{"id":235442,"date":"2022-04-05T06:59:59","date_gmt":"2022-04-04T22:59:59","guid":{"rendered":"\/\/m.iemloyee.com\/?p=235442"},"modified":"2022-04-04T19:01:50","modified_gmt":"2022-04-04T11:01:50","slug":"%e5%91%a8%e8%b1%aa%e6%85%8e%e6%9c%80%e6%96%b0nc%ef%bc%9a%e7%a8%b3%e5%ae%9a%e7%9a%84%e5%87%86%e5%9b%ba%e6%80%81%e7%94%b5%e8%a7%a3%e8%b4%a8%e6%8f%90%e9%ab%98%e4%ba%86%e9%ab%98%e6%95%88%e9%94%82%e9%87%91","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=235442","title":{"rendered":"\u5468\u8c6a\u614e\u6700\u65b0NC\uff1a\u7a33\u5b9a\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u63d0\u9ad8\u4e86\u9ad8\u6548\u9502\u91d1\u5c5e\u8f6f\u5305\u7535\u6c60\u5728\u6076\u52a3\u73af\u5883\u4e0b\u7684\u5b89\u5168\u6027\u80fd"},"content":{"rendered":"<p><strong>\u4e00\u3001\u3010<\/strong><strong>\u5bfc\u8bfb<\/strong><strong>\u3011<\/strong><\/p>\n<p>\u7535\u5b50\u8bbe\u5907\u7684\u5feb\u901f\u53d1\u5c55\u5bf9\u9502\u79bb\u5b50\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u5faa\u73af\u5bff\u547d\u63d0\u51fa\u4e86\u5f88\u9ad8\u7684\u8981\u6c42\u3002\u6b64\u524d\u7684\u62a5\u544a\u663e\u793a\uff0c\u8fc7\u53bb\u4e09\u5e74\u5168\u7403LIB\u5e02\u573a\u548cLIB\u51fa\u8d27\u91cf\u5747\u9010\u6e10\u589e\u957f\uff0c\u9884\u8ba1\u672a\u6765\u4e94\u5e74\u5c06\u7a33\u6b65\u6500\u5347\u3002\u5177\u4f53\u6765\u8bf4\uff0c2025\u5e74\u5168\u7403LIB\u5e02\u573a\u548c\u51fa\u8d27\u91cf\u9884\u8ba1\u5c06\u8fbe\u52301089\u4ebf\u7f8e\u5143\u548c439.3 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V<\/strong><strong>\uff09\u548c\u9ad8\u6e29\u4e0d\u53ef\u71c3\u6027\u3002<\/strong>\u672c\u5de5\u4f5c\u5c06\u8fd9\u79cd\u6709\u8da3\u7684\u7535\u89e3\u8d28\u52a0\u5165\u5230\u9502\u91d1\u5c5e\u7535\u6c60(LMB)\u4e2d\uff0c\u53d1\u73b0\u5728\u51c6\u56fa\u4f53\u7535\u89e3\u8d28\u4e2d\u5faa\u73af\u7684 LMB\u8868\u73b0\u51fa\u65e0\u7535\u89e3\u8d28\u754c\u9762\uff08\u65e0CEI\uff09\u7684\u6b63\u6781\u548c\u65e0\u679d\u6676\u7684\u9502\u91d1\u5c5e\u8868\u9762\u3002\u6b64\u5916\uff0c\u7528\u51c6\u56fa\u4f53\u7535\u89e3\u8d28\u7ec4\u88c5\u7684\u9ad8\u7535\u538bLiNi<sub>0.8<\/sub>Co<sub>0.1<\/sub>Mn<sub>0.1<\/sub>O<sub>2<\/sub>\/\/Li\uff08NCM-811\/\/Li\uff0cNCM-811\uff09\u53ef\u63d0\u4f9b\u9ad8\u5ea6\u7a33\u5b9a\u7684\u7535\u5316\u5b66 \u5373\u4f7f\u572890\u00b0C\u7684\u9ad8\u5de5\u4f5c\u6e29\u5ea6\u4e0b\uff0c300\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u9ad8\u8fbe171\u2009mAh\u2009g<sup>-1<\/sup>\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a89%\uff09\u3002\u8fd9\u79cd\u5236\u5907\u4e0d\u6613\u71c3\u4e14\u8d85\u7a33\u5b9a\u7684\u51c6\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u7b56\u7565\u5bf9\u4e8e\u5f00\u53d1\u7528\u4e8e\u5728\u5404\u79cd\u5b9e\u9645\u5de5\u4f5c\u6761\u4ef6\u4e0b\u4e3a\u7535\u5b50\u8bbe\u5907\u4f9b\u7535\u7684\u5b89\u5168\u4e14\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684LIBs\/LMBs\u5f88\u6709\u524d\u666f\u3002\u76f8\u5173\u8bba\u6587\u4ee5\u9898\u4e3a\uff1a\u201c<em>A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments<\/em>\u201d\u53d1\u8868\u5728<em>Nature