{"id":235178,"date":"2022-04-02T06:10:45","date_gmt":"2022-04-01T22:10:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=235178"},"modified":"2022-04-02T11:33:26","modified_gmt":"2022-04-02T03:33:26","slug":"%e7%9c%8bcofs%e9%a2%86%e5%9f%9fomar-m-yaghi%e3%80%81%e5%86%af%e6%96%b0%e4%ba%ae%e3%80%81%e7%8e%8b%e5%8d%9a%e3%80%81%e9%99%88%e9%be%99%e3%80%81%e8%b5%b5%e4%b8%b9%e7%ad%89%e5%a4%a7%e7%89%9b%e6%98%af","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=235178","title":{"rendered":"\u770bCOFs\u9886\u57dfOmar M. Yaghi\u3001\u51af\u65b0\u4eae\u3001\u738b\u535a\u3001\u9648\u9f99\u3001\u8d75\u4e39\u7b49\u5927\u725b\u662f\u5982\u4f55\u73a9\u8f6c\u5404\u5927\u9876\u520a"},"content":{"rendered":"<p><span style=\"color: #003366;\"><strong>\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)<\/strong><\/span>\u662f\u4e00\u79cd\u4e8c\u7ef4(2D)\u6216\u4e09\u7ef4(3D)\u7ed3\u6676\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\uff0c\u901a\u8fc7\u5171\u4ef7\u952e\u8fde\u63a5\u7ed3\u6784\u5355\u5143\u800c\u6784\u5efa\u3002\u4e0e\u975e\u6676\u6001\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\u4e0d\u540c\u7684\u662fCOFs\u5177\u6709\u7ed3\u6784\u53ef\u8bbe\u8ba1\u3001\u529f\u80fd\u53ef\u5b9a\u5236\u3001\u5468\u671f\u6709\u5e8f\u57df\u3001\u6676\u4f53\u7ed3\u6784\u53ef\u8c03\u3001\u5bc6\u5ea6\u4f4e\u3001\u70ed\u7a33\u5b9a\u6027\u597d\u3001\u6bd4\u8868\u9762\u79ef\u9ad8\u3001\u6c38\u4e45\u5b54\u9699\u7b49\u4f18\u70b9\u3002\u7279\u522b\u662f\u6676\u4f53\u4e2d\u6709\u5e8f\u7ed3\u6784\u5177\u6709\u826f\u597d\u7684\u5171\u8f6d\u957f\u5ea6\uff0c\u6709\u5229\u4e8e\u03c0\u7cfb\u7684\u6392\u5217\u548c\u7535\u8377\u8f93\u8fd0\u3002\u5b83\u8fd8\u8d4b\u4e88COFs\u6750\u6599\u66f4\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u66f4\u9ad8\u7684\u5b54\u9699\u7387\u548c\u66f4\u591a\u7684\u5916\u9732\u6d3b\u6027\u4f4d\u70b9\uff0c\u800c\u975e\u6676\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\u5f80\u5f80\u5177\u6709\u76f8\u5bf9\u8f83\u77ed\u7684\u5171\u8f6d\u957f\u5ea6\u548c\u8f83\u4f4e\u7684\u8868\u9762\u79ef\u3002\u672c\u6587\u68b3\u7406\u4e86\u6700\u8fd1\u53d1\u8868\u5728\u9876\u7ea7\u671f\u520a\u4e0a\u7684COFs\u6587\u7ae0\uff0c\u8ba9\u6211\u4eec\u4e00\u8d77\u6df1\u5165\u4e86\u89e3\u8be5\u6750\u6599\u662f\u5982\u4f55\u6210\u4e3a\u6750\u6599\u9886\u57df\u7684\u4f7c\u4f7c\u8005\u3002<\/p>\n<p>1\u3001<strong><em>J. Am. Chem. Soc<\/em><\/strong>\uff1a\u5171\u4ef7\u6709\u673a\u6846\u67b6\u4e2d\u65b9\u5f62\u7f51\u7684\u7ea0\u7f20<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235180\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-2-26.png\" alt=\"\" width=\"499\" height=\"497\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-2-26.png 499w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-2-26-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-2-26-300x300.png 300w\" sizes=\"(max-width: 499px) 100vw, 499px\" \/><\/p>\n<p>\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u662f\u901a\u8fc7\u5f3a\u5171\u4ef7\u952e\u8fde\u63a5\u6709\u673a\u5efa\u7b51\u5355\u5143\u800c\u5f62\u6210\u7684\u4e00\u7c7b\u6269\u5c55\u7ed3\u6784\u3002\u4e8c\u7ef4COFs\u901a\u5e38\u662f\u7531\u03c0\u2212\u03c0\u5806\u79ef\u4fc3\u6210\u7684\u5e73\u9762\u8fde\u63a5\u5355\u5143\u7ec4\u5408\u800c\u6210\u3002\u8fd1\u65e5\uff0c<strong><b>\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u7684<\/b><\/strong><strong><b>Omar M. Yaghi<\/b><\/strong><strong><b>\u6559\u6388\u4ee5<\/b><\/strong>\uff084,4,4,4-\uff089,9-\u87ba\u73af\u57fa-[\u82b4]-2,2,7,7-\u56db\u9170\u57fa\uff09-\u56db\u82ef\u7532\u919b\uff08SFTB\uff09\u548c\u5bf9\u82ef\u4e8c\u80fa\uff08PPA\uff09\u4e0e\u8054\u82ef\u80fa\uff08BZD\uff09\u4e3a\u6784\u7b51\u5355\u5143\uff0c\u5408\u6210\u4e86\u4e24\u79cd\u7f20\u7ed3\u7684\u4e8c\u7ef4\u65b9\u5f62\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COFs\uff09\uff0c\u5373COF-38\u548cCOF-39\u3002\u8be5\u56e2\u961f\u8fd8\u62a5\u9053\u4e86COF-39\u7684\u5355\u6676\u7535\u5b50\u884d\u5c04\u7ed3\u6784\uff0c\u53d1\u73b0\u5b83\u7531\u76f8\u4e92\u7ea0\u7f20\u7684\u4e8c\u7ef4\u65b9\u5f62\u7f51\u7ec4\u6210\u3002\u8fd9\u4e9bCOF\u4ee3\u8868\u4e86\u7ea0\u7f202D