{"id":232511,"date":"2022-01-30T06:18:29","date_gmt":"2022-01-29T22:18:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=232511"},"modified":"2022-01-29T22:18:56","modified_gmt":"2022-01-29T14:18:56","slug":"%e4%b8%8a%e6%b5%b7%e6%9c%89%e6%9c%ba%e6%89%80%e8%b5%b5%e6%96%b0j-am-chem-soc-%ef%bc%9a%e4%b8%80%e7%a7%8d%e7%ae%80%e4%be%bf%e3%80%81%e9%ab%98%e6%95%88%e3%80%81%e9%80%9a%e7%94%a8%e7%9a%84%e9%85%b0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=232511","title":{"rendered":"\u4e0a\u6d77\u6709\u673a\u6240\u8d75\u65b0J. Am. Chem. Soc.\uff1a\u4e00\u79cd\u7b80\u4fbf\u3001\u9ad8\u6548\u3001\u901a\u7528\u7684\u9170\u80faCOFs\u5408\u6210\u7b56\u7565"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5171\u4ef7\u6709\u673a\u6846\u67b6(Covalent organic frameworks\uff0cCOFs)<\/strong>\u662f\u4e00\u7c7b\u65b0\u5174\u7684\u6709\u673a\u591a\u5b54\u805a\u5408\u7269\uff0c\u5728\u6c14\u4f53\u5438\u9644\u3001\u50ac\u5316\u3001\u5206\u79bb\u3001\u50a8\u80fd\u3001\u4f20\u611f\u7b49\u9886\u57df\u90fd\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002COFs\u7684\u4e00\u4e2a\u5173\u952e\u7279\u5f81\u662f\u5177\u6709\u6676\u6001\u7ed3\u6784\uff0c\u8fd9\u4f7f\u5176\u533a\u522b\u4e8e\u5176\u4ed6\u6709\u673a\u591a\u5b54\u805a\u5408\u7269(\u5927\u591a\u4e3a\u65e0\u5b9a\u5f62\u7ed3\u6784)\uff0c\u8d4b\u4e88\u5176\u7ed3\u6784\u72ec\u7279\u6027\u3002\u4e3a\u4e86\u5b9e\u73b0\u6676\u6001\u7ed3\u6784\u7684\u6784\u7b51\uff0cCOFs\u4e2d\u7ec4\u6210\u57fa\u5143\u901a\u5e38\u4ee5\u9ad8\u53ef\u9006\u6027\u7684\u5171\u4ef7\u952e\u8fdb\u884c\u8fde\u63a5\u3002\u7136\u800c\uff0c\u867d\u7136\u6210\u952e\u53ef\u9006\u6027\u8d4b\u4e88\u7ed3\u6784\u7ea0\u9519\u4e0e\u81ea\u4fee\u590d\u80fd\u529b\uff0c\u89e3\u51b3\u4e86COFs\u7684\u7ed3\u6676\u95ee\u9898\uff0c\u4f46\u540c\u65f6\u4e5f\u964d\u4f4e\u4e86COFs\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u8fd9\u6781\u5927\u5730\u9650\u5236\u4e86\u5176\u5b9e\u9645\u5e94\u7528\u3002\u4e3a\u4e86\u4fdd\u8bc1COFs\u6750\u6599\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u63d0\u9ad8\u5176\u6027\u80fd\uff0c\u8bbe\u8ba1\u4e0d\u53ef\u9006\u952e\u5408\u8fde\u63a5\u7684COFs\u7ed3\u6784\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u9170\u80fa\u952e\u8fde\u7684\u5171\u4ef7\u6709\u673a\u6846\u67b6(\u9170\u80faCOFs)\u7531\u4e8e\u5176\u9ad8\u7a33\u5b9a\u6027\u548c\u805a\u9170\u80fa\u7ed3\u6784\uff0c\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u5177\u6709\u5de8\u5927\u7684\u6f5c\u529b\u3002\u7136\u800c\uff0c\u5b83\u4eec\u7684\u5408\u6210\u6765\u6e90\u975e\u5e38\u6709\u9650\u3002<\/p>\n

