{"id":234180,"date":"2022-03-13T06:15:07","date_gmt":"2022-03-12T22:15:07","guid":{"rendered":"\/\/m.iemloyee.com\/?p=234180"},"modified":"2022-03-12T21:33:51","modified_gmt":"2022-03-12T13:33:51","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e5%a4%96%e7%b1%8d%e9%99%a2%e5%a3%abj-fraser-stoddart%e5%9b%a2%e9%98%9fnature%ef%bc%9a%e6%8e%a7%e5%88%b6%e5%88%86%e5%ad%90%e8%af%86%e5%88%ab%e5%92%8c%e7%bb%84%e8%a3%85","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=234180","title":{"rendered":"\u4e2d\u79d1\u9662\u5916\u7c4d\u9662\u58eb\u56e2\u961fNature\uff1a\u63a7\u5236\u5206\u5b50\u8bc6\u522b\u548c\u7ec4\u88c5\uff0c\u53ea\u9700\u8981\u901a\u70b9\u7535\uff01"},"content":{"rendered":"

\u4e00\u3001<\/strong>\u3010<\/strong>\u5bfc\u8bfb<\/strong>\u3011<\/strong><\/p>\n

\u81ea2014\u5e74\u201c\u7535\u5b50\u50ac\u5316<\/strong>\u201d\u7684\u6982\u5ff5\u88ab\u63d0\u51fa\u4ee5\u6765\uff0c\u8bb8\u591a\u539f\u672c\u4e0d\u6613\u53cd\u5e94\u7684\u60f0\u6027\u5e95\u7269\u5728\u7535\u5b50\u4f5c\u7528\u4e0b\u53ef\u4ee5\u663e\u8457\u7684\u589e\u52a0\u53cd\u5e94\u6d3b\u6027\u3002\u5728\u8fd9\u4e9b\u53cd\u5e94\u4e2d\uff0c\u7535\u5b50\u5c31\u662f\u964d\u4f4e\u53cd\u5e94\u80fd\u5792\u3001\u52a0\u5feb\u53cd\u5e94\u901f\u7387\u7684\u50ac\u5316\u5242\u3002<\/strong>\u5206\u5b50\u8bc6\u522b\u548c\u81ea\u7ec4\u88c5\u662f\u751f\u547d\u4f53\u7cfb\u7ed3\u6784\u548c\u529f\u80fd\u7684\u57fa\u7840\uff0c\u5bf9\u8fd9\u4e9b\u8fc7\u7a0b\u7684\u6df1\u5165\u7406\u89e3\u548c\u7cbe\u51c6\u8c03\u63a7\uff0c\u4e0d\u4ec5\u662f\u5b66\u4e60\u548c\u6a21\u4eff\u81ea\u7136\u754c\u7684\u5fc5\u7531\u4e4b\u8def\uff0c\u800c\u4e14\u63d0\u4f9b\u4e86\u201c\u81ea\u4e0b\u800c\u4e0a\u201d\u521b\u5236\u65b0\u6750\u6599\u7684\u6709\u6548\u9014\u5f84\u3002\u5206\u5b50\u8bc6\u522b\u548c\u8d85\u5206\u5b50\u7ec4\u88c5\u6db5\u76d6\u4e86\u5206\u5b50\u95f4\u975e\u5171\u4ef7\u6392\u5217\u73b0\u8c61\u7b49\u5e7f\u9614\u8303\u56f4\u3002\u7136\u800c\u8fd9\u79cd\u8fc7\u7a0b\u7684\u50ac\u5316\u4f5c\u7528\u4e0e\u5316\u5b66\u5408\u6210\u4e2d\u5f62\u6210\u5171\u4ef7\u952e\u4e0d\u540c\uff0c\u5b83\u4ec5\u9650\u4e8e\u4f9d\u8d56\u590d\u6742\u7684\u50ac\u5316\u5242\u8bbe\u8ba1\u65b9\u6cd5\u3002\u76ee\u524d\u60f3\u8981\u50ac\u5316\u5206\u5b50\u95f4\u7684\u8bc6\u522b\u548c\u7ec4\u88c5\uff0c\u4ecd\u7136\u662f\u8270\u5de8\u7684\u6311\u6218\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u7f8e\u56fd\u897f\u5317\u5927\u5b66J. Fraser Stoddart\u6559\u6388<\/strong>\u8054\u5408\u52a0\u5dde\u7406\u5de5\u5b66\u9662William A. Goddard \u6559\u6388<\/strong>\u5efa\u7acb\u4e86\u4e00\u79cd\u7b80\u5355\u800c\u901a\u7528\u7684\u7b56\u7565\uff0c\u901a\u8fc7\u5c06\u5728\u5408\u6210\u5171\u4ef7\u5316\u5b66\u4e2d\u5e7f\u6cdb\u5e94\u7528\u7684\u7535\u5b50\u50ac\u5316\u6269\u5c55\u5230\u8d85\u5206\u5b50\u975e\u5171\u4ef7\u5316\u5b66\u9886\u57df\u6765\u4fc3\u8fdb\u5206\u5b50\u8bc6\u522b\u3002\u5b9e\u9a8c\u8868\u660e\u5728\u5927\u73af\u4e3b\u4f53\u548c\u54d1\u94c3\u5f62\u5ba2\u4f53\u4e4b\u95f4\u5f62\u6210\u4e09\u81ea\u7531\u57fa\u590d\u5408\u7269\u65f6\uff08\u5728\u73af\u5883\u6761\u4ef6\u4e0b\uff0c\u5206\u5b50\u8bc6\u522b\u662f\u52a8\u529b\u5b66\u7981\u963b\u8fc7\u7a0b\uff09\uff0c\u53ef\u4ee5\u5728\u6dfb\u52a0\u50ac\u5316\u91cf\u7684\u5316\u5b66\u7535\u5b50\u6e90\u65f6\u663e\u8457\u52a0\u901f\u3002\u8fdb\u4e00\u6b65\u5b9e\u9a8c\u8868\u660e\u53ef\u4ee5\u901a\u8fc7\u7535\u5316\u5b66\u6682\u65f6\u63a7\u5236\u5206\u5b50\u8bc6\u522b\uff0c\u7cbe\u51c6\u8c03\u63a7\u7ec4\u88c5\u8fdb\u7a0b\u3002\u8fd9\u79cd\u52a8\u529b\u5b66\u7a33\u5b9a\u7684\u8d85\u5206\u5b50\u4f53\u7cfb\u5f88\u96be\u901a\u8fc7\u5176\u4ed6\u65b9\u6cd5\u7cbe\u786e\u83b7\u5f97\u3002\u5728\u5206\u5b50\u8bc6\u522b\u4e2d\uff0c\u4f7f\u7528\u7535\u5b50\u4f5c\u4e3a\u50ac\u5316\u5242\u53ef\u4ee5\u6fc0\u53d1\u5316\u5b66\u5bb6\u548c\u751f\u7269\u5b66\u5bb6\u63a2\u7d22\u53ef\u7528\u4e8e\u5fae\u8c03\u975e\u5171\u4ef7\u8fc7\u7a0b\u3001\u63a7\u5236\u4e0d\u540c\u89c4\u683c\u7ec4\u88c5\u4f53\uff0c\u5e76\u6700\u7ec8\u521b\u9020\u65b0\u5f62\u5f0f\u7684\u590d\u6742\u7269\u8d28\u3002\u8be5\u8bba\u6587\u4ee5\u9898\u4e3a\u201cElectron-catalysed molecular recognition<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aN<\/em><\/strong>ature<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/p>\n

\u221a\u00a0 \u9996\u6b21\u5b9e\u73b0\u4e86\u7535\u5b50\u5bf9\u5206\u5b50\u8bc6\u522b\u8fc7\u7a0b\u7684\u50ac\u5316<\/strong>\uff1b<\/p>\n

\u221a\u00a0\u00a0\u7cbe\u786e\u63a7\u5236<\/strong>\u5206\u5b50\u8bc6\u522b\u901f\u7387\u548c\u8f6c\u5316\u7387\u3002<\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001<\/strong>\u7535\u5b50\u50ac\u5316\u5206\u5b50\u8bc6\u522b\u8fc7\u7a0b\u7684\u8bbe\u8ba1 <\/strong>\u00a9 2022 Springer Nature<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4e3b\u5ba2\u4f53\u4f53\u7cfb\u7684\u7ed3\u6784\u5f0f\u548c\u76f8\u5e94\u7684\u56fe\u5f62\uff0c\u5206\u522b\u4e3a\u5927\u73af\u4e3b\u5ba2\u4f53R<\/strong>2(\u2022+)<\/sup><\/strong>\u548c\u54d1\u94c3\u5f62\u4e3b\u5ba2\u4f53D<\/strong>+(\u2022+)<\/sup><\/strong>\uff1b<\/p>\n

