{"id":232371,"date":"2022-01-27T06:08:53","date_gmt":"2022-01-26T22:08:53","guid":{"rendered":"\/\/m.iemloyee.com\/?p=232371"},"modified":"2022-01-26T20:09:06","modified_gmt":"2022-01-26T12:09:06","slug":"nano-lett-%e6%a3%89%e8%8a%b1%e8%a1%8d%e7%94%9f%e7%9a%84fe-fe3c%e5%b0%81%e8%a3%85%e7%a2%b3%e7%ba%b3%e7%b1%b3%e7%ae%a1%e5%8a%a9%e5%8a%9b%e9%ab%98%e6%80%a7%e8%83%bd%e9%94%82%e7%a1%ab%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=232371","title":{"rendered":"Nano Lett: \u68c9\u82b1\u884d\u751f\u7684Fe\/Fe3C\u5c01\u88c5\u78b3\u7eb3\u7c73\u7ba1\u52a9\u529b\u9ad8\u6027\u80fd\u9502\u786b\u7535\u6c60"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u7531\u4e8e\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad\u6548\u5e94\uff0c\u9502\u786b\u7535\u6c60\u96be\u4ee5\u5728\u5b9e\u9645\u751f\u6d3b\u4e2d\u5f97\u5230\u5e94\u7528\uff0c\u5c06\u6d3b\u6027\u7269\u8d28\u786b\u9650\u57df\u5230\u78b3\u7eb3\u7c73\u7ba1\u4e2d\u662f\u4e00\u79cd\u6709\u6548\u6291\u5236\u7a7f\u68ad\u6548\u5e94\u7684\u7b56\u7565\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5546\u7528\u78b3\u7eb3\u7c73\u7ba1\u5b54\u5f84\u8f83\u5c0f\uff0c\u96be\u4ee5\u5b9e\u73b0\u5b9e\u9645\u610f\u4e49\u7684\u786b\u5c01\u88c5\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u7f8e\u56fd\u5f17\u5409\u5c3c\u4e9a\u5927\u5b66<\/strong>Xiaodong Li<\/strong>\u8bfe\u9898\u7ec4<\/strong>\uff0c\u62a5\u9053\u4e86\u4e00\u79cdFe\/Fe3<\/sub>C\u4fee\u9970\u7684\u68c9\u82b1\u884d\u751f\u78b3\u7eb3\u7c73\u7ba1\uff0c\u8fd9\u79cd\u78b3\u7eb3\u7c73\u7ba1\u5b54\u5f84\u8fbe\u523040 nm\uff0c\u5728\u5f62\u6210\u78b3\u7eb3\u7c73\u7ba1\u7684\u8fc7\u7a0b\u4e2d\uff0cFe\/Fe3<\/sub>C\u88ab\u5747\u5300\u5730\u5305\u88f9\u5728\u78b3\u7eb3\u7c73\u7ba1\u91cc\u9762\u5f62\u6210\u6709\u6548\u7684\u7535\u5316\u5b66\u5438\u9644\u50ac\u5316\u5242\u3002\u8fd9\u79cd\u78b3\u7eb3\u7c73\u7ba1\u7ed3\u6784\u5728\u5fae\u89c2\u5c3a\u5ea6\u4e0a\u96c6\u7269\u7406\u9650\u57df\uff0c\u5316\u5b66\u5438\u9644\u548c\u7535\u5316\u5b66\u50ac\u5316\u4e09\u4f4d\u4e00\u4f53<\/strong>\uff0c\u5f97\u5230\u7684\u9502\u786b\u7535\u6c60\u62e5\u6709\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5176\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u4e3b\u8981\u5f52\u529f\u4e8eFe\/Fe3<\/sub>C-MWCNTs\u51fa\u8272\u7684\u673a\u68b0\u548c\u5316\u5b66\u6027\u80fd\uff0c\u51cf\u8f7b\u4e86\u78b3\u7eb3\u7c73\u7ba1\u7684\u53d8\u5f62\u5e76\u6291\u5236\u4e86\u591a\u786b\u5316\u7269\u7684\u6eb6\u89e3\u3002\u6b64\u5916\uff0c\u6587\u7ae0\u6df1\u5c42\u6b21\u6316\u6398\u4e86\u78b3\u7eb3\u7c73\u7ba1\u751f\u957f\u7684\u673a\u7406\u8fc7\u7a0b\uff0c\u539f\u5b50\u6a21\u62df\u63ed\u793a\u4e86\u68c9\u82b1\u5982\u4f55\u5206\u89e3\u6210\u65e0\u5b9a\u5f62\u78b3\uff0c\u800c\u65e0\u5b9a\u5f62\u78b3\u53c8\u6210\u4e3a\u591a\u58c1\u7eb3\u7c73\u7ba1\u751f\u957f\u7684\u78b3\u6e90\u3002\u8fd9\u79cd\u65b0\u578b\u7684Fe\/Fe3<\/sub>C\u4fee\u9970\u7684\u68c9\u82b1\u884d\u751f\u78b3\u7eb3\u7c73\u7ba1\u4e3a\u9502\u786b\u7535\u6c60\u7684\u7535\u6781\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002\u76f8\u5173\u8bba\u6587\u4ee5\u9898\u4e3a\u201cCotton-Derived Fe\/Fe3<\/sub>C<\/em>\u2011<\/em>Encapsulated Carbon Nanotubes for <\/em>high <\/em>Performance Lithium<\/em>\u2212<\/em>Sulfur Batteries<\/em>\u201d\u53d1\u8868\u5728Nano Lett<\/em><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u6790\u3011<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1<\/strong> \u68c9\u82b1\u884d\u751f\u7684 Fe\/Fe3<\/sub>C \u586b\u5145\u591a\u58c1\u7eb3\u7c73\u7ba1\u7684\u5236\u5907\u6d41\u7a0b\u56fe\u3001\u56fe\u50cf\u548c MD \u6a21\u62df \u00a9 2022 American Chemical Society<\/p>\n

