{"id":234493,"date":"2022-03-23T06:27:57","date_gmt":"2022-03-22T22:27:57","guid":{"rendered":"\/\/m.iemloyee.com\/?p=234493"},"modified":"2022-03-23T15:44:38","modified_gmt":"2022-03-23T07:44:38","slug":"mof%e9%a1%b6%e5%88%8a%e6%9c%80%e6%96%b0%e8%bf%9b%e5%b1%95%e6%9d%a5%e8%a2%ad","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=234493","title":{"rendered":"MOF\u9876\u520a\u6700\u65b0\u8fdb\u5c55\u6765\u88ad"},"content":{"rendered":"

Adv. Funct. Mater.<\/em><\/strong><\/span>\uff1a<\/strong>MOFs<\/strong>\u78f7\u5316\u7684<\/strong>S<\/strong>\u63ba\u6742\u954d\u94c1\u78f7\u5316\u4f53\u663e\u8457\u4fc3\u8fdb\u7535\u5316\u5b66\u6c34\u5206\u88c2<\/strong><\/p>\n

(Electron Redistributed S-Doped Nickel Iron Phosphides Derived from One-Step Phosphatization of MOFs for Significantly Boosting Electrochemical Water Splitting, https:\/\/doi.org\/10.1002\/adfm.202200733<\/em>)<\/span><\/p>\n

\u975e\u8d35\u91d1\u5c5e\u8fc7\u6e21\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6<\/strong><\/span>(MOFs)\u662f\u5f00\u53d1\u9ad8\u5b54\u9699\u5ea6\u548c\u7ed3\u6784\u521a\u6027\u7535\u50ac\u5316\u5242\u7684\u524d\u4f53\u4e4b\u4e00\u3002\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66Pingyun Feng\u62a5\u9053\u4e86S\u63ba\u6742NiFeP\u7684\u9ad8\u6548\u7535\u50ac\u5316\u5242\u7684\u5408\u6210\u3002\u4ee5S\u63ba\u6742\u7684MOFs\u4e3a\u524d\u9a71\u4f53\uff0c\u4e00\u6b65\u78f7\u5316\u6cd5\u5408\u6210\u4e86NiFeP\u7ed3\u6784<\/span><\/strong>\uff0c\u65e2\u65b9\u4fbf\u53c8\u73af\u4fdd\uff0c\u8fd8\u6709\u52a9\u4e8e\u4fdd\u6301\u6837\u54c1\u7684\u9aa8\u67b6\u7ed3\u6784\u3002P\u90e8\u5206\u66ff\u6362S\u540e\uff0c\u56e0\u4e3a\u7535\u5b50\u7ed3\u6784\u53ef\u8c03\u3002NiFeP\u50ac\u5316\u5242\u7684\u6790\u6c27\u53cd\u5e94(OER)\u548c\u6790\u6c22\u53cd\u5e94(HER)\u6027\u80fd\u5f97\u5230\u6539\u5584\u3002\u4f18\u5316\u540e\u7684CCS-NiFeP-10\u7684OER\u7535\u6d41\u5bc6\u5ea6\u4e3a10 mA cm -2<\/sup>\uff0c\u8fc7\u7535\u4f4d\u4e3a201 mV\uff0c\u6027\u80fd\u4f18\u4e8e\u5927\u591a\u6570\u954d\u94c1\u57fa\u50ac\u5316\u5242\u3002S\u63ba\u6742\u5728\u5c06Ni\u539f\u5b50\u4e2d\u4e2d\u95f4\u4f53\u5f62\u6210\u7684\u0394G\u503c\u8c03\u6574\u5230\u5408\u9002\u7684\u503c\u4e0a\u8d77\u7740\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u5e76\u663e\u8457\u63d0\u9ad8\u4e86OER\u6027\u80fd\u3002CCS-NiFeP-20\u6837\u54c1\u7531\u4e8ed\u6ce2\u6bb5\u4e2d\u5fc3\u4ece\u8d39\u7c73\u80fd\u7ea7\u964d\u9891\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684HER\u6027\u80fd\u3002\u5f53\u7535\u89e3\u6c60\u7535\u538b\u4e3a1.50 V\u65f6\uff0c\u53ef\u83b7\u5f9710 mA cm -2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u3002\u8be5\u7b56\u7565\u4e3a\u8bbe\u8ba1\u9ad8\u6d3b\u6027\u7684\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n

\u56fe1 CCS-NiFeP-x (x = 0,5,10,20,30)\u5236\u5907\u793a\u610f\u56fe \u00a9 2022 The Authors<\/span><\/strong><\/p>\n

