{"id":233241,"date":"2022-02-22T06:53:20","date_gmt":"2022-02-21T22:53:20","guid":{"rendered":"\/\/m.iemloyee.com\/?p=233241"},"modified":"2022-02-21T20:53:29","modified_gmt":"2022-02-21T12:53:29","slug":"%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6%e7%8e%8b%e8%ae%adnat-chem-%ef%bc%9a%e5%9b%a2%e7%b0%87%e6%9e%84%e7%ad%91%e7%9a%84%e5%85%a8%e6%96%b0%e4%ba%9a%e7%ba%b3%e7%b1%b3%e4%ba%8c%e7%bb%b4%e6%9d%90%e6%96%99","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=233241","title":{"rendered":"\u6e05\u534e\u5927\u5b66\u738b\u8badNat. Chem.\uff1a\u56e2\u7c07\u6784\u7b51\u7684\u5168\u65b0\u4e9a\u7eb3\u7c73\u4e8c\u7ef4\u6750\u6599\u2014\u2014\u56e2\u7c07\u7c7b\u70ef"},"content":{"rendered":"<p style=\"text-align: center;\"><strong>\u4e00\u3001\u5f15\u8a00<\/strong><\/p>\n<p>\u4ee5\u77f3\u58a8\u70ef\u4e3a\u4ee3\u8868\u7684\u4e8c\u7ef4\u5c42\u72b6\u6750\u6599\u56e0\u5176\u72ec\u7279\u7684\u5c42\u5185\u539f\u5b50\u8fde\u63a5\u65b9\u5f0f\uff0c\u8868\u73b0\u51fa\u663e\u8457\u7684\u7535\u5b50\u79bb\u57df\u884c\u4e3a\uff0c\u7531\u6b64\u5e26\u6765\u4e86\u51fa\u4f17\u7684\u7269\u7406\u548c\u5316\u5b66\u6027\u8d28\u3002\u7531\u4e8e\u4f20\u7edf\u65e0\u673a\u7eb3\u7c73\u6676\u5404\u5411\u540c\u6027\u7684\u5f62\u72b6\u548c\u8868\u9762\u6027\u8d28\uff0c\u5176\u81ea\u7ec4\u88c5\u901a\u5e38\u5f97\u5230\u5bc6\u5806\u79ef\u6a21\u5f0f\u7684\u8d85\u7ed3\u6784\uff0c\u56e0\u800c\u96be\u4ee5\u5f97\u5230\u4e8c\u7ef4\u7ec4\u88c5\u7ed3\u6784\u3002\u56e2\u7c07\u5177\u6709\u786e\u5b9a\u7684\u539f\u5b50\u6570\u4e0e\u660e\u786e\u7684\u7ed3\u6784\uff0c\u662f\u4e00\u7c7b\u4ecb\u4e8e\u539f\u5b50\/\u5206\u5b50\u4e0e\u7eb3\u7c73\u6676\u4f53\u4e4b\u95f4\u7684\u51dd\u805a\u6001\u7269\u8d28\uff0c\u56e2\u7c07\u7684\u4e9a\u7eb3\u7c73\u5c3a\u5bf8\u4f7f\u5f97\u5355\u5206\u5b50\u7ea7\u522b\u7684\u4f5c\u7528\u529b\u5373\u53ef\u4e3b\u5bfc\u5176\u81ea\u7ec4\u88c5\u884c\u4e3a\uff0c\u53ef\u4f5c\u4e3a\u201c\u8d85\u7ea7\u539f\u5b50\u201d\u6784\u5efa\u5168\u65b0\u7684\u4e9a\u7eb3\u7c73\u5c3a\u5ea6\u4f4e\u7ef4\u6750\u6599\u4f53\u7cfb\u3002\u56e2\u7c07\u7535\u5b50\u7ed3\u6784\u3001\u5316\u5b66\u6027\u8d28\u4e0e\u539f\u5b50\/\u5206\u5b50\u6709\u7c7b\u4f3c\u6027\uff0c\u56e2\u7c07\u7ec4\u88c5\u4f53\u4f5c\u4e3a\u4e00\u7c7b\u201c\u8d85\u7ea7\u5206\u5b50\u201d\uff0c\u5176\u4e2d\u7535\u5b50\u53ef\u80fd\u88ab\u591a\u4e2a\u56e2\u7c07\u6240\u5171\u4eab\uff0c\u5bf9\u4e8e\u9ad8\u5ea6\u6709\u5e8f\u7684\u4e8c\u7ef4\u56e2\u7c07\u7ec4\u88c5\u4f53\uff0c\u7535\u5b50\u5728\u5177\u6709\u76f8\u540c\u5316\u5b66\u73af\u5883\u7684\u56e2\u7c07\u95f4\u7684\