{"id":233148,"date":"2022-02-21T06:56:04","date_gmt":"2022-02-20T22:56:04","guid":{"rendered":"\/\/m.iemloyee.com\/?p=233148"},"modified":"2022-02-20T19:56:12","modified_gmt":"2022-02-20T11:56:12","slug":"nat-commun-%ef%bc%9a%e6%b8%a9%e5%92%8c%e6%9d%a1%e4%bb%b6%e4%b8%8b%e9%ab%98%e9%80%89%e6%8b%a9%e6%80%a7%e5%90%88%e6%88%90%e5%85%a8%e7%a2%b3%e5%9b%9b%e5%8f%96%e4%bb%a3%e7%83%af%e7%83%83","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=233148","title":{"rendered":"Nat. 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style=\"color: #003366;\">\u82b3\u9999\u7fa7\u9178\u4ee5\u53ca\u73af\u72b6\u548c\u65e0\u73af\u70ef\u57fa\u4e09\u6c1f\u78fa\u9178\u916f\u7ecf\u5386C-C\u5076\u8054\u8fc7\u7a0b\uff0c\u4ee5\u4e2d\u7b49\u81f3\u826f\u597d\u7684\u4ea7\u7387\u7acb\u4f53\u5b9a\u5411\u5730\u5f62\u6210\u7ed3\u6784\u591a\u6837\u7684\u70ef\u70c3\u3002<\/span><\/strong>\u590d\u6742\u5206\u5b50\u7684\u540e\u671f\u4fee\u9970\u3001\u4e00\u9505\u6cd5\u5408\u6210\u548c\u514b\u7ea7\u5e94\u7528\u8fdb\u4e00\u6b65\u8bf4\u660e\u4e86\u8be5\u65b9\u6cd5\u7684\u5b9e\u7528\u6027\u3002\u8fd9\u662f\u5bf9\u6316\u6398\u7fa7\u9178\u7684\u91cd\u8981\u4ef7\u503c\u8fc8\u51fa\u7684\u91cd\u8981\u4e00\u6b65\uff0c\u5b83\u8fd8\u7b80\u5316\u4e86Ni\uff080\uff09\u50ac\u5316\u5242\u91d1\u5c5e\u5149\u50ac\u5316\u7684\u5b9e\u9a8c\u64cd\u4f5c\u3002\u8be5\u6587\u7ae0\u8fd1\u65e5\u4ee5\u9898\u4e3a\u201c<strong>Highly selective synthesis of all-carbon tetrasubstituted alkenes by deoxygenative alkenylation of carboxylic acids<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520a<em><strong>Nature Communications<\/strong><\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-233149\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/0-5.jpg\" alt=\"\" width=\"600\" height=\"418\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/0-5.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/0-5-300x209.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe\u4e00\u3001\u5927\u4f53\u79ef\u70ef\u70c3\u5408\u6210\u7684\u4e00\u822c\u65b9\u6cd5 <span style=\"color: #999999;\">\u00a9 2022 The Authors<\/span><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-233150\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/1-14.jpg\" alt=\"\" width=\"600\" 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size-full wp-image-233153\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/4-13.jpg\" alt=\"\" width=\"600\" height=\"686\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/4-13.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/4-13-262x300.jpg 262w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u53ef\u80fd\u7684\u53cd\u5e94\u673a\u7406<\/p>\n<p>\uff08b\uff09DFT\u8ba1\u7b97\u7ed3\u679c<\/p>\n<p>\uff08c\uff09\u4ee5\u5316\u5408\u7269<strong>5<\/strong>\u4e3a\u53c2\u8003\u70b9\u53cd\u5e94\u7684\u52bf\u80fd\u9762<\/p>\n<p style=\"text-align: center;\"><strong>\u56fe\u4e94\u3001\u5408\u6210\u5e94\u7528\u00a0<span style=\"color: #999999;\">\u00a9 2022 The Authors<\/span><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-233154\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/5-6.jpg\" alt=\"\" width=\"600\" height=\"815\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/5-6.