COF\u7ed3\u6784\u7684\u7b2c\u4e00\u4e2a\u4f8b\u5b50\uff0c\u6b63\u5982\u4f5c\u8005\u6240\u8bf4\u660e\u7684\uff0c\u8fd9\u662f\u901a\u8fc7\u4f7f\u7528\u626d\u66f2\u56db\u9762\u4f53SFTB\u6784\u7b51\u5355\u5143\u7684\u7b56\u7565\u5b9e\u73b0\u7684\u3002SFTB\u514b\u670d\u4e86\u4e8c\u7ef4COFs\u901a\u8fc7\u03c0\u2212\u03c0\u5806\u79ef\u7684\u503e\u5411\uff0c\u5e76\u5141\u8bb8\u5f62\u6210\u7ea0\u7f20\u3002\u8fd9\u9879\u5de5\u4f5c\u5bf9COFs\u7684\u8bbe\u8ba1\u539f\u5219\u6709\u91cd\u8981\u7684\u8865\u5145\u4f5c\u7528\u3002\u8be5\u6210\u679c\u4ee5\u201c<strong>Entanglement of Square Nets in Covalent Organic Frameworks<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>J. Am. Chem. Soc<\/strong><strong>\u671f\u520a<\/strong>\u4e0a\u3002<strong>D<\/strong><strong>OI: 10.1021\/jacs.1c13468<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><strong>https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.1c13468.<\/strong><\/p>\n<p>2\u3001<strong><em>J. Am. Chem. Soc<\/em><\/strong>\uff1a\u5177\u6709\u521b\u7eaa\u5f55\u5b54\u5f84\u7684\u5171\u4ef7\u6709\u673a\u9aa8\u67b6<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235183\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-10-5.png\" alt=\"\" width=\"505\" height=\"279\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-10-5.png 505w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-10-5-300x166.png 300w\" sizes=\"(max-width: 505px) 100vw, 505px\" \/><\/p>\n<p>\u5b54\u9699\u5b54\u5f84\u51b3\u5b9a\u5b54\u9699\u7684\u53ef\u8fbe\u6027\uff0c\u8d4b\u4e88\u591a\u5b54\u6750\u6599\u4e0d\u540c\u7684\u529f\u80fd\u3002\u4eba\u4eec\u8feb\u5207\u5e0c\u671b\u6784\u5efa\u5177\u6709\u53ef\u9884\u5148\u8bbe\u8ba1\u548c\u5747\u5300\u4ecb\u5b54\u7684\u7ed3\u6676\u591a\u5b54\u805a\u5408\u7269\uff0c\u4f7f\u5927\u578b\u6709\u673a\u3001\u65e0\u673a\u548c\u751f\u7269\u5206\u5b50\u80fd\u591f\u8fdb\u5165\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5bb9\u6613\u5f62\u6210\u76f8\u4e92\u6e17\u900f\u548c\/\u6216\u8106\u5f31\u7684\u7ed3\u6784\uff0c\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u62a5\u9053\u7684\u6700\u5927\u5b54\u5f84\u4e3a8.5 nm\uff0c\u800c\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u7684\u503c\u4ec5\u4e3a5.8 nm\u3002\u5728\u6b64\uff0c<strong><b>\u5317\u4eac\u7406\u5de5\u5927\u5b66\u51af\u5bb5\u7814\u7a76\u5458\u548c\u738b\u535a\u6559\u6388<\/b><\/strong>\u901a\u8fc7\u8bbe\u8ba1\u5177\u6709\u8f83\u5927\u6784\u8c61\u521a\u5ea6\u3001\u5e73\u9762\u5ea6\u548c\u5408\u9002\u7684\u5c40\u90e8\u6781\u6027\u7684\u914d\u4f53\uff0c\u6784\u5efa\u4e86\u4e00\u7cfb\u5217\u521b\u8bb0\u5f55\u7684\u5b54\u5f847.7 ~ 10.0 nm\u7684COFs\u3002\u6240\u5f97\u78b3\u7ea4\u7ef4\u5747\u5177\u6709\u91cd\u53e0\u5806\u579b\u7ed3\u6784\uff0c\u7ed3\u6676\u5ea6\u9ad8\uff0c\u6c38\u4e45\u5b54\u9699\u7387\u9ad8\uff0c\u7a33\u5b9a\u6027\u597d\u3002\u4f5c\u4e3a\u4e00\u4e2a\u6982\u5ff5\u7684\u8bc1\u660e\uff0c\u8be5\u56e2\u961f\u6210\u529f\u5730\u5229\u7528\u8fd9\u4e9bCOFs\u4ece\u5176\u539f\u6599\u4e2d\u5206\u79bb\u51fa\u7ea67 nm\u5927\u5c0f\u7684\u80c3\u86cb\u767d\u9176\uff0c\u5e76\u4fdd\u62a4\u916a\u6c28\u9178\u9176\u514d\u53d7\u70ed\u8bf1\u5bfc\u7684\u5931\u6d3b\u3002\u8be5\u6210\u679c\u4ee5\u201c<strong>Covalent Organic Frameworks with Record Pore Apertures<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>J. Am. Chem. Soc<\/strong><strong>\u671f\u520a<\/strong>\u4e0a\u3002<strong>D<\/strong><strong>OI: 10.1021\/jacs.2c00584<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><strong>https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.2c00584.