{"id":235117,"date":"2022-03-29T06:25:05","date_gmt":"2022-03-28T22:25:05","guid":{"rendered":"\/\/m.iemloyee.com\/?p=235117"},"modified":"2022-03-28T15:45:30","modified_gmt":"2022-03-28T07:45:30","slug":"%e5%8d%97%e4%ba%ac%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6nat-commun%ef%bc%9a%e9%93%82%e5%9f%ba%e5%82%ac%e5%8c%96%e5%89%82-%e6%b0%a2%e6%ba%a2%e6%b5%81%e6%8f%90%e5%8d%87%e9%85%b8%e6%80%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=235117","title":{"rendered":"\u5357\u4eac\u5de5\u4e1a\u5927\u5b66Nat. Commun\uff1a\u94c2\u57fa\u50ac\u5316\u5242\u2014\u2014\u6c22\u6ea2\u6d41\u63d0\u5347\u9178\u6027HER"},"content":{"rendered":"

\u5bfc\u8bfb<\/strong><\/p>\n

\u6c22\u80fd\u662f\u4e0b\u4e00\u4ee3\u73af\u5883\u53cb\u597d\u80fd\u6e90\u7684\u5019\u9009\u8005\u3002\u5b9e\u73b0\u7eff\u8272\u6c22\u80fd\u7684\u5173\u952e\u662f\u4f7f\u7528\u7531\u98ce\u80fd\u548c\u592a\u9633\u80fd\u4ea7\u751f\u7684\u6e05\u6d01\u7535\u529b\u6765\u8fdb\u884c\u7535\u89e3\u6c34\u5236\u6c22\uff08hydrogen evolution reaction, HER\uff09\u3002\u76ee\u524d\uff0c\u867d\u7136\u4eba\u4eec\u7814\u7a76\u4e86\u5927\u91cf\u7684\u975e\u94c2(Pt)\u7c7bHER\u5019\u9009\u6750\u6599\uff0c\u4f46Pt\u4ecd\u88ab\u8ba4\u4e3a\u662f\u9178\u6027\u4ecb\u8d28\u4e2dHER\u7535\u50ac\u5316\u5242\u7684\u201c\u5723\u676f\u201d\u3002\u5176\u5177\u6709\u826f\u597d\u7684\u6c22\u952e\u80fd\uff0c\u8fc7\u7535\u4f4d\u63a5\u8fd1\u4e8e\u96f6\uff0c\u52a8\u529b\u5b66\u901f\u5ea6\u5feb\u7b49\u4f18\u52bf\u3002\u4f46\u5176\u5929\u7136\u7a00\u7f3a\u6027\u3001\u9ad8\u6210\u672c\u548c\u8010\u4e45\u6027\u5dee\u7684\u95ee\u9898\u9650\u5236\u4e86\u7535\u89e3\u6c34\u7684\u5927\u89c4\u6a21\u5546\u4e1a\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u6709\u5fc5\u8981\u63d0\u9ad8Pt\u7684\u672c\u5f81\u50ac\u5316\u80fd\u529b\u548c\u5229\u7528\u6548\u7387\u3002<\/p>\n

\u63d0\u9ad8Pt HER\u7684\u50ac\u5316\u6548\u7387\u5bf9\u4e8e\u6c34\u5206\u89e3\u6280\u672f\u7684\u53d1\u5c55\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u6c22\u6ea2\u6d41\u5df2\u7ecf\u6210\u4e3a\u8bbe\u8ba1\u53cc\u7ec4\u5206Pt\/\u8f7d\u4f53\u7535\u50ac\u5316\u5242\u7684\u65b0\u7b56\u7565\u3002\u7136\u800c\uff0c\u8fd9\u79cd\u4e8c\u5143\u50ac\u5316\u5242\u901a\u5e38\u5b58\u5728\u957f\u7684\u53cd\u5e94\u8def\u5f84\u3001\u8f83\u9ad8\u7684\u754c\u9762\u80fd\u5792\u548c\u590d\u6742\u7684\u5408\u6210\u8fc7\u7a0b\u7b49\u95ee\u9898\u3002<\/p>\n