\uff08b\uff09\u63d0\u51fa\u7684\u7535\u5b50\u50ac\u5316\u5206\u5b50\u8bc6\u522b\u8fc7\u7a0b\u7684\u673a\u5236\u3002\u5411\u4f53\u7cfb\u4e2d\u6ce8\u5165\u4e00\u4e2a\u7535\u5b50\uff0cR<\/strong>2(\u2022+)<\/sup><\/strong>\u548cD<\/strong>+(\u2022+)<\/sup><\/strong>\u5747\u88ab\u8fd8\u539f\u3002\u7531\u6b64\uff0c\u4f53\u7cfb\u7684\u7535\u8377\u6570\u51cf\u5c11\uff0c\u4e24\u79cd\u5206\u5b50\u4e4b\u95f4\u7684\u9759\u7535\u6392\u65a5\u529b\u4f1a\u660e\u663e\u51cf\u5f31\uff0c\u4ece\u800c\u964d\u4f4e\u5927\u73af\u5206\u5b50\u7a7f\u8fc7\u5421\u5576\u76d0\u57fa\u56e2\u7684\u80fd\u5792\uff0c\u8fc5\u901f\u5f62\u6210\u4e00\u79cd\u53cc\u81ea\u7531\u57fa\u590d\u5408\u7269[D<\/strong>\u2282<\/strong>R]<\/strong>+2(\u2022+)<\/sup><\/strong>\u3002\u8fd9\u4e00\u50ac\u5316\u4e2d\u95f4\u4f53\u80fd\u591f\u81ea\u53d1\u5730\u5c06\u7535\u5b50\u91ca\u653e\u51fa\u6765\uff0c\u8f6c\u53d8\u4e3a\u6700\u7ec8\u7684\u7ec4\u88c5\u4ea7\u7269[D<\/strong>\u2282<\/strong>R]<\/strong>+3(\u2022+)<\/sup><\/strong>\uff0c\u800c\u91ca\u653e\u51fa\u7684\u7535\u5b50\u7ee7\u7eed\u8fd8\u539f\u65b0\u7684\u5e95\u7269\uff0c\u542f\u52a8\u4e0b\u4e00\u4e2a\u50ac\u5316\u5faa\u73af<\/p>\n

\u56fe\u4e8c\u3001<\/strong>\u50ac\u5316\u91cf\u7684\u4e8c\u8302\u94b4\uff08CoCp<\/strong>2<\/sub><\/strong>\uff09\u52a0\u901f\u4e86\u5206\u5b50\u8bc6\u522b <\/strong>\u00a9 2022 Springer Nature<\/strong>\"\"<\/strong><\/p>\n

\uff08a-c\uff09\u52a0\u5165\u4e0d\u540c\u542b\u91cfCoCp2<\/sub>\uff080\u00a0mol%\uff0c4 mol%\u548c8 mol%\uff09\u540e70\u5206\u949f\u5185\u7b49\u6469\u5c14\u91cfR<\/strong>2(\u2022+)<\/sup><\/strong>\u548cD<\/strong>+(\u2022+)<\/sup><\/strong>\u7ed3\u5408\u7684\u7d2b\u5916-\u53ef\u89c1\u5149-\u8fd1\u7ea2\u5916\u5438\u6536\u5149\u8c31\u53d8\u5316\uff1b<\/p>\n

\uff08d\uff09\u901a\u8fc7\u7ed8\u5236\u4e09\u81ea\u7531\u57fa\u590d\u5408\u7269[D<\/strong>\u2282<\/strong>R]<\/strong>+3(\u2022+)<\/sup><\/strong>\u4e0e\u65f6\u95f4\u7684\u5173\u7cfb\uff0c\u8868\u5f81\u4e0d\u540c\u542b\u91cfCoCp2<\/sub>\u5b58\u5728\u65f6R<\/strong>2(\u2022+)<\/sup><\/strong>\u548cD<\/strong>+(\u2022+)<\/sup><\/strong>\u7ed3\u5408\u7684\u52a8\u529b\u5b66\u53d8\u5316<\/p>\n

