{"id":233732,"date":"2022-03-03T06:32:01","date_gmt":"2022-03-02T22:32:01","guid":{"rendered":"\/\/m.iemloyee.com\/?p=233732"},"modified":"2022-03-02T21:33:28","modified_gmt":"2022-03-02T13:33:28","slug":"science-advances%ef%bc%9a%e4%b8%80%e7%a7%8d%e5%88%a9%e7%94%a8%e7%b1%bb%e5%85%b1%e4%bb%b7%e6%b0%a2%e9%94%ae%e7%9a%84%e7%9b%b8%e4%ba%92%e4%bd%9c%e7%94%a8%e5%ae%9e%e7%8e%b0%e7%9a%84%e9%80%9a%e7%94%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=233732","title":{"rendered":"Science Advances\uff1a\u4e00\u79cd\u5229\u7528\u7c7b\u5171\u4ef7\u6c22\u952e\u7684\u76f8\u4e92\u4f5c\u7528\u5b9e\u73b0\u7684\u901a\u7528\u6c34\u51dd\u80f6\u7f51\u7edc\u4fee\u590d\u7b56\u7565"},"content":{"rendered":"<p><strong><span style=\"color: #003366;\">\u6c22\u952e<\/span><\/strong>\u53ef\u4ee5\u8d4b\u4e88\u6c34\u51dd\u80f6\u5ef6\u5c55\u6027\u3001\u97e7\u6027\u548c\u81ea\u6211\u4fee\u590d\u80fd\u529b\u3002\u7136\u800c\uff0c\u5e38\u89c4\u6c22\u952e\u7684\u589e\u5f3a\u4f5c\u7528\u53d7\u5230\u5176\u5f31\u76f8\u4e92\u4f5c\u7528\u5f3a\u5ea6\u7684\u4e25\u91cd\u9650\u5236\u3002\u5728\u81ea\u7136\u754c\u4e2d\uff0c\u7531\u4e8e\u6d77\u85fb\u7cd6\u53ef\u9ad8\u6548\u8bf1\u5bfc\u6c22\u952e\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u56e0\u6b64\u4e00\u4e9b\u751f\u7269\u53ef\u4ee5\u5fcd\u53d7\u6781\u7aef\u7684\u6761\u4ef6\u3002<\/p>\n<p>\u53d7\u6b64\u542f\u53d1\uff0c\u6765\u81ea\u6d59\u6c5f\u5927\u5b66\u7684\u66f2\u7ecd\u5174\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7<strong><span style=\"color: #003366;\">\u7c7b\u5171\u4ef7\u6c22\u952e\u4f5c\u7528\u5b9e\u73b0\u6d77\u85fb\u7cd6\u7f51\u7edc\u4fee\u590d<\/span><\/strong>\u7684\u7b56\u7565\uff0c\u4ee5\u6539\u5584\u6c34\u51dd\u80f6\u7684\u529b\u5b66\u6027\u80fd\uff0c\u540c\u65f6\u4f7f\u5176\u80fd\u591f\u8010\u53d7\u6781\u7aef\u73af\u5883\u6761\u4ef6\uff0c\u5e76\u4fdd\u6301\u5408\u6210\u7684\u7b80\u5355\u6027\uff0c\u8fd9\u88ab\u8bc1\u660e\u5bf9\u5404\u79cd\u6c34\u51dd\u80f6\u90fd\u662f\u6709\u7528\u7684\u3002\u6d77\u85fb\u7cd6\u6539\u6027\u6c34\u51dd\u80f6\u7684\u529b\u5b66\u6027\u80fd(\u5305\u62ec<strong><span style=\"color: #003366;\">\u5f3a\u5ea6\u3001\u4f38\u957f\u6027\u548c\u65ad\u88c2\u97e7\u6027<\/span><\/strong>)\u5728\u8f83\u5bbd\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u5f97\u5230\u663e\u8457\u63d0\u9ad8\u3002\u5728\u8131\u6c34\u540e\uff0c\u6539\u6027\u6c34\u51dd\u80f6\u4fdd\u6301\u5176\u8d85\u5f39\u6027\u548c\u529f\u80fd\uff0c\u800c\u672a\u6539\u6027\u7684\u6c34\u51dd\u80f6\u5d29\u89e3\u3002\u8fd9\u4e00\u7b56\u7565\u4e3a\u5408\u6210\u5177\u6709\u6781\u5f3a\u8010\u53d7\u6027\u3001\u9ad8\u5ea6\u53ef\u4f38\u7f29\u6027\u548c\u97e7\u6027\u7684\u6c34\u51dd\u80f6\u63d0\u4f9b\u4e86\u4e00\u79cd\u901a\u7528\u7684\u65b9\u6cd5\uff0c\u4f7f\u5176\u5728\u5404\u79cd\u6761\u4ef6\u4e0b\u90fd\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u524d\u666f\u3002\u76f8\u5173\u5de5\u4f5c\u4ee5\u9898\u4e3a\u201c<strong>A versatile hydrogel