{"id":234047,"date":"2022-03-13T06:32:10","date_gmt":"2022-03-12T22:32:10","guid":{"rendered":"\/\/m.iemloyee.com\/?p=234047"},"modified":"2022-03-12T21:33:12","modified_gmt":"2022-03-12T13:33:12","slug":"%ef%bc%88%e5%b7%b2%e5%ae%a1%ef%bc%89chemical-reviews%ef%bc%9a%e8%b4%9f%e7%83%ad%e8%86%a8%e8%83%80%e7%9a%84%e5%8c%96%e5%ad%a6%e5%a4%9a%e6%a0%b7%e6%80%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=234047","title":{"rendered":"Chemical Reviews\uff1a\u8d1f\u70ed\u81a8\u80c0\u7684\u5316\u5b66\u591a\u6837\u6027"},"content":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1aQiang Li<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1aXianran Xing\uff08\u90a2\u732e\u7136\uff09<\/p>\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u5317\u4eac\u79d1\u6280\u5927\u5b66<\/p>\n<p>\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/acs.chemrev.1c00756<\/p>\n<p style=\"text-align: center;\"><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong><span style=\"color: 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style=\"text-align: center;\"><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u00a0 \u6765\u81ea<strong>\u5317\u4eac\u79d1\u6280\u5927\u5b66\u7684\u90a2\u732e\u7136\u56e2\u961f<\/strong>\u7cfb\u7edf\u5730\u6982\u8ff0\u4e86\u5316\u5b66\u591a\u6837\u6027\u5728NTE\u5316\u5408\u7269\u65b9\u9762\u7684\u6700\u65b0\u8fdb\u5c55\uff0c\u5bf9\u6676\u683c\u548c\u6df1\u5c42\u7ed3\u6784\u7684\u6709\u6548\u63a7\u5236\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u8ba8\u8bba\u3002\u8fd9\u79cd\u5bf9\u5316\u5b66\u591a\u6837\u6027\u7684\u5168\u9762\u603b\u7ed3\u548c\u5c55\u671b\u6709\u52a9\u4e8e\u4fc3\u8fdb\u529f\u80fd\u6027\u96f6\u81a8\u80c0(ZTE)\u5316\u5408\u7269\u7684\u5f00\u53d1\u548cNTE\u7684\u5b9e\u9645\u5e94\u7528\u3002\u76f8\u5173\u5de5\u4f5c\u4ee5\u9898\u4e3a\u201c<strong>Chemical Diversity for Tailoring Negative Thermal Expansion<\/strong>\u201d\u7684\u7efc\u8ff0\u6587\u7ae0\u5728<strong><em>Chemical Reviews<\/em><\/strong>\u4e0a\u53d1\u8868\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-234048\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3974.png\" alt=\"\" width=\"1432\" height=\"232\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3974.png 1432w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3974-300x49.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3974-768x124.