{"id":232395,"date":"2022-02-03T06:04:26","date_gmt":"2022-02-02T22:04:26","guid":{"rendered":"\/\/m.iemloyee.com\/?p=232395"},"modified":"2022-02-02T21:04:36","modified_gmt":"2022-02-02T13:04:36","slug":"sci-adv-%ef%bc%9a%e5%88%86%e5%ad%90%e7%8c%9d%e7%81%ad-%e4%bb%8b%e5%af%bc%e6%9c%ba%e5%88%b6%e7%9a%84%e9%95%bf%e5%af%bf%e5%91%bd%e9%94%82%e6%b0%a7%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=232395","title":{"rendered":"Sci. Adv.\uff1a\u5206\u5b50\u731d\u706d\/\u4ecb\u5bfc\u673a\u5236\u7684\u957f\u5bff\u547d\u9502\u6c27\u7535\u6c60"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232401\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/0_\u526f\u672c.jpg\" alt=\"\" width=\"600\" height=\"213\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/0_\u526f\u672c.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/0_\u526f\u672c-300x107.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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diimide\u9aa8\u67b6\u76f8\u8fde\u63a5\uff0c\u4f5c\u4e3a\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u50ac\u5316\u653e\u7535\/\u5145\u7535\u53cd\u5e94\uff0c\u5e76\u4f5c\u4e3a\u53ef\u91cd\u590d\u4f7f\u7528\u7684\u8d85\u6c27\u5316\u7269\u6dec\u706d\u5242\uff0c\u4e0e\u7535\u6c60\u8fd0\u4e2d\u4ea7\u751f\u7684\u8d85\u6c27\u5316\u7269\u53d1\u751f\u5316\u5b66\u53cd\u5e94\u3002\u8fd9\u79cd\u591a\u529f\u80fd\u7684\u5206\u5b50\u53ef\u4ee5\u540c\u65f6\u89e3\u51b3\u4e0e\u8d85\u6c27\u81ea\u7531\u57fa\u3001\u5355\u7ebf\u6001\u6c27\u3001\u9ad8\u8fc7\u7535\u4f4d\u548c\u9502\u8150\u8680\u6709\u5173\u7684\u5bc4\u751f\u53cd\u5e94\u95ee\u9898\u3002\u8fd9\u79cd\u7ed3\u5408\u5404\u79cd\u80fd\u529b\u7684\u591a\u529f\u80fd\u5206\u5b50\u6dfb\u52a0\u5242\u7684\u8bbe\u8ba1\u548c\u5236\u5907\uff0c\u4e3a\u5f00\u53d1\u9ad8\u6027\u80fd\u7684Li-O<sub>2<\/sub>\u7535\u6c60\u5f00\u8f9f\u4e86\u4e00\u6761\u65b0\u9014\u5f84\u3002\u76f8\u5173\u6210\u679c\u4ee5<strong>\u201c<\/strong><strong>A long-life lithium-oxygen battery via a molecular quenching\/mediating mechanism<\/strong>\u201d\u53d1\u8868\u5728<em><strong>Science Advances<\/strong><\/em>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u9502\u6c27\uff08Li-O<sub>2<\/sub>\uff09\u7535\u6c60\u5177\u6709\u9ad8\u7684\u7406\u8bba\u6bd4\u80fd\u91cf\uff0c\u5176\u5b9e\u7528\u88c5\u7f6e\u88ab\u8ba4\u4e3a\u662f\u4e00\u9879\u98a0\u8986\u6027\u6280\u672f\u3002\u975e\u6c34\u7cfbLi-O<sub>2<\/sub>\u7535\u6c60\u662f\u7531Li\u8d1f\u6781\u548c\u591a\u5b54\u6c27\u6b63\u6781\u7ec4\u6210\uff0c\u4e2d\u95f4\u7531Li<sup>+<\/sup>\u5bfc\u7535\u7684\u7535\u89e3\u8d28\u9694\u5f00\uff0c\u5145\u653e\u7535\u8fc7\u7a0b\u4f9d\u8d56\u8d1f\u6781\u4e0aLi\u7684\u5265\u79bb\/\u6c89\u79ef\u548c\u6b63\u6781\u4e0aLi<sub>2<\/sub>O<sub>2<\/sub>\u7684\u5f62\u6210\/\u5206\u89e3\u3002\u7136\u800c\uff0c\u76ee\u524d\u7684Li-O<sub>2<\/sub>\u7535\u6c60\u8fd8\u5b58\u5728\u653e\u7535\u5bb9\u91cf\u4f4e\u3001\u5f80\u8fd4\u6548\u7387\u4f4e\u3001\u5bc4\u751f\u53cd\u5e94\u4e25\u91cd\u7b49\u95ee\u9898\u3002\u76ee\u524d\u7684Li-O<sub>2<\/sub>\u7535\u6c60\u7684\u653e\u7535\u8fc7\u7a0b\u662f\u901a\u8fc7\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u4ea7\u751f\u8d85\u6c27\u5316\u7269\uff08\u8d85\u6c27\u81ea\u7531\u57faO<sub>2<\/sub><sup>.