\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u90b5\u5b97\u5e73\u6559\u6388\uff0c\u83ab\u7eb3\u4ec0\u5927\u5b66<\/strong>Yinlong Zhu<\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728Nat. Commun<\/em>\u4e0a\u53d1\u8868\u6587\u7ae0\uff0c\u9898\u4e3a\u201cHydrogen spillover in complex oxide multifunctional sites improves acidic hydrogen evolution electrocatalysis<\/strong>\u201d\u3002 \u6587\u7ae0\u5c55\u793a\u4e86\u4e00\u79cd\u901a\u8fc7\u7b80\u5355\u7684\u56fa\u76f8\u53cd\u5e94\u65b9\u6cd5\uff0c\u6210\u529f\u5236\u5907\u4e86\u72ec\u7279\u7684\u590d\u5408\u91d1\u5c5e\u6c27\u5316\u7269La2<\/sub>Sr2<\/sub>PtO7+\u03b4<\/sub>\uff0c\u4f5c\u4e3a\u9178\u6027\u4ecb\u8d28\u4e2d\u9ad8\u6d3b\u6027\u548c\u8010\u7528\u7684HER\u7535\u50ac\u5316\u5242\u3002\u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86La2<\/sub>Sr2<\/sub>PtO7+\u03b4<\/sub>\u4e2d\u591a\u529f\u80fd\u50ac\u5316\u4e2d\u5fc3\u534f\u540c\u4f5c\u7528\u7684\u72ec\u7279\u673a\u7406\uff1aO\u4f4d\u70b9\u8d77\u8d28\u5b50\u5bcc\u96c6\u4f5c\u7528\uff0c\u70ed\u4e2d\u6027La-Pt\u6865\u4f4d\u70b9\u8d77\u5230\u6709\u5229\u7684\u6c22\u6ea2\u6d41\/\u8fc1\u79fb\u7684\u4e2d\u4ecb\u4f5c\u7528\uff0cPt\u4f4d\u70b9\u6709\u5229\u4e8eH2<\/sub>\u7684\u6700\u7ec8\u8131\u9644\u3002\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0cLa2<\/sub>Sr2<\/sub>PtO7+\u03b4<\/sub>\u6c27\u5316\u7269\u8868\u73b0\u51fa\u663e\u8457\u7684HER\u6d3b\u6027\uff0c\u572810 mA cm\u2212<\/sup>2<\/sup>\u65f6\u7684\u8fc7\u7535\u4f4d\u4e3a13 mV\uff0c\u57280.5M H2<\/sub>SO4<\/sub>\u4e2d\u7684Tafel\u659c\u7387\u4e3a22 mV dec\u2212<\/sup>1<\/sup>\uff0c\u4f18\u4e8e\u5df2\u62a5\u9053\u7684\u6700\u5148\u8fdb\u7684\u6c22\u6ea2\u6d41\u578b\u5355\u7ec4\u5206\u50ac\u5316\u5242\uff08HSBCCs\uff09\u548c\u5176\u4ed6Pt\u57fa\u50ac\u5316\u5242\u3002\u6b64\u5916\uff0c\u76f8\u6bd4\u4e8e\u5546\u7528\u94c2\u9ed1\u50ac\u5316\u5242\uff0cLa2<\/sub>Sr2<\/sub>PtO7+\u03b4<\/sub>\u50ac\u5316\u5242\u7684\u672c\u5f81\u6d3b\u6027\u548c\u64cd\u4f5c\u5bff\u547d\u5f97\u5230\u663e\u8457\u63d0\u9ad8\u3002<\/p>\n