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Adv. Funct. Mater.<\/em><\/span>\uff1a\u53cc\u6c27\u5316\u8fd8\u539f\u4f4d\u70b9\u52a9\u529b\u4e8c\u7ef4\u5171\u8f6d\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u4e2d\u94a0\u7684\u9ad8\u5bb9\u91cf\u5b58\u50a8<\/strong>(Dual-Redox Sites Guarantee High-Capacity Sodium Storage in Two-Dimension Conjugated Metal\u2013Organic Frameworks, https:\/\/doi.org\/10.1002\/adfm.202112072<\/em>)<\/span><\/p>\n

\u03c0-d\u5171\u8f6d\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6<\/strong><\/span>(c-MOFs)\u5177\u6709\u8f83\u9ad8\u7684\u672c\u5f81\u5bfc\u7535\u6027\u548c\u5728\u6709\u673a\u7535\u89e3\u8d28\u4e2d\u7684\u7a33\u5b9a\u6027\uff0c\u662f\u94a0\u79bb\u5b50\u7535\u6c60(SIBs)\u7684\u7406\u60f3\u9633\u6781\u6750\u6599\u3002\u7136\u800c\uff0c\u5f00\u53d1\u5177\u6709\u591a\u6c27\u5316\u8fd8\u539f\u4f4d\u70b9\u7684c-MOFs\u6765\u63d0\u9ad8SIB\u7684\u6574\u4f53\u6027\u80fd\u662f\u975e\u5e38\u7406\u60f3\u7684\uff0c\u4f46\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u5e7f\u4e1c\u5de5\u4e1a\u5927\u5b66\u674e\u6210\u8d85\u6559\u6388\uff0cJun He\u7b49\u4eba\u62a5\u9053\u4e86\u5177\u6709\u7535\u5316\u5b66\u6d3b\u6027\u7684\u516d\u6c2e\u6742\u4e09\u8418\u57fa2D \u03c0-d c-MOFs \uff08HATN-XCu\uff0cX = O\u6216S\uff09\u4f5c\u4e3a\u5177\u6709\u53cc\u6c27\u5316\u8fd8\u539f\u4f4d\u70b9\u7684\u8d1f\u6781\u6750\u6599<\/span><\/strong>\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86Na+<\/sup>\u7684\u9ad8\u5bb9\u91cf\u53ef\u9006\u5b58\u50a8\u3002\u6709\u5e8f\u7684\u591a\u5b54\u5c42\u53e0\u7ed3\u6784\u53ef\u4ee5\u4e3a\u79bb\u5b50\u63d0\u4f9b\u6cbf\u5806\u53e0\u65b9\u5411\u7684\u5feb\u901f\u4f20\u8f93\u548c\u6269\u6563\u901a\u9053\u3002\u975e\u539f\u4f4d\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\uff08FTIR\uff09\u548cX\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\uff08XPS\uff09\u8868\u5f81\u8868\u660e\uff0cHATN-XCu\u7684\u53cc\u6c27\u5316\u8fd8\u539f\u4f4d\u70b9\u5206\u522b\u6765\u81eaHATN-\u914d\u4f53\u548c[CuX4<\/sub>]\u5355\u5143\u4e30\u5bcc\u7684C=N\u57fa\u56e2\u3002\u57fa\u4e8e\u53cc\u6c27\u5316\u8fd8\u539f\u4f4d\u70b9\u7684\u534f\u540c\u6548\u5e94\uff0cHATN-OCu\u9633\u6781\u5177\u6709\u4ee4\u4eba\u5370\u8c61\u6df1\u523b\u7684\u53ef\u9006\u5bb9\u91cf(\u57280.1 A g\u22121<\/sup>\u65f6\u4e3a500 mAh g\u22121<\/sup>)\u548c\u9ad8\u901f\u7387\u6027\u80fd(\u57285 A g\u22121<\/sup>\u65f6\u4e3a151 mAh g\u22121<\/sup>)\u3002\u53e6\u5916\uff0c\u91c7\u7528Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>O2<\/sub>F\uff08NVPOF\uff09\u8d1f\u6781\u548cHATN-OCu\u8d1f\u6781\u7ec4\u88c5\u6210\u94a0\u79bb\u5b50\u5168\u7535\u6c60\uff0c\u5176\u5177\u6709\u9ad8\u500d\u7387\u5bb9\u91cf\uff08\u57285 A g\u2212<\/sup>1<\/sup>\u4e0b\u8fbe\u5230117mAh g\u2212<\/sup>1<\/sup>\uff09\u548c\u7a33\u5b9a\u7684\u957f\u5faa\u73af\u5bff\u547d\uff08\u57282 A g\u2212<\/sup>1<\/sup>\u4e0b500\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a80%\uff09\u3002<\/p>\n

\u56fe2 HATN-OCu\u548cHATN-SCu\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd \u00a0\u00a9 2022 Wiley<\/span><\/strong><\/p>\n