network\u2013repairing strategy achieved by the covalent-like hydrogen bond interaction<\/strong>\u201d\u7684\u7814\u7a76\u6027\u6587\u7ae0\u5728<strong><em>Science Advances<\/em><\/strong>\u4e0a\u53d1\u8868\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-233733 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3783.png\" alt=\"\" width=\"745\" height=\"285\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3783.png 745w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3783-300x115.png 300w\" sizes=\"(max-width: 745px) 100vw, 745px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>[\u56fe\u6587\u5206\u6790]<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p>\u6c34\u51dd\u80f6\u7f51\u7edc\u5305\u542b\u5404\u79cd\u7f3a\u9677;\u5305\u62ec\u60ac\u5782\u94fe\uff08\u4f8b\u5982\uff0c\u94fe\u7aef\u6216\u5206\u652f\u94fe\uff09\u548c\u73af\u7f3a\u9677\u3002\u5c06\u6d77\u85fb\u7cd6\u52a0\u5165<strong>\u805a\u4e19\u70ef\u9170\u80fa\uff08PAAm\uff09<\/strong>\u6c34\u51dd\u80f6\u540e\uff0c\u6d77\u85fb\u7cd6\u5206\u5b50\u4e0e\u957f\u805a\u5408\u7269\u94fe\u4e2d\u7684\u8bb8\u591a\u6781\u6027\u57fa\u56e2\u4e4b\u95f4\u53ef\u4ee5\u5f62\u6210\u5f3a\u6c22\u952e\u3002\u6d77\u85fb\u7cd6\u4e0e\u6c34\u51dd\u80f6\u7f51\u7edc\u4e4b\u95f4\u6709\u8bb8\u591a\u76f8\u4e92\u4f5c\u7528\u7684\u65b9\u5f0f\uff08<strong>\u56fe1A<\/strong>\uff09\uff0c\u4f8b\u5982\uff0c\u60ac\u94fe\u53ef\u4ee5\u901a\u8fc7\u6d77\u85fb\u7cd6\u5728\u591a\u4e2a\u76f8\u4e92\u4f5c\u7528\u70b9\u5904\u4e0e\u5176\u5b83\u60ac\u94fe\u6216\u4ea4\u8054\u805a\u5408\u7269\u94fe\u8fde\u63a5\uff0c\u4ea4\u8054\u805a\u5408\u7269\u94fe\u4e5f\u53ef\u4ee5\u901a\u8fc7\u6d77\u85fb\u7cd6\u4e0e\u5176\u5b83\u4ea4\u8054\u805a\u5408\u7269\u94fe\u76f8\u4e92\u4f5c\u7528\u7b49\u7b49\u3002\u6240\u6709\u8fd9\u4e9b\u76f8\u4e92\u4f5c\u7528\u65b9\u5f0f\u90fd\u53ef\u4ee5\u52a0\u5f3a\u6c34\u51dd\u80f6\u7f51\u7edc\u3002\u4e3a\u4e86\u5b9a\u91cf\u7814\u7a76\u6c34\u51dd\u80f6\u4e2d\u6c34\u5206\u5b50\uff08W\uff09\u3001\u6d77\u85fb\u7cd6\u5206\u5b50\uff08T\uff09\u548cPAAm\u5206\u5b50\uff08P\uff09\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u5f3a\u5ea6\uff08<strong>\u56fe1B<\/strong>\uff09\uff0c\u672c\u6587\u5229\u7528Materials Studio\u8fdb\u884c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u6a21\u62df\u5206\u5b50\u7ed3\u6784\u5e76\u8ba1\u7b97\u76f8\u4e92\u4f5c\u7528\u80fd\u3002\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\uff08FTIR\uff09\u548c\u8d28\u5b50\u6838\u78c1\u5171\u632f\uff081H-NMR\uff09\u5149\u8c31\u4e5f\u7528\u4e8e\u8868\u5f81\u6d77\u85fb\u7cd6\u8bf1\u5bfc\u7684\u6c22\u952e\u3002PAAm\u6c34\u51dd\u80f6\u5728N\u2500H\u7684\u62c9\u4f38\u632f\u52a8\u4e3a3478\u548c3206 cm<sup>\u2212<\/sup><sup>1<\/sup>\uff0c\u5728C\u2550O\u7684\u62c9\u4f38\u632f\u52a8\u4e3a1705 