{"id":236611,"date":"2022-05-11T06:25:28","date_gmt":"2022-05-10T22:25:28","guid":{"rendered":"\/\/m.iemloyee.com\/?p=236611"},"modified":"2022-05-10T14:25:47","modified_gmt":"2022-05-10T06:25:47","slug":"%e9%a6%99%e6%b8%af%e4%b8%ad%e6%96%87%e5%a4%a7%e5%ad%a6nature-energy%ef%bc%9a%e4%bd%8e%e6%b8%a9%e4%b8%8b%e7%94%a8%e4%ba%8e%e9%ab%98%e5%8a%9f%e7%8e%87%e5%af%86%e5%ba%a6%e6%b0%b4%e7%b3%bb%e6%b0%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=236611","title":{"rendered":"\u9999\u6e2f\u4e2d\u6587\u5927\u5b66Nature Energy\uff1a\u4f4e\u6e29\u4e0b\u7528\u4e8e\u9ad8\u529f\u7387\u5bc6\u5ea6\u6c34\u7cfb\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\u7684\u8d1f\u6781\u7535\u89e3\u6db2"},"content":{"rendered":"

01<\/strong>\u5bfc\u8bfb<\/strong><\/p>\n

\u5728\u4f4e\u6e29\u4e0b\u64cd\u4f5c\u6c34\u7cfb\u6c27\u5316\u8fd8\u539f\u6d41\u7535\u6c60(ARFBs)\u7684\u6548\u679c\u4e0d\u4f73\uff0c\u8fd9\u6e90\u81ea\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7269\u8d28\u7684\u6eb6\u89e3\u5ea6\u6709\u9650\u3001\u7535\u89e3\u8d28\u7684\u51bb\u7ed3\u548c\u53cd\u5e94\u52a8\u529b\u5b66\u7f13\u6162\u3002\u4e00\u79cd\u57fa\u4e8e\u591a\u7535\u5b50\u6742\u591a\u9178\uff08H6<\/sub>P2<\/sub>W18<\/sub>O62<\/sub>, HPWO\uff09\u7684\u7535\u89e3\u6db2\u80fd\u4f7f\u5f97\u6c34\u7cfb\u6db2\u6d41\u7535\u6c60\u80fd\u591f\u5728\u4f4e\u6e29\u4e0b\u7a33\u5b9a\u5de5\u4f5c\u3002\u4e0e\u5176\u4ed6\u9633\u79bb\u5b50(Li+<\/sup>\/Na+<\/sup>\/K+<\/sup>)\u76f8\u6bd4\uff0cHPOM\u4e2d\u7684\u8d28\u5b50(H+<\/sup>)\u5177\u6709\u66f4\u9ad8\u7684\u591a\u91d1\u5c5e\u6c27\u9178\u76d0(POM)\u6eb6\u89e3\u5ea6(25\u00b0C\u65f6\u4e3a0.74 M\uff0c\u221220\u00b0C\u65f6\u4e3a0.5 M)\uff0c\u8fd9\u662f\u56e0\u4e3aH+<\/sup>\u5177\u6709\u8f83\u5f3a\u7684\u6eb6\u5242\u5316\u58f3\u5c42\uff0c\u9632\u6b62\u4e86\u6c89\u6dc0\u3002\u7531\u4e8e\u9ad8\u6eb6\u89e3\u5ea6\u548cGrotthuss\u8d28\u5b50\u4f20\u5bfc\u673a\u5236\uff0cHPOM\u8fd8\u8868\u73b0\u51fa\u5f02\u5e38\u4f4e\u7684\u51dd\u56fa\u70b9\u548c\u9ad8\u7535\u5bfc\u7387\u3002\u8fd9\u4e9b\u4f18\u70b9\u4f7fHPOM\u6210\u4e3a\u9ad8\u529f\u7387\u5bc6\u5ea6\u4f4e\u6e29ARFB\u5e94\u7528\u7684\u4e00\u79cd\u7406\u60f3\u7684\u9009\u62e9\u3002<\/p>\n

