{"id":237015,"date":"2022-05-13T06:17:46","date_gmt":"2022-05-12T22:17:46","guid":{"rendered":"\/\/m.iemloyee.com\/?p=237015"},"modified":"2022-05-28T22:23:38","modified_gmt":"2022-05-28T14:23:38","slug":"nat-nanotechnol-cof%e5%8d%95%e5%b1%82%e8%86%9c%e7%94%a8%e4%ba%8e%e9%ab%98%e6%95%88%e6%b8%97%e9%80%8f%e5%8f%91%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=237015","title":{"rendered":"Nat. Nanotechnol.: COF\u5355\u5c42\u819c\u7528\u4e8e\u9ad8\u6548\u6e17\u900f\u53d1\u7535"},"content":{"rendered":"

\u4e00\u3001<\/strong>\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u6e17\u900f\u80fd\uff08<\/strong>Osmotic power<\/strong><\/span>\uff09<\/span>\uff0c\u662f\u7531\u4e0d\u540c\u6d53\u5ea6\u7684\u76d0\u6eb6\u6db2\u6df7\u5408\u65f6\u4ea7\u751f\u7684\uff0c\u662f\u4e00\u79cd\u53ef\u89c4\u6a21\u5316\u3001\u53ef\u6301\u7eed\u7684\u6e05\u6d01\u80fd\u6e90\uff0c\u4e5f\u88ab\u79f0\u4e3a\u201c\u84dd\u8272\u80fd\u6e90\u201d\u3002<\/strong>\u5728\u6d53\u5ea6\u68af\u5ea6\u7684\u9a71\u52a8\u4e0b\uff0c\u6b63\u8d1f\u79bb\u5b50\u901a\u8fc7\u9009\u62e9\u6027\u900f\u8fc7\u819c\u7684\u901f\u5ea6\u4e0d\u540c\uff0c\u819c\u4e24\u4fa7\u4f1a\u4ea7\u751f\u7535\u52bf\u5dee\uff0c\u4ece\u800c\u5728\u5916\u7535\u8def\u4ea7\u751f\u7535\u6d41\u3002\u6e17\u900f\u80fd\u7684\u6536\u96c6\u6548\u7387\uff0c\u5373\u6e17\u900f\u53d1\u7535\u6548\u7387\u4e3b\u8981\u53d6\u51b3\u4e8e\u9009\u62e9\u900f\u8fc7\u6027\u819c\u7684\u6027\u80fd\uff0c\u5373\u79bb\u5b50\u7535\u5bfc\u6027\u4ee5\u53ca\u5bf9\u6b63\u8d1f\u79bb\u5b50\u7684\u900f\u8fc7\u9009\u62e9\u6027\u3002\u5176\u4e2d\uff0c\u8868\u9762\u5e26\u7535\u7684\u8d85\u8584\u4e8c\u7ef4\u6750\u6599\uff0c\u5982\u6c2e\u5316\u787c\u3001\u4e8c\u786b\u5316\u94bc\u3001\u77f3\u58a8\u70ef\u7b49\u7531\u4e8e\u8f83\u4f4e\u7684\u819c\u7535\u963b\uff0c\u662f\u7528\u4e8e\u6e17\u900f\u53d1\u7535\u7684\u7406\u60f3\u6750\u6599\u3002\u4f46\u662f\u4f20\u7edf\u7684\u4e8c\u7ef4\u6750\u6599\u96be\u4ee5\u83b7\u5f97\u9ad8\u5bc6\u5ea6\u3001\u5c3a\u5bf8\u5747\u5300\u7684\u7eb3\u7c73\u5b54\uff1b\u5e76\u4e14\u4f4e\u7684\u819c\u7535\u963b\u4f1a\u5bfc\u81f4\u4e0d\u53ef\u907f\u514d\u7684\u6d53\u5dee\u6781\u5316\u73b0\u8c61\uff0c\u7279\u522b\u662f\u5b54\u5bc6\u5ea6\u589e\u52a0\u65f6\uff0c\u819c\u4e24\u4fa7\u7684\u6d53\u5ea6\u5dee\u96be\u4ee5\u4fdd\u6301\uff0c\u4f1a\u5f15\u8d77\u6e17\u900f\u7535\u538b\u548c\u7535\u6d41\u7684\u5feb\u901f\u4e0b\u964d\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u5236\u5907\u5177\u6709\u9ad8\u5b54\u5bc6\u5ea6\u548c\u5747\u5300\u5b54\u5c3a\u5bf8\u7684\u9009\u62e9\u6027\u900f\u8fc7\u819c\uff0c\u5728\u4fdd\u8bc1\u79bb\u5b50\u9009\u62e9\u6027\u7684\u57fa\u7840\u4e0a\u63d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u6027\u662f\u5b9e\u73b0\u9ad8\u6548\u6e17\u900f\u53d1\u7535\u7684\u5173\u952e\u3002<\/strong><\/p>\n