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Adv. Sci. <\/strong><\/em><\/span>\uff1a<\/strong>Lewis<\/strong>\u78b1\u6027\u6c2e\u529f\u80fd\u5316<\/strong>MOF<\/strong>\u63a8\u52a8\u6c34\u5438\u9644\u5f0f\u70ed\u91cf\u5206\u914d<\/strong>(Immobilization of Lewis Basic Nitrogen Sites into a Chemically Stable Metal\u2013Organic Framework for Benchmark Water-Sorption-Driven Heat Allocations, https:\/\/doi.org\/10.1002\/advs.202105556<\/em>)<\/span><\/p>\n

\u7531\u4e8e\u7f3a\u4e4f\u6709\u6548\u7684\u63d0\u9ad8\u4f4e\u538b\u6c34\u5438\u9644\u5242<\/strong><\/span>\u7684\u7b56\u7565\uff0c\u5f00\u53d1\u9ad8\u6548\u7a33\u5b9a\u7684\u5438\u9644\u5242\u7528\u4e8e\u5438\u9644\u9a71\u52a8\u4f20\u70ed\u6280\u672f\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002\u6d59\u6c5f\u5927\u5b66\u94b1\u56fd\u680b\u3001\u674e\u658c\u56e2\u961f\u7b49\u4eba\u7814\u7a76\u8868\u660e\uff0c\u5c06Lewis\u78b1\u6027\u6c2e\u4f4d\u70b9\u56fa\u5b9a\u5230\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\u4e2d\uff0c\u53ef\u4ee5\u63d0\u9ad8\u5438\u6c34\u6027\u3001\u5236\u51b7\u548c\u4f9b\u70ed\u7684\u76ee\u6807\u57fa\u51c6\u6027\u80fd\u7cfb\u6570(COPs)<\/strong><\/span>\u3002\u5b83\u4eec\u8868\u73b0\u51fa\u4e00\u79cd\u5316\u5b66\u7a33\u5b9a\u7684MOF\u7684\u5438\u6c34\u7279\u6027(Zr-adip)\uff0c\u901a\u8fc7\u5728\u5438\u9644\u5242MIP-200\u4e2d\u52a0\u5165\u4eb2\u6c34\u6c2e\u4f4d\u70b9\u8bbe\u8ba1\u3002Zr-adip\u5448\u73b0s\u5f62\u5438\u9644\u7b49\u6e29\u7ebf\uff0c\u5728303 K\u5904\u7684\u5438\u6c34\u6027\u4e3a0.43 g g\u22121<\/sup>,P\/P0 = 0.25\uff0c\u9ad8\u4e8eMIP -200 (0.39 g g\u22121<\/sup>)\u3001KMF-1 (0.39 g g\u22121<\/sup>)\u548cMOF-303 (0.38 g g\u22121<\/sup>)\u3002\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u52a0\u5165\u7684N\u4f4d\u70b9\u53ef\u4ee5\u4f5c\u4e3a\u4e8c\u6b21\u5438\u9644\u4f4d\u70b9\uff0c\u4e0e\u6c34\u9002\u5ea6\u76f8\u4e92\u4f5c\u7528\uff0c\u63d0\u4f9b\u66f4\u591a\u7684\u7ed3\u5408\u4f4d\u70b9\uff0c\u589e\u5f3a\u6c34\u7ed3\u5408\u4eb2\u548c\u529b\u3002Zr-adip\u572870\u00b0C\u7684\u4f4e\u9a71\u52a8\u6e29\u5ea6\u4e0b\uff0c\u5b9e\u73b0\u4e860.79(\u51b7\u5374)\u548c1.75(\u52a0\u70ed)\u7684\u8d85\u9ad8COP\uff0c\u4f18\u4e8eMIP-200(0.78\u548c1.53)\u548cKMF-1(0.75\u548c1.74)\u3002Zr-adip\u5177\u6709\u8d85\u9ad8\u7684\u7a33\u5b9a\u6027\u3001\u4f18\u5f02\u7684\u5faa\u73af\u6027\u80fd\u548c\u6613\u4e8e\u518d\u751f\u7b49\u4f18\u70b9\uff0c\u662f\u5438\u9644\u9a71\u52a8\u51b7\u5374\u548c\u52a0\u70ed\u7684\u6700\u4f73\u5438\u9644\u5242\u4e4b\u4e00\u3002<\/p>\n

\u56fe3 Zr-adip\u6676\u4f53\u7ed3\u6784 \u00a9 2022 The Authors<\/span><\/strong><\/p>\n

