{"id":234517,"date":"2022-03-20T06:00:18","date_gmt":"2022-03-19T22:00:18","guid":{"rendered":"\/\/m.iemloyee.com\/?p=234517"},"modified":"2022-03-18T18:02:46","modified_gmt":"2022-03-18T10:02:46","slug":"%e5%ad%99%e5%ad%a6%e8%89%af%e3%80%81%e6%a5%bc%e9%9b%84%e6%96%87%e3%80%81%e5%8c%85%e4%bf%a1%e5%92%8c%e8%83%bd%e6%ba%90%e7%b1%bb%e8%af%be%e9%a2%98%e7%bb%84%e7%ae%80%e4%bb%8b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=234517","title":{"rendered":"\u5b59\u5b66\u826f\u3001\u697c\u96c4\u6587\u3001\u5305\u4fe1\u548c\u80fd\u6e90\u7c7b\u8bfe\u9898\u7ec4\u7b80\u4ecb"},"content":{"rendered":"

\u4e00\u3001\u5b59\u5b66\u826f\u6e05\u6d01\u80fd\u6e90\u8bfe\u9898\u7ec4<\/strong><\/p>\n

\u4eba\u7269\u4ecb\u7ecd\uff1a<\/strong><\/p>\n

\"\"<\/p>\n

\u5b59\u5b66\u826f\u6559\u6388\uff0c\u52a0\u62ff\u5927\u7687\u5bb6\u79d1\u5b66\u9662\u9662\u58eb\uff0c\u52a0\u62ff\u5927\u5de5\u7a0b\u9662\u9662\u58eb\uff0c\u52a0\u62ff\u5927\u7eb3\u7c73\u80fd\u6e90\u6750\u6599\u9996\u5e2d\u79d1\u5b66\u5bb6\uff0c\u52a0\u62ff\u5927\u897f\u5b89\u5927\u7565\u5927\u5b66\u7ec8\u8eab\u6559\u6388\u30021999\u5e74\u83b7\u5f97\u82f1\u56fd\u66fc\u5f7b\u65af\u7279\u5927\u5b66\u6750\u6599\u5316\u5b66\u535a\u58eb\u5b66\u4f4d\u30021999-2001\u5e74\uff0c\u5728\u52a0\u62ff\u5927\u4e0d\u5217\u98a0\u54e5\u4f26\u6bd4\u4e9a\u5927\u5b66\u4ece\u4e8b\u535a\u58eb\u540e\u5de5\u4f5c\uff0c2001-2004\u5e74\uff0c\u5728\u52a0\u62ff\u5927\u9b41\u5317\u514b\u5927\u5b66\u56fd\u5bb6\u79d1\u5b66\u7814\u7a76\u9662\u4efb\u52a9\u7406\u7814\u7a76\u5458\uff0c2004\u5e74\u4ee5\u52a9\u7406\u6559\u6388\u8eab\u4efd\u52a0\u5165\u897f\u5b89\u5927\u7565\u5927\u5b66\uff0c2008\u5e74\u5347\u4e3a\u526f\u6559\u6388\uff0c2012\u5e74\u5347\u4e3a\u6b63\u6559\u6388\u3002\u73b0\u4efbElectrochemical Energy Review\uff08EER\uff09<\/em>\u7684\u4e3b\u7f16\uff0c\u8fde\u7eed4\u5e74\uff082018\u20142021\u5e74\uff09\u5165\u9009\u79d1\u777f\u552f\u5b89\u5168\u7403\u201c\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u201d\u3002<\/p>\n

\u7814\u7a76\u5185\u5bb9\uff1a<\/strong><\/p>\n

\u5b59\u9662\u58eb\u7684\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u662f\u6e05\u6d01\u80fd\u6e90\u9886\u57df\u53ca\u80fd\u6e90\u6750\u6599\u5728\u80fd\u6e90\u50a8\u5b58\u548c\u8f6c\u5316\uff0c\u6d89\u53ca\u4e86\u57fa\u7840\u79d1\u5b66\u3001\u5e94\u7528\u7eb3\u7c73\u6280\u672f\u3001\u65b0\u5174\u5de5\u7a0b\u5b66\u7b49\u9886\u57df\uff0c\u4ee5\u5f00\u53d1\u548c\u5e94\u7528\u57fa\u4e8e\u7eb3\u7c73\u6750\u6599\u7684\u65b0\u578b\u80fd\u6e90\u7cfb\u7edf\u548c\u5668\u4ef6\u4e3a\u7814\u7a76\u6838\u5fc3\u3002\u76ee\u524d\u5177\u4f53\u4ece\u4e8b\u5f00\u53d1\u4e0d\u540c\u65b9\u6cd5\u6765\u5408\u6210\u4f4e\u7ef4\u7eb3\u7c73\u6750\u6599\uff0c\u5982\u78b3\u7eb3\u7c73\u7ba1\uff0c\u77f3\u58a8\u70ef\uff0c\u534a\u5bfc\u4f53\u548c\u91d1\u5c5e\u7eb3\u7c73\u7ebf\uff0c\u7eb3\u7c73\u9897\u7c92\uff0c\u8584\u819c\u548c\u5b83\u4eec\u7684\u590d\u5408\u6750\u6599\uff0c\u5b83\u4eec\u53ef\u4f5c\u4e3a\u80fd\u91cf\u8f6c\u6362\u548c\u5b58\u50a8\u7684\u7535\u5316\u5b66\u7535\u6781\uff0c\u5305\u62ec\u71c3\u6599\u7535\u6c60\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u548c\u9502\u7a7a\u6c14\u7535\u6c60\u3002\u3002\u540c\u65f6\uff0c\u5b59\u6559\u6388\u79ef\u6781\u4e0e\u5de5\u4e1a\u754c\u8fdb\u884c\u5408\u4f5c\u7814\u7a76\uff0c\u76ee\u524d\u7684\u5408\u4f5c\u8005\u5305\u62ec\u52a0\u62ff\u5927\u5df4\u62c9\u5fb7\u7535\u6e90\u7cfb\u7edf\u516c\u53f8\u3001\u7f8e\u56fd\u901a\u7528\u6c7d\u8f66\u516c\u53f8\u3001\u52a0\u62ff\u5927\u5e84\u4fe1\u4e07\u4e30\u7535\u6c60\u516c\u53f8\u548c\u4e2d\u56fd\u52a8\u529b\u7535\u6c60\u521b\u65b0\u4e2d\u5fc3\u3002\u4e0e\u516c\u53f8\u548c\u653f\u5e9c\u5b9e\u9a8c\u5ba4\uff08\u5982\u5df4\u62c9\u5fb7\u52a8\u529b\u7cfb\u7edf\u3001\u901a\u7528\u3001\u52a0\u62ff\u5927Phostech\u516c\u53f8\u4ee5\u53ca\u52a0\u62ff\u5927\u56fd\u9632\u90e8\uff09\u4e5f\u5f00\u5c55\u4e86\u76f8\u5173\u5408\u4f5c\u7814\u7a76\u3002\u5df2\u5728\u76f8\u5173\u9886\u57df\u9876\u7ea7\u671f\u520a\u53d1\u8868\u9ad8\u6c34\u5e73\u8bba\u6587500\u4f59\u7bc7\uff0c\u5176\u8bba\u6587\u603b\u5f15\u7528\u6b21\u65704\u4e07\u6b21\uff0cH\u56e0\u5b50105\uff0c\u5176\u4e2d\u5305\u62ecNat. Energy, Nat. Comm., Adv. Mater., J. Am. Chem. Soc., Angew.<\/em>\u7b49\u9ad8\u6c34\u5e73\u671f\u520a\u3002<\/p>\n