<\/strong><\/p>\n<p>3\u3001<strong><em>J. Am. Chem. Soc<\/em><\/strong>\uff1a\u626d\u66f2\u82b3\u9999\u5316\u5408\u7269\u7684\u975e\u5e73\u9762\u83f1\u5f62\u548c<em><i>Kagome<\/i><\/em>\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u5728\u7535\u5b50\u4f20\u5bfc\u4e2d\u7684\u5e94\u7528<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235187\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-15-4.png\" alt=\"\" width=\"502\" height=\"499\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-15-4.png 502w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-15-4-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-15-4-300x298.png 300w\" sizes=\"(max-width: 502px) 100vw, 502px\" \/><\/p>\n<p>\u4e8c\u7ef4(2D)\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u662f\u4e00\u7c7b\u5177\u6709\u9ad8\u7ed3\u6676\u5ea6\u548c\u7ed3\u6784\u53ef\u8c03\u7684\u65b0\u5174\u4e8c\u7ef4\u6750\u6599\u3002\u4f46\u5176\u4f4e\u5bfc\u7535\u6027\u963b\u788d\u4e86\u5176\u5728\u7535\u5b50\u548c\u5149\u7535\u5b50\u9886\u57df\u7684\u5e94\u7528\u3002<strong><b>\u5409\u6797\u5927\u5b66\u9648\u9f99\u6559\u6388\u8bfe\u9898\u7ec4<\/b><\/strong>\u5c06\u5927<em><i>\u03c0<\/i><\/em>-\u5171\u8f6d\u914d\u4f53\u96c6\u6210\u5230\u4e8c\u7ef4\u6676\u683c\u4e2d\uff0c\u589e\u5f3a\u9ad8\u6548<em><i>\u03c0<\/i><\/em>-\u53e0\u52a0\u548c\u5316\u5b66\u63ba\u6742\u662f\u63d0\u9ad8\u4e8c\u7ef4COFs\u7535\u5bfc\u7387\u7684\u6709\u6548\u9014\u5f84\u3002\u4ee5\u5177\u6709\u4e0d\u540c<em><i>\u03c0<\/i><\/em>-\u5171\u8f6d\u7ed3\u6784(\u67d4\u6027\u7ed3\u6784\u548c\u521a\u6027\u7ed3\u6784)\u7684\u626d\u66f2\u82b3\u70c3\u4e3a\u539f\u6599\uff0c\u8bbe\u8ba1\u5408\u6210\u4e86\u4e24\u79cd\u975e\u5e73\u9762\u4e8c\u7ef4kagome (DHP-COF)\u548c\u83f1\u5f62(c-HBC-COF)\u6676\u683c\u3002DHP-COF\u663e\u793a\u4e86\u4e00\u4e2a\u9ad8\u5ea6\u626d\u66f2\u7684\u4e8c\u7ef4\u6676\u683c\uff0c\u963b\u788d\u4e86\u5806\u79ef\uff0c\u4ece\u800c\u9650\u5236\u4e86\u5176\u8f7d\u6d41\u5b50\u4f20\u8f93\u7279\u6027\u3002\u4e0e\u4e4b\u76f8\u53cd\uff0cc-HBC-COF\u5728\u5177\u6709\u51f9\u51f8\u81ea\u4e92\u8865\u8282\u70b9\u7684\u60c5\u51b5\u4e0b\uff0c\u8868\u73b0\u51fa\u8f83\u4f4e\u7684\u7578\u53d8\u4e8c\u7ef4\u70b9\u9635\uff0c\u4e14\u4e0d\u5f71\u54cd\u5c42\u95f4<em><i>\u03c0<\/i><\/em>-\u53e0\u52a0\u3002\u5229\u7528\u65f6\u95f4\u548c\u9891\u7387\u5206\u8fa8\u7684\u592a\u8d6b\u5179\u5149\u8c31\uff0c\u4f5c\u8005\u63ed\u793a\u4e86\u9ad8\u8fbe44 cm<sup>2<\/sup>\u00a0V<sup>-1<\/sup>\u00a0s<sup>-1<\/sup>\u7684\u9ad8\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\uff0c\u8fd9\u662f\u76ee\u524d\u62a5\u9053\u76842D COFs\u4e2d\u6700\u9ad8\u7684\u3002\u8be5\u6210\u679c\u4ee5\u201c<strong>Nonplanar Rhombus and Kagome 2D Covalent Organic Frameworks from Distorted Aromatics for Electrical Conduction<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>J. Am. Chem. Soc<\/strong><strong>\u671f\u520a<\/strong>\u4e0a\u3002<strong>D<\/strong><strong>OI: 10.1021\/jacs.1c13534<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><strong>https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.1c13534.<\/strong><\/p>\n<p>4\u3001<strong><em>Angew. Chem. Int. Ed<\/em><\/strong>\uff1a\u901a\u8fc7\u8c03\u8282\u5171\u4ef7\u6709\u673a\u6846\u67b6\u9650\u5b9a\u901a\u9053\u4e2d\u7684\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u63d0\u9ad8\u9176\u6d3b\u6027<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235184\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-11-10.png\" alt=\"\" width=\"499\" height=\"365\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-11-10.png 499w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-11-10-300x219.png 300w\" sizes=\"(max-width: 499px) 100vw, 