\u4e8c\u3001<\/strong>\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u56fd\u5bb6\u7eb3\u7c73\u79d1\u5b66\u4e2d\u5fc3\u7684\u5510\u667a\u52c7\u4e0e\u674e\u8fde\u5c71\u7814\u7a76\u5458<\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\uff0c\u5229\u7528\u5177\u6709\u6709\u5e8f\u5b54\u6392\u5217\u7684\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COF\uff09\u5355\u5c42\u819c\u5b9e\u73b0\u4e86\u6781\u4f4e\u7684\u819c\u7535\u963b\u548c\u8d85\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u5c06\u5236\u5907\u7684COF\u5355\u5c42\u819c\u7528\u4e8e\u6df7\u5408\u4eba\u5de5\u6d77\u6c34\/\u6cb3\u6c34\u7684\u6e17\u900f\u53d1\u7535\uff0c\u53ef\u4ee5\u83b7\u5f97\u8d85\u8fc7200 W m-2<\/sup>\u7684\u524d\u6240\u672a\u6709\u7684\u8f93\u51fa\u529f\u7387\u5bc6\u5ea6\u3002\u8fd9\u9879\u5de5\u4f5c\u5f00\u8f9f\u4e86\u539f\u5b50\u7ea7\u7cbe\u786e\u7ed3\u6784\u7684\u591a\u5b54\u5355\u5c42\u819c\u5728\u6e17\u900f\u53d1\u7535\u4e2d\u7684\u5e94\u7528\u3002<\/strong>\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cAdvancing osmotic power generation by covalent organic framework monolayer<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature Nanotechnology<\/em><\/strong>\u671f\u520a\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001<\/strong>\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

    \n
  1. COF\u6750\u6599\u5177\u6709\u9ad8\u7684\u5b54\u5bc6\u5ea6\u548c\u5747\u5300\u7684\u5b54\u5c3a\u5bf8<\/span><\/strong>\uff0c\u901a\u8fc7\u9884\u7ec4\u88c5\u754c\u9762\u805a\u5408\u53cd\u5e94\u5236\u5907\u7684COF\u5355\u5c42\u819c\u53ef\u4ee5\u5b9e\u73b0\u8d85\u4f4e\u7684\u819c\u7535\u963b\uff0c\u63d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u6027\u548c\u7535\u6d41\u5bc6\u5ea6\u3002<\/li>\n
  2. COF\u819c\u4e2d\u76f8\u90bb\u7eb3\u7c73\u5b54\u95f4\u7684\u5b54-\u5b54\u8026\u5408\u6548\u5e94<\/span><\/strong>\u53ef\u4ee5\u6709\u6548\u6297\u8861\u819c\u4e24\u4fa7\u7684\u6d53\u5dee\u6781\u5316\uff0c\u6291\u5236\u7535\u6d41\u7535\u538b\u7684\u4e0b\u964d\u3002<\/li>\n
  3. \u5c06\u5236\u5907\u7684COF\u5355\u5c42\u819c\u5e94\u7528\u4e8e\u6df7\u5408\u4eba\u5de5\u6d77\u6c34\/\u6cb3\u6c34\u7684\u6e17\u900f\u53d1\u7535\uff0c\u53ef\u4ee5\u83b7\u5f97\u9ad8\u8fbe200 W m-2<\/sup>\u7684\u8f93\u51fa\u529f\u7387\u5bc6\u5ea6<\/span><\/strong>\u3002<\/li>\n<\/ol>\n

    \u56db\u3001<\/strong>\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

    \u56fe<\/strong>1. COF<\/strong>\u5355\u5c42\u819c\u7684\u5f62\u8c8c\u548c\u7ed3\u6784\u8868\u5f81<\/strong> \u00a9 2022 Springer Nature<\/span><\/p>\n

    \"\"<\/p>\n

    \uff08a\uff09\u76d0\u6d53\u5ea6\u68af\u5ea6\u9a71\u52a8\u4e0b\u79bb\u5b50\u7a7f\u8fc7COF\u5355\u5c42\u819c\u7684\u793a\u610f\u56fe\u3002<\/p>\n

    \uff08b\uff09\u57fa\u4e8e\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u7684ZnTPP-COF\u6a21\u62df\u7ed3\u6784\u3002<\/p>\n

    \uff08c\uff09ZnTPP-COF\u5355\u5c42\u819c\u7684SEM\u56fe\u50cf\u3002<\/p>\n

    \uff08d\uff09ZnTPP-COF\u5355\u5c42\u819c\u7684AFM\u9ad8\u5ea6\u56fe\u50cf\u3002<\/p>\n