\u8fd1\u671f\u7814\u7a76\u8fdb\u5c55\uff1a<\/strong><\/p>\n

Nano Energy<\/strong><\/span><\/em>\uff1a<\/strong>COFs<\/strong>\u57fa\u7535\u89e3\u8d28\u52a0\u901f\u51c6\u56fa\u6001\u6709\u673a\u7535\u6c60\u4e2d<\/strong>Na+<\/sup><\/strong>\u6269\u6563\uff0c\u6291\u5236\u679d\u6676\u751f\u957f<\/strong>(COFs-based electrolyte accelerates the Na+<\/sup> diffusion and restrains dendrite growth in quasi-solid-state organic batteries, DOI: 10.1016\/j.nanoen.2021.106756)<\/em><\/span><\/p>\n

\u56fa\u6001\u94a0\u79bb\u5b50\u7535\u6c60\u5728\u672a\u6765\u7684\u50a8\u80fd\u9886\u57df\u6709\u7740\u5e7f\u9614\u7684\u53d1\u5c55\u524d\u666f\uff0c\u56e0\u6b64\u63a2\u7d22\u4e00\u79cd\u9ad8\u6548\u7684\u94a0\u79bb\u5b50\u5bfc\u4f53\u662f\u8feb\u5207\u9700\u8981\u89e3\u51b3\u7684\u95ee\u9898\u3002\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u5177\u6709\u7cbe\u786e\u5b9a\u5411\u548c\u660e\u786e\u5b9a\u4e49\u7684\u79bb\u5b50\u901a\u9053\uff0c\u662f\u56fa\u4f53\u94a0\u79bb\u5b50\u5bfc\u4f53\u7684\u7406\u60f3\u5e73\u53f0\u3002\u5728\u672c\u5de5\u4f5c\u4e2d\uff0c\u5b59\u5b66\u826f\u6559\u6388\u7b49\u4eba\u7814\u7a76\u4e86\u7fa7\u9178\u94a0\u529f\u80fd\u5316\u805a\u82b3\u919a\u94feCOF(NaOOC-COF)\u4f5c\u4e3a\u4e00\u79cd\u5148\u8fdb\u7684\u94a0\u79bb\u5b50\u51c6\u56fa\u6001\u5bfc\u4f53\u8584\u819c\u7684\u7b2c\u4e00\u4e2a\u4f8b\u5b50\u3002\u5229\u7528\u660e\u786e\u7684\u79bb\u5b50\u901a\u9053\uff0c\u529f\u80fd\u5316NaOOC-COF\u5728\u5ba4\u6e29\u4e0b\u7684Na+<\/sup>\u7535\u5bfc\u7387\u4e3a2.68 \u00d7 10\u22124<\/sup> S cm\u22121<\/sup>\uff0c\u6d3b\u5316\u80fd(Ea)\u4e3a0.24 eV\uff0c\u8f6c\u79fb\u6570\u4e3a0.9\u3002\u5176\u4e2d\uff0cNaOOC-COF\u5728\u7ec4\u88c5\u597d\u7684\u51c6\u56fa\u6001\u7535\u6c60\u4e2d\u8868\u73b0\u51fa\u957f\u65f6\u95f4\u5faa\u73af\u6027\u80fd\uff0c\u5e76\u901a\u8fc7\u754c\u9762\u8c03\u63a7\u6291\u5236\u679d\u6676\u751f\u957f\u3002\u6b64\u5916\uff0c\u8fd8\u6df1\u5165\u7814\u7a76\u4e86Na+<\/sup>\u5728\u5168\u7535\u6c60\u4f53\u7cfb\u4e2d\u7684\u6269\u6563\u673a\u7406\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u9996\u6b21\u53d6\u5f97\u4e86\u5982\u6b64\u4f18\u5f02\u7684\u94a0\u79bb\u5b50\u8f93\u8fd0\u7ed3\u679c\u3002\u8fd9\u4e00\u65b0\u7b56\u7565\u53ef\u4ee5\u5f00\u62d3\u94a0\u79bb\u5b50\u51c6\u56fa\u6001\u7535\u89e3\u5668\u4ef6\u7684\u65b0\u9886\u57df\uff0c\u540c\u65f6\u4e5f\u53ef\u4ee5\u52a0\u901f\u529f\u80fd\u5316COFs\u7684\u53d1\u5c55\u3002<\/p>\n

\u56fe1 NaOOC-COF\u7684SEM\u3001TEM\u56fe\u50cf(b)\u53caC, O\u548cNa (d-g)\u7684EDS\u6210\u50cf<\/strong><\/p>\n

\"\"<\/p>\n

EnSM<\/em><\/strong><\/span>\uff1a\u5b9e\u73b0\u6d3b\u6027Li2<\/sub>S\u7684\u53ef\u9006\u6c89\u6dc0\u5206\u89e3\u7528\u4e8e\u5bbd\u6e29\u5ea6\u8303\u56f4\u7684\u9ad8\u5bb9\u91cf\u9502\u786b\u7535\u6c60<\/strong>(Achieving reversible precipitation-decomposition of reactive Li2S towards high-areal-capacity lithium-sulfur batteries with a wide-temperature range, DOI: 10.1016\/j.ensm.2021.10.035)<\/em><\/span><\/p>\n