u79bb\u57df\u884c\u4e3a\uff0c\u53ef\u80fd\u5e26\u6765\u5f02\u4e4e\u5bfb\u5e38\u7684\u7535\u5b50\u7ed3\u6784\u548c\u50ac\u5316\u6027\u8d28\u3002<\/p>\n<p>\u5728\u672c\u6587\u4e2d\uff0c\u4f5c\u8005\u6210\u529f\u5236\u5907\u51fa\u4e00\u7c7b\u57fa\u4e8e\u591a\u91d1\u5c5e\u6c27\u7c07\uff08POM\uff09\u7684\u65b0\u578b\u7c7b\u77f3\u58a8\u70ef\u6750\u6599\u2014\u2014\u201c\u56e2\u7c07\u7c7b\u70ef\u201d\u3002\u4e0e\u4ee5\u5f80\u4e8c\u7ef4\u6750\u6599\u4f53\u7cfb\u4ee5\u539f\u5b50\u3001\u5206\u5b50\u4e3a\u7ed3\u6784\u57fa\u5143\u4e0d\u540c\uff0c\u8be5\u56e2\u7c07\u7c7b\u70ef\u4ee5\u4e9a\u7eb3\u7c73\u5c3a\u5ea6\u7684\u56e2\u7c07\u4e3a\u7ed3\u6784\u57fa\u5143\uff0c\u6784\u7b51\u4e86\u4e00\u7c7b\u65b0\u578b\u7684\u4e9a\u7eb3\u7c73\u4e8c\u7ef4\u6750\u6599\u4f53\u7cfb\u300213\u79cd\u591a\u91d1\u5c5e\u6c27\u7c07\u5747\u53ef\u7528\u4e8e\u56e2\u7c07\u7c7b\u70ef\u7684\u6784\u5efa\uff0c\u8868\u660e\u4e86\u56e2\u7c07\u57fa\u81ea\u7ec4\u88c5\u7684\u666e\u9002\u6027\u3002\u76f8\u6bd4\u4e8e\u5176\u4ed6\u56e2\u7c07\u6750\u6599\uff0c\u56e2\u7c07\u7c7b\u70ef\u5bf9\u70ef\u70c3\u73af\u6c27\u5316\u53cd\u5e94\u5177\u6709\u66f4\u9ad8\u7684\u50ac\u5316\u6548\u7387\u548c\u7a33\u5b9a\u6027\u3002\u56e2\u7c07\u7c7b\u70ef\u5c42\u4e2d\u7684\u7535\u5b50\u79bb\u57df\u53ef\u4ee5\u6709\u6548\u5730\u964d\u4f4e\u73af\u6c27\u5316\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\uff0c\u5e76\u5c06\u8f6c\u6362\u9891\u7387(TOF)\u63d0\u9ad8\u81f34.16 <em><i>h<\/i><\/em><em><sup><i>\u2212<\/i><\/sup><\/em><em><sup><i>1<\/i><\/sup><\/em>\uff0c\u662f\u672a\u7ec4\u88c5\u56e2\u7c07\u768476.5\u500d\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u4e8c\u3001\u7814\u7a76\u8fdb\u5c55<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u6e05\u534e\u5927\u5b66<\/strong><strong><b>\u738b\u8bad<\/b><\/strong><strong>\u56e2\u961f\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728<em>Nat. Chem.<\/em>\u4e0a\u53d1\u8868\u6587\u7ae0\uff0c\u9898\u4e3a\u201c<strong>Self-assembly of polyoxometalate clusters into two-dimensional clusterphene structures featuring hexagonal pores<\/strong>\u201d\u3002\u738b\u8bad\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u591a\u91d1\u5c5e\u6c27\u7c07\u81ea\u7ec4\u88c5\u884c\u6210\u7684\u5177\u6709\u5747\u5300\u516d\u65b9\u5b54\u548c\u9762\u5185\u7535\u5b50\u79bb\u57df\u7279\u6027\u7684\u65b0\u578b\u4e9a\u7eb3\u7c73\u4e8c\u7ef4\u6750\u6599\u4f53\u7cfb\u2014\u2014\u201c\u56e2\u7c07\u7c7b\u70ef\u201d\u3002\u7a00\u571f\u539f\u5b50\u53d6\u4ee3\u7684Keggin\u578b\u56e2\u7c07[LnPW<sub>11<\/sub>O<sub>39<\/sub>]<sup>4-<\/sup>\u901a\u8fc7\u91d1\u5c5e-\u6c27\u914d\u4f4d\u952e\u76f4\u63a5\u76f8\u8fde\uff0c\u8fdb\u800c\u5728\u5b63\u94f5\u76d0\u9633\u79bb\u5b50\u5305\u8986\u4e0b\u5f62\u6210\u5177\u6709\u5747\u5300\u7684\u516d\u8fb9\u5f62\u5b54\u6d1e\u7684\u5355\u5c42\u56e2\u7c07\u7c7b\u70ef\u7ed3\u6784\uff0c\u5176\u5c3a\u5bf8\u53ef\u8fbe\u6570\u5fae\u7c73\u3002\u56e2\u7c07\u7c7b\u70ef\u5bf9\u4e8e\u70ef\u70c3\u73af\u6c27\u5316\u53cd\u5e94\u5177\u6709\u663e\u8457\u63d0\u5347\u7684\u50ac\u5316\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6548\u7387\uff0c\u5176\u8f6c\u6362\u9891\u7387\u4e3a4.16 <em><i>h<\/i><\/em><em><sup><i>\u2212<\/i><\/sup><\/em><em><sup><i>1<\/i><\/sup><\/em>\uff0c\u662f\u56e2\u7c07\u7ec4\u88c5\u57fa\u5143\u768476.5\u500d\u3002\u4e0a\u8ff0\u50ac\u5316\u6d3b\u6027\u6765\u6e90\u4e8e\u56e2\u7c07\u7c7b\u70ef\u5c42\u5185\u7684\u7535\u5b50\u79bb\u57df\u884c\u4e3a\uff0c\u4ece\u800c\u6709\u6548\u5730\u964d\u4f4e\u4e86\u50ac\u5316\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-233400 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72471-11.png\" alt=\"\" width=\"554\" height=\"181\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72471-11.png 554w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72471-11-300x98.png 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u4e09\u3001\u56fe\u6587\u4ecb\u7ecd<\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe1<\/strong> \u56e2\u7c07\u7c7b\u70ef\u7684\u5236\u5907\u6d41\u7a0b\u4e0e\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u793a\u610f\u56fe <span style=\"color: #999999;\">\u00a92022 Springer Nature<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-233242\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/1-15.jpg\" alt=\"\" width=\"1511\" height=\"1079\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/1-15.jpg 1511w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/1-15-300x214.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/1-15-768x548.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/1-15-1024x731.jpg 1024w\" sizes=\"(max-width: 1511px) 100vw, 1511px\" \/><\/p>\n<p>a. \u591a\u9178\u56e2\u7c07\u7ec4\u88c5\u57fa\u5143<\/p>\n<p>b. \u5177\u6709\u516d\u8fb9\u5f62\u5b54\u9053\u7684\u591a\u5c42\u56e2\u7c07\u7c7b\u70ef<\/p>\n<p>c. \u7ecf\u8fc7\u5265\u79bb\u540e\u5f62\u6210\u7684\u5355\u5c42\u56e2\u7c07\u7c7b\u70ef\uff0c\u63d2\u56fe\uff1a\u5176\u4e2d\u7684\u56e2\u7c07\u8fde\u63a5\u65b9\u5f0f<\/p>\n<p>d. \u8d85\u8584\u7eb3\u7c73\u5e26\uff0c\u63d2\u56fe\uff1a\u5176\u4e2d\u7684\u56e2\u7c07\u8fde\u63a5\u65b9\u5f0f<\/p>\n<p>e. \u56e2\u7c07\u5355\u4f53\u4e0e\u9633\u79bb\u5b50\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528<\/p>\n<p>f, g. (f)\u591a\u5c42\u56e2\u7c07\u7c7b\u70ef\u548c(g)\u5355\u5c42\u56e2\u7c07\u7c7b\u70ef\u7684\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u7ed3\u679c<\/p>\n<p