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Angew. Chem. Int. Ed.<\/i><\/span> \uff1a\u591a\u523a\u6fc0\u54cd\u5e94\u4e8c\u7ef4\u67d4\u6027<\/strong>MOF<\/strong>\u4e2d\u6709\u673a\u53d1\u8272\u56e2\u7684\u52a8\u6001\u5168\u8272\u8c03\u8c10(<\/span><\/strong>Dynamic Full-Color Tuning of Organic Chromophore in a Multi-Stimuli-Responsive 2D Flexible MOF,\u00a0https:\/\/doi.org\/10.1002\/anie.202202073<\/em>)<\/strong><\/span><\/p>\n

\u5f00\u53d1\u80fd\u591f\u53d1\u5c04\u5e7f\u8c31\u989c\u8272\u7684\u901a\u7528\u523a\u6fc0\u54cd\u5e94\u6750\u6599\u662f\u975e\u5e38\u7406\u60f3\u7684\u3002\u5728\u6b64\u7814\u7a76\u4e2d\uff0c\u5357\u5f00\u5927\u5b66\u535c\u663e\u548c\u9662\u58eb\u3001\u8bb8\u5065\u7b49\u4eba\u5c06\u4e00\u4e2a\u6784\u8c61\u9002\u5e94\u6027\u6709\u673a\u53d1\u8272\u56e2\u63a5\u679d\u5230\u4e00\u4e2a\u67d4\u6027\u91d1\u5c5e-\u6709\u673a\u6846\u67b6(MOF)\u5efa\u7acb\u7684\u914d\u4f4d\u7a7a\u95f4<\/span><\/strong>\u4e2d\u3002\u5728\u8026\u5408\u7684\u7ed3\u6784\u8f6c\u6362\u548c\u7a7a\u95f4\u9650\u5236\u4e0b\uff0cMOF\u57fa\u4f53\u4e2d\u7684\u53d1\u8272\u56e2\u5728\u7269\u7406\u548c\u5316\u5b66\u523a\u6fc0\u4e0b\u53d1\u751f\u4e86\u826f\u597d\u7684\u6784\u8c61\u53d8\u5316\uff0c\u540c\u65f6\u8868\u73b0\u51fa\u70ed\u81f4\u53d8\u8272\u3001\u538b\u7535\u53d8\u8272\u548c\u6eb6\u5242\u8367\u5149\u53d8\u8272\uff0c\u5728\u53ef\u89c1\u8303\u56f4\u5185\u5177\u6709\u989c\u8272\u53ef\u8c03\u6027\u3002\u7531\u4e8e\u6240\u9009\u62e9\u7684\u534f\u8c03\u7a7a\u95f4\u7684\u5f39\u6027\u548c\u964d\u7ef4\u6027\uff0c\u6240\u6709\u4e09\u79cd\u989c\u8272\u8c03\u5236\u90fd\u8868\u73b0\u51fa\u654f\u611f\u548c\u81ea\u53ef\u9006\u7684\u65b9\u5f0f\uff0c\u6bcf\u4e00\u79cd\u90fd\u9075\u5faa\u53d1\u5c04\u6700\u5927\u503c\u4e0e\u523a\u6fc0\u7684\u7ebf\u6027\u76f8\u5173\u3002\u5355\u6676x\u5c04\u7ebf\u884d\u5c04\u7684\u53d8\u6e29\u7ed3\u6784\u548c\u6eb6\u5242\u5305\u88f9\u4f53\u6676\u4f53\u9610\u660e\u4e86\u590d\u6742\u7684\u989c\u8272\u53d8\u5316\u673a\u5236\u3002<\/p>\n

\u56fe4 NKU-128\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u7ed3\u6784\u8f6c\u53d8\u548c\u53d1\u5c04\u5149\u8c31\u53d8\u5316 \u00a9 2022 Wiley<\/span><\/strong><\/p>\n

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J. Am. Chem. Soc.<\/i><\/span>\uff1a<\/strong>MOF<\/strong>\u4f5c\u4e3a\u8d85\u8f7b<\/strong>,<\/strong>\u9ad8\u5f3a\u5ea6\u673a\u68b0\u8d85\u6750\u6599\u7684\u63a2\u7d22<\/strong>(Exploration of Hierarchical Metal\u2212Organic Framework as Ultralight, High-Strength Mechanical Metamaterials, https:\/\/doi.org\/10.1021\/jacs.1c11136)<\/em><\/span><\/p>\n