\u56fe<\/strong>1<\/strong>\u8be6\u7ec6\u4ecb\u7ecd\u4e86\u68c9\u82b1\u884d\u751f\u7684 Fe\/Fe3<\/sub>C \u586b\u5145\u7684\u591a\u58c1\u7eb3\u7c73\u7ba1(Fe\/Fe3<\/sub>C-MWCNTs)\u7684\u5408\u6210\u8fc7\u7a0b\uff0c\u901a\u8fc7SEM\u8bc1\u5b9e\u5f97\u5230\u7684Fe\/Fe3<\/sub>C-MWCNTs\u5e73\u5747\u76f4\u5f84\u4e3a40 nm\uff0c\u957f\u5ea6\u4e3a300 nm\u3002TEM\u663e\u793a\u6240\u6709\u7eb3\u7c73\u7ba1\u90fd\u586b\u5145\u6709\u76f4\u5f8420\u81f350 nm\u7684\u7eb3\u7c73\u7ebf\uff0cHR-TEM\u663e\u793a\u7eb3\u7c73\u7ebf\u7684\u6676\u683c\u6761\u7eb9\u95f4\u8ddd\u4e3a0.20 \u548c0.34 nm\uff0c\u5206\u522b\u5bf9\u5e94\u03b1-Fe\u7684(110)\u6676\u9762\u548cFe3<\/sub>C\u7684(002)\u6676\u9762\u3002\u03b1-Fe\u7eb3\u7c73\u7c92\u5b50\u7531C6<\/sub>H5<\/sub>FeO7<\/sub> \u524d\u9a71\u4f53\u4ea7\u751f\uff0c\u7531\u68c9\u82b1\u5206\u89e3\u5f97\u5230\u7684\u542b\u78b3\u6c14\u4f53\u548c\u65e0\u5b9a\u5f62\u78b3\u6269\u6563\u5230\u5f97\u5230\u7684 \u03b1-Fe \u9897\u7c92\u4e2d\u5e76\u91ca\u653e\u51fa\u78b3\u539f\u5b50\uff0c\u5c06\u5176\u77f3\u58a8\u5316\u4ee5\u5f62\u6210 Fe\/Fe3<\/sub>C \u5c01\u88c5\u7684 MWCNT\u3002\u5b8c\u6574\u7684\u7eb3\u7c73\u7ba1\u58c1\u5177\u67090.34 nm\u6676\u683c\u6761\u7eb9\u95f4\u8ddd\uff0c\u4e0e\u6676\u4f53\u78b3\u7684(002)\u6676\u9762\u4e00\u81f4\u3002\u4e3a\u4e86\u4e86\u89e3\u68c9\u82b1\u7684\u5206\u89e3\u548c\u77f3\u58a8\u5316\u673a\u5236\uff0c\u8fdb\u884c\u4e86\u4e00\u7cfb\u5217\u5b9e\u9a8c\u548c MD\u6a21\u62df\u3002MD\u6a21\u62df\u663e\u793a\uff0c\u8f83\u5c0f\u7684\u78b3\u7c07\u5206\u89e3\u6210\u5355\u4e2a\u78b3\u539f\u5b50\uff0c\u800c\u8f83\u5927\u7684\u78b3\u7c07\u5206\u89e3\u6210\u8bb8\u591a\u78b3\u94fe\uff0c\u5176\u4e2d\u4e00\u4e9b\u94fe\u592a\u5927\u800c\u65e0\u6cd5\u91cd\u65b0\u7ec4\u88c5\u6210\u516d\u5143\u78b3\u73af\uff0c\u56e0\u6b64\u5728\u7eb3\u7c73\u7ba1\u58c1\u4e2d\u4fdd\u6301\u65e0\u5e8f\u3002<\/p>\n