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3974-1024x166.png 1024w\" sizes=\"(max-width: 1432px) 100vw, 1432px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u4e09\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><strong>\u5177\u6709NTE\u7684\u67d4\u6027\u7ed3\u6784<\/strong><\/p>\n<p>\u67d4\u6027\u7ed3\u6784\u7531\u914d\u4f4d\u591a\u9762\u4f53\u548c\u6865\u8fde\u539f\u5b50\u6216\u5b98\u80fd\u56e2\u8fde\u63a5\u800c\u6210\uff0c\u901a\u5e38\u5177\u6709\u4f4e\u5bc6\u5ea6\u548c\u5927\u5b54\u5bb9\u7684\u7279\u70b9\u3002\u6709\u8db3\u591f\u7684\u5185\u90e8\u7a7a\u95f4\u548c\u7075\u6d3b\u7684\u7ed3\u6784\u5141\u8bb8\u67d0\u4e9b\u539f\u5b50\u6216\u5206\u5b50\u76f8\u5bf9\u81ea\u7531\u7684\u632f\u52a8\uff0c\u8fd9\u5c31\u8d4b\u4e88\u4e86NTE\u7684\u5927\u91cf\u53ef\u80fd\u6027\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u67d4\u6027\u662f\u9ad8\u5ea6\u4f9d\u8d56\u4e8e\u7ed3\u6784\u548c\u6210\u5206\u7684\uff0c\u5b83\u6d89\u53ca\u5230\u7ed3\u6784\u5c3a\u5bf8\u3001\u76f8\u4e92\u7a7f\u900f\u7684\u6570\u91cf\u3001\u914d\u4f53\u7684\u5f62\u72b6\u548c\u957f\u5ea6\u3001\u91d1\u5c5e\u79bb\u5b50\u7684\u914d\u4f4d\u65b9\u5f0f\u3001\u62d3\u6251\u7ed3\u6784\u548c\u9aa8\u67b6\u7684\u51e0\u4f55\u7ed3\u6784\u30021996\u5e74\uff0c\u901a\u8fc7Zr-O-W\u952e\u7531WO<sub>4<\/sub>\u56db\u9762\u4f53\u548cZrO<sub>6<\/sub>\u516b\u9762\u4f53\u7ec4\u6210\u7684ZrW<sub>2<\/sub>O<sub>8<\/sub>\u57280.3-1050K\u4e4b\u95f4\u8868\u73b0\u51fa\u5404\u5411\u540c\u6027\u7684NTE\uff0c\u5176\u673a\u7406\u88ab\u8ba4\u4e3a\u4e0e\u6865-\u6c27\u539f\u5b50\u7684\u6a2a\u5411\u632f\u52a8\u6709\u5173\u3002\u4ece\u90a3\u65f6\u8d77\uff0c\u8bb8\u591a\u5177\u6709\u5f00\u653e\u6846\u67b6\u7ed3\u6784\u7684\u6750\u6599\u88ab\u53d1\u73b0\u5177\u6709NTE\uff0c\u7b80\u5355\u7684ReO<sub>3<\/sub>\u7ed3\u6784\u957f\u671f\u4ee5\u6765\u4e00\u76f4\u88ab\u7528\u4f5c\u539f\u578b\u6750\u6599\u6765\u8bf4\u660eRUM\u662f\u5982\u4f55\u8bf1\u5bfcNTE\u7684\u3002\u7136\u800c\uff0cReO<sub>3<\/sub>\u53ea\u6709\u5728\u5f88\u4f4e\u7684\u6e29\u5ea6\u4e0b\u624d\u8868\u73b0\u51faNTE\u3002\u5e78\u8fd0\u7684\u662f\uff0c2010\u5e74\uff0c\u5a01\u5c14\u91d1\u68ee\u7b49\u4eba\u53d1\u73b0\u5177\u6709ReO<sub>3<\/sub>\u578b\u7ed3\u6784\u7684ScF<sub>3<\/sub>\u572810-1100K\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u8868\u73b0\u51fa\u660e\u663e\u7684NTE(<strong>\u56fe1a<\/strong>)\u3002\u7136\u540e\u6709\u5b66\u8005\u5229\u7528EXAFS\u3001\u540c\u6b65\u8f90\u5c04X\u5c04\u7ebf\u603b\u6563\u5c04\u548c\u4e2d\u5b50\u7c89\u672b\u884d\u5c04(NPD)\u4ee5\u53ca\u5bf9\u5206\u5e03\u51fd\u6570(PDF)\u7684\u8054\u5408\u5206\u6790\u63ed\u793a\u4e86\u201c\u771f\u201dSc-F\u952e\u7684\u6b63\u70ed\u81a8\u80c0(PTE)\uff0c\u5176\u7cfb\u6570\u4e3a+18.4\u00d710<sup>-6<\/sup>K<sup>-1<\/sup>\uff0c\u4e0eSc-Sc\u7684NTE\u884c\u4e3a\u4e0d\u540c\u3002\u8fd9\u79cd\u201c\u5409\u4ed6\u5f26\u201d\u6548\u5e94\u88ab\u8ba4\u4e3a\u662f\u9020\u6210\u6676\u683cNTE\u7684\u539f\u56e0(<strong>\u56fe1b<\/strong>)\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-234049 