\u91d1\u5c5e-\u6709\u673a\u6846\u67b6(MOFs)\u7531\u4e8e\u5177\u6709\u6781\u9ad8\u7684\u8868\u9762\u4f53\u79ef\u6bd4\u548c\u5de8\u5927\u7684\u7ed3\u6784\u548c\u5316\u5b66\u591a\u6837\u6027\uff0c\u5728\u591a\u76f8\u50ac\u5316\u3001\u6c14\u4f53\u50a8\u5b58\u5206\u79bb\u548c\u836f\u7269\u4f20\u9012\u7b49\u5e94\u7528\u4e2d\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0cMOF\u6750\u6599\u4f5c\u4e3a\u529b\u5b66\u8d85\u6750\u6599\u7684\u6f5c\u529b\u5c1a\u672a\u88ab\u7814\u7a76\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u5317\u822aDayong Hu\u3001\u4e0a\u6d77\u79d1\u6280\u5927\u5b66Tao Li\u3001Hongti Zhang\u7b49\u4eba\u8bc1\u660e\u4e86\u901a\u8fc7\u5206\u5b50\u7ed3\u6784\u548c\u4ecb\u89c2\u7ed3\u6784\u8bbe\u8ba1\u7684\u5171\u540c\u52aa\u529b\uff0c\u5206\u5c42MOFs\u53ef\u4ee5\u8868\u73b0\u51fa\u5353\u8d8a\u7684\u529b\u5b66\u6027\u80fd<\/span><\/strong>\u3002\u5229\u7528\u5148\u8fdb\u7684\u539f\u4f4d\u900f\u5c04\u7535\u955c\u548c\u626b\u63cf\u7535\u955c(TEM\u548cSEM)\u6280\u672f\uff0c\u901a\u8fc7\u538b\u7f29\u5355\u4e2a\u8bd5\u6837\u5b9a\u91cf\u7814\u7a76\u4e86UiO-66\u516b\u9762\u4f53\u7a7a\u5fc3\u9897\u7c92\u7684\u529b\u5b66\u6027\u80fd\u3002\u7ed3\u679c\u8868\u660e:\u5206\u7ea7\u591a\u5b54\u6846\u67b6\u6750\u6599\u7684\u5c48\u670d\u5f3a\u5ea6\u548c\u6768\u6c0f\u6a21\u91cf\u5448\u660e\u663e\u7684\u201c\u8d8a\u5c0f\u8d8a\u5f3a\u8d8a\u786c\u201d\u7684\u5c3a\u5bf8\u4f9d\u8d56\u6027\uff0c\u6700\u5927\u5c48\u670d\u5f3a\u5ea6\u548c\u6768\u6c0f\u6a21\u91cf\u5206\u522b\u8fbe\u5230580\u00b155 MPa\u548c4.3\u00b10.5 GPa\uff0c\u6bd4\u5f3a\u6d4b\u5b9a\u4e3a0.15\u00b10.03 ~ 0.68\u00b10.11 GPa g\u22121<\/sup> cm3<\/sup>\u3002\u8fd9\u53ef\u4ee5\u4e0e\u4e4b\u524d\u62a5\u9053\u7684\u6700\u5148\u8fdb\u7684\u673a\u68b0\u8d85\u6750\u6599\uff0c\u5982\u73bb\u7483\u78b3\u7eb3\u7c73\u6676\u683c\u548c\u70ed\u89e3\u78b3\u7eb3\u7c73\u6676\u683c\u76f8\u5ab2\u7f8e\u3002\u8fd9\u9879\u5de5\u4f5c\u63ed\u793a\u4e86\u7eb3\u7c73MOFs\u6750\u6599\u53ef\u4ee5\u5236\u6210\u4e00\u79cd\u65b0\u578b\u7684\u4f4e\u5bc6\u5ea6\u3001\u9ad8\u5f3a\u5ea6\u673a\u68b0\u8d85\u6750\u6599\uff0c\u5e76\u4e3a\u5b9e\u9645\u5e94\u7528\u63d0\u4f9b\u4e86\u5bf9\u7eb3\u7c73MOFs\u529b\u5b66\u7a33\u5b9a\u6027\u7684\u8ba4\u8bc6\u3002<\/p>\n

\u56fe5 SEM\u5185\u5355\u4e2aUiO-66 MOF\u7a7a\u5fc3\u9897\u7c92\u7684\u539f\u4f4d\u538b\u7f29\u8bd5\u9a8c \u00a9 \u00a02022 ACS<\/span><\/strong><\/p>\n

\"\"<\/p>\n

Nat. Commun.<\/i><\/span>\uff1a\u975e\u5171\u683c\u94dc\u535f\u5549\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u4e2d<\/strong>Au<\/strong>\u6d3b\u5316\u7684<\/strong>N<\/strong>\u57fa\u5e8f\u4fc3\u8fdb\u548c\u7a33\u5b9a\u4e59\u70ef\u751f\u6210<\/strong>(Au-activated N motifs in non-coherent cupric porphyrin metal organic frameworks for promoting and stabilizing ethylene production, https:\/\/www.nature.com\/articles\/s41467-021-27768-6)<\/em><\/span><\/p>\n