style=\"text-align: center;\"><strong>\u56fe2<\/strong> \u00a0NdPW<sub>11<\/sub>\u5355\u5c42\u56e2\u7c07\u7c7b\u70ef<span style=\"color: #999999;\"> \u00a92022 Springer Nature<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-233243\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/2-16.jpg\" alt=\"\" width=\"2122\" height=\"1469\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/2-16.jpg 2122w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/2-16-300x208.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/2-16-768x532.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/2-16-1024x709.jpg 1024w\" sizes=\"(max-width: 2122px) 100vw, 2122px\" \/><\/p>\n<p>a,b. \u5355\u5c42\u56e2\u7c07\u7c7b\u70ef\u5728\u4e0d\u540c\u5c3a\u5ea6\u4e0b\u7684TEM\u56fe\u50cf<\/p>\n<p>c,d. \u5355\u5c42\u56e2\u7c07\u7c7b\u70ef\u5728\u4e0d\u540c\u5c3a\u5ea6\u4e0b\u7684\u9ad8\u5206\u8fa8\u7387\u7403\u5dee\u6821\u6b63TEM\u56fe\u50cf\uff1b<\/p>\n<p>e. \u56e2\u7c07\u7c7b\u70ef\u548cf\u5355\u4e2a\u56e2\u7c07\u7684EXAFS\u62df\u5408\u66f2\u7ebf\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u56fe3<\/strong> \u00a0NdPW<sub>11<\/sub>\u591a\u5c42\u56e2\u7c07\u7c7b\u70ef\u548c\u8d85\u8584\u7eb3\u7c73\u5e26 <span style=\"color: #999999;\">\u00a92022 Springer Nature<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-233244\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/3-15.jpg\" alt=\"\" width=\"2120\" height=\"1444\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/3-15.jpg 2120w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/3-15-300x204.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/3-15-768x523.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/3-15-1024x697.jpg 1024w\" sizes=\"(max-width: 2120px) 100vw, 2120px\" \/><\/p>\n<p>a. \u5927\u5c3a\u5bf8\u7684\u591a\u5c42\u56e2\u7c07\u7c7b\u70efTEM\u56fe\u50cf<\/p>\n<p>b. \u591a\u5c42\u56e2\u7c07\u7c7b\u70ef\u7684\u4e0d\u540c\u89d2\u5ea6\u6295\u5f71\u56fe<\/p>\n<p>c,d. \u5177\u6709\u4e0d\u540c\u957f\u5f84\u6bd4\u7684\u8d85\u8584\u7eb3\u7c73\u5e26TEM\u56fe\u50cf<\/p>\n<p>e. \u591a\u5c42\u56e2\u7c07\u7c7b\u70ef(\u9ed1\u8272)\u3001\u5355\u5c42\u56e2\u7c07\u7c7b\u70ef(\u84dd\u8272)\u548c\u7eb3\u7c73\u5e26(\u7ea2\u8272)\u7684\u5c0f\u89d2XRD\u884d\u5c04\u7ed3\u679c<\/p>\n<p>f. \u56fee\u4e2d\u5bf9\u5e94\u5355\u5c42\u56e2\u7c07\u7c7b\u70ef(\u9876\u90e8)\u548c\u7eb3\u7c73\u5e26(\u5e95\u90e8)\u7684\u7ed3\u6784\u53c2\u6570<\/p>\n<p