\"\"<\/p>\n

\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n

1.\u00a0 \u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86La2<\/sub>Sr2<\/sub>PtO7+\u03b4<\/sub>\u4e2d\u591a\u529f\u80fd\u50ac\u5316\u4e2d\u5fc3\u534f\u540c\u4f5c\u7528\u7684\u72ec\u7279\u673a\u7406\uff1aO\u4f4d\u70b9\u8d77\u8d28\u5b50\u5bcc\u96c6\u4f5c\u7528\uff0c\u70ed\u4e2d\u6027La-Pt\u6865\u4f4d\u70b9\u8d77\u5230\u6709\u5229\u7684\u6c22\u6ea2\u6d41\/\u8fc1\u79fb\u7684\u4e2d\u4ecb\u4f5c\u7528\uff0cPt\u4f4d\u70b9\u6709\u5229\u4e8eH2<\/sub>\u7684\u6700\u7ec8\u8131\u9644\u3002<\/p>\n

2. \u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0cLa2<\/sub>Sr2<\/sub>PtO7+\u03b4<\/sub>\u6c27\u5316\u7269\u8868\u73b0\u51fa\u663e\u8457\u7684HER\u6d3b\u6027\uff0c\u572810 mA cm\u2212<\/sup>2<\/sup>\u65f6\u7684\u8fc7\u7535\u4f4d\u4e3a13 mV\uff0c\u57280.5M H2<\/sub>SO4<\/sub>\u4e2d\u7684Tafel\u659c\u7387\u4e3a22 mV dec\u2212<\/sup>1<\/sup>\uff0c\u4f18\u4e8e\u5df2\u62a5\u9053\u7684\u6700\u5148\u8fdb\u7684\u6c22\u6ea2\u6d41\u578b\u5355\u7ec4\u5206\u50ac\u5316\u5242\uff08HSBCCs\uff09\u548c\u5176\u4ed6Pt\u57fa\u50ac\u5316\u5242\u3002\u6b64\u5916\uff0c\u6b64\u5916\uff0c\u76f8\u6bd4\u4e8e\u5546\u7528\u94c2\u9ed1\u50ac\u5316\u5242\uff0cLa2<\/sub>Sr2<\/sub>PtO7+\u03b4<\/sub>\u50ac\u5316\u5242\u7684\u672c\u5f81\u6d3b\u6027\u548c\u64cd\u4f5c\u5bff\u547d\u5f97\u5230\u663e\u8457\u63d0\u9ad8\u3002<\/p>\n

\u6570\u636e\u6982\u89c8<\/strong><\/p>\n

\u56fe1. \u6676\u4f53\u7ed3\u6784\u4e0e\u5f62\u8c8c\u8868\u5f81\u00a9 2022, The Author(s)<\/p>\n

\"\"<\/p>\n

a. La2<\/sub>Sr2<\/sub>PtO7+<\/sub>\u03b4<\/sub>\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

b. La2<\/sub>Sr2<\/sub>PtO7+<\/sub>\u03b4<\/sub>\u7684\u7cbe\u4feeXRD\u56fe<\/p>\n

c. \u6cbf[-110]\u65b9\u5411\u7684La2<\/sub>Sr2<\/sub>PtO7+<\/sub>\u03b4<\/sub>\u7684SAED\u56fe<\/p>\n

d. La2<\/sub>Sr2<\/sub>PtO7+<\/sub>\u03b4<\/sub>\u7684HRTEM\u56fe<\/p>\n

e. La2<\/sub>Sr2<\/sub>PtO7+<\/sub>\u03b4<\/sub>\u7684HAADF-STEM\u548c\u76f8\u5e94\u7684\u5143\u7d20mapping<\/p>\n

\u56fe2. \u9178\u6eb6\u6db2\u4e0b\u7535\u50ac\u5316HER\u6027\u80fd\u00a9 2022, The Author(s)<\/p>\n