cm<sup>\u2212<\/sup><sup>1<\/sup>\u5904\u663e\u793a\u51fa\u51e0\u4e2a\u7279\u5f81\u5cf0\u3002\u6d77\u85fb\u7cd6\u548cPAAm\u94fe\u4e4b\u95f4\u5206\u5b50\u95f4\u6c22\u952e\u7684\u5f62\u6210\u662fN\u2500H\u548cC\u2550O\u5cf0\u4f4d\u79fb\u7684\u539f\u56e0\uff08<strong>\u56fe1C<\/strong>\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-233734 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3784.png\" alt=\"\" width=\"762\" height=\"721\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3784.png 762w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3784-300x284.png 300w\" sizes=\"(max-width: 762px) 100vw, 762px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe1<\/strong> \u901a\u8fc7\u7c7b\u5171\u4ef7\u6c22\u952e\u4f5c\u7528\u5b9e\u73b0\u7684\u6d77\u85fb\u7cd6\u7f51\u7edc\u4fee\u590d\u7b56\u7565 <span style=\"color: #999999;\">\u00a9 2022 The Authors<\/span><\/p>\n<p>&nbsp;<\/p>\n<p>\u672c\u6587\u901a\u8fc7\u5411PAAm\u6c34\u51dd\u80f6\u4e2d\u6dfb\u52a00\uff0c10\uff0c20\u548c30wt%\u6d77\u85fb\u7cd6\u6765\u5408\u6210\u4e00\u7cfb\u5217\u6c34\u51dd\u80f6\uff0c\u5e76\u901a\u8fc7\u6d4b\u91cf\u7f3a\u53e3\u548c\u5b8c\u6574\u6837\u54c1\u7684\u5e94\u529b\u62c9\u4f38\u66f2\u7ebf\u6765\u8868\u5f81\u8fd9\u4e9b\u6c34\u51dd\u80f6\u7684\u673a\u68b0\u6027\u80fd\u3002<strong>\u56fe2A<\/strong>\u5206\u522b\u663e\u793a\u4e86\u5ba4\u6e29\u4e0b0\uff0c10\uff0c20\u548c30 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mm\u7684\u8fb9\u7f18\u5207\u5272\u5f15\u5165\u6837\u54c1\u4e2d\uff08<strong>\u56fe2B<\/strong>\uff09\u3002\u88c2\u9699\u97e7\u6027\u5206\u522b\u4e3a 0%\u300110%\u300120%\u548c30 wt%\u6d77\u85fb\u7cd6\u6539\u6027PAAm\u6c34\u51dd\u80f6\uff0c\u5206\u522b\u6d4b\u5f97\u4e3a474\u30011163\u30012039\u548c5116 J\/m<sup>2<\/sup>\u3002\u5f88\u660e\u663e\uff0c\u65ad\u88c2\u97e7\u6027\u968f\u7740\u6d77\u85fb\u7cd6\u542b\u91cf\u7684\u589e\u52a0\u800c\u5927\u5927\u589e\u52a0\uff08<strong>\u56fe2C<\/strong>\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-233735 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3785.png\" alt=\"\" width=\"894\" height=\"614\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3785.png 894w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3785-300x206.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/03\/3785-768x527.png 768w\" sizes=\"(max-width: 894px) 100vw, 894px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe2<\/strong> \u6d77\u85fb\u7cd6\u7f51\u7edc\u4fee\u590d\u7b56\u7565\u5bf9PAAm\u6c34\u51dd\u80f6\u5ba4\u6e29\u529b\u5b66\u6027\u80fd\u7684\u589e\u5f3a\u4f5c\u7528\u00a0<span style=\"color: #999999;\">\u00a9 2022 The Authors<\/span><\/p>\n<p>&nbsp;<\/p>\n<p>\u7531\u4e8e\u6d77\u85fb\u7cd6\u53ef\u4ee5\u8d4b\u4e88\u6c34\u51dd\u80f6\u6297\u51bb\u80fd\u529b\uff0c\u56e0\u6b64\u672c\u6587\u8fdb\u4e00\u6b65\u63a2\u7d22\u4e86\u6d77\u85fb\u7cd6\u4fee\u9970\u7684PAAm\u6c34\u51dd\u80f6\u5728\u4f4e\u6e29\u4e0b\u7684\u529b\u5b66\u884c\u4e3a\u3002\u4e3a\u6b64\uff0c\u5728\u221215\u2103\u4e0b\u6d4b\u91cfPAAm\u6c34\u51dd\u80f6\u4e0e0\uff0c10\uff0c20\u548c30 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