499px\" \/><\/p>\n<p>\u5bf9\u9176\u7684\u6784\u8c61\u8fdb\u884c\u8c03\u63a7\u4ee5\u4f18\u5316\u5176\u50ac\u5316\u6027\u80fd\u662f\u56fa\u5b9a\u5316\u751f\u7269\u50ac\u5316\u5242\u4e9f\u5f85\u89e3\u51b3\u7684\u95ee\u9898\u3002\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u5177\u6709\u72ed\u7a84\u7684\u901a\u9053\u548c\u53ef\u8c03\u7684\u5b54\u9699\u73af\u5883\uff0c\u4e3a\u9176\u7684\u5c01\u88c5\u63d0\u4f9b\u4e86\u4e00\u4e2a\u6709\u524d\u9014\u7684\u5e73\u53f0\u3002\u56e0\u6b64\uff0c<strong><b>\u5317\u4eac\u7406\u5de5\u5927\u5b66\u738b\u535a\u6559\u6388\u548c\u5f20\u5a9b\u5a9b\u52a9\u7406\u6559\u6388<\/b><\/strong>\u5c06\u7ec6\u80de\u8272\u7d20c (Cyt c)\u5171\u4ef7\u56fa\u5b9a\u5728\u5927\u5c0f\u5339\u914d\u7684COFs\u901a\u9053\u4e2d\uff0c\u901a\u8fc7\u4f18\u5316\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u53ef\u663e\u8457\u63d0\u9ad8\u5176\u7a33\u5b9a\u6027\u548c\u6d3b\u6027(\u76f8\u5bf9\u4e8e\u6e38\u79bb\u9176\u6d3b\u6027\u7ea6600%)\u3002\u5bf9\u56fa\u5b9a\u5316Cyt c\u7684\u7ed3\u6784\u5206\u6790\u8868\u660e\uff0c\u5171\u4ef7\u952e\u53ef\u4ee5\u8bf1\u5bfc\u6784\u8c61\u6270\u52a8\uff0c\u4ece\u800c\u4ea7\u751f\u66f4\u591a\u7684\u6d3b\u6027\u4f4d\u70b9\u3002\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u8c03\u5236\u7684\u6709\u6548\u6027\u4ee5\u53caCOFs\u7684\u53ef\u5b9a\u5236\u53d7\u9650\u901a\u9053\u4e3a\u5f00\u53d1\u9ad8\u6027\u80fd\u751f\u7269\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u5e0c\u671b\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Enhancing Enzyme Activity by the Modulation of Covalent Interactions in the Confined Channels of Covalent Organic Frameworks<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>Angew. Chem. Int. Ed.<\/strong>\u4e0a\u3002<strong>D<\/strong><strong>OI:<\/strong>\u00a0<strong>10.1002\/anie.202201378<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><strong>https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.202201378.<\/strong><\/p>\n<p>5\u3001<strong><em>Angew. Chem. Int. Ed<\/em><\/strong>\uff1aKnoevenagel\u7f29\u805a\u548c\u6c34\u8f85\u52a9\u52a8\u6001Michael\u52a0\u6210-\u6d88\u9664\u6cd5\u5408\u6210\u4e59\u70ef\u57fa\u8fde\u63a5\u76842D\u5171\u4ef7\u6709\u673a\u6846\u67b6<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235181\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-3-24.png\" alt=\"\" width=\"751\" height=\"476\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-3-24.png 751w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-3-24-300x190.png 300w\" sizes=\"(max-width: 751px) 100vw, 751px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\u4e59\u70ef\u8fde\u63a5\u7684\u4e8c\u7ef4\u5171\u8f6d\u5171\u4ef7\u6709\u673a\u9aa8\u67b6(V-2D-COFs)\u662f\u4e00\u7c7b\u5177\u6709\u8f83\u9ad8\u5316\u5b66\u7a33\u5b9a\u6027\u7684\u4e8c\u7ef4\u5171\u8f6d\u805a\u5408\u7269\uff0c\u7531\u4e8e\u5176\u5728\u4e8c\u7ef4\u4e3b\u9aa8\u67b6\u4e0a\u7684\u5ef6\u4f38\u03c0\u5171\u8f6d\u800c\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002Knoevenagel\u7f29\u805a\u5df2\u88ab\u8bc1\u660e\u662f\u4e00\u79cd\u53ef\u9760\u7684\u5408\u6210\u65b9\u6cd5\uff0c\u53ef\u63d0\u4f9b\u5177\u6709\u72ec\u7279\u5149\u7535\u3001\u78c1\u6027\u548c\u6c27\u5316\u8fd8\u539f\u7279\u6027\u7684\u6c30\u57fa(CN)\u53d6\u4ee3V-2D-COFs\u3002\u867d\u7136\u5408\u6210\u6210\u529f\uff0c\u4f46\u5176\u805a\u5408\u673a\u7406\u5c1a\u4e0d\u660e\u786e\uff0c\u7ed3\u6676\u5ea6\u8f83\u4f4e\uff0c\u91cd\u73b0\u6027\u8f83\u5dee\u3002\u8fd1\u65e5\uff0c<strong><b>\u5fb7\u56fd\u5fb7\u7d2f\u65af\u987f\u5de5\u4e1a\u5927\u5b66\u51af\u65b0\u4eae\u8bfe\u9898\u7ec4<\/b><\/strong>\u5c55\u793a\u4e86\u901a\u8fc7Knoevenagel\u7f29\u805a\u548c\u6c34\u8f85\u52a9\u52a8\u6001Michael\u52a0\u6210-\u6d88\u9664\uff08\u7b80\u79f0KMAE\u805a\u5408\uff09\u6765\u5408\u6210CN\u53d6\u4ee3\u7684V-2D-COFs\u7684\u65b0\u65b9\u6cd5\u3002\u4f5c\u8005\u901a\u8fc7\u6a21\u578b\u53