\"\"<\/p>\n

a. \u6781\u5316\u66f2\u7ebf<\/p>\n

b. \u5854\u83f2\u5c14\u659c\u7387<\/p>\n

c. HER\u6d3b\u6027\u6bd4\u8f83<\/p>\n

La2<\/sub>Sr2<\/sub>PtO7+<\/sub>\u03b4<\/sub>\u548c\u94c2\u9ed1\u7684d ECSA\u548ce RSA\u4e0e\u5e94\u7528\u504f\u538b\u7684\u5173\u7cfb<\/p>\n

f. TOF\u548c\u4e0e\u6d4b\u8bd5\u7535\u4f4d\u7684\u5173\u7cfb<\/p>\n

g-j. \u7a33\u5b9a\u6027\u6d4b\u8bd5<\/p>\n

\u56fe3. \u6c22\u6ea2\u6d41\u7684\u5b9e\u9a8c\u8bc1\u636e\u00a9 2022, The Author(s)<\/p>\n

\"\"<\/p>\n

a. \u57280.03 V (vs. RHE)log j<\/em>\u4e0epH\u7684\u7ebf\u6027\u5173\u7cfb<\/p>\n

b. CV\u66f2\u7ebf<\/p>\n

c. \u6c22\u8131\u9644\u5cf0\u4f4d\u7f6e\u4e0e\u626b\u63cf\u901f\u7387\u7684\u5173\u7cfb\u56fe<\/p>\n

d. \u5728\u4e0d\u540c\u8fc7\u7535\u4f4d\u4e0bLa2<\/sub>Sr2<\/sub>PtO7+<\/sub>\u03b4<\/sub>\u7684Nyquist\u66f2\u7ebf<\/p>\n

e. EIS\u5bfc\u51fa\u7684\u5854\u83f2\u5c14\u659c\u7387\u66f2\u7ebf<\/p>\n

f. La2<\/sub>Sr2<\/sub>PtO7+<\/sub>\u03b4<\/sub>\u50ac\u5316\u5242\u7684\u6781\u5316\u66f2\u7ebf<\/p>\n

\u56fe4. DFT\u8ba1\u7b97\u00a9 2022, The Author(s)<\/p>\n

\"\"<\/p>\n

a. \u4e0d\u540c\u4f4d\u70b9\u7684La2<\/sub>Sr2<\/sub>PtO7+\u03b4<\/sub>\u4ee5\u53ca\u4f18\u5316\u540e\u7684\u7ed3\u6784\u6a21\u578b(001)\u8868\u9762\u6a21\u578b<\/p>\n

b. \u6c22\u5438\u9644\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u56fe<\/p>\n

c. \u6c22\u8fc1\u79fb\/\u6ea2\u6d41\u8fc7\u7a0b\u7684\u52a8\u529b\u5b66\u80fd\u5792<\/p>\n