Communications<\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235443\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/1.png\" 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Limited<\/p>\n<ul>\n<li><strong>\u4e9a\u7eb3\u7c73\u7ea6\u675f\u5236\u5907\u51c6\u56fa\u4f53\u7535\u89e3\u8d28\u53ca\u5176\u7269\u7406\u5316\u5b66\u6027\u80fd<\/strong><\/li>\n<\/ul>\n<p>\u672c\u5de5\u4f5c\u4ee5\u5b54\u9053\u5185\u4fee\u9970PSS\u805a\u5408\u7269(\u805a4 -\u82ef\u4e59\u70ef\u78fa\u9178\u94a0)\u7684CuBTC MOF\u4e3a\u5bbf\u4e3b\u6750\u6599(CuBTC-PSS,6.5 \u03bc\u03b5)\u5236\u5907\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u3002\u9996\u5148\u5229\u7528\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04(XRD)\u6d4b\u91cf\u521d\u6b65\u786e\u5b9a\u4e86MOF\u5b54\u9053\u5185\u6db2\u4f53\u7535\u89e3\u8d28(\u56fe2a, b)\u7684\u5b58\u5728\u3002\u4e00\u4e2a\u91cd\u73b0\u7684(111)\u5cf0\u6e05\u695a\u5730\u8868\u660eMOF\u5b54\u9053\u5185\u90e8\u5b58\u5728\u4e00\u4e2a\u6db2\u6001\u7535\u89e3\u8d28\u7684\u914d\u4f4d\uff0c\u5c3d\u7ba1\u8fd9\u4e2a\u5cf0\u5e76\u6ca1\u6709\u51fa\u73b0\u5728\u6d3b\u5316MOF\u7684\u6a21\u5f0f\u4e2d\uff0c\u6ca1\u6709\u4efb\u4f55\u6c34\u5206\u5b50\u5728\u5176\u5b54\u9053\u5185\u90e8\u88ab\u675f\u7f1a\u6216\u914d\u4f4d\u3002<strong>\u660e\u663e\u51cf\u5c0f\u7684\u5b54\u5f84\u8fdb\u4e00\u6b65\u8868\u660e\u6db2\u4f53\u7535\u89e3\u8d28\u5728<\/strong><strong>MOF<\/strong><strong>\u5b54\u9053\u5185\u88ab\u6210\u529f\u5730\u914d\u4f4d<\/strong><strong>(<\/strong><strong>\u56fe<\/strong><strong>2c)<\/strong>\u3002\u672c\u5de5\u4f5c\u5c06MOF\u53d7\u9650\u7535\u89e3\u8d28\u5b9a\u4e49\u4e3a\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u3002\u70ed\u91cd\u5206\u6790(TGA)\u4e5f\u7528\u4e8e\u8bc4\u4ef7\u6240\u5236\u5907\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7684\u70ed\u7a33\u5b9a\u6027\u3002\u5178\u578b\u6db2\u4f53\u7535\u89e3\u8d28(1 \u2009M LiTFSI-PC)\u7684TG\u66f2\u7ebf\u663e\u793a\u4e86\u4e24\u4e2a\u660e\u663e\u7684\u5931\u91cd\uff1a\u7b2c\u4e00\u4e2a\u5931\u91cd(\u4ee5\u9ec4\u8272\u4e3a\u4e3b)\u59cb\u4e8e\u5927\u7ea6100 \u2103\uff0c\u53ef\u5f52\u56e0\u4e8e\u6db2\u4f53\u6eb6\u5242\u7684\u5206\u89e3\uff1b\u7b2c\u4e8c\u4e2a\u5931\u91cd(\u4ee5\u6d45\u84dd\u8272\u7a81\u51fa)\u662f\u7531\u9502\u76d0\u7684\u5206\u89e3(LiTFSI)\u5f15\u8d77\u7684(\u56fe2d)\u3002\u7136\u800c\uff0c\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7684TG\u66f2\u7ebf\u663e\u793a\u4e86\u4e0d\u540c\u7684\u7ed3\u679c(\u56fe2e,f)\u3002\u867d\u7136\u4ecd\u6e05\u695a\u5730\u89c2\u5bdf\u52302\u6b21\u660e\u663e\u7684\u5931\u91cd\uff0c\u4f46\u7535\u89e3\u8d28\u5f00\u59cb\u5931\u91cd\u7684\u6e29\u5ea6\u8981\u9ad8\u5f97\u591a\uff0c\u7279\u522b\u662f\u6db2\u4f53\u6eb6\u5242\u7684\u5206\u89e3\u6e29\u5ea6\u3002\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u5185\u6db2\u4f53\u6eb6\u5242\u7684\u5206\u89e3\u6e29\u5ea6(\u4ee5\u9ec4\u8272\u7a81\u51fa)\u9047\u5230\u4e86\u6700\u5927\u7684\u53d8\u5316\uff1a\u5728\u8fd1200\u2009\u2103\u5f00\u59cb\u5206\u89e3\uff0c\u6bd4\u5178\u578b\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u5206\u89e3\u6e29\u5ea6\u63d0\u9ad8\u4e86\u8fd1100\u2009\u2103\u3002\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7684\u76d0\u5206\u89e3\u6e29\u5ea6(\u56fe2e\u3001f\u5747\u4ee5\u6d45\u84dd\u8272\u7a81\u51fa)\u4e5f\u7ecf\u5386\u4e86\u660e\u663e\u7684\u5347\u9ad8\uff0c\u5f00\u59cb\u4e8e\u8fd1400\u2103\uff0c\u6bd4\u5178\u578b\u7684\u6db2\u6001\u7535\u89e3\u8d28\u9ad8\u51fa\u8fd150\u2009\u2103\u3002<strong>\u663e\u8457\u63d0\u9ad8\u7684\u5206\u89e3\u6e29\u5ea6\u53ef\u4ee5\u5f52\u56e0\u4e8e\u591a\u5b54\u6781\u6027<\/strong><strong>MOF<\/strong><strong>\u4e3b\u4f53\u7684\u4e9a\u7eb3\u7c73\u914d\u4f4d<\/strong><strong>(<\/strong><strong>\u7a84<\/strong><strong>MOF<\/strong><strong>\u901a\u9053\u7684\u7269\u7406\u9650\u5236\u53ca\u4e0e\u901a\u9053\u5185\u91d1\u5c5e\u4f4d\u7684\u5316\u5b66\u4f5c\u7528<\/strong><strong>)<\/strong><strong>\u5bf9\u5c11\u91cf\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u72ec\u7279\u4f5c\u7528<\/strong>\u3002\u672c\u5de5\u4f5c\u62a5\u9053\u7684\u4e9a\u7eb3\u7c73\u5316\u548c\u914d\u4f4d\u6548\u5e94\u4e0e\u5176\u4ed6\u5de5\u4f5c\u62a5\u9053\u7684\u4e0d\u540c\u3002\u7531\u4e8e\u5927\u591a\u6570\u5176\u4ed6\u7814\u7a76\u62a5\u544a\u4e86\u6c34\u6eb6\u6db2\u4e2d\u7684\u4e9a\u7eb3\u7c73\u5316\u548c\u914d\u4f4d\uff0c\u56e0\u6b64<strong>\u672c\u5de5\u4f5c\u4e2d\u6240\u5c55\u793a\u7684\u4e9a\u7eb3\u7c73\u5316\u548c\u914d\u4f4d\u4e3b\u8981\u96c6\u4e2d\u5728\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\u4e0a<\/strong>\u3002\u6b64\u5916\uff0c\u672c\u5de5\u4f5c\u4e2d\u6240\u62a5\u9053\u7684\u4e9a\u7eb3\u7c73\u5316\u548c\u914d\u4f4d\u6240\u5bfc\u81f4\u7684\u6700\u663e\u8457\u5dee\u5f02\u662f\u805a\u96c6\u7684\u7535\u89e3\u8d28\u6784\u578b\u548c\u5c11\u91cf\u6db2\u4f53\u7535\u89e3\u8d28\u5728\u7a84MOF\u5b54\u9053\u5185\u7684\u5206\u89e3\u6e29\u5ea6\u5f97\u5230\u4e86\u5f88\u5927\u7684\u63d0\u9ad8\u3002<\/p>\n<p>\u672c\u5de5\u4f5c\u8fdb\u4e00\u6b65\u8bc4\u4ef7\u4e86\u6240\u5236\u5907\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u3002\u4e0e\u5178\u578b\u7684\u7a00\u91ca\u6db2\u7535\u89e3\u8d28(1 M LiTFSI-PC)\u76f8\u6bd4\uff0c\u5c11\u91cf\u53d7\u9650\u5728MOF\u5b54\u9053\u5185\u7684\u6db2\u4f53\u7535\u89e3\u8d28\u8868\u73b0\u51fa\u66f4\u5f3a\u7684Li -PC\u76f8\u4e92\u4f5c\u7528\u548c\u66f4\u96c6\u4e2d\u7684TFSI-\uff0c\u663e\u793a\u51fa\u66f4\u805a\u96c6\u7684\u7535\u89e3\u8d28\u6784\u578b\u3002\u7136\u540e\u7528\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u6cd5(LSV)\u8bc4\u4ef7\u4e86\u6240\u5236\u5907\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3\u3002<strong>\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u8868\u73b0\u51fa\u660e\u663e\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u7a97\u53e3\uff0c\u6269\u5c55\u5230<\/strong><strong>5.4 V (<\/strong><strong>\u56fe<\/strong><strong>3c<\/strong><strong>\u4e2d\u7684\u84dd\u8272\u66f2\u7ebf<\/strong><strong>)<\/strong><strong>\uff0c\u660e\u663e\u9ad8\u4e8e\u5178\u578b\u6db2\u6001\u7535\u89e3\u8d28<\/strong><strong>(<\/strong><strong>\u56fe<\/strong><strong>3c<\/strong><strong>\u4e2d\u7684\u7eff\u8272\u66f2\u7ebf<\/strong><strong>)<\/strong>\u3002\u867d\u7136\u5178\u578b\u7684\u6db2\u4f53\u7535\u89e3\u8d28\u5177\u6709\u6700\u9ad8\u7684\u7535\u5bfc\u7387\u548c\u6700\u4f4e\u7684Ea\uff0c\u4f46\u672c\u5de5\u4f5c\u4ecd\u7136\u8ba4\u4e3a\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u662f\u6784\u5efa\u9ad8\u5b89\u5168\u6027LMBs\u6700\u9002\u5b9c\u7684\u7535\u89e3\u8d28\u3002\u5982\u56fe3h\u6240\u793a\uff0c\u7531\u4e8e\u7535\u89e3\u8d28\u7684\u521a\u6027\uff0c\u7535\u6781\u4e0e\u56fa\u6001\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u7269\u7406\u63a5\u89e6\u666e\u904d\u5f88\u5dee\uff0c\u5bfc\u81f4\u7535\u6c60\u7684\u9ad8\u7535\u963b\u548c\u5feb\u901f\u5931\u6548\u3002\u5178\u578b\u7684\u6db2\u4f53\u7535\u89e3\u8d28\u867d\u7136\u5177\u6709\u6700\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u4f46\u6781\u6613\u53d1\u751f\u6325\u53d1\u548c\u5206\u89e3\uff0c\u7279\u522b\u662f\u5728\u8f83\u9ad8\u7684\u5de5\u4f5c\u6e29\u5ea6\u4e0b\uff0c\u8fd9\u4e9b\u73b0\u8c61\u4f1a\u5bfc\u81f4\u7535\u6c60\u5931\u6548\uff0c\u751a\u81f3\u9020\u6210\u5371\u9669\u7684\u5b89\u5168\u9690\u60a3\u3002<strong>\u672c\u5de5\u4f5c\u5236\u5907\u7684\u6709\u524d\u9014\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u4e0d\u4ec5\u80fd\u4f7f\u7535\u6781<\/strong><strong>\/<\/strong><strong>\u7535\u89e3\u6db2\u754c\u9762\u6bd4\u56fa\u6001\u7535\u89e3\u8d28\u6709\u5f88\u5927\u7684\u63d0\u9ad8\uff0c\u800c\u4e14\u6bd4\u5178\u578b\u7684\u6db2\u6001\u7535\u89e3\u8d28\u7a33\u5b9a\u5f97\u591a\uff0c\u5373\u4f7f\u5728\u9ad8\u6e29\u4e0b\u4e5f\u662f\u5982\u6b64<\/strong>\u3002\u56e0\u6b64\uff0c\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u5728\u6784\u5efa\u9ad8\u5b89\u5168\u6027\u7684LMBs\u65b9\u9762\u663e\u793a\u4e86\u826f\u597d\u7684\u524d\u666f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235445\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/3.png\" alt=\"\" width=\"794\" height=\"618\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/3.png 794w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/3-300x234.