\u7535\u50ac\u5316\u4fc3\u8fdb\u591a\u786b\u5316\u7269\u7684\u8f6c\u5316\u662f\u6291\u5236\u9502-\u786b\uff08Li-S\uff09\u7535\u6c60\u7a7f\u68ad\u6548\u5e94\u7684\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u7b56\u7565\u3002\u7136\u800c\uff0c\u968f\u7740\u5faa\u73af\u8fc7\u7a0b\u4e2dLi2S\u949d\u5316\u5c42\u7684\u4e0d\u65ad\u5f62\u6210\uff0c\u7535\u50ac\u5316\u5242\u4e2d\u7684\u6d3b\u6027\u4e2d\u5fc3\u9010\u6e10\u949d\u5316\uff0c\u8fd9\u65e0\u7591\u7ed9\u5b9e\u73b0\u786b\u7269\u79cd\u7684\u7a33\u5b9a\u8f6c\u5316\u5e26\u6765\u4e86\u6311\u6218\u3002\u4e3a\u6b64\uff0c\u5b59\u5b66\u826f\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u79cd\u53cd\u5e94\u6027Li2<\/sub>S\u4e0e\u53cc\u5411Fe3<\/sub>C\u7535\u50ac\u5316\u5242\u534f\u540c\u7684\u7b56\u7565\uff0c\u5b9e\u73b0\u786b\u7684\u5feb\u901f\u8fde\u7eed\u8f6c\u5316\uff0c\u4ece\u800c\u5927\u5e45\u63d0\u9ad8Li-S\u7535\u6c60\u7684\u6027\u80fd\u3002\u5728\u8fd8\u539f\u8fc7\u7a0b\u4e2d\uff0cFe3<\/sub>C\u8868\u9762\u6790\u51fa\u4e86\u5177\u6709\u72ec\u7279\u4e09\u7ef4\u591a\u5b54\u7ed3\u6784\u7684\u6d3b\u6027Li2<\/sub>S\uff0c\u4e0d\u4ec5\u7f29\u77ed\u4e86\u79bb\u5b50\/\u7535\u5b50\u6269\u6563\u8def\u5f84\uff0c\u800c\u4e14\u66b4\u9732\u5e76\u4fdd\u7559\u4e86Fe3<\/sub>C\u4e2d\u66f4\u591a\u7684\u6d3b\u6027\u4f4d\u70b9\u3002\u800c\u5728\u63a5\u4e0b\u6765\u7684\u6c27\u5316\u8fc7\u7a0b\u4e2d\uff0cFe3<\/sub>C\u8fd8\u4fc3\u8fdb\u4e86\u6d3b\u6027Li2<\/sub>S\u7684\u5206\u89e3\uff0c\u5237\u65b0\u4e86\u7535\u50ac\u5316\u5242\u8868\u9762\u3002\u56e0\u6b64\uff0cFe3<\/sub>C\u5728\u6574\u4e2a\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u4e86\u826f\u597d\u7684\u9ad8\u50ac\u5316\u6d3b\u6027\uff0c\u7efc\u5408\u5b9e\u9a8c\u548c\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u9a8c\u8bc1\u4e86\u8fd9\u4e00\u70b9\u3002\u6700\u7ec8\uff0cFe3<\/sub>C\u53ef\u4ee5\u4f7f\u9ad8\u9762\u79ef\u5bb9\u91cfLi- S\u7535\u6c60(> 6.0 mAh cm\u22122<\/sup>)\u5728\u5bbd\u6e29\u5ea6\u8303\u56f4(-10 ~ 40\u2103)\u4e0b\u7a33\u5b9a\u8fd0\u884c\u3002\u53cc\u5411\u7535\u50ac\u5316\u5242\u5076\u8054\u53cd\u5e94\u6027Li2<\/sub>S\u7684\u7b56\u7565\u4e3a\u5f00\u53d1\u9ad8\u80fd\u5bbd\u6e29Li-S\u7535\u6c60\u63d0\u4f9b\u4e86\u65b0\u7684\u9014\u5f84\u3002<\/p>\n

\u56fe2 Fe3<\/sub>C@FC\/S-CF\u8d1f\u6781\u7535\u5316\u5b66\u7279\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

Sci. China Chem.<\/strong><\/span><\/em>\uff1a<\/strong>Ru<\/strong>\u5728<\/strong>N<\/strong>\u63ba\u6742\u77f3\u58a8\u70ef\u4e0a\u7684\u5408\u7406\u8bbe\u8ba1\u4fc3\u8fdb\u6c34\u89e3\u79bb\u6790\u6c22<\/strong>(Rational design of Ru species on N-doped graphene promoting water dissociation for boosting hydrogen evolution reaction,DOI: 10.1007\/s11426-021-1163-7)<\/em><\/span><\/p>\n

\u5b59\u5b66\u826f\u7b49\u4eba\u901a\u8fc7\u8c03\u8282Ru\u524d\u9a71\u4f53\u4e0e\u54aa\u5511\u9178\u5206\u5b50\u7b5b\u9aa8\u67b6-8 (ZIF-8)\u7684\u7ed3\u5408\u65b9\u5f0f\uff0c\u53ef\u4ee5\u5408\u7406\u8c03\u63a7Ru\u5728\u6c2e\u63ba\u6742\u77f3\u58a8\u70ef(NG)\u4e0a\u7684\u5f62\u6001\u5206\u5e03\u3002\u901a\u8fc7\u9633\u79bb\u5b50\u4ea4\u6362\u548c\u4e3b\u5ba2\u4f53\u7b56\u7565\uff0c\u948c\u524d\u9a71\u4f53\u4e0eZIF-8\u951a\u5b9a\u5728\u77f3\u58a8\u70ef\u4e0a\u5f62\u6210\u4e86\u4e24\u79cd\u4e0d\u540c\u7684\u7ed3\u5408\u6a21\u5f0f\u3002\u901a\u8fc7\u5bf9\u4e0a\u8ff0\u524d\u9a71\u4f53\u7684\u70ed\u89e3\uff0c\u53ef\u4ee5\u9009\u62e9\u6027\u5730\u5728NG(\u5206\u522b\u8868\u793a\u4e3aRu SASs+NPs\/NG\u548cRu SASs\/NG)\u4e0a\u5f62\u6210Ru\u5355\u539f\u5b50\u4f4d\u70b9(SASs)\u3002Ru SASs+NPs\/NG\u5728\u78b1\u6027\u6eb6\u6db2(\u03b710<\/sub>=12 mV, 12.57 A mg\u22121<\/sup>Ru<\/sub>\u5728100 mV\u4e0b)\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6790\u6c22\u53cd\u5e94(HER)\u6027\u80fd\uff0c\u660e\u663e\u4f18\u4e8eRu SASs\/NG\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u7814\u7a76\u8868\u660e\uff0cRu SASs\u80fd\u4ee5\u6700\u4f73\u5438\u9644\u5f3a\u5ea6\u5438\u9644\u6c22\uff0c\u800cRu NPs\u80fd\u964d\u4f4e\u6c34\u5206\u5b50\u89e3\u79bb\u7684\u969c\u788d\uff0c\u56e0\u6b64Ru SASs\u548cRu NPs\u80fd\u534f\u540c\u4fc3\u8fdb\u78b1\u6027\u6eb6\u6db2\u4e2dHER\u7684\u50ac\u5316\u6027\u80fd\u3002<\/p>\n

\u56fe3 Ru SASs+NPs\/NG\u548cRu SASs\/NG\u5408\u6210\u65b9\u6848<\/strong><\/p>\n