style=\"text-align: center;\"><strong>\u56fe4<\/strong> MPW<sub>11<\/sub>\u5355\u5c42\u56e2\u7c07\u7c7b\u70ef\u7684TEM\u56fe\u50cf <span style=\"color: #999999;\">\u00a92022 Springer Nature<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-233245\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/4-14.jpg\" alt=\"\" width=\"1772\" height=\"1328\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/4-14.jpg 1772w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/4-14-300x225.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/4-14-768x576.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/4-14-1024x767.jpg 1024w\" sizes=\"(max-width: 1772px) 100vw, 1772px\" \/><\/p>\n<p>\u56fe\u4e2d\u53f3\u4e0a\u89d2\u663e\u793a\u4e86\u5bf9\u5e94\u7684\u7a00\u571f\u91d1\u5c5eM\u53ca\u5176\u539f\u5b50\u5e8f\u6570\u548c\u7535\u8377\u534a\u5f84\u6bd4\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u56fe5<\/strong> \u00a0NdPW<sub>11<\/sub>\u56e2\u7c07\u7c7b\u70ef\u7528\u4e8e\u70ef\u70c3\u50ac\u5316\u73af\u6c27\u5316\u53cd\u5e94 <span style=\"color: #999999;\">\u00a92022 Springer Nature<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-233246\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/5-7.jpg\" alt=\"\" width=\"1780\" height=\"1134\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/5-7.jpg 1780w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/5-7-300x191.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/5-7-768x489.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/5-7-1024x652.jpg 1024w\" sizes=\"(max-width: 1780px) 100vw, 1780px\" \/><\/p>\n<p>a. \u4e0d\u540c\u5e95\u7269\u4e0b\u7684\u4ea7\u7387<\/p>\n<p>b. NdPW<sub>11<\/sub>\u56e2\u7c07\u7c7b\u70ef\u572810\u6b21\u50ac\u5316\u5faa\u73af\u4e2d\u7684\u7a33\u5b9a\u6027<\/p>\n<p>c. \u56e2\u7c07\u7c7b\u70ef\u7ed3\u6784\u4e0e\u5176\u4ed6\u56e2\u7c07\u50ac\u5316\u5242\u7684\u8f6c\u6362\u9891\u7387\uff08TOF\uff09\u5bf9\u6bd4<\/p>\n<p>d. NdPW<sub>11<\/sub>\u5355\u5c42\u56e2\u7c07\u7c7b\u70ef\u50ac\u5316\u524d\uff08\u9ed1\uff09\u540e\uff08\u7ea2\uff09\u7684FTIR\u8c31\u56fe<\/p>\n<p style=\"text-align: center;\"><strong>\u56fe6<\/strong> \u00a0NdPW<sub>11<\/sub>\u7ec4\u88c5\u57fa\u5143\u5728\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u4e2d\u7684\u5206\u5b50\u6a21\u578b\u53ca\u6d3b\u5316\u80fd <span style=\"color: #999999;\">\u00a92022 Springer Nature<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-233247\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/6-5.jpg\" alt=\"\" width=\"1804\" height=\"1101\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/6-5.jpg 1804w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/6-5-300x183.