\u7531\u4e8e\u5bfc\u7535\u6027\u5dee\u3001\u7a33\u5b9a\u6027\u5dee\u4ee5\u53ca\uff1e2e-\u4ea7\u7269\u7684\u9650\u5236\u7b49\u95ee\u9898\uff0c\u76f4\u63a5\u5b9e\u73b0\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u4f5c\u4e3a\u4e8c\u6c27\u5316\u78b3\uff08CO2<\/sub>\uff09\u7535\u8fd8\u539f\u50ac\u5316\u5242\u4e00\u76f4\u6781\u5177\u6311\u6218\u6027\u3002\u8fd1\u65e5\uff0c\u82cf\u5dde\u5927\u5b66\u5f6d\u626c\uff0cTao Cheng\u8054\u5408\u52a0\u5dde\u7406\u5de5\u5b66\u9662William A. Goddard III\u7b49\u4eba\u62a5\u9053\u4e86\u5c06Au\u7eb3\u7c73\u9488\u6d78\u6e0d\u5230\u5206\u79bb\u4e86\u94dc\u535f\u5549\u4e2d\u5fc3\u7684\u9506\u57faPCN-222 MOF\u4e2d\uff0c\u5e76\u8bc4\u4f30\u5176\u4f5c\u4e3aCO2RR\u7535\u50ac\u5316\u5242\u7684\u6027\u80fd\u3002\u672c\u7814\u7a76\u5229\u7528\u914d\u4f53\u7fa7\u9178\u76d0\u4f5c\u4e3aAu3+<\/sup>\u8fd8\u539f\u5242\uff0c\u5c06Au\u7eb3\u7c73\u9488\u6d78\u6e0d\u5230\u94dc\u535f\u5549\u57fa\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u4e2d\uff0c\u540c\u65f6\u88c2\u89e3\u914d\u4f53-\u8282\u70b9<\/span><\/strong>\u3002\u4ee4\u4eba\u60ca\u8bb6\u7684\u662f\uff0c\u5c3d\u7ba1\u7f3a\u4e4f\u76f8\u5e72\u7ed3\u6784\uff0c\u4f46\u91d1\u5d4c\u5165\u6846\u67b6\u63d0\u4f9b\u4e86\u6781\u597d\u7684\u4e59\u70ef\u9009\u62e9\u6027\uff0c\u6cd5\u62c9\u7b2c\u6548\u7387\u9ad8\u8fbe52.5%\u3002\u901a\u8fc7x\u5c04\u7ebf\u3001\u7ea2\u5916\u5149\u8c31\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\uff0c\u53d1\u73b0\u91d1\u6d3b\u5316\u7684\u6c2e\u57fa\u5e8f\u4e0eCu\u4e2d\u5fc3\u534f\u540c\u4f5c\u7528\u4e8e\u91d1\u5c5e\u535f\u5549\u4f4d\u70b9\u4e0a\u7684C-C\u5076\u8054\u589e\u5f3a\u4e86\u4e59\u70ef\u7684\u9009\u62e9\u6027\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u6539\u53d8\u4e86\u7535\u8377\u4f20\u5bfc\u8def\u5f84\uff0c\u7ed5\u8fc7\u4e86\u975e\u5171\u683c\u6846\u67b6\uff0c\u6dfb\u52a0\u7684\u50ac\u5316\u5242\u7684\u7ed3\u6784\u548c\u50ac\u5316\u7a33\u5b9a\u6027\u90fd\u5f97\u5230\u4e86\u6539\u5584\u3002\u672c\u7814\u7a76\u7740\u91cd\u7814\u7a76\u4e86\u91d1\u5c5e\u6d78\u6e0d\u5bf9\u7f51\u72b6\u91d1\u5c5e\u535f\u5549\u7ed3\u6784\u7684\u8c03\u63a7\uff0c\u4ee5\u6307\u5bfcCO2<\/sub>\u8fd8\u539f\u53cd\u5e94\u8def\u5f84\u3002<\/p>\n

\u56fe6 \u4e09\u79cdPCN-222(Cu)\u50ac\u5316\u5242\u7684\u7ed3\u6784\u8868\u5f81 \u00a9 2022 The Authors<\/span><\/strong><\/p>\n

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Nat. Biomed. Eng.<\/strong><\/em><\/span>\uff1a\u901a\u8fc7\u514d\u75ab\u8c03\u8282\u7eb3\u7c73\u5c3a\u5ea6\u91d1\u5c5e<\/strong>–<\/strong>\u6709\u673a\u6846\u67b6\u534f\u540c\u68c0\u67e5\u70b9\u963b\u65ad\u548c\u653e\u7597<\/strong>–<\/strong>\u653e\u5c04\u52a8\u529b\u5b66\u6cbb\u7597<\/strong>(Synergistic checkpoint-blockade and radiotherapy\u2013radiodynamic therapy via an immunomodulatory nanoscale metal\u2013organic framework, https:\/\/www.nature.com\/articles\/s41551-022-00846-w<\/em>)<\/span><\/p>\n