02<\/strong>\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n

\u9999\u6e2f\u4e2d\u6587\u5927\u5b66\u5362\u6021\u541b\u7b49\u8bbe\u8ba1\u5408\u6210\u4e86\u4e00\u79cd\u591a\u7535\u5b50\u6742\u591a\u9178\u7535\u89e3\u6db2\uff08HPOM\uff09\uff0c\u5176\u5177\u6709\u5f02\u5e38\u5feb\u7684\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\uff0c\u4f4e\u51dd\u56fa\u70b9\u548c\u9ad8\u7535\u5b50\u6eb6\u89e3\u5ea6\u3002\u79bb\u57df\u7535\u5b50\u548c\u5b8c\u5168\u6c27\u5316\u7684\u94a8\u53ef\u4ee5\u5728\u4e0d\u6539\u53d8\u7ed3\u6784\u7684\u60c5\u51b5\u4e0b\u8fdb\u884c\u5feb\u901f\u7684\u516d\u7535\u5b50\u53cd\u5e94\uff0c\u5176\u5ba4\u6e29\u4e0b\u7535\u8377\u8f6c\u79fb\u901f\u7387\u5e38\u6570\u9ad8\u8fbe6.8\u00d710-3<\/sup>cm\/s\u3002\u4e0e\u5176\u4ed6\u9633\u79bb\u5b50(Li+<\/sup>\/Na+<\/sup>\/K+<\/sup>)\u76f8\u6bd4\uff0cHPOM\u4e2d\u7684\u8d28\u5b50(H+<\/sup>)\u5177\u6709\u66f4\u9ad8\u7684\u591a\u91d1\u5c5e\u6c27\u9178\u76d0(POM)\u6eb6\u89e3\u5ea6(25o<\/sup>C\u65f6\u4e3a0.74 M\uff0c\u221220o<\/sup>C\u65f6\u4e3a0.5 M) \u3002\u4e0a\u8ff0\u4f18\u52bf\u4f7f\u5f97\u57fa\u4e8eHPOM\u7684\u5168\u9492\u6db2\u6d41\u7535\u6c60(HPVBs)\u80fd\u591f\u5728\u4f4e\u6e29-20o<\/sup>C\u4e0b\uff0c\u4ee5160 mA cm-2<\/sup>\u7684\u7535\u6d41\u5faa\u73af\u8d85\u8fc71200 h\uff08800\u6b21\u5faa\u73af\uff09\uff0c\u5c55\u73b0\u51fa79.6 Ah L-1<\/sup>\u5bb9\u91cf\u5374\u6ca1\u6709\u8870\u51cf\uff0c\u8bc1\u660e\u4e86\u4f4e\u6e29\u6db2\u6d41\u7535\u6c60\u521b\u7eaa\u5f55\u7684\u7a33\u5b9a\u6027\u548c\u529f\u7387\u5bc6\u5ea6\uff08282.4 mW cm-2<\/sup>\uff09\u3002\u572825\u2103\u65f6\uff0cHPVBS(\u6d41\u52a8\u6a21\u5f0f)\u8868\u73b0\u51fa\u4f18\u8d8a\u7684\u901f\u7387\u6027\u80fd100 mA cm\u22122<\/sup>\u81f3500 mA cm\u22122<\/sup>,\u5728100 mA cm\u22122<\/sup>\u65f6\u5177\u6709\u9ad8\u80fd\u6548(81.82%)\uff0c\u5728300 mA cm\u22122<\/sup>\u65f6\u7a33\u5b9a\u5faa\u73af(78.8 Ah L-1<\/sup>)\u8d85\u8fc7450\u6b21\u5faa\u73af\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cHeteropoly acid negolytes for high-power-density aqueous redox flow batteries at low temperatures<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u4e8eNature Energy<\/em><\/strong>\u4e0a\u3002<\/p>\n

03<\/strong>\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n

1\u3001\u00a0 POM\u9633\u79bb\u5b50<\/span><\/strong>\u7684\u5408\u7406\u8bbe\u8ba1\u4e0e\u5408\u6210\uff1b<\/p>\n