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/6-5-768x469.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/6-5-1024x625.jpg 1024w\" sizes=\"(max-width: 1804px) 100vw, 1804px\" \/><\/p>\n<p>a. H<sub>4<\/sub>[NdPW<sub>11<\/sub>O<sub>39<\/sub>]\u56e2\u7c07\u5355\u4f53<\/p>\n<p>b. H<sub>8<\/sub>[NdPW<sub>11<\/sub>O<sub>39<\/sub>]<sub>2<\/sub>\u4e8c\u805a\u4f53<\/p>\n<p>c. \u56e2\u7c07\u4e0d\u540c\u6c27\u5316\u6001\u4e0b\u7684\u7edd\u70ed\u7535\u79bb\u80fd<\/p>\n<p>d. \u56e2\u7c07\u4e8c\u805a\u4f53\u7684\u5206\u5b50\u8f68\u9053\u80fd\u91cf\u53ca\u5bf9\u5e94\u7684Kohn-Sham\u524d\u7ebf\u5206\u5b50\u8f68\u9053<\/p>\n<p style=\"text-align: center;\"><strong>\u56db\u3001\u5c0f\u7ed3<\/strong><\/p>\n<p>\u672c\u6587\u5236\u5907\u51fa\u4e00\u7cfb\u5217\u4e8c\u7ef4\u56e2\u7c07\u7c7b\u70ef\u6750\u6599\u3002\u7a00\u571f\u53d6\u4ee3\u7684Keggin\u578b\u56e2\u7c07\u901a\u8fc7\u91d1\u5c5e-\u6c27\u914d\u4f4d\u952e\u76f4\u63a5\u76f8\u8fde\uff0c\u8fdb\u800c\u5728\u5b63\u94f5\u76d0\u9633\u79bb\u5b50\u5305\u8986\u4e0b\u5f62\u6210\u5177\u6709\u5747\u5300\u7684\u516d\u8fb9\u5f62\u5b54\u6d1e\u7684\u5355\u5c42\u56e2\u7c07\u7c7b\u70ef\u7ed3\u6784\uff0c\u5176\u5c3a\u5bf8\u53ef\u8fbe\u6570\u5fae\u7c73\u3002\u901a\u8fc7\u8c03\u63a7\u53cd\u5e94\u6761\u4ef6(\u79bb\u5b50\u5f3a\u5ea6\u548c\u53cd\u5e94\u65f6\u95f4)\uff0c\u8fd8\u53ef\u4ee5\u83b7\u5f97\u4e00\u7cfb\u5217\u591a\u5c42\u56e2\u7c07\u7c7b\u70ef\u3001\u5355\u5c42\u56e2\u7c07\u7c7b\u70ef\u548c\u8d85\u8584\u7eb3\u7c73\u5e26\u300213 \u79cd\u7a00\u571f\u5143\u7d20\u53d6\u4ee3\u7684Keggin \u578b\u56e2\u7c07\u5747\u53ef\u7528\u4e8e\u56e2\u7c07\u7c7b\u70ef\u7684\u6784\u5efa\uff0c\u4e0a\u8ff0\u7ed3\u6784\u5177\u6709\u76f8\u4f3c\u7684\u5f62\u8c8c\u4e0e\u50ac\u5316\u6027\u8d28\uff0c\u63ed\u793a\u51fa\u6b64\u7c7b\u4e8c\u7ef4\u6750\u6599\u826f\u597d\u7684\u7ed3\u6784\u666e\u9002\u6027\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u663e\u793a\uff0c\u56e2\u7c07\u5206\u5b50\u8f68\u9053\u76f8\u4e92\u4f5c\u7528\u548c\u5176\u95f4\u7535\u5b50\u79bb\u57df\u884c\u4e3a\u6709\u6548\u964d\u4f4e\u4e86\u56e2\u7c07\u7c7b\u70ef\u53c2\u4e0e\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\uff0c\u4ece\u800c\u663e\u8457\u63