d. Heyrovsky\u6b65\u7684\u81ea\u7531\u80fd\u5206\u5e03<\/p>\n

e. \u50ac\u5316\u673a\u7406\u793a\u610f\u56fe<\/p>\n

\u6210\u679c\u542f\u793a<\/strong><\/p>\n

\u4f5c\u8005\u6210\u529f\u5730\u5408\u6210\u4e86\u4e00\u79cd\u5355\u76f8\u590d\u5408\u6c27\u5316\u7269La2<\/sub>Sr2<\/sub>PtO7+\u03b4<\/sub>\uff0c\u5728\u9178\u6027\u4ecb\u8d28\u4e2d\u5177\u6709\u4f18\u5f02\u7684HER\u6027\u80fd\u3002\u8fd9\u79cd\u590d\u5408\u6c27\u5316\u7269\u4ee5\u516d\u89d2\u5f62\u7ed3\u6784\u7ed3\u6676\uff0c\u5177\u6709\u5305\u542b\u5b64\u7acb\u7684PtIV<\/sup>O6<\/sub>\u516b\u9762\u4f53\u548c[Sr2<\/sub>O1+\u03b4<\/sub>]\u9762\u7684[La2<\/sub>PtO6<\/sub>]\u4ea4\u66ff\u5c42\u3002\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0cLa2<\/sub>Sr2<\/sub>PtO7+\u03b4<\/sub>\u6c27\u5316\u7269\u8868\u73b0\u51fa\u663e\u8457\u7684HER\u6d3b\u6027\uff0c\u572810 mA cm\u2212<\/sup>2<\/sup>\u65f6\u7684\u8fc7\u7535\u4f4d\u4e3a13 mV\uff0c\u57280.5M H2<\/sub>SO4<\/sub>\u4e2d\u7684Tafel\u659c\u7387\u4e3a22 mV dec\u2212<\/sup>1<\/sup>\uff0c\u4f18\u4e8e\u5df2\u62a5\u9053\u7684\u6700\u5148\u8fdb\u7684\u6c22\u6ea2\u6d41\u578b\u5355\u7ec4\u5206\u50ac\u5316\u5242\uff08HSBCCs\uff09\u548c\u5176\u4ed6Pt\u57fa\u50ac\u5316\u5242\u3002\u6b64\u5916\uff0c\u6b64\u5916\uff0c\u76f8\u6bd4\u4e8e\u5546\u7528\u94c2\u9ed1\u50ac\u5316\u5242\uff0cLa2<\/sub>Sr2<\/sub>PtO7+\u03b4<\/sub>\u50ac\u5316\u5242\u7684\u672c\u5f81\u6d3b\u6027\u548c\u64cd\u4f5c\u5bff\u547d\u5f97\u5230\u663e\u8457\u63d0\u9ad8\u3002\u7814\u7a76\u4eba\u5458\u5bf9La2<\/sub>Sr2<\/sub>PtO7+\u03b4<\/sub>\u8fdb\u884c\u4e86\u5168\u9762\u7684\u5b9e\u9a8c\u548c\u7535\u5316\u5b66\u6d4b\u8bd5\uff0c\u8bc1\u5b9e\u4e86La2<\/sub>Sr2<\/sub>PtO7<\/sub>+La2<\/sub>Sr2<\/sub>PtO7<\/sub>+SnO2<\/sub>\u4e2d\u53ef\u80fd\u5b58\u5728\u6c22\u6ea2\u6d41\u73b0\u8c61\u3002\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u8868\u660e\uff0cLa2<\/sub>Sr2<\/sub>PtO7+\u03b4<\/sub>\u4e2dLa-Pt\u6865\u4f4d\u4e0a\u7684\u6c22\u5438\u9644\u662f\u8fd1\u70ed\u4e2d\u6027\uff0c\u8fd9\u53ef\u80fd\u662f\u6709\u5229\u7684\u6c22\u6ea2\u6d41\u7684\u5a92\u4ecb\uff0c\u4ece\u800c\u5bfc\u81f4\u5f02\u5e38\u9ad8\u7684\u6d3b\u6027\u3002\u672c\u5de5\u4f5c\u901a\u8fc7\u5355\u7ec4\u5206\u591a\u529f\u80fd\u4f4d\u70b9\u534f\u540c\u6548\u5e94\u7684\u6c22\u6ea2\u6d41\u6548\u5e94\uff0c\u4e3a\u9178\u6027\u4ecb\u8d28\u4e2d\u9ad8\u6027\u80fdHER\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u5f00\u8f9f\u4e86\u4e00\u6761\u65b0\u7684\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aHydrogen spillover in complex oxide multifunctional sites improves acidic hydrogen evolution electrocatalysis<\/a>. 2022, Nat. Commun<\/em>, DOI: 0.1038\/s41467-022-28843-2.<\/p>\n

\u672c\u6587\u7531\u7eb3\u7c73\u5c0f\u767d\u4f9b\u7a3f<\/p>\n

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