cd\u5e94\u7684\u539f\u4f4d\u9ad8\u6e29\u6838\u78c1\u5171\u632f\u8c31\u7814\u7a76\uff0c\u9996\u6b21\u8bc1\u5b9e\u4e86\u4e24\u4e2a\u4e8c\u82ef\u4e19\u70ef\u8148(M1\u548cM6)\u4e4b\u95f4\u5b58\u5728C=C\u952e\u4ea4\u6362\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u901a\u8fc7Michael\u52a0\u6210\u5408\u6210\u7684\u4e2d\u95f4\u4ea7\u7269M4\u53ef\u4ee5\u8fdb\u884c\u5b9a\u91cf\u7684Michael-\u6d88\u9664\uff0c\u5bfc\u81f4\u4e86\u6709\u6548\u7684C=C\u952e\u4ea4\u6362\uff0c\u660e\u786e\u5730\u8bc1\u5b9e\u4e86Michael\u52a0\u6210-\u6d88\u9664\u7684\u52a8\u529b\u5b66\u6027\u8d28\u3002\u6b64\u5916\uff0c\u6c34\u7684\u52a0\u5165\u57285min\u5185\u53ef\u663e\u8457\u4fc3\u8fdbMichael\u52a0\u6210-\u6d88\u9664\u53cd\u5e94\u901f\u5ea6\uff0c\u5b9e\u73b0\u9ad8\u6548\u7684C=C\u952e\u4ea4\u6362\u3002\u901a\u8fc7V-2D-COF-TFPB-PDAN\u3001V-2D-COF-TFPB-PDAN\u3001V-2D-COF-TFPB-BDAN\u548cV-2D-COF-HATN-BDAN\u56db\u4e2a\u4f8b\u5b50\uff0c\u53ef\u4ee5\u770b\u51faKMAE\u805a\u5408\u4e3aCN\u53d6\u4ee3\u7684\u9ad8\u7ed3\u6676\u5ea6V-2D-COFs\u7684\u5408\u6210\u63d0\u4f9b\u4e86\u4e00\u79cd\u9ad8\u6548\u7684\u7b56\u7565\u3002\u57fa\u4e8e\u6a21\u62df\u548c\u5b9e\u9a8c\u7684\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04(PXRD)\u6a21\u5f0f\u548cN<sub>2<\/sub>\u5438\u9644-\u8131\u9644\u6d4b\u91cf\u3002\u6b64\u5916\uff0c\u9ad8\u5206\u8fa8\u7387\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c(HR-TEM)\u5206\u6790\u8868\u660e\uff0c\u65b0\u5408\u6210\u7684V-2D-COFs\u7684\u6676\u57df\u5927\u5c0f\u4e3a20~100 nm\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Combination of Knoevenagel Polycondensation and Water-Assisted Dynamic Michael-Addition-Elimination for the Synthesis<\/strong><strong>\u00a0<\/strong><strong>of Vinylene-Linked 2D Covalent Organic Frameworks<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>Angew. Chem. Int. Ed.<\/strong>\u4e0a\u3002<strong>D<\/strong><strong>OI:<\/strong>\u00a0<strong>10.1002\/anie.202202492<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><strong>https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202202492.<\/strong><\/p>\n<p>6\u3001<strong><em>Nat. Commun<\/em><\/strong>\uff1a\u901a\u8fc7\u4e2d\u95f4\u8ffd\u8e2a\u7814\u7a76\u5b9e\u73b0\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u6846\u67b6\u5355\u6676\u7684\u751f\u957f<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235182\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-4-26.png\" alt=\"\" width=\"749\" height=\"543\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-4-26.png 749w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-4-26-300x217.png 300w\" sizes=\"(max-width: 749px) 100vw, 749px\" \/><\/p>\n<p>\u89e3\u6790\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u6846\u67b6(2D COFs)\u7684\u5355\u6676\u7ed3\u6784\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\uff0c\u8fd9\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u53d7\u5230\u4e86\u751f\u4ea7\u9ad8\u8d28\u91cf\u6676\u4f53\u7684\u6709\u9650\u7b56\u7565\u7684\u963b\u788d\u3002\u66f4\u597d\u5730\u7406\u89e3\u751f\u957f\u673a\u7406\u6709\u52a9\u4e8e\u5f00\u53d1\u9ad8\u8d28\u91cf\u4e8c\u7ef4COF\u5355\u6676\u7684\u751f\u957f\u65b9\u6cd5\u3002\u5728\u8fd9\u91cc\uff0c<strong><b>\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u8d75\u4e39\u6559\u6388\u56e2\u961f<\/b><\/strong>\u91c7\u7528\u4e0d\u540c\u7684\u89c6\u89d2\uff0c\u901a\u8fc7\u8ffd\u8e2a\u751f\u957f\u4e2d\u95f4\u4f53\u6765\u63a2\u7d222D COF\u7684\u751f\u957f\u8fc7\u7a0b\u3002\u4f5c\u8005\u53d1\u73b0\u4e86\u4e24\u79cd\u4e0d\u540c\u7684\u751f\u957f\u673a\u5236\uff0c\u5373\u6210\u6838\u548c\u81ea\u6108\u5408\uff0c\u5176\u4e2d\u5355\u4f53\u548c\u5be1\u805a\u7269\u7684\u81ea\u7ec4\u88c5\u548c\u9884\u6392\u5217\u662f\u83b7\u5f97\u9ad8\u7ed3\u66762D