\"\"<\/p>\n

\u4e8c\u3001\u697c\u96c4\u6587\u8bfe\u9898\u7ec4<\/strong><\/p>\n

\u4eba\u7269\u4ecb\u7ecd\uff1a<\/strong><\/p>\n

\"\"<\/p>\n

\u697c\u96c4\u6587\uff0c\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u5316\u5b66\u4e0e\u751f\u7269\u5de5\u7a0b\u7cfb\u6559\u6388\uff0c\u5148\u540e\u4e8e2002\u548c2004\u5e74\u5728\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u83b7\u5f97\u5b66\u58eb\u5b66\u4f4d\u548c\u7855\u58eb\u5b66\u4f4d\uff0c2008\u5e74\u5728\u7f8e\u56fd\u5eb7\u5948\u5c14\u5927\u5b66\u83b7\u5f97\u5316\u5b66\u4e0e\u751f\u7269\u5206\u5b50\u5de5\u7a0b\u4e13\u4e1a\u535a\u58eb\u5b66\u4f4d\u7814\u7a76\u65b9\u5411\u3002\u6bd5\u4e1a\u540e\uff0c\u52a0\u5165\u5357\u6d0b\u7406\u5de5\u5927\u5b66\uff0c2017\u5e74\u5f53\u9009\u4e3a\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1a\u4f1a\u58eb\u3002\u4ed6\u517c\u4efb\u56fd\u9645\u8457\u540d\u6742\u5fd7Science Advances<\/em>\u526f\u7f16\u8f91\u3001Journal of Materials Chemistry A<\/em>\u526f\u4e3b\u7f16\u3001Small Methods<\/em>\u7f16\u59d4\u3002\u5728\u57f9\u517b\u4eba\u624d\u65b9\u9762\u4e5f\u6210\u7ee9\u5353\u7136\uff0c\u5f88\u591a\u535a\u58eb\u5df2\u7ecf\u5728\u6d59\u6c5f\u5927\u5b66\u3001\u6b66\u6c49\u5927\u5b66\u3001\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u3001\u5357\u4eac\u5927\u5b66\u3001\u4e2d\u79d1\u9662\u7b49\u77e5\u540d\u5927\u5b66\u6216\u7814\u7a76\u673a\u6784\u4efb\u6559\u3002\u76ee\u524d\u4e3a\u6b62\uff0c\u8bfe\u9898\u7ec4\u4ea7\u751f\u4e8616\u4f4d\u9752\u5e74\u5343\u4eba\uff0c3\u4f4d\u4f18\u9752\u3002\u8fde\u7eed4\u5e74\uff082018\u20142021\u5e74\uff09\u5165\u9009\u79d1\u777f\u552f\u5b89\u5168\u7403\u201c\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u201d\u3002<\/p>\n

\u7814\u7a76\u65b9\u5411\uff1a<\/strong><\/p>\n

\u4e3b\u8981\u7814\u7a76\u5174\u8da3\u4e3a\u8bbe\u8ba1\u5408\u6210\u7eb3\u7c73\u7ed3\u6784\u6750\u6599\uff08\u5982 MOFs\u3001\u5fae\u7eb3\u4e2d\u7a7a\u6750\u6599\u7b49\uff09\u53ca\u5176\u5728\u80fd\u6e90\u65b9\u5411\u7684\u5e94\u7528\uff0c\u6df1\u5ea6\u63a2\u8ba8\u4e86\u65b0\u578b\u7eb3\u7c73\u7ed3\u6784\u6750\u6599\u5728\u80fd\u6e90\u8d2e\u5b58\u548c\u7ed3\u6784\u4e2d\u7684\u5e94\u7528\u3002\u5177\u4f53\u53ef\u5206\u4e3a\u7535\u50ac\u5316\u3001\u5149\u50ac\u5316\u3001\u7535\u6c60\u53ca\u7535\u5bb9\u5668\u7b49\u80fd\u6e90\u8f6c\u5316\u53ca\u5b58\u50a8\u9886\u57df\u3002\u5df2\u5728\u76f8\u5173\u9886\u57df\u9876\u7ea7\u671f\u520a\u53d1\u8868\u9ad8\u6c34\u5e73\u8bba\u6587300\u4f59\u7bc7\uff0c\u5176\u8bba\u6587\u603b\u5f15\u7528\u6b21\u65709\u4e07\u6b21\uff0cH\u56e0\u5b50186\u3002<\/p>\n

\u8fd1\u671f\u7814\u7a76\u8fdb\u5c55\uff1a<\/strong><\/p>\n

AM<\/strong><\/span><\/em>\uff1a\u57fa\u4e8e\u62d3\u6251\u5316\u5b66\u53cd\u5e94\u6784\u7b51<\/strong>Ni(CN)2<\/sub>\/NiSe2<\/sub><\/strong>\u5f02\u8d28\u7ed3\u6784\u5b9e\u73b0\u9ad8\u6548\u7535\u50ac\u5316\u6790\u6c27<\/strong>(Construction of Ni(CN)2\/NiSe2 Heterostructures by Stepwise Topochemical Pathways for Efficient Electrocatalytic Oxygen Evolution\u201d, DOI: 10.1002\/adma.202104405)<\/span><\/em><\/p>\n

\u5f00\u53d1\u57fa\u4e8e\u590d\u6742\u5f02\u8d28\u7ed3\u6784\u7684\u9ad8\u6548\u7535\u50ac\u5316\u5242\u7528\u4e8e\u6790\u6c27\u53cd\u5e94(OER)\u662f\u63d0\u9ad8\u6c34\u88c2\u89e3\u6548\u7387\u3001\u751f\u4ea7\u6e05\u6d01\u80fd\u6e90\u6c22\u7684\u4e00\u79cd\u6709\u524d\u9014\u7684\u7b56\u7565\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5408\u6210\u65b9\u9762\u7684\u6311\u6218\uff0c\u6784\u5efa\u5177\u6709\u50ac\u5316\u6d3b\u6027\u7684\u7ed3\u6784\u548c\u7ec4\u6210\u65b0\u9896\u7684\u5f02\u8d28\u7ed3\u6784\u4ecd\u672a\u5f97\u5230\u5f88\u597d\u7684\u53d1\u5c55\u3002\u697c\u96c4\u6587\u6559\u6388\u5f00\u53d1\u51fa\u4e00\u79cd\u5305\u62ec\u8131\u6c34\u548c\u9634\u79bb\u5b50\u4ea4\u6362\u5728\u5185\u7684\u9010\u6b65\u62d3\u6251\u5316\u5b66\u7b56\u7565\uff0c\u5c06Ni-Ni \u970d\u592b\u66fc\u578b\u914d\u4f4d\u805a\u5408\u7269\uff08HCP\uff09\u7eb3\u7c73\u677f\u8f6c\u53d8\u4e3a\u72ec\u7279\u7684Ni(CN)2<\/sub>\/NiSe2<\/sub>\u5f02\u8d28\u7ed3\u6784\u3002\u5f53\u7528\u4f5cOER\u7535\u50ac\u5316\u5242\u65f6Ni(CN)2<\/sub>\/NiSe2<\/sub>\u5f02\u8d28\u7ed3\u6784\u7684\u6027\u80fd\u5f97\u5230\u4e86\u63d0\u9ad8\uff0c\u8fd9\u4e3b\u8981\u662f\u7531\u4e8e\u4e24\u7ec4\u5206\u534f\u540c\u4f5c\u7528\u6240\u8d4b\u4e88\u7684\u50ac\u5316\u4e2d\u5fc3\u7684\u51e0\u4f55\u7ed3\u6784\u548c\u7535\u5b50\u7ed3\u6784\u5f97\u5230\u4e86\u4f18\u5316\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u521b\u9020\u4e00\u79cd\u65b0\u578b\u7684\u954d\u57faOER\u7535\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u4e00\u6761\u5408\u7406\u7684\u5408\u6210\u8def\u7ebf\uff0c\u8be5\u50ac\u5316\u5242\u5177\u6709\u7eb3\u7c73\u7ea7\u7684\u5f02\u8d28\u7ed3\u6784\uff0c\u5176\u7ec4\u6210\u3001\u7a7a\u95f4\u7ec4\u7ec7\u548c\u754c\u9762\u6784\u578b\u53ef\u4ee5\u88ab\u7cbe\u7ec6\u63a7\u5236\u3002<\/p>\n