2 \u3001\u221220\u00b0C<\/span><\/strong>\uff0cHPOM\u6c27\u5316\u8fd8\u539f\u5177\u6709\u5f02\u5e38\u9ad8\u7684\u6c27\u5316\u8fd8\u539f\u53ef\u9006\u6027\u548c\u53cd\u5e94\u52a8\u529b\u5b66\u3002<\/p>\n

3\u3001HPOM\u5728\u5168\u7535\u6c60\u73af\u5883\u4e0b\u5177\u6709\u8f83\u9ad8\u7684\u7a33\u5b9a\u6027<\/span><\/strong>\u3002<\/p>\n

 <\/p>\n

04<\/strong>\u6570\u636e\u6982\u89c8<\/strong><\/p>\n

\u56fe1<\/strong> MPOM\u7535\u89e3\u8d28\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28 \u00a9 2022 Springer Nature<\/span><\/p>\n

\"\"<\/p>\n

a, \u4e0d\u540c\u9633\u79bb\u5b50POM\u7684\u7d2b\u5916\u53ef\u89c1\u5149\u8c31<\/p>\n

b, \u4e0d\u540c\u9633\u79bb\u5b50POM\u7535\u89e3\u8d28\u5728\u221250\u2103~ 25\u2103\u8303\u56f4\u5185\u7684\u79bb\u5b50\u7535\u5bfc\u7387<\/p>\n

c, \u8d28\u5b50Grotthuss\u673a\u5236\u548c\u6eb6\u5242\u5316\u79bb\u5b50\u4f20\u5bfc\u673a\u5236\u793a\u610f\u56fe<\/p>\n

d, POM\u7535\u89e3\u8d28\u7684\u51dd\u56fa\u70b9\u4e0e\u4e0d\u540c\u9633\u79bb\u5b50\u7684POM\u6d53\u5ea6\u6709\u5173\u3002<\/p>\n

e, \u5149\u8c31\u91c7\u7528\u9ad8\u65af\u51fd\u6570\u62df\u5408<\/p>\n

f, HPOM\u6d53\u5ea6\u7684\u51fd\u6570<\/p>\n

 <\/p>\n

\u56fe2<\/strong> HPOM\u7684\u7535\u5316\u5b66\u6027\u80fd\u00a0\u00a9 2022 Springer Nature<\/span><\/p>\n

\"\"<\/p>\n

\u56fe3<\/strong> HPOM\u7535\u89e3\u6db2\u572825\u2103\u4e0b\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u00a0\u00a9 2022 Springer Nature<\/span><\/p>\n

\"\"<\/p>\n

a, \u5bf9\u79f0\u7535\u6c60\u5faa\u73af\u8bd5\u9a8c<\/p>\n

b-c, \u5bf9\u79f0\u9759\u6001\u7535\u6c60\u5728\u4e0d\u540c\u5468\u671f\u4e0b\u7684\u6052\u6d41\u7535\u538b\u5206\u5e03<\/p>\n

d, 0.05 M HPOM\u6eb6\u6db2\u572825\u00b0C\u4e0b\u7684FTIR\u5149\u8c31<\/p>\n

e, 0.1 M HPOM, 1.5 M VOSO4\u7684HPVB\u9759\u6001\u7535\u6c60\u572840 mA cm\u22122\u4e0b\u7684\u5faa\u73af\u6027\u80fd<\/p>\n

\u56fe4<\/strong> \u4f7f\u75280.5 M HPOM (40 mL min\u22121<\/sup>)\u65f6HPVB\u6d41\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u00a0\u00a9 2022 Springer Nature<\/span><\/p>\n

\"\"<\/p>\n

a-e, 25\u00b0CHPVB\u6d41\u69fd\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n

f-k, \u221220\u2103\u4e0bHPVB\u6d41\u69fd\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n