COFs\u7684\u91cd\u8981\u56e0\u7d20\u3002\u8fd9\u4e9b\u53d1\u73b0\u4f7f\u4ed6\u4eec\u80fd\u591f\u751f\u957f\u51fa\u5fae\u7c73\u5927\u5c0f\u7684\u4e8c\u7ef4\u5355\u6676COF Py-1P\u3002\u901a\u8fc7\u4e09\u7ef4\u7535\u5b50\u884d\u5c04(3DED)\u6210\u529f\u5730\u8868\u5f81\u4e86Py-1P\u7684\u6676\u4f53\u7ed3\u6784\uff0c\u8bc1\u5b9e\u4e86Py-1P\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u91c7\u7528\u4e86\u5e7f\u6cdb\u9884\u6d4b\u7684AA\u5806\u79ef\u7ed3\u6784\u3002\u6b64\u5916\uff0c\u8be5\u56e2\u961f\u8fd8\u53d1\u73b0\u5927\u90e8\u5206Py-1P\u6676\u4f53(&gt;90%)\u5177\u6709\u672a\u77e5\u7684\u7ed3\u6784\uff0c\u5728\u4e00\u4e2a\u5355\u5143\u80de\u5185\u5305\u542b6\u5c42\u5806\u53e0\u5c42\u3002\u8be5\u6210\u679c\u4ee5\u201c<strong>Growing single crystals of two-dimensional covalent organic frameworks enabled by intermediate tracing study<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>Nat. Commun<\/strong>\u4e0a\u3002<strong>D<\/strong><strong>OI<\/strong><strong>\uff1a<\/strong><strong>10.1038\/s41467-022-29086-x<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><strong>https:\/\/www.nature.com\/articles\/s41467-022-29086-x?utm_source=xmol&amp;utm_medium=affiliate&amp;utm_content=meta&amp;utm_campaign=DDCN_1_GL01_metadata.<\/strong><\/p>\n<p>7\u3001<strong><em>ACS Catal<\/em><\/strong>\uff1a\u754c\u9762\u7535\u5b50\u6548\u5e94\u4ecb\u5bfc\u7684\u5149\u7535\u5b50\u8f6c\u79fb\u4fc3\u8fdb\u53ef\u89c1\u5149\u9a71\u52a8\u7684CO<sub>2<\/sub>\u51cf\u6392<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235179\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-1-33.png\" alt=\"\" width=\"398\" height=\"270\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-1-33.png 398w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-1-33-300x204.png 300w\" sizes=\"(max-width: 398px) 100vw, 398px\" \/><\/p>\n<p>\u4e9a\u80fa\u952e\u8fde\u63a5\u7684\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u662f\u5149\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u7684\u70ed\u95e8\u5019\u9009\u6750\u6599\uff0c\u4f46\u7531\u4e8e\u4e9a\u80fa\u952e\u7684\u9ad8\u6781\u5316\u7387\uff0c\u5bfc\u81f4\u5176\u8fde\u63a5\u7684\u7ed3\u6784\u5355\u5143\u4e4b\u95f4\u03c0\u7535\u5b50\u79bb\u57df\u7684\u6548\u7387\u8f83\u4f4e\uff0c\u5bfc\u81f4\u5206\u5b50\u5185\u7535\u5b50\u8f6c\u79fb\u4f4e\uff0c\u5149\u50ac\u5316\u6548\u7387\u8f83\u5dee\u3002\u8fd1\u65e5\uff0c<strong><b>\u798f\u5efa\u7269\u8d28\u7ed3\u6784\u7814\u7a76\u6240\u738b\u745e\u864e\u7814\u7a76\u5458\u56e2\u961f<\/b><\/strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u7ed3\u6784\u548c\u7535\u5b50\u5de5\u7a0b\u7b56\u7565\uff0c\u5c06\u7531Zn -\u535f\u5549\u548cCo -\u8054\u5421\u5576\u57fa\u5355\u5143\u7ec4\u6210\u7684\u4e9a\u80fa\u8fde\u63a5\u7684COF\u4e0e\u786b\u5316\u9549(CdS)\u7eb3\u7c73\u7ebf\u96c6\u6210\uff0c\u5f62\u6210CdS@COF\u6838-\u58f3\u7ed3\u6784\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u7ed3\u679c\u9a8c\u8bc1\u4e86CdS\u4f5c\u4e3a\u7535\u5b50\u8f6c\u79fb\u901a\u9053\uff0c\u901a\u8fc7\u754c\u9762\u7535\u5b50\u6548\u5e94\u8bf1\u5bfc\u5149\u7535\u5b50\u4eceZn -\u535f\u5549\u8f6c\u79fb\u5230CdS\uff0c\u5e76\u968f\u540e\u6ce8\u5165Co -\u8054\u5421\u5576\u57fa\u5355\u5143\u8fdb\u884cCO<sub>2<\/sub>\u8fd8\u539f\u3002\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\uff0cCdS@COF\u57288 h\u5185\u4ea7\u751f4057 \u03bcmol g<sup>-1<\/sup>\u7684CO\uff0c\u660e\u663e\u9ad8\u4e8e\u7eafCdS\u548c\u4e9a\u80fa\u8fde\u63a5\u7684COF\u3002\u8fd9\u9879\u5de5\u4f5c\u63d0\u4f9b\u4e86\u89e3\u51b3\u5149\u654f\u5242\u548c\u6d3b\u6027\u4f4d\u70b9\u4e4b\u95f4\u7684\u6781\u6027\u8fde\u63a5\u7684\u5206\u5b50\u5185\u7535\u8377\u8f6c\u79fb\u65b9\u6848\uff0c\u7528\u4e8e\u592a\u9633\u80fd\u5230\u5316\u5b66\u80fd\u91cf\u7684\u8f6c\u6362\u3002\u8be5\u6210\u679c\u4ee5\u201c<strong>Photoelectron Transfer Mediated by the Interfacial Electron Effects<\/strong><strong>\u00a0<\/strong><strong>for Boosting Visible-Light-Driven CO<\/strong><strong><sub>2 <\/sub><\/strong><strong>Reduction<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>ACS Catalysis<\/strong>\u4e0a\u3002<strong>D<\/strong><strong>OI:<\/strong><strong>\u00a0<\/strong><strong>10.1021\/acscatal.1c05449<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><strong>https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acscatal.1c05449.