\u56fe\u4e09\u3001<\/strong>\u7535\u5b50\u50ac\u5316\u5206\u5b50\u8bc6\u522b\u8fc7\u7a0b\u7684\u673a\u7406\u7814\u7a76 <\/strong>\u00a9 2022 Springer Nature<\/strong>\"\"<\/strong><\/p>\n

\uff08a-b\uff09\u76d1\u6d4b\u793a\u610f\u56fe\u4ee5\u53ca\u9010\u6b65\u7535\u5b50\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7d2b\u5916-\u53ef\u89c1\u5149-\u8fd1\u7ea2\u5916\u5438\u6536\u5149\u8c31\u53d8\u5316\uff1b<\/p>\n

\uff08c\uff09\u4e00\u5f53\u91cfCoCp2<\/sub>\u52a0\u5165\u540e\u4eceCat<\/strong>3(\u2022+)<\/sup><\/strong>\u5230Cat<\/strong>2(\u2022+)<\/sup><\/strong>\u7684\u5b9a\u91cf\u8f6c\u6362\u7684\u7ed3\u6784\u5f0f\u548c\u56fe\u793a\uff1b<\/p>\n

\uff08d\uff09\u52a0\u5165CoCp2<\/sub>\u6ef4\u5b9a\u65f6\u6eb6\u6db2\u989c\u8272\u7684\u53d8\u5316\u53ca\u76f8\u5e94\u7684\u7d2b\u5916-\u53ef\u89c1\u5149-\u8fd1\u7ea2\u5916\u5438\u6536\u5149\u8c31\u53d8\u5316\uff1b<\/p>\n

\uff08e\uff09\u5ba4\u6e29\u4e0b\u8bb0\u5f55\u7684MeCN\u6eb6\u6db2\u4e2dCat<\/strong>3(\u2022+)<\/sup><\/strong>\u548cCat<\/strong>2(\u2022+)<\/sup><\/strong>\u7684EPR\u5149\u8c31\uff1b<\/p>\n

\uff08f\uff09Cat<\/strong>2(\u2022+)<\/sup><\/strong>\u7684\u5355\u6676\u7ed3\u6784<\/p>\n

\u56fe\u56db\u3001<\/strong>\u7535\u5316\u5b66\u63a7\u5236\u7684\u5206\u5b50\u8bc6\u522b\u5e94\u7528 <\/strong>\u00a9 2022 Springer Nature<\/strong>\"\"<\/strong><\/p>\n

\uff08a\uff09\u5728\u65e0\u9694\u819c\u7535\u89e3\u6c60\u4e2d\u7535\u89e3\u8fc7\u7a0b\u4e2d\u6d89\u53ca\u5206\u5b50\u8bc6\u522b\u7684\u4e00\u79cd\u53ef\u80fd\u9014\u5f84\u7684\u7ec4\u5408\u7ed3\u6784\u5f0f\u53ca\u5176\u56fe\u793a\uff1b<\/p>\n

\uff08b-c\uff09\u4e0d\u540c\u6761\u4ef6\u4e0b\u95f4\u6b47\u6027\u7535\u89e3R<\/strong>2(\u2022+)<\/sup><\/strong>\u548cD<\/strong>+(\u2022+)<\/sup><\/strong>\u6df7\u5408\u7269\u65f61080 nm\u5904\u5438\u6536\u5f3a\u5ea6\u7684\u53d8\u5316\u3002\uff08b\uff09\u6405\u62cc\u901f\u7387\u4e3a300 rpm\uff0c\u7535\u6d41\u4e3a0.5,1.0\u548c2.0 mA\u3002\uff08c\uff09\u7535\u6d41\u4e3a1.0 mA\uff0c\u6405\u62cc\u901f\u7387\u4e3a200,300\u548c400rpm<\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aElectron-catalysed molecular recognition<\/u><\/a>\u00a0(\u00a0Na<\/em>ure<\/em>\u00a0<\/em>2022<\/strong>, 603<\/em>, 265-270)<\/p>\n

\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f\u3002<\/p>\n

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