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/3-768x598.png 768w\" sizes=\"(max-width: 794px) 100vw, 794px\" \/><\/p>\n<p>\u56fe2. MOF\u57fa\u7684\u51c6\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u7269\u7406\u8868\u5f81\u00a9 2022 Springer Nature Limited<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235448\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/4-1.png\" alt=\"\" width=\"831\" height=\"578\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/4-1.png 831w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/4-1-300x209.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/4-1-768x534.png 768w\" sizes=\"(max-width: 831px) 100vw, 831px\" \/><\/p>\n<p>\u56fe3. MOF\u57fa\u51c6\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u00a9 2022 Springer Nature Limited<\/p>\n<ul>\n<li><strong>\u51c6\u56fa\u4f53\u7535\u89e3\u8d28\u4e0e\u6b63\u6781\u548c\u8d1f\u6781\u7684\u76f8\u5bb9\u6027<\/strong><\/li>\n<\/ul>\n<p>\u672c\u5de5\u4f5c\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86\u5236\u5907\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u4e0e\u9ad8\u538b\u6b63\u6781\u548c\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u76f8\u5bb9\u6027\u3002\u9996\u5148\uff0c\u91c7\u7528\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c(SEM)\u7814\u7a76\u4e86\u7531\u5178\u578b\u6db2\u6001\u7535\u89e3\u8d28\u6216\u5236\u5907\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7ec4\u88c5\u7684LiNi<sub>0.8<\/sub>Co<sub>0.1<\/sub>Mn<sub>0.1<\/sub>O<sub>2<\/sub>\/\/Li(NCM-811\/\/Li)\u534a\u7535\u6c60\u6536\u83b7\u7684\u5faa\u73afLiNi<sub>0.8<\/sub>Co<sub>0.1<\/sub>Mn<sub>0.1<\/sub>O<sub>2<\/sub>(NCM-811)\u6b63\u6781\u7684\u5f62\u8c8c\u3002\u5728\u5178\u578b\u7684\u6db2\u4f53\u7535\u89e3\u8d28\u4e2d\u5faa\u73af\u7684NCM-811\u6b63\u6781\u5728\u7ecf\u8fc750\u6b21\u5faa\u73af(\u56fe4a,b)\u540e\uff0c\u5f62\u6210\u4e86\u7c97\u7cd9\u7684\u8868\u9762\uff0c\u88ab\u4e0d\u5747\u5300\u7684CEI\u5c42\u590d\u76d6\u3002\u4e0e\u6b64\u5f62\u6210\u9c9c\u660e\u5bf9\u6bd4\u7684\u662f\uff0c\u5728\u51c6\u56fa\u6001\u7535\u89e3\u6db2\u4e2d\u5faa\u73af\u7684NCM-811\u6b63\u6781\u5448\u73b0\u51fa\u5b8c\u5168\u4e0d\u540c\u7684\u5f62\u8c8c\uff1aNCM-811\u9897\u7c92\u4fdd\u6301\u4e86\u5149\u6ed1\u7684\u8868\u9762\uff0c\u5373\u4f7f\u5faa\u73af300\u5708(\u56fe4e,f)\u4e5f\u51e0\u4e4e\u6ca1\u6709\u89c2\u5bdf\u5230CEI\u5c42\u3002\u7136\u800c\uff0cSEM\u65e0\u6cd5\u63ed\u793a\u590d\u76d6NCM-811\u6b63\u6781\u7684CEI\u5c42\u7684\u539a\u5ea6\u548c\u6210\u5206\u7684\u8be6\u7ec6\u4fe1\u606f\u3002\u4e3a\u4e86\u4ece\u5faa\u73af\u7684NCM-811\u6b63\u6781\u8868\u9762\u83b7\u5f97\u66f4\u7cbe\u786e\u7684\u7ed3\u679c\uff0c\u91c7\u7528\u4e86\u9ad8\u5206\u8fa8\u7387\u7684\u523b\u8680