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3975.png\" alt=\"\" width=\"609\" height=\"689\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3975.png 609w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3975-265x300.png 265w\" sizes=\"(max-width: 609px) 100vw, 609px\" \/><\/p>\n<p><strong>\u56fe1<\/strong> \uff08a\uff09 \u8d85\u4e34\u754c\u6d41\u4f53\u7684\u6e29\u5ea6\u4f9d\u8d56\u6676\u683c\u53c2\u6570\u548c\u70ed\u81a8\u80c0\u7cfb\u6570\uff08\u5de6\uff09\uff0c\u63d0\u51fa\u7684NTE\u6765\u6e90\uff08\u53f3\uff09\uff1b<span style=\"color: #999999;\">\u00a9 2010 ACS<\/span>\uff08b\uff09 \u52a0\u70ed\u65f6\u6700\u8fd1\u7684Sc\u2013F\u548cSc\u2013Sc\u7684\u5c40\u90e8\u539f\u5b50\u5bf9\u7684\u8ddd\u79bb<span style=\"color: #999999;\"> \u00a9 2016 ACS<\/span><\/p>\n<p><strong>\u94c1\u7535\u6709\u5e8f\u4e0eNTE<\/strong><\/p>\n<p>\u94c1\u7535\u6750\u6599\u5177\u6709\u5728\u5916\u7535\u573a\u4f5c\u7528\u4e0b\u53ef\u53cd\u8f6c\u7684\u81ea\u53d1\u6781\u5316(<em>P<\/em><sub>S<\/sub>)\u30021921\u5e74\uff0cValasek\u9996\u5148\u5728\u7f57\u606f\u76d0(\u56db\u6c34\u5408\u9152\u77f3\u9178\u94be\u94a0)\u4e2d\u53d1\u73b0\u4e86\u8fd9\u4e00\u7269\u7406\u6027\u8d28\uff0c\u5b83\u8868\u73b0\u51fa\u4e0e\u94c1\u78c1\u6750\u6599\u7c7b\u4f3c\u7684\u7535\u6781\u5316\u6ede\u56de\uff0c\u5e76\u5728\u81ea\u7136\u72b6\u6001\u4e0b\u4fdd\u6301\u6c38\u4e45\u6781\u5316\u3002\u76ee\u524d\u5df2\u77e5\u7684\u94c1\u7535\u6750\u6599\u6570\u4ee5\u5343\u8ba1\uff0c\u5305\u62ec\u65e0\u673a\u3001\u6709\u673a\u548c\u5206\u5b50\u5316\u5408\u7269\uff0c\u5e76\u5b9e\u9645\u7528\u4e8e\u94c1\u7535\u968f\u673a\u5b58\u53d6\u5b58\u50a8\u5668(RAM)\u3001\u70ed\u91ca\u7535\u7ea2\u5916\u4f20\u611f\u5668\u3001\u538b\u7535\u6362\u80fd\u5668\u7b49\u3002\u5728\u94c1\u7535\u6750\u6599\u4e2d\uff0c\u6781\u6027\u53ea\u5b58\u5728\u4e8e\u67d0\u4e00\u6e29\u5ea6\u4ee5\u4e0b\uff0c\u5373\u5c45\u91cc\u6e29\u5ea6(<em>T<\/em><sub>C<\/sub>)\u3002\u5728<em>T<\/em>c\u4ee5\u4e0a\uff0c\u5b83\u4eec\u8f6c\u53d8\u4e3a\u987a\u7535(PE)\u72b6\u6001\uff0c\u800c<em>P<\/em><sub>S<\/sub>\u76f8\u5e94\u5730\u6d88\u5931\u3002\u6709\u8da3\u7684\u662f\uff0c\u4e00\u4e9b\u94c1\u7535\u5316\u5408\u7269\u5728\u94c1\u7535\u6001\u4e0b\u8868\u73b0\u4e3aNTE\u6216\u51cf\u5f31\u7684PTE\uff0c\u800c\u5728<em>T<\/em><sub>C<\/sub>\u4e0a\u5219\u8868\u73b0\u51fa\u6b63\u5e38\u7684PTE\uff0c\u5982PbTiO<sub>3<\/sub>\uff0cSn<sub>2<\/sub>P<sub>2<\/sub>S<sub>6<\/sub>\uff0cPbNb<sub>2<\/sub>O<sub>6<\/sub>\u7b49\u3002\u663e\u7136\uff0c\u6676\u683cNTE\u4e0e\u94c1\u7535\u6027\u4e4b\u95f4\u5b58\u5728\u7740\u5bc6\u5207\u7684\u5173\u7cfb\u3002\u6700\u5178\u578b\u7684NTE\u94c1\u7535\u5316\u5408\u7269\u662fPbTiO<sub>3<\/sub>(PT)\u3002PT\u662f\u4e00\u79cd\u9499\u949b\u77ff\u7ed3\u6784\u7684\u5316\u5408\u7269\uff0c\u7531\u5171\u89d2\u7684TiO<sub>6<\/sub>\u516b\u9762\u4f53\u7ec4\u6210\uff0c\u800cPb\u539f\u5b50\u4f4d\u4e8e\u7acb\u65b9\u516b\u9762\u4f53\u4f4d\u7f6e(<strong>\u56fe2<\/strong>)\u3002\u5b83\u5728\u94c1\u7535\u72b6\u6001\u4e0b\u5f62\u6210\u56db\u65b9<em>P<\/em>4 <em>mm<\/em>\u7ed3\u6784\uff0c\u5728PE\u72b6\u6001\u4e0b\u5f62\u6210\u7acb\u65b9<em>Pm<\/em>3\u0305<em>m<\/em>\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-234050 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3976.png\" alt=\"\" width=\"524\" height=\"231\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3976.png 524w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3976-300x132.png 300w\" sizes=\"(max-width: 524px) 100vw, 524px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe2<\/strong> PT\u5728\u5ba4\u6e29(RT)\u548c\u9ad8\u6e29(HT)\u4e0b\u7684\u6676\u4f53\u7ed3\u6784<span style=\"color: #999999;\"> \u00a9 2022 ACS<\/span><\/p>\n<p><strong>\u78c1\u6709\u5e8f\u4e0eNTE<\/strong><\/p>\n<p>\u5404\u79cd\u78c1\u6027\u6750\u6599\u90fd\u8868\u73b0\u51faNTE\uff0c\u5982\u5408\u91d1\u3001\u6c27\u5316\u7269\u3001\u548c\u6c2e\u5316\u7269\u3002\u8fd9\u4e9b\u53cd\u5e38\u7684\u70ed\u81a8\u80c0\u884c\u4e3a\u4e0e\u5b83\u4eec\u7684\u81ea\u53d1\u78c1\u5e8f\u5bc6\u5207\u76f8\u5173\uff0c\u8fd9\u4e9b\u81ea\u53d1\u78c1\u5e8f\u5728\u78c1\u5e8f\u6e29\u5ea6\u4ee5\u4e0b\u4ea7\u751f\u4f53\u79ef\u53d8\u5316(\u5373\u78c1\u4f53\u79ef\u6548\u5e94\uff0cMVEs)\u3002\u5927\u591a\u6570\u78c1\u6027\u6750\u6599\u5177\u6709\u5fae\u5f31\u7684\u78c1\u81f4\u4f38\u7f29\u6548\u5e94\uff0c\u5176PTE\u884c\u4e3a\u4e3b\u8981\u53d7\u58f0\u5b50\u632f\u52a8\u7684\u5f71\u54cd\u3002\u5f53MVE\u5728\u52a0\u70ed\u65f6\u8d85\u8fc7\u6676\u683c\u4f53\u79ef\u4e0a\u7684\u58f0\u5b50\u8d21\u732e\u65f6\uff0c\u5c06\u53d1\u751fNTE\u884c\u4e3a\u3002\u8fd9\u4e00\u73b0\u8c61\u6700\u65e9\u662f\u7531Guillaume\u4e8e1897\u5e74\u5728\u9762\u5fc3\u7acb\u65b9\u94c1\u548c\u954d\u5408\u91d1\u4e2d\u53d1\u73b0\u7684\uff0c\u8fd9\u79cd\u7acb\u65b9\u5408\u91d1\u7684\u6210\u5206\u5728Fe<sub>65<\/sub>Ni<sub>35<\/sub>\u5de6\u53f3\uff0c\u5728\u5ba4\u6e29\u9644\u8fd1\u5448\u73b0\u4e0d\u53d8\u7684\u957f\u5ea6\uff0c\u5728300K\u65f6\uff0c\u03b1<sub>L<\/sub>\u4e3a1.2\u00d710<sup>-6<\/sup>K<sup>-1\u00a0<\/sup>(<strong>\u56fe3<\/strong>)\u3002Fe-Ni\u5408\u91d1\u7684\u53cd\u5e38\u70ed\u81a8\u80c0\u884c\u4e3a\u88ab\u79f0\u4e3a\u201c\u56e0\u74e6\u6548\u5e94\uff08Invar