\"\"<\/p>\n

\u56fe\uff12<\/strong> Fe\/Fe3<\/sub>C-MWCNT@ACT\/S\u590d\u5408\u6750\u6599\u7684\u5408\u6210\u4e0e\u8868\u5f81 \u00a9 2022 American Chemical Society<\/p>\n

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\"\"<\/p>\n

\u56fe\uff13<\/strong> Li-Fe\/Fe3<\/sub>C-MWCNT@ACT\/S\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81 \u00a9 2022 American Chemical Society<\/p>\n

\u5728\u56fe\uff13<\/strong>\u4e2d\uff0c\u4e3a\u4e86\u63a2\u7a76Fe\/Fe3<\/sub>C-MWCNTs\u5728Li-S\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u6f5c\u529b\uff0c\u5c06Fe\/Fe3<\/sub>C-MWCNT@ACT\/S\u590d\u5408\u6750\u6599\u4f5c\u4e3a\u6b63\u6781\uff0cFe\/Fe3<\/sub>C-MWCNT@ACT\u4f5c\u4e3a\u4e2d\u95f4\u5c42\u7ec4\u88c5\u6263\u5f0fLi-S\u7535\u6c60\u3002\u57281000\u6b21\u5faa\u73af\u540e\uff0c\u7535\u6c60CV\u66f2\u7ebf\u5f62\u72b6\u548c\u5cf0\u503c\u4fdd\u6301\u4e0d\u53d8\uff0c\u8bc1\u660e\u4e86Li-Fe\/Fe3<\/sub>C-MWCNT@ACT\/S \u7535\u6c60\u7684\u5f3a\u5927\u53ef\u9006\u6027\u3002\u5728\u524d350\u4e2a\u5faa\u73af\u671f\u95f4\uff0c\u5145\/\u653e\u7535\u66f2\u7ebf\u7684\u6574\u4f53\u7279\u5f81\u4fdd\u6301\u4e0d\u53d8\uff0c\u8868\u660e Li-Fe\/Fe3<\/sub>C-MWCNT@ACT\/S \u7535\u6c60\u5177\u6709\u7a33\u5b9a\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002EIS \u56fe\u8c31\u5728\u7b2c\u4e00\u6b21\u5faa\u73af\u4e2d\u8868\u73b0\u51fa\u76f8\u5bf9\u8f83\u5c0f\u7684\u5185\u963b\uff0c\u8868\u660eFe\/Fe3<\/sub>C-MWCNTs\u5728\u589e\u52a0\u7535\u5bfc\u7387\u65b9\u9762\u662f\u6709\u6548\u7684\u3002\u4ee4\u4eba\u5370\u8c61\u6df1\u523b\u7684\u662f\uff0c\u7531\u4e8eACTs\u548cFe\/Fe3<\/sub>C-MWCNTs\u7684\u786b\u5229\u7528\u7387\u63d0\u9ad8\uff0c\u5728173\u6b21\u5145\/\u653e\u7535\u5faa\u73af\u540e\uff0c\u7535\u6c60\u5bb9\u91cf\u589e\u52a0\u5230948 mAh g-1<\/sup>\u3002\u5177\u6709\u4e2d\u95f4\u5c42\u7684Li-Fe\/Fe3<\/sub>C-MWCNT@ACT\/S\u7535\u6c60\u57281.0 C\u4e0b\u4e5f\u8868\u73b0\u51fa\u8d85\u8fc71000\u6b21\u5145\/\u653e\u7535\u5faa\u73af\u7684\u8d85\u957f\u5bff\u547d\uff0c\u5176\u5bf9\u5e94\u7684\u5e93\u4ed1\u6548\u7387\u51e0\u4e4e\u4fdd\u6301100%\u3002<\/p>\n

\"\"<\/p>\n

\u56fe\uff14<\/strong> Fe\/Fe3<\/sub>C-MWCNT@ACT\/S\u6b63\u6781\u548cFe\/Fe3<\/sub>C-MWCNT@ACT\u4e2d\u95f4\u5c42\u63d0\u5347\u7535\u6c60\u6027\u80fd\u7684\u673a\u7406\u7814\u7a76 \u00a9 2022 American Chemical Society<\/p>\n

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\u6587\u732e\u94fe\u63a5: Cotton-Derived Fe\/Fe3<\/sub>C\u2011Encapsulated Carbon Nanotubes for High Performance Lithium\u2212Sulfur Batteries. 2022, Nano Lett, doi: 10.1021\/acs.nanolett.<\/p>\n","protected":false},"excerpt":{"rendered":"

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