FT-IR\u5149\u8c31(\u56fe4c,g)\u3002\u5bf9\u4e8e\u4f7f\u7528\u5178\u578b\u6db2\u4f53\u7535\u89e3\u8d28(\u56fe4d)\u4ece\u7535\u6c60\u4e2d\u83b7\u5f97\u7684\u5faa\u73afNCM-811\u6b63\u6781\uff0c\u56fe\u8c31\u663e\u793a\u4e86\u8bb8\u591a\u663e\u8457\u7684\u526f\u4ea7\u7269\u76f8\u5173\u5cf0\uff0c\u8fd9\u4e9b\u5cf0\u662f\u7531\u7535\u5316\u5b66\u5faa\u73af\u8fc7\u7a0b\u4e2d\u53d1\u751f\u7684\u526f\u53cd\u5e94\u5f15\u8d77\u7684\u3002<\/p>\n<p>\u672c\u5de5\u4f5c\u8868\u660e\uff0c<strong>\u91c7\u7528\u6240\u5236\u5907\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u5f88\u597d\u5730\u89e3\u51b3\u4e86\u5e38\u89c4\u6db2\u6001\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\u4e0e\u9502\u91d1\u5c5e\u76f8\u5bb9\u6027\u5dee\u7684\u95ee\u9898<\/strong>\u3002\u7531\u4e8e\u6240\u5236\u5907\u7684\u51c6\u56fa\u6001\u7535\u89e3\u6db2\u4e2d\u542b\u6709\u5c11\u91cf\u6db2\u4f53\u7535\u89e3\u6db2\uff0c\u7535\u89e3\u6db2\/\u9502-\u91d1\u5c5e\u95f4\u76f8\u7684\u663e\u8457\u589e\u5f3a\u662f\u7531\u4e8e\u7535\u89e3\u6db2\u72ec\u7279\u7684\u805a\u96c6\u6001\uff0c\u4ece\u800c\u663e\u8457\u964d\u4f4e\u4e86\u7535\u89e3\u6db2\u6eb6\u5242\u4e0e\u6d3b\u6027\u9502-\u91d1\u5c5e\u95f4\u7684\u63a5\u89e6\u673a\u4f1a\u3002<\/p>\n<p>\u8fd9\u4e9b\u7279\u6027\u53ea\u96c6\u4e2d\u5728NCM-811\u6b63\u6781\u8868\u9762\u3002\u4e3a\u8fdb\u4e00\u6b65\u4e86\u89e3\u5236\u5907\u7684MOF\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u6db2\u5728\u9502\u91d1\u5c5e\u7535\u6c60\u4e2d\u7684\u5de5\u4f5c\u673a\u7406\uff0c\u9700\u8981\u8fdb\u4e00\u6b65\u7814\u7a76\u5faa\u73af\u6b63\u6781\u5185\u90e8\u6df1\u5ea6\u7684\u8be6\u7ec6\u4fe1\u606f\u3002\u56e0\u6b64\uff0c\u672c\u6587\u91c7\u7528\u62c9\u66fc\u5149\u8c31\u7814\u7a76\u4e86\u7528\u51c6\u56fa\u6001\u7535\u89e3\u8d28(\u7ecf\u8fc7700\u6b21\u5faa\u73af\u540e)\u4eceNCM-811\/\/Li\u4e2d\u6536\u96c6\u7684\u5faa\u73afNCM-811\u6b63\u6781\u3002\u5982\u56fe5a\u6240\u793a\uff0c\u4e3a\u4e86\u6536\u96c6\u8be6\u7ec6\u548c\u51c6\u786e\u7684\u4fe1\u606f\uff0c\u751a\u81f3\u5728\u5faa\u73afNCM-811\u6b63\u6781\u7684\u6df1\u5904\uff0c\u5229\u7528\u72ec\u7279\u7684\u5265\u79bb\u8bd5\u9a8c\u5265\u79bb\u4e86\u5faa\u73afNCM-811\u6b63\u6781\u7684\u8868\u5c42\uff0c\u4ece\u800c\u5c06\u65b0\u7684NCM-811\u6b63\u6781\u76f8\u66b4\u9732\u5728\u62c9\u66fc\u6fc0\u5149\u5668\u4e2d\u3002<strong>\u6bcf\u6b21\u5265\u843d\u540e\uff0c<\/strong><strong>NCM-811<\/strong><strong>\u6b63\u6781\u5728\u4e0d\u540c\u6df1\u5ea6<\/strong><strong>(<\/strong><strong>\u56fe<\/strong><strong>5b-g)<\/strong><strong>\u89c2\u5bdf\u5230\u65b0\u7684\u4e2d\u95f4\u76f8<\/strong>\u3002\u7136\u540e\uff0c\u8fdb\u4e00\u6b65\u8003\u5bdf\u5404\u6df1\u5ea6\u83b7\u5f97\u7684\u62c9\u66fc\u5149\u8c31\u3002\u5982\u56fe5h\u6240\u793a\uff0c\u5728\u6240\u6709\u6df1\u5ea6\u90fd\u4e0d\u65ad\u68c0\u6d4b\u5230\u4e0e