<\/strong><\/p>\n<p>8\u3001<strong><em>Angew. Chem. Int. Ed<\/em><\/strong>\uff1a\u8d85\u4eb2\u6c34\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u6846\u67b6\u4f5c\u4e3a\u9ad8\u6548\u592a\u9633\u80fd\u84b8\u6c7d\u4ea7\u751f\u5bbd\u9891\u5438\u6536\u5242<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235185\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-13-3.png\" alt=\"\" width=\"523\" height=\"358\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-13-3.png 523w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-13-3-300x205.png 300w\" sizes=\"(max-width: 523px) 100vw, 523px\" \/><\/p>\n<p>\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\u672c\u8eab\u7684\u758f\u6c34\u6027\u548c\u5728\u8fd1\u7ea2\u5916\u533a\u6709\u9650\u7684\u5149\u5438\u6536\u662f\u963b\u788d\u5176\u5728\u592a\u9633\u80fd\u84b8\u6c7d\u53d1\u7535(SSG)\u4e2d\u5e94\u7528\u7684\u4e24\u4e2a\u74f6\u9888\u3002\u5728\u6b64\uff0c<strong><b>\u4e2d\u56fd\u4eba\u6c11\u5927\u5b66\u738b\u4e9a\u57f9\u6559\u6388<\/b><\/strong>\u548c<strong><b>\u5409\u6797\u5927\u5b66\u9648\u9f99<\/b><\/strong><strong><b>\u6559\u6388<\/b><\/strong>\u5408\u4f5c\u5f00\u53d1\u4e86\u4e00\u79cd\u57fa\u4e8e1,4,5,8-\u56db(\u82ef\u57fa\u6c28\u57fa)\u84bd-9,10-\u4e8c\u916e(TPAD)\u7684\u5171\u4ef7\u6709\u673a\u6846\u67b6(TPAD-COF)\uff0c\u8be5\u6846\u67b6\u5177\u6709\u8d85\u4eb2\u6c34\u6027\u548c\u8986\u76d6\u6574\u4e2a\u7d2b\u5916\/\u53ef\u89c1\u5230\u8fd1\u7ea2\u5916\u533a\u57df\u7684\u5e7f\u5149\u5438\u6536\u7279\u6027\u3002TPAD-COF\u662f\u4e00\u79cd\u4e0d\u542b\u4efb\u4f55\u6dfb\u52a0\u5242\u7684\u9ad8\u6548\u5149\u70ed\u8f6c\u6362\u6750\u6599\uff0c\u57281\u6b21\u592a\u9633\u7167\u5c04\u4e0b\uff0c\u5176\u6c34\u5206\u84b8\u53d1\u91cf\u8fbe\u52301.42 kg m<sup>\u22122<\/sup>\u00a0h<sup>\u22121<\/sup>\uff0c\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u9ad8\u8fbe94%\u3002\u901a\u8fc7\u87af\u5408BF<sub>2<\/sub>\u57fa\u56e2\u7684\u5408\u6210\u540e\u6539\u6027\uff0c\u8fdb\u4e00\u6b65\u6269\u5927\u4e86TPAD-COF\u7684\u5149\u5438\u6536\u8303\u56f4\u3002\u8be5\u4f5c\u8005\u901a\u8fc7\u7cfb\u7edf\u7684\u63a7\u5236\u5b9e\u9a8c\u548c\u5206\u6790\u8bc1\u5b9e\uff0c\u5149\u70ed\u8f6c\u6362\u6750\u6599\u7684\u4eb2\u6c34\u6027\u5728\u76ee\u524d\u57fa\u4e8eTPAD-COFs\u7684SSG\u4e2d\u8d77\u4e3b\u5bfc\u4f5c\u7528\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Superhydrophilic 2D Covalent Organic Frameworks as Broadband Absorbers for Efficient Solar Steam Generation<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u8457\u540d\u671f\u520a<strong>Angew. Chem. Int. Ed<\/strong>\u4e0a\u3002<strong>D<\/strong><strong>OI:<\/strong><strong>\u00a0<\/strong><strong>10.1002\/anie.202201900<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><strong>https:\/\/onlinelibrary.wiley.com\/doi\/epdf\/10.1002\/anie.202201900.