\u68c0\u67e5\u70b9\u963b\u65ad(checkpoint-blockade)<\/strong><\/span>\u5728\u514d\u75ab\u539f\u6027\u764c\u75c7\u4e2d\u5f15\u8d77\u6301\u4e45\u7684\u53cd\u5e94\uff0c\u4f46\u5728\u514d\u75ab\u201c\u51b7\u201d\u80bf\u7624\u4e2d\u57fa\u672c\u4e0a\u662f\u65e0\u6548\u7684\u3002\u5728\u8fd9\u91cc\uff0c\u829d\u52a0\u54e5\u5927\u5b66\u7684\u6797\u6587\u658c\u56e2\u961f\u62a5\u9053\u4e86\u94cb\u57fa\u7eb3\u7c73\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u7684\u8bbe\u8ba1\u3001\u5408\u6210\u548c\u6027\u80fd\uff0c\u8be5\u6846\u67b6\u53ef\u4ee5\u8c03\u8282\u80bf\u7624\u5fae\u73af\u5883\u7684\u514d\u75ab\u5b66\u548c\u529b\u5b66\u7279\u6027\uff0c\u7528\u4e8e\u589e\u5f3a\u653e\u5c04\u6cbb\u7597-\u653e\u5c04\u52a8\u529b\u5b66\u6cbb\u7597\u3002\u5728\u4f4eX\u5c04\u7ebf\u5242\u91cf\u7167\u5c04\u975e\u514d\u75ab\u539f\u6027\u524d\u5217\u817a\u548c\u80f0\u817a\u80bf\u7624\u7684\u5c0f\u9f20\u4e2d\uff0c\u80bf\u7624\u5185\u6ce8\u5c04\u653e\u5c04\u589e\u654f\u5242\u901a\u8fc7\u514d\u75ab\u6291\u5236\u7684M2\u5de8\u566c\u7ec6\u80de\u518d\u6781\u5316\u4e3a\u514d\u75ab\u523a\u6fc0\u7684M1\u5de8\u566c\u7ec6\u80de\uff0c\u4ecb\u5bfc\u4e86\u6709\u6548\u7684\u7ed3\u679c\uff0c\u4f7f\u80bf\u7624\u5185\u8f6c\u5316\u751f\u957f\u56e0\u5b50(TGF-\u03b2)\u548c\u80f6\u539f\u5bc6\u5ea6\u6d53\u5ea6\u7684\u964d\u4f4e\uff0c\u4ee5\u53ca\u764c\u75c7\u76f8\u5173\u6210\u7ea4\u7ef4\u7ec6\u80de\u7684\u5931\u6d3b\u3002\u5f53\u4e0e\u68c0\u67e5\u70b9\u963b\u65ad\u6cbb\u7597\u8054\u5408\u9759\u8109\u6ce8\u5c04\u65f6\uff0c\u653e\u5c04\u589e\u654f\u5242\u901a\u8fc7\u5168\u8eab\u964d\u4f4eTGF-\u03b2\u6c34\u5e73\uff0c\u5bfc\u81f4\u80f6\u539f\u86cb\u767d\u8868\u8fbe\u4e0b\u8c03\uff0c\u523a\u6fc0\u80bf\u7624\uff0c\u4ece\u800c\u9006\u8f6c\u539f\u53d1\u548c\u8fdc\u5904\u80bf\u7624\u7684\u514d\u75ab\u6291\u5236T\u7ec6\u80de\u5728\u80bf\u7624\u4e2d\u7684\u6d78\u6da6\u548c\u5f3a\u5927\u7684\u8fdc\u8ddd\u6548\u5e94\u3002 \u7eb3\u7c73\u7ea7\u653e\u5c04\u589e\u654f\u5242\u53ef\u523a\u6fc0\u6297\u80bf\u7624\u514d\u75ab\u548ct\u7ec6\u80de\u6d78\u6da6\uff0c\u53ef\u589e\u5f3a\u5176\u4ed6\u7c7b\u578b\u80bf\u7624\u68c0\u67e5\u70b9\u5c01\u9501\u7684\u6cbb\u7597\u6548\u679c\u3002<\/p>\n

\u56fe7 Bi-DBP\u7684\u8868\u5f81\u548c\u8f90\u5c04\u654f\u5316 \u00a9 \u00a02022 Springer Nature<\/span><\/strong><\/p>\n