\u6db2\u4f53\u7535\u89e3\u8d28\u6709\u5173\u7684\u4e24\u4e2a\u660e\u663e\u5cf0\u3002\u800c\u4e14\uff0c\u8fd9\u4e24\u4e2a\u5cf0\u7684\u5f62\u72b6\u4e0e\u9650\u5236\u5728\u51c6\u56fa\u6001\u7535\u89e3\u8d28MOF\u5b54\u9053\u5185\u7684\u6db2\u6001\u7535\u89e3\u8d28\u5bf9\u5e94\u7684\u5cf0\u7684\u5f62\u72b6\u51e0\u4e4e\u76f8\u540c\u3002<strong>\u8fd9\u4e00\u7ed3\u679c\u8bf4\u660e\uff0c\u5c3d\u7ba1\u7535\u89e3\u8d28\u76f8\u5173\u5cf0\u7684\u5f3a\u5ea6\u9010\u6e10\u964d\u4f4e\uff0c\u4f46\u6db2\u6001\u7535\u89e3\u8d28\u53ef\u4ee5\u9000\u51fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7684<\/strong><strong>MOF<\/strong><strong>\u901a\u9053\uff0c\u4ece\u800c\u4f7f<\/strong><strong>NCM-811<\/strong><strong>\u6b63\u6781\u6df1\u5165\u5185\u90e8\u6da6\u6e7f<\/strong><strong>(<\/strong><strong>\u56fe<\/strong><strong>5i)<\/strong>\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235449\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/5.png\" alt=\"\" width=\"779\" height=\"527\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/5.png 779w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/5-300x203.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/5-768x520.png 768w\" sizes=\"(max-width: 779px) 100vw, 779px\" \/><\/p>\n<p>\u56fe4. \u4f7f\u7528\u5178\u578b\u7535\u89e3\u8d28\u548c\u57fa\u4e8eMOF\u7684\u51c6\u56fa\u4f53\u7535\u89e3\u8d28\u5bf9\u5faa\u73afNCM-811\u6b63\u6781\u7684\u8868\u5f81\u00a9 2022 Springer Nature Limited<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235450\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/6.png\" alt=\"\" width=\"694\" height=\"528\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/6.png 694w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/6-300x228.png 300w\" sizes=\"(max-width: 694px) 100vw, 694px\" \/><\/p>\n<p>\u56fe5. \u5faa\u73af\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u548c\u5faa\u73af\u540eNCM-811\u6b63\u6781\u5728\u4e0d\u540c\u6df1\u5ea6\u7684\u8868\u5f81\u00a9 2022 Springer Nature Limited<\/p>\n<ul>\n<li><strong>\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u9a71\u52a8\u7684<\/strong><strong>NCM-811\/\/Li<\/strong><strong>\u8f6f\u5305\u7535\u6c60\u5728\u6076\u52a3\u6761\u4ef6\u4e0b\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/li>\n<\/ul>\n<p><strong>\u672c\u5de5\u4f5c\u6240\u5236\u5907\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u5177\u6709\u8f83\u5bbd\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u754c\u9762\u6027\u80fd\uff0c\u663e\u8457\u6291\u5236\u4e86\u7535\u89e3\u8d28\u7684\u5206\u89e3\uff0c\u5e76\u663e\u8457\u6d88\u9664\u4e86\u5faa\u73af\u8fc7\u7a0b\u4e2d\u679d\u6676\u9502\u7684\u751f\u6210<\/strong>\u3002\u66f4\u4e3a\u91cd\u8981\u7684\u662f\uff0c\u5f97\u76ca\u4e8e\u72ec\u7279\u7684\u7535\u89e3\u8d28\u5236\u5907\u7b56