\u56fe4 Ni(CN)2<\/sub>\/NiSe2<\/sub>\u5f02\u8d28\u7ed3\u6784\u7684\u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

Adv. Sci.<\/strong><\/em><\/span>\uff1a\u6c2e\u63ba\u6742\u4e14\u5bcc\u542b\u6c27\u7a7a\u4f4d\u7684<\/strong>KMn8<\/sub>O16<\/sub><\/strong>\u7528\u4f5c\u7a33\u5b9a\u7684\u7528\u4e8e\u7a33\u5b9a\u7684\u950c\u79bb\u5b50\u7535\u6c60<\/strong>(Synthesis of Nitrogen-Doped KMn8O16 with Oxygen Vacancy for Stable Zinc-Ion Batteries, DOI: 10.1002\/advs.202106067)<\/em><\/span><\/p>\n

\u9530\u57fa\u6c27\u5316\u7269\u56e0\u5177\u6709\u4f4e\u6210\u672c\u3001\u4f4e\u6bd2\u6027\u3001\u50a8\u91cf\u4e30\u5bcc\u3001\u9ad8\u5de5\u4f5c\u7535\u538b\u7b49\u4f18\u70b9\u800c\u5907\u53d7\u5173\u6ce8\uff0c\u4f46\u540c\u65f6\u9762\u4e34\u7740\u672c\u5f81\u7535\u5bfc\u7387\u4f4e\u3001\u6676\u4f53\u7ed3\u6784\u4e0d\u7a33\u5b9a\u7b49\u95ee\u9898\uff0c\u6700\u7ec8\u5bfc\u81f4\u7535\u6c60\u5bb9\u91cf\u7684\u5feb\u901f\u8870\u51cf\u3002\u4e3a\u6b64\uff0c\u697c\u96c4\u6587\u6559\u6388\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u79cd\u591a\u529f\u80fd\u4fee\u9970\u7b56\u7565\uff0c\u901a\u8fc7\u7b80\u5355\u7684\u4e00\u6b65\u6c34\u70ed\u6cd5\u6784\u5efa\u4e86\u5177\u6709\u4e30\u5bcc\u6c27\u7a7a\u4f4d\u548c\u5927\u6bd4\u8868\u9762\u79ef\u7684N\u63ba\u6742KMn8<\/sub>O16<\/sub> (N-KMO)\u3002N-KMO\u4e2dN\u63ba\u6742\u3001\u6c27\u7a7a\u4f4d\u548c\u591a\u5b54\u7ed3\u6784\u7684\u534f\u540c\u4f5c\u7528\u80fd\u6709\u6548\u6291\u5236\u9530\u79bb\u5b50\u7684\u6eb6\u89e3\uff0c\u4fc3\u8fdb\u79bb\u5b50\u6269\u6563\u548c\u7535\u5b50\u4f20\u5bfc\u3002\u7ed3\u679c\u8868\u660e\uff0cN-KMO\u9634\u6781\u7684\u7a33\u5b9a\u6027\u548c\u53cd\u5e94\u52a8\u529b\u5b66\u663e\u8457\u63d0\u9ad8\uff0c\u4f18\u4e8e\u539f\u59cbMnO2<\/sub>\u548c\u53ea\u6709\u6c27\u7a7a\u4f4d\u7684MnO2<\/sub>\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cN-KMO\u8d1f\u6781\u57281 A g\u22121<\/sup>\u7684\u7535\u538b\u4e0b\u5faa\u73af2500\u6b21\u540e\uff0c\u53ef\u9006\u5bb9\u91cf\u9ad8\u8fbe262 mAh g\u22121<\/sup>\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u9ad8\u8fbe91%\u3002\u540c\u65f6\uff0c\u57280.1 A g\u22121<\/sup>\u65f6\uff0c\u6700\u9ad8\u6bd4\u5bb9\u91cf\u53ef\u8fbe298 mAh g\u22121<\/sup>\u3002\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u6c27\u7a7a\u4f4d\u548cN\u63ba\u6742\u53ef\u4ee5\u63d0\u9ad8MnO2<\/sub>\u7684\u5bfc\u7535\u6027\uff0c\u4ece\u800c\u53ef\u4ee5\u89e3\u91caMnO2<\/sub>\u4f18\u5f02\u7684\u901f\u7387\u6027\u80fd\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u5404\u79cd\u975e\u539f\u4f4d\u8868\u5f81\u65b9\u6cd5\u8bc1\u5b9e\u4e86N-KMO\u6b63\u6781\u6750\u6599\u7684\u50a8\u80fd\u673a\u7406\u4e3b\u8981\u662fH +<\/sup> \u548cZn2+ <\/sup>\u5171\u5d4c\u5165\/\u8131\u51fa\u8fc7\u7a0b\u3002<\/p>\n

\u56fe5 \u57fa\u4e8eN-KMO\u3001Ov<\/sub>-MnO2-x<\/sub>\u548cMnO2<\/sub>\u9634\u6781\u7684AZIBs\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

AEnM<\/strong><\/em><\/span>\uff1a\u539f\u4f4d\u76d1\u6d4b\u548c\u89e3\u6790\u6790\u6c27\u7535\u50ac\u5316\u4e2d\u7684\u7ed3\u6784\u6f14\u5316<\/strong>(Operando Monitoring and Deciphering the Structural Evolution in Oxygen Evolution Electrocatalysis\u201d,DOI: 10.1002\/aenm.202103383)<\/span><\/em><\/p>\n