d0\u5347\u4e86\u5176\u50ac\u5316\u6d3b\u6027\u3002\u76f8\u6bd4\u4e8e\u56e2\u7c07\u7ec4\u88c5\u57fa\u5143\uff0c\u56e2\u7c07\u7c7b\u70ef\u7ed3\u6784\u5bf9\u70ef\u70c3\u73af\u6c27\u5316\u53cd\u5e94\u5c55\u73b0\u51fa\u66f4\u9ad8\u7684\u50ac\u5316\u6548\u7387\u548c\u7a33\u5b9a\u6027\u3002\u672c\u7814\u7a76\u63ed\u793a\u4e86\u56e2\u7c07\u7c7b\u70ef\u6750\u6599\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u3001\u51fa\u4f17\u7684\u50ac\u5316\u6027\u8d28\u548c\u826f\u597d\u7684\u7ed3\u6784\u666e\u9002\u6027\uff0c\u6709\u671b\u542f\u53d1\u57fa\u4e8e\u56e2\u7c07\u7684\u65b0\u6750\u6599\u7684\u8bbe\u8ba1\u4e0e\u5408\u6210\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/doi.org\/10.1038\/s41557-022-00889-1\" target=\"_blank\" rel=\"noopener\"><u>Self-assembly of polyoxometalate clusters into two-dimensional clusterphene structures featuring hexagonal pores<\/u><\/a>.\u00a0<em><i>Nature Chemistry.<\/i><\/em>\u00a02022. DOI: 10.1038\/s41557-022-00889-1.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-233401\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72472-8.png\" alt=\"\" width=\"1266\" height=\"887\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72472-8.png 1266w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72472-8-300x210.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72472-8-768x538.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72472-8-1024x717.png 1024w\" sizes=\"(max-width: 1266px) 100vw, 1266px\" \/><\/p>\n<p><strong><b>\u56e2\u961f\u4ecb\u7ecd\uff1a<\/b><\/strong><\/p>\n<p>\u6e05\u534e\u5927\u5b66\u5316\u5b66\u7cfb\u738b\u8bad\u8bfe\u9898\u7ec4\u81f4\u529b\u4e8e\u4e9a\u7eb3\u7c73\u5c3a\u5ea6\u65e0\u673a\u6750\u6599\u5408\u6210\u65b9\u6cd5\u5b66\u53ca\u6027\u8d28\u7814\u7a76\u3002\u57fa\u4e8e\u826f\u6eb6\u5242-\u4e0d\u826f\u6eb6\u5242\u9650\u5236\u6676\u6838\u5c3a\u5bf8\u7b56\u7565\uff0c\u53d1\u5c55\u51fa\u4e9a\u7eb3\u7c73\u5c3a\u5ea6\u6750\u6599\u5408\u6210\u65b9\u6cd5\u5b66\uff0c\u63d0\u51fa\u4e86\u4e9a\u7eb3\u7c73\u5c3a\u5ea6\u6750\u6599\u6982\u5ff5\uff1b\u53d1\u73b0\u4e86\u65e0\u673a\u4e9a\u7eb3\u7c73\u7ebf\u7684\u7c7b\u9ad8\u5206\u5b50\u7279\u6027\uff0c\u4ee5\u6b64\u4e3a\u57fa\u7840\u6784\u5efa\u4e86\u67d4\u6027\u7ec4\u88c5\u4f53\u3001\u67d4\u6027\u504f\u5149\u5668\u4ef6\u3001\u624b\u6027\u5b8f\u89c2\u7ec4\u88c5\u4f53\u7b49\uff1b\u53d1\u5c55\u4e86\u56e2\u7c07\u81ea\u7ec4\u88c5\u3001\u56e2\u7c07-\u6676\u6838\u5171\u7ec4\u88c5\u7b56\u7565\uff0c\u6784\u5efa\u4e86\u56e2\u7c07\u7c7b\u70ef\u3001\u56e2\u7c07-\u65e0\u673a\u6750\u6599\u4e9a\u7eb3\u7c73\u8d85\u7ed3\u6784\u7ec4\u88c5\u4f53\uff1b\u57fa\u4e8e\u65e0\u673a\u4e9a\u7eb3\u7c73\u5c3a\u5ea6\u6750\u6599\u63a5\u8fd1100%\u8868\u9762\u539f\u5b50\u7279\u6027\uff0c\u53d1\u5c55\u51fa\u7cfb\u5217\u9ad8\u6548\u50ac\u5316\u4e0e\u80fd\u91cf\u8f6c\u6362\u4f53\u7cfb\u3002<\/p>\n<p><strong><b>\u4e9a\u7eb3\u7c73\u6750\u6599\/\u56e2\u7c07\u81ea\u7ec4\u88c5\u8fd1\u671f\u4ee3\u8868\u6027\u5de5\u4f5c\uff1a<\/b><\/strong><\/p>\n<p><em><i>1. Nat. Chem.<\/i><\/em>\u00a02022, DOI: 10.1038\/s41557-022-00889-1.<\/p>\n<p><em><i>2. Nat. Chem.<\/i><\/em>2019, 11, 839-845.<\/p>\n<p><em><i>3. Sci. Adv.<\/i><\/em>\u00a02019, 5, eaax1081.<\/p>\n<p><em><i>4. Matter.<\/i><\/em>2020, 2, 816-841.<\/p>\n<p><em><i>5. J. Am. Chem. Soc.<\/i><\/em>2021, 143, 16217-16225.<\/p>\n<p><em><i>6. J. Am. Chem. Soc.<\/i><\/em>2021, 143, 26, 9858-9865.<\/p>\n<p><em><i>7. J. Am. Chem. Soc.<\/i><\/em>2020, 142, 41, 17557-17563.<\/p>\n<p><em><i>8. J. Am. Chem. Soc.<\/i><\/em>2020, 142, 3, 1375-1381.<\/p>\n<p><em><i>9. J. Am. Chem. Soc.<\/i><\/em>2019, 141, 47, 18754-1875811.<\/p>\n<p>10.\u00a0<i style=\"font-style: italic;\">Angew. Chem. Int. Ed.<\/i>2021, 60, 17404-17409.<\/p>\n<p><em><i>11. Angew. Chem. Int. Ed.<\/i><\/em>2019, 58, 8730-8735.<\/p>\n<p>\u672c\u6587\u7531\u7eb3\u7c73\u5c0f\u767d\u4f9b\u7a3f<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u5f15\u8a00 \u4ee5\u77f3\u58a8\u70ef\u4e3a\u4ee3\u8868\u7684\u4e8c\u7ef4\u5c42\u72b6\u6750\u6599\u56e0\u5176\u72ec\u7279\u7684\u5c42\u5185\u539f\u5b50\u8fde\u63a5\u65b9\u5f0f\uff0c\u8868\u73b0\u51fa\u663e\u8457\u7684\u7535\u5b50\u79bb\u57df\u884c\u4e3a\uff0c\u7531\u6b64\u5e26\u6765\u4e86\u51fa\u4f17\u7684\u7269\u7406\u548c\u5316\u5b66\u6027\u8d28\u3002\u7531\u4e8e\u4f20\u7edf\u65e0\u673a\u7eb3\u7c73\u6676\u5404\u5411\u540c\u6027\u7684\u5f62\u72b6\u548c\u8868&#8230;<\/p>\n","protected":false},"author":31345,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-233241","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/233241"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/31345"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=233241"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/233241\/revisions"}],"predecessor-version":[{"id":233443,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/233241\/revisions\/233443"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=233241"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=233241"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=233241"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}