\u3010\u7814\u7a76\u8fdb\u5c55\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u4e0a\u6d77\u6709\u673a\u6240\u8d75\u65b0\u7814\u7a76\u5458<\/strong>\uff08<\/strong>\u901a\u8baf\u4f5c\u8005<\/strong>\uff09<\/strong>\u8bfe\u9898\u7ec4<\/strong>\u5728J. Am. Chem. Soc.<\/em>\u4e0a\u53d1\u8868\u6587\u7ae0\uff0c\u9898\u4e3a\u201cA Facile, Efficient, and General Synthetic Method to Amide-Linked Covalent Organic Frameworks<\/strong>\u201d\u3002\u00a0\u8be5\u8bba\u6587\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u7684\u9170\u80faCOFs\u5408\u6210\u65b9\u6cd5\uff0c\u5728\u975e\u5e38\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u548c\u8f83\u77ed\u65f6\u95f4\u5185\uff0c\u4ee5KHSO5<\/sub>\u4e3a\u6c27\u5316\u5242\u5c06\u4e9a\u80fa\u952e\u8fde\u7684COFs(\u4e9a\u80faCOFs)\u4e2d\u7684\u4e9a\u80fa\u952e\u6c27\u5316\u4e3a\u9170\u80fa\u952e\uff0c\u540c\u65f6\u8fd8\u4fdd\u6301\u4e86\u524d\u8005\u7684\u6676\u6001\u591a\u5b54\u7ed3\u6784\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u7ed3\u6676\u6027\u9170\u80faCOFs\u7684\u5feb\u901f\u5236\u5907\u3002\u8be5\u5408\u6210\u65b9\u6cd5\u5177\u6709\u901a\u7528\u3001\u7b80\u4fbf\u3001\u9ad8\u6548\u3001\u53ef\u653e\u5927\u7b49\u4f18\u70b9\u3002\u4ee5\u65e0\u6c34N,N-\u4e8c\u7532\u57fa\u7532\u9170\u80fa\u4e3a\u6eb6\u5242\uff0c\u7b80\u5355\u5730\u6405\u62cc\u4e9a\u80faCOFs\uff087\u4e2a\u5b9e\u4f8b\uff09\u548cKHSO5<\/sub>\u7684\u6df7\u5408\u7269\uff0c\u51e0\u4e2a\u5c0f\u65f6\u5373\u53ef\u5b8c\u6210\u8f6c\u5316\uff0c\u5e76\u53ef\u5b9e\u73b0\u514b\u7ea7\u5408\u6210\u3002\u57fa\u4e8e\u8fd9\u4e00\u65b9\u6cd5\uff0c\u53ef\u5c06\u6765\u6e90\u5e7f\u6cdb\u7684\u4e9a\u80faCOFs\u9ad8\u6548\u3001\u4fbf\u6377\u5730\u8f6c\u5316\u4e3a\u9170\u80faCOFs\uff0c\u4e3a\u5f00\u53d1\u8fd9\u79cd\u72ec\u7279\u7c7b\u578b\u7684\u805a\u9170\u80fa\u6750\u6599\u7684\u5b9e\u9645\u5e94\u7528\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n

\u56fe\u6587\u4ecb\u7ecd<\/strong><\/p>\n

\u56fe1<\/strong> COF-QPTA-PDA\u6c27\u5316\u524d\u540e\u7684\u7ed3\u6784\u5206\u6790 \u00a92022\u00a0American Chemical Society<\/span><\/p>\n

\"\"<\/p>\n

COF-QPTA-PDA\u6c27\u5316\u524d\u540e\u7684\uff08a\uff09PXRD\u56fe\uff1b\uff08b\uff09FT-IR\u56fe\uff1b\uff08c\uff0913<\/sup>C CP-MAS\u56fa\u4f53\u6838\u78c1\u5171\u632f\u8c31<\/p>\n

\u56fe2<\/strong> \u00a0COF-QPTA-PDA\u6c27\u5316\u524d\u540e\u7684XPS\u548c\u6c2e\u5438\u9644\u5206\u6790\u00a0\u00a92022\u00a0American Chemical Society<\/span><\/p>\n

\"\"<\/p>\n

\uff08a\uff09Am-COF-QPTA-PDA\u00a0XPS\u5168\u8c31\uff1b\uff08b\uff09COF-QPTA-PDA\u6c27\u5316\u524d\u540eN 1s\u7684\u9ad8\u5206\u8fa8XPS\u8c31\uff1b\uff08c\uff09COF-QPTA-PDA\u6c27\u5316\u524d\u540eN2<\/sub>\u5438\u9644\u6d4b\u8bd5<\/p>\n

\u56fe3<\/strong> \u514b\u91cf\u7ea7\u5408\u6210\u7684Am-COF-QPTA-PDA\u7684\u7ed3\u6784\u5206\u6790\u00a92022\u00a0American Chemical Society<\/p>\n

\"\"<\/p>\n

\u514b\u91cf\u7ea7\u5408\u6210\u7684Am-COF-QPTA-PDA\u7684PXRD\u56fe\u3002\u6ce8\uff1a(110)\u548c(200)\u5cf0\u7684\u76f8\u5bf9\u5f3a\u5ea6\u4e0e\u56fe1a\u6709\u6240\u4e0d\u540c\uff0c\u8fd9\u662f\u7531\u4e8e\u6676\u9762\u751f\u957f\u62e9\u4f18\u53d6\u5411\u9020\u6210\u7684<\/p>\n

\u56fe4<\/strong> \u514b\u91cf\u7ea7\u5408\u6210\u7684Am-COF-QPTA-PDA\u7684\u7ed3\u6784\u8868\u5f81\u00a92022\u00a0American Chemical Society<\/span><\/p>\n

\"\"<\/p>\n

\u514b\u91cf\u7ea7\u5408\u6210\u7684Am-COF-QPTA-PDA\u7684\uff08a\uff09FT-IR\u56fe\uff1b\uff08b\uff0913<\/sup>C CP-MAS\u56fa\u4f53\u6838\u78c1\u5171\u632f\u8c31<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a\u00a0<\/u>A Facile, Efficient, and General Synthetic Method to Amide-Linked Covalent Organic Frameworks<\/u><\/a>.\u00a02022, J. Am. Chem. Soc.<\/em>, DOI: 10.1021\/jacs.1c12392.<\/p>\n

\u672c\u6587\u7531\u7eb3\u7c73\u5c0f\u767d\u4f9b\u7a3f<\/p>\n

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