\u6790\u6c27\u53cd\u5e94(OER)\u662f\u6c34\u7535\u89e3\u3001\u4e8c\u6c27\u5316\u78b3\u7535\u89e3\u3001\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u7b49\u5173\u952e\u80fd\u91cf\u8f6c\u6362\u548c\u5b58\u50a8\u6280\u672f\u7684\u74f6\u9888\u3002\u901a\u8fc7\u5f00\u53d1\u9ad8\u6548\u7684\u7535\u50ac\u5316\u5242\uff0c\u53ef\u4ee5\u514b\u670dOER\u53cd\u5e94\u52a8\u529b\u5b66\u7f13\u6162\u7684\u95ee\u9898\uff0c\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\uff0c\u7535\u50ac\u5316\u5242\u7ecf\u5386\u4e86\u4e00\u4e2a\u52a8\u6001\u7684\u7ed3\u6784\u6f14\u5316\u8fc7\u7a0b\u3002\u7136\u800c\uff0c\u5bf9OER\u8fc7\u7a0b\u4e2d\u7535\u50ac\u5316\u5242\u7ed3\u6784\u8f6c\u53d8\u7684\u53cd\u5e94\u673a\u7406\u548c\u771f\u6b63\u6d3b\u6027\u4f4d\u70b9\u7684\u6784\u6548\u5173\u7cfb\u7684\u7406\u89e3\u4ecd\u662f\u4e00\u4e2a\u8c1c\u3002\u5e78\u8fd0\u7684\u662f\uff0c\u00a0<\/span>\u52a8\u6001\u73b0\u573a\u539f\u4f4d\u8868\u5f81\u4e3a\u7814\u7a76OER\u7535\u50ac\u5316\u5242\u7684\u7ed3\u6784\u6f14\u5316\u8fc7\u7a0b\u548c\u53cd\u5e94\u673a\u7406\u63d0\u4f9b\u4e86\u5e73\u53f0\u3002\u697c\u96c4\u6587\u6559\u6388\u7b49\u4eba\u4e3b\u8981\u4ecb\u7ecd\u4e86\u7535\u50ac\u5316\u5242\u7ed3\u6784\u6f14\u5316\u8fc7\u7a0b\u7684\u8ddf\u8e2a\u3001\u7535\u50ac\u5316\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u8bb0\u5f55\u4ee5\u53ca\u7535\u50ac\u5316\u5242\u7ed3\u6784\u4e0e\u6d3b\u6027\/\u7a33\u5b9a\u6027\u4e4b\u95f4\u7684\u8054\u7cfb\u7b49\u65b9\u9762\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u5f3a\u8c03\u4e86\u6a21\u62df\u8fc7\u7a0b\u7684\u7406\u8bba\u8003\u8651\uff0c\u4ee5\u5236\u5b9a\u66f4\u6709\u6548\u7684\u8ba1\u7b97\u6a21\u578b\u3002\u672c\u7efc\u8ff0\u4e2d\u5bf9\u00a0<\/span>\u52a8\u6001\u73b0\u573a\u539f\u4f4d\u8868\u5f81\u7ed3\u679c\u7684\u5f53\u524d\u8fdb\u5c55\u7684\u603b\u7ed3\u548c\u6240\u63d0\u4f9b\u7684\u89c2\u70b9\u6709\u671b\u4e3aOER\u7535\u50ac\u5316\u5242\u5728\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7684\u7ed3\u6784\u6f14\u5316\u8fc7\u7a0b\u548c\u53cd\u5e94\u673a\u5236\uff0c\u7279\u522b\u662f\u7ed3\u6784-\u6027\u80fd\u5173\u7cfb\u63d0\u4f9b\u66f4\u5168\u9762\u7684\u7406\u89e3\uff0c\u4ece\u800c\u63d0\u4f9b\u4e3a\u5728\u4e0d\u4e45\u7684\u5c06\u6765\u5927\u89c4\u6a21\u5546\u4e1a\u5316\u8bbe\u8ba1\u548c\u5236\u5907\u66f4\u9ad8\u6548\u7684OER\u7535\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u5408\u7406\u7684\u6307\u5bfc\u3002<\/p>\n

\u56fe6 \u00a0<\/span>\u52a8\u6001\u73b0\u573a\u539f\u4f4d\u8868\u5f81 OER\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u7eb3\u7c73\u548c\u754c\u9762\u50ac\u5316\u8bfe\u9898\u7ec4<\/strong><\/p>\n

\u4eba\u7269\u4ecb\u7ecd\uff1a<\/strong><\/p>\n

\"\"<\/p>\n

\u5305\u4fe1\u548c\u9662\u58eb\uff0c\u5728\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u5de5\u4f5c\uff0c\u4efb\u50ac\u5316\u57fa\u7840\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7814\u7a76\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u6240\u5b66\u672f\u59d4\u5458\u4f1a\u4e3b\u4efb\uff0c\u6d01\u51c0\u80fd\u6e90\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u80fd\u6e90\u57fa\u7840\u548c\u6218\u7565\u7814\u7a76\u90e8\u90e8\u957f\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u7814\u7a76\u751f\u9662\u6559\u6388\uff1b2020\u5e74\uff0c\u5305\u4fe1\u548c\u9662\u58eb\u4f5c\u4e3a\u7b2c\u4e00\u5b8c\u6210\u4eba\u7684\u9879\u76ee\u300a\u7eb3\u7c73\u9650\u57df\u50ac\u5316\u300b\u88ab\u63d0\u540d\u4e3a\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956\uff1b2017\u5e746\u6708\u8d77\u4efb\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u6821\u957f\u30022009\u5e74\u5f53\u9009\u4e3a\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\uff1b2011\u5e74\u5f53\u9009\u4e3a\u53d1\u5c55\u4e2d\u56fd\u5bb6\u79d1\u5b66\u9662\u9662\u58eb\uff1b2016\u5e74\u5f53\u9009\u4e3a\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1a\u8363\u8a89\u4f1a\u58eb\u3002<\/p>\n

\u7814\u7a76\u65b9\u5411\uff1a<\/strong><\/p>\n

\u5305\u4fe1\u548c\u9662\u58eb\u957f\u671f\u4ece\u4e8b\u4ece\u4e8b\u80fd\u6e90\u9ad8\u6548\u8f6c\u5316\u76f8\u5173\u7684\u8868\u9762\u79d1\u5b66\u548c\u50ac\u5316\u5316\u5b66\u57fa\u7840\u7814\u7a76\uff0c\u4ee5\u53ca\u65b0\u578b\u50ac\u5316\u5242\u7814\u5236\u548c\u5f00\u53d1\u5de5\u4f5c\uff0c\u9996\u6b21\u63d0\u51fa\u7eb3\u7c73\u9650\u57df\u50ac\u5316\u65b0\u6982\u5ff5\uff0c\u662f\u56fd\u9645\u50ac\u5316\u9886\u57df\u7684\u9886\u519b\u4eba\u7269\u4e4b\u4e00\u3002\u5305\u4fe1\u548c\u9662\u58eb\u8bfe\u9898\u7ec4\u5728\u50ac\u5316\u76f8\u5173\u7684\u8868\u9762\u79d1\u5b66\u548c\u50ac\u5316\u5316\u5b66\u57fa\u7840\u7814\u7a76\uff0c\u65b0\u578b\u50ac\u5316\u6750\u6599\u7684\u5f00\u53d1\u4ee5\u53ca\u80fd\u6e90\u6e05\u6d01\u9ad8\u6548\u8f6c\u5316\u8fc7\u7a0b\u7b49\u9886\u57df\u505a\u51fa\u4e86\u91cd\u8981\u8d21\u732e\uff0c\u7814\u7a76\u9886\u57df\u4e3b\u8981\u5305\u62ec\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u8868\u9762\u5316\u5b66\u548c\u7eb3\u7c73\u50ac\u5316\u7406\u8bba\uff0c\u591a\u5b54\u6750\u6599\u7684\u5408\u6210\u4e0e\u8868\u5f81\uff0c\u7532\u70f7\u6d3b\u5316\u3001\u5408\u6210\u6c14\u50ac\u5316\u8f6c\u5316\u4ee5\u53ca\u5c0f\u5206\u5b50\u9009\u62e9\u6c27\u5316\u7b49\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u5206\u522b\u4e8e2014\u5e74\u548c2016\u5e74\u5165\u9009\u201c\u4e2d\u56fd\u79d1\u5b66\u5341\u5927\u8fdb\u5c55\u201d\u3002\u76ee\u524d\u5728Science\u3001Nature Mater.\u3001JACS\u3001Angew.\u3001 Energy & Env. Sci. \u7b49\u56fd\u9645\u9876\u7ea7\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u6587700\u4f59\u7bc7\u3002<\/p>\n