05\u6210\u679c\u542f\u793a<\/strong><\/p>\n

\u7814\u7a76\u5c55\u793a\u4e86\u4e00\u79cd\u591a\u7535\u5b50\u6742\u591a\u9178\u7535\u89e3\u6db2HPOM\uff0c\u5728\u9ad8\u529f\u7387\u5bc6\u5ea6\u7684\u4f4e\u6e29\u4e0b\u663e\u793a\u4e86\u5f02\u5e38\u9ad8\u7684\u7535\u5b50\u6eb6\u89e3\u5ea6\u3001\u4f4e\u51dd\u56fa\u70b9\u548c\u9ad8\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u7684ARFB\u5e94\u7528\u3002P2<\/sub>W18<\/sub>O62<\/sub>6<\/sup>\u2212<\/sup>\u4e2d\u7684\u8d28\u5b50(H+<\/sup>)\u4e0e\u5176\u4ed6\u9633\u79bb\u5b50(Li+<\/sup>\/Na+<\/sup>\/K+<\/sup>)\u76f8\u6bd4\uff0cHPOM\u9002\u7528\u4e8e\u4f4e\u6e29\u4e0b\u7684\u5927\u529f\u7387\u3001\u9ad8\u80fd\u91cf\u6d41\u7535\u6c60\u3002\u901a\u8fc7\u5faa\u73af\u4f0f\u5b89\u6cd5\u548cRRDE\u7814\u7a76\u4e86HPOM\u7684\u53cd\u5e94\u673a\u7406\u548c\u52a8\u529b\u5b66\uff0c\u8bc1\u5b9e\u572825\u2103\u548c\u221220\u2103\u4e0b\u5177\u6709\u5feb\u901f\u7684\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u548c\u9ad8\u53ef\u9006\u6027\u3002\u572825\u2103\u548c\u221220\u2103\u6761\u4ef6\u4e0b\uff0c\u4e0e\u7a33\u5b9a\u7684VOSO4<\/sub> \u7535\u89e3\u6db2\u5076\u8054\u5f97\u5230\u7684HPVBs\uff0c\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u7a33\u5b9a\u6027\u548c\u4f18\u8d8a\u7684\u901f\u7387\u6027\u80fd\u3002\u8be5\u7814\u7a76\u4e3a\u6781\u7aef\u5bd2\u51b7\u6761\u4ef6\u4e0b\u9ad8\u529f\u7387\u7a33\u5b9a\u7684\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\u63d0\u4f9b\u4e86\u6709\u6548\u7684\u8bbe\u8ba1\u7b56\u7565\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/strong>Heteropoly acid negolytes for high-power-density aqueous redox flow batteries at low temperatures<\/em>\u201d<\/strong>\uff08<\/strong>Nature Energy<\/em>\uff0c<\/strong>2022<\/strong>\uff0c<\/strong>10.1038\/s41560-022-01011-y<\/strong>\uff09<\/strong><\/p>\n

\u6587\u4e2d\u6240\u8ff0\u5982\u6709\u4e0d\u59a5\u4e4b\u5904\uff0c\u6b22\u8fce\u8bc4\u8bba\u533a\u7559\u8a00~<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4ebaJunas\u7f16\u8bd1\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

01\u5bfc\u8bfb \u5728\u4f4e\u6e29\u4e0b\u64cd\u4f5c\u6c34\u7cfb\u6c27\u5316\u8fd8\u539f\u6d41\u7535\u6c60(ARFBs)\u7684\u6548\u679c\u4e0d\u4f73\uff0c\u8fd9\u6e90\u81ea\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7269\u8d28\u7684\u6eb6\u89e3\u5ea6\u6709\u9650\u3001\u7535\u89e3\u8d28\u7684\u51bb\u7ed3\u548c\u53cd\u5e94\u52a8\u529b\u5b66\u7f13\u6162\u3002\u4e00\u79cd\u57fa\u4e8e\u591a\u7535\u5b50\u6742\u591a\u9178\uff08H6P…<\/p>\n","protected":false},"author":35331,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-236611","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/236611"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/35331"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=236611"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/236611\/revisions"}],"predecessor-version":[{"id":237043,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/236611\/revisions\/237043"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=236611"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=236611"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=236611"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}