effect\uff09\u201d\uff0c\u540e\u6765\u88ab\u63a8\u5e7f\u5230\u5904\u7406\u78c1\u6027\u6750\u6599\u7684\u4f4e(\u51e0\u4e4e\u4e3a\u96f6)\u70ed\u81a8\u80c0\u4e2d\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-234051 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3977.png\" alt=\"\" width=\"493\" height=\"517\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3977.png 493w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3977-286x300.png 286w\" sizes=\"(max-width: 493px) 100vw, 493px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe3<\/strong> \u56e0\u74e6\u5408\u91d1Fe<sub>65<\/sub>Ni<sub>35<\/sub>\u7684\u70ed\u81a8\u80c0\u884c\u4e3a <span style=\"color: #999999;\">\u00a9 2015 RSC<\/span><\/p>\n<p><strong>NTE<\/strong><strong>\u5316\u5408\u7269\u7684\u5c40\u57df\u7ed3\u6784\u7814\u7a76<\/strong><\/p>\n<p>\u5e73\u5747\u800c\u8a00\uff0c\u5316\u5b66\u8def\u7ebf\u7684\u6676\u683c\u5b9a\u5236\u5e76\u4e0d\u603b\u662f\u5c40\u9650\u4e8e\u957f\u671f\u4ee5\u6765\u7684\u7ed3\u6784\u5b9a\u5236\u3002\u4ece\u66f4\u5e7f\u6cdb\u7684\u610f\u4e49\u4e0a\u8bb2\uff0c\u5316\u5b66\u591a\u6837\u6027\u76f4\u63a5\u6307\u7684\u662f\u6700\u8fd1\u7684\u5316\u5b66\u952e\u3001\u77ed\u7a0b\u914d\u4f4d\u5bf9\u79f0\u6027\u3001\u7ed3\u6784\u5355\u5143\u7684\u7ec4\u88c5\u5f62\u5f0f\u4ee5\u53ca\u6709\u5e8f\u53c2\u6570\u4e0e\u6e29\u5ea6\u7684\u76f8\u4e92\u4f5c\u7528\u5173\u7cfb\u3002\u4e0e\u7531\u6676\u4f53\u542b\u91cf\u786e\u5b9a\u539f\u5b50\u4f4d\u7f6e\u76f8\u6bd4\uff0c\u53d8\u6e29\u6761\u4ef6\u4e0b\u6676\u683c\u7684\u5f80\u5f80\u53d7\u539f\u5b50\u76f8\u5bf9\u4f4d\u7f6e\u7684\u63a7\u5236\uff0c\u56e0\u4e3a\u5b83\u4e0e\u5316\u5b66\u952e\u548c\u632f\u52a8\u6709\u5bc6\u5207\u7684\u8026\u5408\u5173\u7cfb\u3002\u5c40\u90e8\u7ed3\u6784\u5728\u51e0\u4e2a\u5230\u51e0\u5341\u4e2a\u5355\u6676\u80de\u7684\u8303\u56f4\u5185\uff0c\u53ef\u8868\u73b0\u51fa\u66f4\u591a\u7684\u7ed3\u6784\u591a\u6837\u6027\u548c\u975e\u5e38\u89c4\u7684\u7ed3\u6784-\u529f\u80fd\u5173\u7cfb\u3002\u5bf9\u8fd9\u4e9b\u7ed3\u6784\u7684\u7406\u89e3\u5f88\u5927\u7a0b\u5ea6\u4e0a\u4f9d\u8d56\u4e8e\u76f8\u5173\u7684\u63a2\u6d4b\u6280\u672f\uff0c\u5982PDF\u3001XAFS\u548c\u5176\u4ed6\u5149\u8c31\u65b9\u6cd5\u3002\u4ece\u5c40\u90e8\u7ed3\u6784\u7684\u89d2\u5ea6\u770b\uff0cNTE\u6750\u6599\u4e2d\u6676\u683c\u5b9a\u5236\u7684\u4e00\u4e9b\u65b0\u5185\u5bb9\u4e3a\u5316\u5b66\u5b9a\u5236\u548c\u6df1\u5165