-<\/sup>\/\u8d85\u6c27\u5316\u9502LiO<sub>2<\/sub>\uff09\uff0c\u8fd9\u4e9b\u8d85\u6c27\u5316\u7269\u53ef\u4ee5\u5438\u9644\u5728\u6b63\u6781\u8868\u9762\u6216\u8005\u6eb6\u89e3\u5728\u7535\u89e3\u8d28\u6eb6\u6db2\u4e2d\uff0c\u5e76\u4f34\u968f\u7740Li<sub>2<\/sub>O<sub>2<\/sub>\u7684\u5f62\u6210\u3002\u5728\u653e\u7535\u548c\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0c\u5bc4\u751f\u53cd\u5e94\u90fd\u4e0d\u53ef\u907f\u514d\u5730\u53d1\u751f\u3002\u76ee\u524d\u51cf\u8f7b\u5bc4\u751f\u53cd\u5e94\u7684\u7b56\u7565\u5305\u62ec\u4f7f\u7528\u4f4eLi<sup>+<\/sup>\u53cd\u5e94\u6027\u7684\u9ad8\u4f9b\u4f53\u6570\u91cf\u7684\u6eb6\u5242\u548c\u76d0\u7c7b\uff0c\u53ef\u4ee5\u7a33\u5b9a\u8d85\u6c27\u81ea\u7531\u57fa\u7684\u6dfb\u52a0\u5242\uff0c\u4ee5\u53ca\u53ef\u4ee5\u5728\u6b63\u6781\u8868\u9762\u548c\u6eb6\u89e3\u6c27\u4e4b\u95f4\u4f20\u9012\u7535\u5b50\u7684\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u3002\u4fc3\u8fdbLi<sub>2<\/sub>O<sub>2<\/sub>\u5728\u7535\u89e3\u8d28\u6eb6\u6db2\u4e2d\u7684\u5f62\u6210\uff0c\u589e\u52a0\u653e\u7535\u5bb9\u91cf\uff0c\u5176\u4e2d\u6c27\u5316\u8fd8\u539f\u5242\u8868\u73b0\u51fa\u7a81\u51fa\u7684\u6027\u80fd\u3002\u7136\u800c\uff0cLi<sub>2<\/sub>O<sub>2<\/sub>\u5f88\u96be\u88ab\u6c27\u5316\uff0c\u56e0\u4e3a\u5b83\u4e0e\u6b63\u6781\u8868\u9762\u7684\u7269\u7406\u63a5\u89e6\u5f88\u5dee\uff0c\u800c\u4e14\u5176\u672c\u8eab\u7684\u7535\u5b50\u548c\u79bb\u5b50\u4f20\u5bfc\u6027\u5f88\u4f4e\u3002\u6c27\u6c14\u8fdb\u5316\u53cd\u5e94\uff08OER\uff09\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u80fd\u591f\u6709\u6548\u5730\u6c27\u5316Li<sub>2<\/sub>O<sub>2<\/sub>\u3002\u5728\u6b63\u6781\u8868\u9762\u4ea7\u751f\u7684\u6c27\u5316\u5242\u53ef\u4ee5\u6269\u6563\u5230\u7535\u89e3\u8d28\u6eb6\u6db2\u4e2d\uff0c\u5e76\u5c06Li<sub>2<\/sub>O<sub>2<\/sub>\u6c27\u5316\u6210O<sub>2<\/sub>\uff0c\u5176\u672c\u8eab\u4e5f\u53ef\u4ee5\u518d\u751f\u3002\u7531\u4e8eOER\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u901a\u5e38\u8fdc\u4f4e\u4e8e\u4e3aLi-O<sub>2<\/sub>\u7535\u6c60\u5145\u7535\u6240\u9700\u7684\u7535\u4f4d\uff08&gt;4.0 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1 <\/strong><strong>\u5728\u7535\u89e3\u8d28\u4e2d\uff0c<\/strong><strong>PDI-TEMPO<\/strong><strong>\u7684\u6c27\u5316\u8fd8\u539f\u80fd\u529b\u5206\u6790 <span style=\"color: #999999;\">\u00a9 2022 The Authors<\/span><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232400\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/sciadv.abm1899-f1.jpg\" alt=\"\" width=\"600\" height=\"442\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/sciadv.abm1899-f1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/sciadv.abm1899-f1-300x221.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08A\uff0cB\uff09PDI-TEMPO\u7684\u5206\u5b50\u7ed3\u6784\u548c\u7acb\u4f53\u7ed3\u6784\uff1b<\/p>\n<p>\uff08C\uff09\u5728\u6c29\u6c14\u6c14\u6c1b\u7684DEGDME\u7535\u89e3\u6db2\u4e2d\uff0c\u6709\u65e0PDI-TEMPO\u65f6\u4e09\u7535\u6781\u7535\u6c60\u7684CV\u66f2\u7ebf<\/p>\n<p>\uff08D\uff09\u57281.8-4.4 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src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/sciadv.abm1899-f4.jpg\" alt=\"\" width=\"600\" height=\"325\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/sciadv.abm1899-f4.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/sciadv.abm1899-f4-300x163.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08A\uff0cB\uff09\u6dfb\u52a0PDI-TEMPO\u7535\u89e3\u8d28\u548c\u88f8DEGDME\u7535\u89e3\u8d28\u7684Li-O<sub>2<\/sub>\u7535\u6c60\u7684\u653e\u7535-\u5145\u7535\u66f2\u7ebf\u548c\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p>\uff08C\uff0cD\uff09\u88f8DEGDME\u7535\u89e3\u6db2\u548c\u6dfb\u52a0PDI-TEMPO\u7535\u89e3\u6db2\u5faa\u73af\u540e\u7535\u6781\u7684FTIR\u5149\u8c31\u3002<\/p>\n<p>\uff08E\uff0cF\uff09\u88f8DEGDME\u7535\u89e3\u6db2\u548c\u6dfb\u52a0PDI-TEMPO\u7535\u89e3\u6db2\u5faa\u73af\u540e\u7684\u7535\u6781\u7684XRD\u56fe\u8c31\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong> 5<\/strong> P<strong>DI-TEMPO<\/strong><strong>\u5bf9<\/strong><strong>Li<\/strong><strong>\u8d1f\u6781\u548c\u5faa\u73af\u6027\u80fd\u7684\u5f71\u54cd\u00a0<span style=\"color: #999999;\">\u00a9 2022 The Authors<\/span><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232396\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/sciadv.abm1899-f5.jpg\" alt=\"\" width=\"600\" height=\"359\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/sciadv.abm1899-f5.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/sciadv.abm1899-f5-300x180.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08A\uff09PDI-TEMPO\u548c\u77f3\u58a8\u78b3\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08B\uff0cC\uff09\u5faa\u73af10\u6b21\u540e\uff0c\u88f8DEGDME\u7535\u89e3\u6db2\u548c\u6dfb\u52a0PDI-TEMPO\u7535\u89e3\u6db2\u7684Li\u8d1f\u6781\u7684SEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08D\uff0cE\uff09\u6dfb\u52a010 mM 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href=\"https:\/\/www.science.org\/doi\/10.1126\/sciadv.abm1899\" target=\"_blank\" rel=\"noopener\"><strong>A long-life lithium-oxygen battery via a molecular quenching\/mediating mechanism<\/strong><\/a>\uff08Science Advances DOI: 10.1126\/sciadv.abm1899\uff09\u3002<\/p>\n<p><strong>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<\/strong><strong>cailiaokefu<\/strong><strong>\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002\u672c\u6587\u7531\u6750\u6599\u4ebaMaterials_1219\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 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