<\/strong><\/p>\n<p>9\u3001<strong><em>Energy Storage Materials<\/em><\/strong>\uff1a\u7528\u4e8e\u9ad8\u7a33\u5b9a\u6027\u53ef\u5145\u7535\u6c34\u950c\u79bb\u5b50\u7535\u6c60\u7684\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u819c\u4fdd\u62a4\u950c\u9633\u6781<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235186\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-14-5.png\" alt=\"\" width=\"719\" height=\"421\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-14-5.png 719w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/\u56fe\u7247-14-5-300x176.png 300w\" sizes=\"(max-width: 719px) 100vw, 719px\" \/><\/p>\n<p>\u867d\u7136\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60(ZIBs)\u5177\u6709\u5de8\u5927\u7684\u50a8\u80fd\u6f5c\u529b\uff0c\u4f46\u950c\u91d1\u5c5e\u9633\u6781\u7684\u679d\u6676\u751f\u957f\u5bfc\u81f4\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u5dee\u548c\u5faa\u73af\u5bff\u547d\u4e0d\u7406\u60f3\uff0c\u9650\u5236\u4e86ZIBs\u7684\u5e7f\u6cdb\u5e94\u7528\u3002\u56e0\u6b64\uff0c<strong><b>\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u8d75\u4e39\u6559\u6388<\/b><\/strong>\u3001<strong><b>Jim<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>Yang Lee<\/b><\/strong><strong><b>\u6559\u6388\u548c\u54c8\u5c14\u6ee8\u5de5\u7a0b\u5927\u5b66\u738b\u8d35\u9886\u6559\u6388\u5408\u4f5c<\/b><\/strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u4eb2\u950c\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u7ed3\u6784(COF;\u901a\u8fc7\u754c\u9762\u53cd\u5e94\u5236\u5907TpPa-SO<sub>3<\/sub>)\u819c\uff0c\u7a33\u5b9aZn\u9633\u6781(TpPa-SO<sub>3<\/sub>H@Zn-foil)\u3002TpPa-SO<sub>3<\/sub>H\u819c\u4e0a\u7684\u78fa\u9178\u57fa\u4e0eZn<sup>2+<\/sup>\u79bb\u5b50\u534f\u540c\u4f5c\u7528\uff0c\u8c03\u8282Zn<sup>2+<\/sup>\u79bb\u5b50\u7684\u5747\u5300\u6c89\u79ef\uff0c\u6291\u5236\u679d\u6676\u7684\u5f62\u6210\u3002\u6b64\u5916\uff0cTpPa-SO<sub>3<\/sub>H\u53ef\u4ee5\u91ca\u653e\u5927\u91cf\u7684\u8d28\u5b50(H<sup>+<\/sup>)\uff0c\u5e76\u4e0eOH<sup>\u2212<\/sup>\u8fbe\u5230\u52a8\u6001\u5e73\u8861\uff0c\u4ece\u800c\u8c03\u8282[Zn(H<sub>2<\/sub>O)6]<sup>2+<\/sup>\u7684\u8131\u6eb6\uff0c\u9632\u6b62\u4e8c\u6b21\u53cd\u5e94\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0cCOF\u8584\u819c\u6d82\u5c42Zn\u9633\u6781\u662f\u4e00\u7ec4\u5f88\u6709\u524d\u9014\u7684\u5019\u9009\u7535\u6781\uff0c\u5e76\u4e3a\u7535\u6c60\u7684\u5176\u4ed6\u9886\u57df\uff0c\u5982\u9694\u819c\u548c\u7535\u89e3\u8d28\u6750\u6599\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u542f\u793a\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Covalent Organic Framework Film Protected Zinc Anode for Highly Stable Rechargeable Aqueous Zinc-Ion Batteries<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u8457\u540d\u671f\u520a<strong>Energy Storage Materials<\/strong>\u4e0a\u3002<strong>D<\/strong><strong>OI:<\/strong><strong>\u00a0<\/strong><strong>10.1016\/j.ensm.2022.02.054<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><\/p>\n<p><strong>https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2405829722001301?via%3Dihub.<\/strong><\/p>\n<p>\u672c\u6587\u7531\u79d1\u7814\u767e\u6653\u751f\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u662f\u4e00\u79cd\u4e8c\u7ef4(2D)\u6216\u4e09\u7ef4(3D)\u7ed3\u6676\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\uff0c\u901a\u8fc7\u5171\u4ef7\u952e\u8fde\u63a5\u7ed3\u6784\u5355\u5143\u800c\u6784\u5efa\u3002\u4e0e\u975e\u6676\u6001\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\u4e0d\u540c\u7684\u662fCOFs\u5177\u6709\u7ed3\u6784\u53ef\u8bbe\u8ba1\u3001&#8230;<\/p>\n","protected":false},"author":35234,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-235178","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/235178"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/35234"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=235178"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/235178\/revisions"}],"predecessor-version":[{"id":235379,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/235178\/revisions\/235379"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=235178"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=235178"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=235178"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}