u6210\u6f5c\u529b\u5728\u590d\u6742\u751f\u7269\u6d3b\u6027\u5206\u5b50\u7684\u540e\u671f\u4fee\u9970\u4ee5\u53ca\u4e0e\u5f53\u524d\u4ea4\u53c9\u5076\u8054\u6280\u672f\u7684\u6bd4\u8f83\u4e2d\u5f97\u5230\u4e86\u5f3a\u8c03\u3002\u5373\u5229\u7528\u201c\u91d1\u5c5e\u8fc1\u79fb\u201d\u7b56\u7565\uff0c\u89e3\u51b3\u4e86\u73af\u5df1\u70f7\u5408\u6210\u9886\u57df\u957f\u671f\u5b58\u5728\u7684\u96be\u9898\u3002\u5177\u4f53\u7684\u6210\u679c\u4ee5\u201c<strong>Modular access to substituted cyclohexanes with kinetic stereocontrol<\/strong>\u201d\u4e3a\u9898\u53d1\u5e03\u5728<strong><em>Science<\/em><\/strong>\u4e0a\u3002\u897f\u73ed\u7259\u62c9\u91cc\u5965\u54c8\u5927\u5b66\u7684\u535a\u58eb\u540eIgnacio Funes-Ardoiz\u4e3a\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff0c\u9ad8\u7b49\u7814\u7a76\u96622018\u7ea7\u535a\u58eb\u7814\u7a76\u751f\u674e\u9633\u9633\u4e3a\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full 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srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f2.jpg 3366w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f2-240x300.jpg 240w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f2-768x959.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f2-820x1024.jpg 820w\" sizes=\"(max-width: 3366px) 100vw, 3366px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><span class=\"heading\">\u56fe 3\u00a0<\/span><\/strong>\u53cd\u5e94\u8303\u56f4<span style=\"color: #808080;\">\u00a9 2022 AAAS<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-237217\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f3.jpg\" alt=\"\" width=\"3347\" height=\"4988\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f3.jpg 3347w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f3-201x300.jpg 201w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f3-768x1145.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f3-687x1024.jpg 687w\" sizes=\"(max-width: 3347px) 100vw, 3347px\" \/><\/p>\n<p style=\"text-align: center;\"><span class=\"heading\"><strong>\u56fe 4<\/strong>\u00a0<\/span>\u4ee3\u8868\u4ea7\u54c1\u7684\u591a\u6837\u5316\u00a0<span style=\"color: #808080;\">\u00a9 2022 AAAS<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-237218\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f4.jpg\" alt=\"\" width=\"3383\" height=\"1180\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f4.jpg 3383w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f4-300x105.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f4-768x268.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/05\/science.abn9124-f4-1024x357.jpg 1024w\" sizes=\"(max-width: 3383px) 100vw, 3383px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56db\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u901a\u8fc7\u8fd9\u9879\u5de5\u4f5c\uff0c\u5b9e\u73b0\u4e86\u954d\u50ac\u5316\u7684\u5316\u5b66\u9009\u62e9\u6027\u4e09\u7ec4\u5206\u5076\u8054\u53cd\u5e94\uff0c\u8be5\u53cd\u5e94\u4e3a\u4ece\u6613\u4e8e\u63a5\u8fd1\u7684\u4e9a\u7532\u57fa\u73af\u5df1\u70f7\u3001B<sub>2<\/sub>pin<sub>2<\/sub>\u548c\u82c4\u57fa\u5364\u5316\u7269\u5230\u70ed\u529b\u5b66\u4e0a\u4e0d\u53d7\u6b22\u8fce\u7684\u53d6\u4ee3\u73af\u5df1\u70f7\u7684\u6846\u67b6\u63d0\u4f9b\u4e86\u65b9\u4fbf\u3002\u5e7f\u6cdb\u7684\u5b98\u80fd\u56e2\uff0c\u5305\u62ec\u82b3\u57fa\u6eb4\u3001\u916f\u3001\u80fa\u3001\u9170\u80fa\u3001\u4e9a\u80fa\u548c\u03b1\u3001\u03b2-\u4e0d\u9971\u548c\u916e\uff0c\u90fd\u4e0e\u8be5\u8f6c\u5316\u76f8\u517c\u5bb9\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1aLi, Y.; Li, Y.; Shi, H.; Wei, H.; Li, H.; Funes-Ardoiz, I.; Yin, G., Modular access to substituted cyclohexanes with kinetic stereocontrol. <em>Science<\/em> 2022, 376 (6594), 749-753.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 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