\u8fd1\u671f\u7814\u7a76\u8fdb\u5c55\uff1a<\/strong><\/p>\n

Angew.<\/strong><\/span><\/em>\uff1a<\/strong>Cu2<\/sub>P2<\/sub>O7<\/sub><\/strong>\u91cd\u6784\u50ac\u5316\u5242\u7528\u4e8e<\/strong>CO2<\/sub><\/strong>\u7535\u8fd8\u539f\u591a\u78b3\u4ea7\u7269\u00a0<\/strong>(A Reconstructed Cu2<\/sub>P2<\/sub>O7<\/sub> Catalyst for Selective CO2<\/sub> Electroreduction to Multicarbon Products,DOI: 10.1002\/anie.202114238)<\/span><\/em><\/p>\n

\u7535\u5316\u5b66CO2<\/sub>\u8fd8\u539f\u53cd\u5e94(CO2<\/sub>RR)\u5728\u5c06CO2<\/sub>\u8f6c\u5316\u4e3a\u591a\u78b3(C2+<\/sub>)\u71c3\u6599\u548c\u5316\u5b66\u54c1\u65b9\u9762\u663e\u793a\u51fa\u5de8\u5927\u7684\u6f5c\u529b\u3002\u5305\u4fe1\u548c\u9662\u58eb\u7b49\u4eba\u901a\u8fc7\u56fa\u76f8\u53cd\u5e94\u5408\u6210\u65b9\u6cd5\uff0c\u5c06A2<\/sub>M2<\/sub>O7<\/sub>\u7ed3\u6784\u5f15\u5165Cu\u57fa\u50ac\u5316\u5242\u4e2d\uff0c\u5f00\u53d1\u4e86\u91cd\u6784\u7684Cu2<\/sub>P2<\/sub>O7<\/sub>\u50ac\u5316\u5242\u7528\u4e8eCO2<\/sub>RR\uff0c\u8be5\u50ac\u5316\u5242\u662f\u4e00\u79cd\u9ad8\u6548\u7684CO2<\/sub>RR\u50ac\u5316\u5242\u3002\u5728CO2<\/sub>RR\u6761\u4ef6\u4e0b\uff0cCu2<\/sub>P2<\/sub>O7<\/sub>\u50ac\u5316\u5242\u88ab\u7535\u5316\u5b66\u8fd8\u539f\u6210\u91d1\u5c5eCu\uff0c\u5e76\u53d1\u751f\u4e86\u7531\u9897\u7c92\u805a\u96c6\u5230\u9ad8\u5b54\u7ed3\u6784\u7684\u663e\u8457\u7ed3\u6784\u6f14\u5316\u3002\u5728350 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u91cd\u6784\u7684Cu2<\/sub>P2<\/sub>O7<\/sub>\u50ac\u5316\u5242\u5bf9C2+<\/sub>\u4ea7\u7269\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u8fbe\u523073.6%\uff0c\u4e59\u70ef\u6cd5\u62c9\u7b2c\u6548\u7387\u8fbe\u523039.8%\u3002C2+<\/sub>\u4ea7\u7269\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u548c\u90e8\u5206\u7535\u6d41\u5bc6\u5ea6\u5747\u663e\u8457\u9ad8\u4e8eCuO\u50ac\u5316\u5242\u3002\u91cd\u6784Cu2<\/sub>P2<\/sub>O7<\/sub>\u50ac\u5316\u5242\u5177\u6709\u8f83\u9ad8\u7684\u7535\u5316\u5b66\u6d3b\u6027\u8868\u9762\u79ef\u3001\u4e30\u5bcc\u7684\u7f3a\u9677\u548c\u4f4e\u914d\u4f4d\u4f4d\u70b9\u3002\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0cCO\u5728\u5177\u6709\u7f3a\u9677\u548c\u4f4e\u914d\u4f4d\u7684Cu\u4e0a\u7684\u6865\u72b6\u548c\u9876\u90e8\u6784\u578b\u7684\u5438\u9644\u5f97\u5230\u4e86\u5f88\u5927\u7684\u6539\u5584\uff0c\u964d\u4f4e\u4e86C2+<\/sub>\u4ea7\u7269C-C\u8026\u5408\u53cd\u5e94\u7684\u80fd\u5792\u3002<\/p>\n

\u56fe7 CO2<\/sub>RR\u8fc7\u7a0b\u4e2d\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

J.Phys. Chem. C<\/strong><\/em><\/span>\uff1a\u94dc<\/strong>(111)<\/strong>\u8868\u9762\u4e0a\u6c27\u5316\u94c1\u7eb3\u7c73\u7ed3\u6784\u7684\u52a8\u6001\u7ed3\u6784\u53d8\u5316<\/strong>(Dynamic Structural Changes of Iron Oxide Nanostructures On Cu(111), DOI: 10.1021\/acs.jpcc.1c08309)<\/span><\/em><\/p>\n

\u89e3\u8d1f\u8f7d\u578b\u6c27\u5316\u94c1\u7eb3\u7c73\u7ed3\u6784(NSs)\u53ca\u5176\u4e0e\u91d1\u5c5e\u754c\u9762\u7684\u7ed3\u6784\u52a8\u529b\u5b66\uff0c\u5bf9\u4e8e\u5408\u7406\u8bbe\u8ba1\u6c27\u5316\u94c1\u57fa\u50ac\u5316\u5242\u7528\u4e8e\u8bb8\u591a\u4e3b\u8981\u7684\u50ac\u5316\u53cd\u5e94\u81f3\u5173\u91cd\u8981\u3002\u5728\u672c\u7814\u7a76\u4e2d\uff0c\u5305\u4fe1\u548c\u9662\u58eb\u7b49\u4eba\u5728Cu(111)\u4e0a\u6784\u5efa\u4e86FeO\u7eb3\u7c73\u9897\u7c92\uff0c\u5229\u7528\u626b\u63cf\u96a7\u9053\u663e\u5fae\u955c(STM)\u548cx\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31(XPS)\u7814\u7a76\u5176\u8868\u9762\u7ed3\u6784\u548c\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u4e2d\u7684\u52a8\u6001\u53d8\u5316\u3002\u5728Cu(111)\u8868\u9762\u4e0a\u53d1\u73b0\u4e86\u591a\u5c42FeOx<\/sub>\u3001\u4f4d\u9519\u548c\u7f3a\u9677\u7ebf\u3002FeO NSs\u7684\u5b58\u5728\u4fc3\u8fdb\u4e86FeO\/Cu(111)\u8868\u9762\u5728O2<\/sub>\u4e2d\u7684\u6c27\u5316\uff0c\u5bfc\u81f4FeO\u5468\u56f4Cu2<\/sub>O1+x<\/sub>\u6761\u5e26\u76f8\u7684\u5f62\u6210\u3002\u540c\u65f6\uff0cFeO NSs\u7684\u6c27\u5316\u4e5f\u5bfc\u81f4FeO x\u56e2\u7c07\u7684\u5f62\u6210\uff0c\u4e3b\u8981\u662fFe3+<\/sup>\u3002\u5728\u9000\u706b\u540e\u8f6c\u5316\u4e3a\u4e09\u7ef4FeOx<\/sub>\u7eb3\u7c73\u7c92\u5b50(NPs)\u5728800 K\u7684\u7279\u9ad8\u538b\u4e0b\uff0cXPS\u663e\u793aFe3+<\/sup>\u6ca1\u6709\u660e\u663e\u7684\u8fd8\u539f\u3002\u603b\u7684\u6765\u8bf4\uff0c\u5728Cu(111)\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u4e2d\uff0cFeO NSs\u5728\u539f\u5b50\u6c34\u5e73\u4e0a\u89c2\u5bdf\u5230\u4e86\u4e0d\u53ef\u9006\u7684\u7ed3\u6784\u52a8\u529b\u5b66\uff0c\u8fd9\u8fdb\u4e00\u6b65\u52a0\u6df1\u4e86\u5bf9FeO – Cu\u754c\u9762\u7684\u7406\u89e3\u3002<\/p>\n