\u7406\u89e3NTE\u7684\u7ed3\u6784\u63d0\u4f9b\u4e86\u65b0\u7684\u65b9\u5411\u3002\u5728\u65e9\u671f\u7684\u7814\u7a76\u4e2d\uff0c\u5bf9NTE\u5316\u5408\u7269\u7684\u5c40\u57df\u7ed3\u6784\u7684\u6d1e\u5bdf\u6765\u81ea\u4e8e\u8868\u89c2\u952e\u957f\u548c\u5b9e\u9645\u952e\u957f\u7684\u4e89\u8bba\u3002\u8fd9\u79cd\u7ed3\u6784\u8bc6\u522b\u4e0a\u7684\u5dee\u5f02\u53ef\u4ee5\u5728\u8bb8\u591a\u9aa8\u67b6\u7c7bNTE\u5316\u5408\u7269\u4e2d\u627e\u5230\u3002\u5728\u65e9\u671f\u7684\u7814\u7a76\u4e2d\uff0c\u77f3\u82f1\u662f\u901a\u8fc7 <span class=\"fontstyle0\">Rietveld re<\/span><span class=\"fontstyle2\">fi<\/span><span class=\"fontstyle0\">nement<\/span> <br \/>\n \u7528\u76f8\u90bb\u7684Si-O\u952e\u7684NTE\u6d4b\u5b9a\u7684(<strong>\u56fe4<\/strong>)\uff0c\u4e5f\u5c31\u662f\u5728\u4e2d\u5b50\u603b\u6563\u5c04\u7684\u57fa\u7840\u4e0a\uff0c\u7528\u6b63\u5e38PTE\u786e\u5b9a\u4e86Si-O\u7684\u5b9e\u9645\u952e\u957f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-234052\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3979.png\" alt=\"\" width=\"722\" height=\"320\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3979.png 722w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3979-300x133.png 300w\" sizes=\"(max-width: 722px) 100vw, 722px\" \/><\/p>\n<p>\u56fe4. (a)\u7531PDF(\u5f00\u73af)\u548c <span class=\"fontstyle0\">Rietveld re<\/span><span class=\"fontstyle2\">fi<\/span><span class=\"fontstyle0\">nement<\/span>(\u586b\u5145\u6b63\u65b9\u5f62)\u5f97\u5230\u7684Si-O\u952e\u8ddd\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\uff1b(b)\u5b9e\u9645\u952e\u957f\u4e0e\u8868\u89c2\u952e\u957f\u4e4b\u95f4\u7684\u5dee\u989d\u793a\u610f\u56fe <span style=\"color: #999999;\">\u00a92000 IOP<\/span><\/p>\n<p><strong>\u7eb3\u7c73\/\u754c\u9762\u5bf9NTE\u7684\u5f71\u54cd<\/strong><\/p>\n<p>\u7eb3\u7c73\u6750\u6599\u5728\u4e09\u7ef4\u7a7a\u95f4\u4e2d\u5177\u6709\u7eb3\u7c73\u5c3a\u5bf8\u7684\u9650\u5236\uff0c\u8fd9\u6253\u7834\u4e86\u6676\u4f53\u5b66\u7684\u5468\u671f\u6027\u5e73\u79fb\u7279\u6027\u3002\u5728\u7eb3\u7c73\u72b6\u6001\u4e0b\uff0c\u53ef\u4ee5\u5b9e\u73b0\u8bb8\u591a\u65b0\u51fa\u73b0\u7684\u7279\u6b8a\u7269\u7406\u6027\u8d28\uff0c\u5982\u5c0f\u5c3a\u5bf8\u6548\u5e94\u3001\u8868\u9762\/\u754c\u9762\u6548\u5e94\u6216\u91cf\u5b50\u76f8\u5173\u6548\u5e94\u3002\u800cNTE\u6676\u683c\u7684\u5b9a\u5236\u662f\u4e00\u4e2a\u65b0\u7684\u53d1\u5c55\u65b9\u5411\uff0c\u76ee\u524d\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u70ed\u81a8\u80c0\u53ef\u63a7\u529f\u80fd\u7eb3\u7c73\u5668\u4ef6\u7684\u7814\u5236\u6210\u529f\u4e3a\u8bbe\u8ba1\u5177\u6709\u9ad8\u70ed\u7a33\u5b9a\u6027\u548c\u9ad8\u6027\u80fd\u7684\u7eb3\u7c73\u5668\u4ef6\u63d0\u4f9b\u4e86\u91cd\u8981\u7684\u57fa\u7840\u3002\u968f\u7740\u9897\u7c92\u5c3a\u5bf8\u7684\u51cf\u5c0f\u6216\u754c\u9762\u7684\u5f15\u5165\uff0c\u8868\u9762\u5f1b\u8c6b\/\u91cd\u6784\u3001\u754c\u9762\u5e94\u53d8\u3001\u5316\u5b66\u914d\u4f4d\u7f3a\u5931\u3001\u6676\u683c\u7f3a\u9677\u7b49\u65b0\u7684\u7ed3\u6784\u7279\u5f81\u5728\u8868\u9762\u6216\u754c\u9762\u51fa\u73b0\u3002\u8fd9\u4e9b\u65b0\u7684\u7ed3\u6784\u5728\u6676\u683c\u70ed\u81a8\u80c0\u7684\u88c1\u526a\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u4e86\u5927\u91cf\u7684\u70b9\u5207\u5272\u3002\u5728\u65e9\u671f\u7684\u7814\u7a76\u4e2d\uff0c\u4e0e\u5c3a\u5bf8\u76f8\u5173\u7684\u6027\u8d28\u5728\u65b0\u7684\u7ed3\u6784\u5173\u7cfb\u4e2d\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u5173\u6ce8\uff0c\u56e0\u6b64\u5728\u7eb3\u7c73\u6837\u54c1\u6216\u8584\u819c\u4e2d\u53d1\u73b0\u4e86\u8bb8\u591a\u5f02\u5e38\u7684\u70ed\u884c\u4e3a\u3002\u4e00\u822c\u60c5\u51b5\u4e0b\uff0c\u6676\u683c\u7684\u70ed\u81a8\u80c0\u7cfb\u6570\u968f\u7740\u7c92\u5f84\u7684\u51cf\u5c0f\u800c\u589e\u5927\u3002\u7136\u800c\uff0c\u901a\u8fc7\u4f4e\u80fd\u7535\u5b50\u884d\u5c04\uff0c\u89c2\u5bdf\u5230Mg(101\u03050)\u548cAl(110)\u8868\u9762\u7684\u53cd\u5e38\u70ed\u6536\u7f29\u3002\u5728\u5316\u5b66\u5438\u9644\u6c22\u7684\u70ed\u8131\u9644\u4f5c\u7528\u4e0b\uff0c\u7528EXAFS\u539f\u4f4d\u5206\u6790\u4e86\u7eb3\u7c73Pt\u4e2d\u7684NTE\u952e\u3002\u8d1f\u8f7d\u5728\u03b3-Al<sub>2<\/sub>O<sub>3<\/sub>\u4e0a\u76840.9 nm Pt\u7eb3\u7c73\u7c92\u5b50\u4e0a\uff0cPt-Pt\u952e\u7684\u5e73\u5747\u03b1<sub>L<\/sub>\u503c\u53ef\u8fbe\u221224\u00d710<sup>-6<\/sup>K<sup>-1<\/sup>\u3002Li\u7b49\u5b66\u8005\u89c2\u5bdf\u4e86\u6c14\u4f53\u51b7\u51dd\u6cd5\u5408\u6210\u76844 nm\u91d1\u7eb3\u7c73\u7c92\u5b50\u7684\u53cd\u5e38\u70ed\u884c\u4e3a\u3002\u4ece\u4f4e\u6e29\u5230100K\uff0cPTE\u7684\u503c\u4e3a+32\u00d710<sup>-6<\/sup>K<sup>-1<\/sup>\uff0c\u662f\u5757\u72b6Au\u76842.3\u500d\u3002\u5947\u602a\u7684\u662f\uff0c\u4ecePTE\u5230NTE\u7684\u70ed\u81a8\u80c0\u4ea4\u53c9\u53ef\u4ee5\u5728125K\u5de6\u53f3\u5f97\u5230\u9a8c\u8bc1(<strong>\u56fe5<\/strong>)\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-234053 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3980.png\" alt=\"\" width=\"396\" height=\"670\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3980.png 396w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3980-177x300.png 177w\" 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