    \uff08e\uff0cf\uff09\u5927\u8303\u56f4\uff08e\uff09\u548c\u9ad8\u5206\u8fa8\uff08f\uff09\u7684ZnTPP-COF\u5355\u5c42\u819c\u7684STM\u56fe\u50cf\u3002<\/p>\n

    \u56fe<\/strong>2. <\/strong>\u8de8\u819c\u79bb\u5b50\u7535\u6d41\u548c\u7535\u538b\u8868\u5f81\u00a0<\/strong> \u00a9 2022 Springer Nature<\/span>\"\"<\/p>\n

    \uff08a\uff090.1\u2009M KCl\u6eb6\u6db2\u4e2dCOF\u5355\u5c42\u819c\u7684\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\uff08\u819c\u652f\u6491\u57fa\u5e95SiNx<\/sub>\u7247\u542b2 \u03bcm\u5bbd\u7684\u5355\u5b54\uff09\u3002<\/p>\n

    \uff08b\uff09\u4e0d\u540c\u6d53\u5ea6\u68af\u5ea6\u6bd4\u7684KCl\u6eb6\u6db2\u4e2dCOF\u5355\u5c42\u819c\u7684\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\uff08CH<\/sub>\uff0cCL<\/sub>\u5206\u522b\u4ee3\u8868\u9ad8\u4f4e\u6d53\u5ea6\uff09\u3002<\/p>\n

    \uff08c\uff09\u6e17\u900f\u7535\u6d41\uff08I<\/em>os<\/sub>\uff09\u4e0e\u6e17\u900f\u7535\u538b\uff08V<\/em>os<\/sub>\uff09\u4e0e\u6d53\u5ea6\u68af\u5ea6\u6bd4\u4e4b\u95f4\u7684\u51fd\u6570\u5173\u7cfb\u3002<\/p>\n

    \uff08d\uff09\u901a\u8fc7\u8de8\u819c\u79bb\u5b50\u8fc1\u79fb\u6570\uff08t<\/em>+<\/sub>\uff09\u786e\u5b9a\u79bb\u5b50\u9009\u62e9\u6027\u3002<\/p>\n

    \uff08e\uff09\u4e2d\u5fc3\u5355\u5b54\u7684\u6a21\u62dfI<\/em>os<\/sub>\u4e0eKCl\u6d53\u5ea6\u68af\u5ea6\u6bd4\u7684\u51fd\u6570\u5173\u7cfb\u3002<\/p>\n

    \uff08f\uff09COF\u5355\u5c42\u819c\u5b9e\u9a8c\u6d4b\u5f97\u7684I<\/em>os<\/sub>\u4e0e\u6a21\u62df\u503c\u7684\u6bd4\u8f83\u3002<\/p>\n

    \u56fe<\/strong>3. NaCl<\/strong>\u6eb6\u6db2\u4e2d\u7684\u6e17\u900f\u53d1\u7535 \u00a0<\/strong> \u00a9 2022 Springer Nature<\/span><\/p>\n

    \"\"<\/p>\n

    \uff08a\uff090.5\u2009M NaCl\/0.01\u2009M NaCl\u6eb6\u6db2\u4e2dCOF\u5355\u5c42\u819c\u7684\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

    \uff08b\uff090.5\u2009M NaCl\/0.01\u2009M NaCl\u6eb6\u6db2\u4e2d\u7684\u7535\u6d41\u5bc6\u5ea6\u548c\u8f93\u51fa\u529f\u7387\u5bc6\u5ea6\u5bf9\u5916\u90e8\u8d1f\u8f7d\u7535\u963b\u7684\u4f9d\u8d56\u5173\u7cfb\u3002<\/p>\n

    \uff08c\uff09\u4f7f\u7528ZnTPP-COF\u5355\u5c42\u819c\u7684\u6e17\u900f\u53d1\u7535\u6027\u80fd\u4e0e\u6587\u732e\u62a5\u9053\u7684\u5176\u4ed6\u4f18\u5f02\u7ed3\u679c\u8fdb\u884c\u5bf9\u6bd4\uff0c\u4e3b\u8981\u5305\u62ec\u819c\u539a\u3001\u5b54\u5bc6\u5ea6\u3001\u8f93\u51fa\u529f\u7387\u5bc6\u5ea6\u7b49\u65b9\u9762\u3002<\/p>\n

    \u56fe<\/strong>4. <\/strong>\u591a\u4ef7\u79bb\u5b50\u7535\u89e3\u6db2\u4e2d\u6e17\u900f\u53d1\u7535\u6027\u80fd\u7684\u63d0\u9ad8 \u00a0<\/strong> \u00a9 2022 Springer Nature<\/span><\/p>\n