\u56fe8 Cu(111)\u8868\u9762\u751f\u957fFeO NSs\u7684\u5f62\u6001\u548c\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

Chinese Journal of Catalysis<\/strong><\/em><\/span>\uff1a\u80fd\u6e90\u50ac\u5316\u6750\u6599\u7684\u7535\u5316\u5b66\u5408\u6210<\/strong>(Electrochemical synthesis of catalytic materials for energy catalysis,DOI: 10.1016\/S1872\u20102067(21)63940-2<\/em>)<\/span><\/p>\n

\u7535\u50ac\u5316\u662f\u4e00\u79cd\u5904\u7406\u5316\u5b66\u80fd\u548c\u7535\u80fd\u76f8\u4e92\u8f6c\u6362\u7684\u7535\u5316\u5b66\u53cd\u5e94\u7684\u8fc7\u7a0b\u3002\u50ac\u5316\u6d3b\u6027\u7eb3\u7c73\u7ed3\u6784\u7684\u7cbe\u786e\u5408\u6210\u662f\u963b\u788d\u8bb8\u591a\u91cd\u8981\u7684\u80fd\u6e90\u76f8\u5173\u7535\u50ac\u5316\u53cd\u5e94\u5b9e\u9645\u5e94\u7528\u7684\u5173\u952e\u6311\u6218\u4e4b\u4e00\u3002\u4e0e\u4f20\u7edf\u7684\u6e7f\u5316\u5b66\u6cd5\u3001\u56fa\u76f8\u6cd5\u548c\u6c14\u76f8\u6c89\u79ef\u6cd5\u76f8\u6bd4\uff0c\u7535\u5316\u5b66\u5408\u6210\u6cd5\u662f\u4e00\u79cd\u7b80\u5355\u3001\u5feb\u901f\u3001\u7ecf\u6d4e\u3001\u7cbe\u786e\u53ef\u63a7\u7684\u5236\u5907\u9ad8\u6548\u50ac\u5316\u6750\u6599\u7684\u65b9\u6cd5\u3002\u5305\u4fe1\u548c\u9662\u58eb\u7b49\u4eba\u7efc\u8ff0\u4e86\u8fd1\u5e74\u6765\u7535\u5316\u5b66\u5408\u6210\u5355\u539f\u5b50\u3001\u7403\u5f62\u548c\u5f62\u72b6\u7eb3\u7c73\u7c92\u5b50\u3001\u7eb3\u7c73\u7247\u3001\u7eb3\u7c73\u7ebf\u3001\u6838\u58f3\u7eb3\u7c73\u7ed3\u6784\u3001\u5c42\u72b6\u7eb3\u7c73\u6750\u6599\u3001\u6811\u679d\u72b6\u7eb3\u7c73\u7ed3\u6784\u3001\u5206\u5c42\u591a\u5b54\u7eb3\u7c73\u7ed3\u6784\u4ee5\u53ca\u590d\u5408\u6750\u6599\u7b49\u50ac\u5316\u6750\u6599\u7684\u7814\u7a76\u8fdb\u5c55\u7eb3\u7c73\u7ed3\u6784\u3002\u8ba8\u8bba\u4e86\u7535\u5316\u5b66\u5408\u6210\u7684\u57fa\u672c\u539f\u7406\u548c\u51e0\u79cd\u4e3b\u8981\u7684\u7535\u5316\u5b66\u5408\u6210\u65b9\u6cd5\u3002\u7535\u5316\u5b66\u5408\u6210\u7684\u50ac\u5316\u5242\u53ca\u5176\u72ec\u7279\u7684\u7535\u50ac\u5316\u6027\u80fd\u4e4b\u95f4\u7684\u7ed3\u6784-\u6027\u80fd\u76f8\u5173\u6027\u901a\u8fc7\u9009\u62e9\u7684\u4f8b\u5b50\u52a0\u4ee5\u8bf4\u660e\u3002\u63d0\u4f9b\u4e86\u5229\u7528\u7535\u5316\u5b66\u65b9\u6cd5\u5408\u6210\u9ad8\u6548\u50ac\u5316\u5242\u7684\u57fa\u672c\u6307\u5357\uff0c\u5e76\u63d0\u51fa\u4e86\u8be5\u9886\u57df\u7684\u4e00\u4e9b\u7814\u7a76\u6311\u6218\u548c\u672a\u6765\u7684\u673a\u9047\u3002<\/p>\n

\u56fe9 \u80fd\u6e90\u50ac\u5316\u6750\u6599\u7684\u7535\u5316\u5b66\u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u6587\u4e2d\u6240\u8ff0\u5982\u6709\u4e0d\u59a5\u4e4b\u5904\uff0c\u6b22\u8fce\u8bc4\u8bba\u533a\u7559\u8a00~<\/p>\n

\u672c\u6587\u7531\uff4a\uff55\uff4e\uff41\uff53\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00\u3001\u5b59\u5b66\u826f\u6e05\u6d01\u80fd\u6e90\u8bfe\u9898\u7ec4 \u4eba\u7269\u4ecb\u7ecd\uff1a \u5b59\u5b66\u826f\u6559\u6388\uff0c\u52a0\u62ff\u5927\u7687\u5bb6\u79d1\u5b66\u9662\u9662\u58eb\uff0c\u52a0\u62ff\u5927\u5de5\u7a0b\u9662\u9662\u58eb\uff0c\u52a0\u62ff\u5927\u7eb3\u7c73\u80fd\u6e90\u6750\u6599\u9996\u5e2d\u79d1\u5b66\u5bb6\uff0c\u52a0\u62ff\u5927\u897f\u5b89\u5927\u7565\u5927\u5b66\u7ec8\u8eab\u6559\u6388\u30021999\u5e74\u83b7…<\/p>\n","protected":false},"author":35331,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-234517","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/234517"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/35331"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=234517"}],"version-history":[{"count":8,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/234517\/revisions"}],"predecessor-version":[{"id":234818,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/234517\/revisions\/234818"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=234517"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=234517"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=234517"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}