\u7565\uff0c\u6240\u5236\u5907\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u8fd8\u8868\u73b0\u51fa\u4e86<strong>\u8f83\u9ad8\u7684\u6cb8\u70b9\u3001\u8f83\u9ad8\u7684\u5206\u89e3\u6e29\u5ea6\u4ee5\u53ca\u5373\u4f7f\u5728\u8f83\u9ad8\u7684\u5de5\u4f5c\u6e29\u5ea6\u4e0b\u4e5f\u6709\u5b89\u5168\u8fd0\u884c\u7684\u6f5c\u529b<\/strong>\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u672c\u5de5\u4f5c\u7684\u731c\u60f3\uff0c\u5206\u522b\u5728\u5ba4\u6e29(25\u2103)\u548c\u9ad8\u6e29(90\u2103)\u4e0b\u6d4b\u8bd5\u4e86\u7528\u6240\u5236\u5907\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7ec4\u88c5\u7684NCM-811\/\/Li\u8f6f\u5305\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u91c7\u7528\u5178\u578b\u7684\u6db2\u4f53\u7535\u89e3\u8d28\u5236\u5907\u4e86NCM-811\/\/Li\u8f6f\u5305\u7535\u6c60\u5e76\u8fdb\u884c\u4e86\u6d4b\u8bd5\u6bd4\u8f83\u3002\u5236\u5907\u4e86\u4e00\u79cd\u57fa\u4e8e\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7684NCM-811\/\/Li\u8f6f\u5305\u7535\u6c60\uff0c\u5982\u56fe6a\u6240\u793a\u3002\u7ec4\u88c5\u6210\u529f\u540e\uff0c\u5ba4\u6e29\u5faa\u73af\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28NCM-811\/\/Li\u8f6f\u5305\u7535\u6c60(\u9ad8NCM-811\u8d28\u91cf\u8d1f\u8f7d\u91cf)\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5faa\u73af\u6027\u80fd(\u56fe6c,\u84dd\u8272\u66f2\u7ebf)\u3002\u5f53\u572890\u2103\u7684\u82db\u523b\u6761\u4ef6\u4e0b\u6d4b\u8bd5\u65f6\uff0c\u4ee4\u4eba\u60ca\u8bb6\u7684\u662f\uff0c\u57fa\u4e8e\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7684NCM-811\/\/Li\u8f6f\u5305\u7535\u6c60\u4ecd\u7136\u5177\u6709\u5f88\u9ad8\u7684\u521d\u59cb\u5bb9\u91cf(191.5 mAh g<sup>-1<\/sup>)\u548c\u8d85\u7a33\u5b9a\u5faa\u73af\u7a33\u5b9a\u6027(300\u6b21\u5faa\u73af\uff0c\u5bb9\u91cf\u4fdd\u6301\u5728171.2 mAh g<sup>-1<\/sup>\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u63a5\u8fd190%)\u3002\u636e\u672c\u5de5\u4f5c\u6240\u77e5\uff0c<strong>\u8fd9\u4e2a\u7ed3\u679c\u662f\u76ee\u524d\u4e3a\u6b62\u5728\u5982\u6b64\u9ad8\u7684\u5de5\u4f5c\u6e29\u5ea6\u4e0b\u83b7\u5f97\u7684\u6700\u4f73\u7684\u8f6f\u5305\u7535\u6c60\u6027\u80fd<\/strong>\u3002\u7136\u800c\uff0c\u7528\u5178\u578b\u7684\u6db2\u4f53\u7535\u89e3\u8d28\u7ec4\u88c5\u7684NCM-811\/\/Li\u8f6f\u5305\u7535\u6c60\u65e0\u8bba\u5728\u5e38\u6e29(\u56fe6d;\u56fe 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loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235452\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/7.png\" alt=\"\" width=\"701\" height=\"563\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/7.png 701w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/04\/7-300x241.png 300w\" sizes=\"(max-width: 701px) 100vw, 701px\" \/><\/p>\n<p>\u56fe6. 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