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Nat. Mater.<\/span><\/em>\uff1a\u53ef\u8c03\u8c10\u91d1\u5c5e\u6c22\u6c27\u5316\u7269\u6709\u673a\u6846\u67b6\u7528\u4e8e\u50ac\u5316\u6c27\u5316<\/strong>(Tunable metal hydroxide\u2013organic frameworks for catalysing oxygen evolution,https:\/\/www.nature.com\/articles\/s41563-022-01199-0<\/em>)<\/span><\/p>\n

\u6790\u6c27\u53cd\u5e94\u662f\u5229\u7528\u7535\u5b50\u5236\u5907\u5316\u5b66\u54c1\u548c\u80fd\u6e90\u8f7d\u4f53\u7684\u6838\u5fc3\u3002\u901a\u8fc7\u5c06\u9176\u7cfb\u7edf\u7684\u9ad8\u5ea6\u53ef\u8c03\u63a7\u6027\u4e0e\u5df2\u77e5\u7684\u6c27\u5316\u7269\u57fa\u50ac\u5316\u5242\u76f8\u7ed3\u5408\uff0c\u53ef\u4ee5\u4e3a\u5b9e\u73b0\u9ad8\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u521b\u9020\u7a81\u7834\u6027\u7684\u673a\u4f1a\u3002\u9ebb\u7701\u7406\u5de5\u5b66\u9662\u90b5\u9633\u9662\u58eb\u3001Yuriy Rom\u00e1n-Leshkov\u7b49\u4eba\u901a\u8fc7\u5c06\u5c42\u72b6\u6c22\u6c27\u5316\u7269\u8f6c\u5316\u4e3a\u4f7f\u7528\u82b3\u9999\u7fa7\u9178\u76d0\u914d\u4f53\u4ea4\u8054\u7684\u4e8c\u7ef4\u7247\u5c42\u6750\u6599\uff0c\u6210\u529f\u5408\u6210\u51fa\u4e00\u7cfb\u5217\u91d1\u5c5e\u6c22\u6c27\u5316\u7269-\u6709\u673a\u6846\u67b6(MHOFs)\u3002\u6240\u5236\u5907\u51fa\u7684MHOFs\u53ef\u4f5c\u4e3a\u7528\u4e8e\u6790\u6c27\u53cd\u5e94\u7684\u53ef\u8c03\u63a7\u50ac\u5316\u5e73\u53f0\uff0c\u4f4d\u4e8e\u76f8\u90bb\u5806\u53e0\u914d\u4f53\u4e4b\u95f4\u7684\u03c0-\u03c0\u76f8\u4e92\u4f5c\u7528\u51b3\u5b9a\u7740\u7a33\u5b9a\u6027\uff0c\u800c\u6c22\u6c27\u5316\u7269\u4e2d\u8fc7\u6e21\u91d1\u5c5e\u7684\u6027\u8d28\u53ef\u4ee5\u8c03\u8282\u50ac\u5316\u6d3b\u6027\u3002\u5229\u7528\u9178\u6027\u9633\u79bb\u5b50\u6216\u5438\u7535\u5b50\u914d\u4f53\u53d6\u4ee3Ni\u57faMHOFs\uff0c\u53ef\u4ee5\u4f7f\u6bcf\u4e2a\u91d1\u5c5e\u4f4d\u70b9\u7684\u6790\u6c27\u53cd\u5e94\u6d3b\u6027\u63d0\u9ad8\u4e09\u4e2a\u6570\u91cf\u7ea7\u4ee5\u4e0a\uff0cFe\u53d6\u4ee3\u53ef\u4ee5\u4f7f\u50ac\u5316\u5242\u57280.3V\u8fc7\u7535\u4f4d\u4e0b\u8fd0\u884c20h\u540e\u4ecd\u8868\u73b0\u51fa\u9ad8\u8fbe80 A g–<\/sup>1<\/sup>catalyst<\/sub>\u7684\u8d28\u91cf\u6d3b\u6027\u3002\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u4f18\u5f02\u7684\u6790\u6c27\u53cd\u5e94\u6d3b\u6027\u53ef\u5f52\u529f\u4e8eMHOF\u57faNi\u6c27\u5316\u8fd8\u539f\u7684\u8c03\u63a7\u53ca\u542b\u6c27\u4e2d\u95f4\u4f53\u7684\u7ed3\u5408\u80fd\u4f18\u5316\u3002<\/p>\n

\u56fe8 M\/Ni2<\/sub> (OH)2<\/sub> (L4)\u7eb3\u7c73\u7247OER\u6d3b\u6027\u7684\u8c03\u8282 \u00a9 2022 Springer Nature<\/span><\/strong><\/p>\n

\"\"<\/p>\n

\u6587\u4e2d\u6240\u8ff0\u5982\u6709\u4e0d\u59a5\u4e4b\u5904\uff0c\u6b22\u8fce\u8bc4\u8bba\u533a\u7559\u8a00~<\/p>\n","protected":false},"excerpt":{"rendered":"

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