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/02\/5-6-221x300.jpg 221w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u4e00\u9505\u6cd5\u4e24\u6b65\u5408\u6210\u5316\u5408\u7269<strong>3<\/strong><\/p>\n<p>\uff08b\uff09\u5316\u5408\u7269\u7684\u514b\u7ea7\u5b9e\u9a8c\u5408\u6210<\/p>\n<p>\uff08c\uff09\u4e32\u8054C-C\u8026\u5408\/Nazarov\u73af\u5316\u5e94\u7528<\/p>\n<p>\uff08d\uff09\u5316\u5408\u7269<strong>3c<\/strong>\u7684\u8fd8\u539f<\/p>\n<p><strong>\u3010\u7ed3\u8bba\u5c55\u671b\u3011<\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u7814\u7a76\u4eba\u5458\u5f00\u53d1\u4e86\u4e00\u79cd\u5728\u7a7a\u6c14\u6c14\u6c1b\u4e0b\u901a\u8fc7\u534f\u540c\u5149\u6c27\u5316\/\u954d\u50ac\u5316\u5408\u6210\u5168\u78b3\u56db\u53d6\u4ee3\u70ef\u70c3\u7684\u7b56\u7565\u3002\u5927\u91cf\u73b0\u6210\u7684\u82b3\u9999\u9178\u548c\u70ef\u57fa\u4e09\u6c1f\u78fa\u9178\u916f\u662f\u8be5C-C\u5076\u8054\u4e2d\u7684\u6709\u6548\u5076\u8054\u5242\uff0c\u4ee5\u4e2d\u7b49\u81f3\u826f\u597d\u7684\u4ea7\u7387\u63d0\u4f9b\u4e86\u4e30\u5bcc\u7684\u7ed3\u6784\u591a\u6837\u7684\u65e0\u73af\u548c\u73af\u5168\u78b3\u56db\u53d6\u4ee3\u70ef\u70c3\u5e93\uff0c\u5e76\u5177\u6709\u4f18\u5f02\u7684Z\/E\u7acb\u4f53\u9009\u62e9\u6027\u3002DFT\u8ba1\u7b97\u8868\u660e\uff0c\u8fd9\u79cd\u8f6c\u53d8\u53ef\u80fd\u901a\u8fc7Ni\uff080\uff09\/Ni\uff08II\uff09\/Ni\uff08III\uff09\u9014\u5f84\u8fdb\u884c\u3002\u8be5\u65b9\u6848\u53ef\u4ee5\u907f\u514d\u4f7f\u7528\u5bf9\u6c34\u5206\u654f\u611f\u7684\u6709\u673a\u91d1\u5c5e\u8bd5\u5242\uff0c\u5e76\u4e14\u4e0d\u9700\u8981\u60f0\u6027\u6c14\u4f53\u4fdd\u62a4\uff0c\u4ece\u800c\u5927\u5927\u7b80\u5316\u5177\u6709Ni\uff080\uff09\u50ac\u5316\u5242\u7684\u91d1\u5c5e\u5149\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u64cd\u4f5c\u3002\u8fd9\u4e5f\u662f\u4ece\u73b0\u6210\u7684\u539f\u6599\u5316\u5b66\u54c1\u5408\u6210\u5168\u78b3\u56db\u53d6\u4ee3\u70ef\u70c3\u7684\u4e00\u4e2a\u91cd\u8981\u8fdb\u5c55\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41467-021-27507-x\" target=\"_blank\" rel=\"noopener\">Highly selective synthesis of all-carbon tetrasubstituted alkenes by deoxygenative alkenylation of carboxylic acids<\/a> (<em>Nature Communications<\/em> <strong>2022<\/strong>, DOI: 10.1038\/s41467-021-27507-x)<\/p>\n<p>\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1a<a href=\"mailto:tougao@cailiaoren.com\">tougao@cailiaoren.com<\/a><\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u7814\u7a76\u80cc\u666f\u3011 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