    \u00a0\"\"<\/strong><\/p>\n

    \uff08a\uff09\u4e0d\u540c\u7535\u89e3\u6db2\u4e2dZnTPP-COF\u5355\u5c42\u819c\u7684\u8f93\u51fa\u529f\u7387\u5bc6\u5ea6\u3002<\/p>\n

    \uff08b\uff09\u6e17\u900f\u7535\u6d41\uff08I<\/em>os<\/sub>\uff09\u4e0e\u6e17\u900f\u7535\u538b\uff08V<\/em>os<\/sub>\uff09\u4e0e\u9633\u79bb\u5b50\u6269\u6563\u7cfb\u6570\u4e4b\u95f4\u7684\u51fd\u6570\u5173\u7cfb\u3002<\/p>\n

    \uff08c\uff09\u4eba\u5de5\u6d77\u6c34\/\u4eba\u5de5\u6cb3\u6c34\u6df7\u5408\u6eb6\u6db2\u4e2d\u7684\u7535\u6d41\u5bc6\u5ea6\u548c\u8f93\u51fa\u529f\u7387\u5bc6\u5ea6\u5bf9\u5916\u90e8\u8d1f\u8f7d\u7535\u963b\u7684\u4f9d\u8d56\u5173\u7cfb\u3002<\/p>\n

    \uff08d\uff09\u6700\u5927\u8f93\u51fa\u529f\u7387\u5bc6\u5ea6\u6761\u4ef6\u4e0bZnTPP-COF\u5355\u5c42\u819c\u7684\u7535\u6d41\u5bc6\u5ea6-\u65f6\u95f4\u66f2\u7ebf\u3002<\/p>\n

    \uff08e\uff09ZnTPP-COF\uff0cNiTPP-COF\u548cCuTPP-COF\u5355\u5c42\u819c\u57280.5\u2009M NaCl\/0.01\u2009M NaCl\u6eb6\u6db2\u3001\u4eba\u5de5\u6d77\u6c34\/\u4eba\u5de5\u6cb3\u6c34\u6eb6\u6db2\u4e2d\u7684I<\/em>os<\/sub>\u4e0eV<\/em>os<\/sub>\u7684\u603b\u7ed3\u3002<\/p>\n

    \uff08f\uff09ZnTPP-COF\uff0cNiTPP-COF\u548cCuTPP-COF\u5355\u5c42\u819c\u57280.5\u2009M NaCl\/0.01\u2009M NaCl\u6eb6\u6db2\u3001\u4eba\u5de5\u6d77\u6c34\/\u4eba\u5de5\u6cb3\u6c34\u6eb6\u6db2\u4e2d\u7684\u8f93\u51fa\u529f\u7387\u5bc6\u5ea6\u7684\u603b\u7ed3\u3002<\/p>\n

    \u4e94\u3001<\/strong>\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

    \u672c\u5de5\u4f5c\u4e2d\uff0c COF\u5355\u5c42\u819c\u7684\u9ad8\u5b54\u5bc6\u5ea6\u548c\u5747\u5300\u5b54\u5c3a\u5bf8\uff0c\u53ef\u4ee5\u5b9e\u73b0\u8d85\u4f4e\u7684\u819c\u7535\u963b\uff0c\u540c\u65f6\u76f8\u90bb\u5b54\u95f4\u7684\u5b54-\u5b54\u8026\u5408\u6548\u5e94\u53ef\u4ee5\u6709\u6548\u6297\u8861\u819c\u4e24\u4fa7\u7684\u6d53\u5dee\u6781\u5316\u3002\u53e6\u5916\uff0c\u5229\u7528COF\u7ed3\u6784\u7684\u591a\u6837\u6027\u548c\u7cbe\u786e\u53ef\u63a7\u6027\uff0c COF<\/strong>\u5355\u5c42\u819c\u4e0d\u4ec5\u53ef\u5e94\u7528\u4e8e\u9ad8\u6548\u7684\u6e17\u900f\u53d1\u7535\uff0c\u800c\u4e14\u6709\u671b\u4e3a\u5176\u4ed6\u4f4e\u963b\u819c\u7684\u5e94\u7528\u63d0\u4f9b\u65b0\u7684\u7814\u7a76\u601d\u8def<\/strong>\uff0c<\/strong>\u4f8b\u5982\u6c14\u4f53\u5206\u79bb\u3001\u79bb\u5b50\u7b5b\u5206\u3001\u8d28\u5b50\u4f20\u5bfc\u3001\u6d77\u6c34\u6de1\u5316\u3001\u86cb\u767d\u8d28\u7eaf\u5316\u7b49\uff0c\u5177\u6709\u5341\u5206\u91cd\u8981\u7684\u7814\u7a76\u4ef7\u503c\u4e0e\u610f\u4e49\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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