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(a) CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u5728\u5fae\u6ce2\u7167\u5c04\u4e0b\u7684\u5f62\u6001\u6f14\u5316\u793a\u610f\u56fe\uff1b(b\uff0cc) \u539f\u59cb\u786b\u5316\u94dc\uff1b(d\uff0ce) CuS<sub>0.96<\/sub>Te<sub>0.04<\/sub>\uff1b(f\uff0cg) CuS<sub>0.78<\/sub>Te<sub>0.22<\/sub>\uff0c(h\uff0ci)CuS<sub>0.77<\/sub>Te<sub>0.23<\/sub>\u7eb3\u7c73\u7247\u7684\u5178\u578bFESEM\u56fe\u50cf\u3002<\/p>\n<p><a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72471-6.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232130\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72471-6.jpg\" alt=\"\" width=\"837\" height=\"498\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72471-6.jpg 837w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72471-6-300x178.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72471-6-768x457.jpg 768w\" sizes=\"(max-width: 837px) 100vw, 837px\" \/><\/a><\/p>\n<p>2.Te\u53d6\u4ee3CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u7684\u8868\u5f81<\/p>\n<p>\u968f\u7740Te\u542b\u91cf\u7684\u589e\u52a0\uff0cCuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u4f1a\u9010\u6e10\u6536\u7f29\u5e76\u7d27\u5bc6\u7ec4\u88c5\uff0c\u5355\u4e2a\u7eb3\u7c73\u7247\u7684\u5e73\u9762\u5185\u5c3a\u5bf8\u4f1a\u9010\u6e10\u51cf\u5c0f\u3002\u5728\u63ba\u6742\u5c11\u91cfTe\u7684\u60c5\u51b5\u4e0b\uff0c\u6bcf\u4e2a\u7eb3\u7c73\u7247\u7684\u6574\u4f53\u7ec4\u88c5\u5c3a\u5bf8\u5c06\u4f1a\u589e\u52a0\u3002CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u4e2d\u786b\u4e0e\u7852\u7684\u539f\u5b50\u6570\u6bd4\u5206\u522b\u4e3a0.96:0.04\u30010.78:0.22\u548c0.77:0.23\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u7535\u611f\u8026\u5408\u7b49\u79bb\u5b50\u4f53\u8d28\u8c31(ICP-MS)\u7684\u8fdb\u4e00\u6b65\u6d4b\u5b9a\u4e86Te\u7684\u7cbe\u786e\u542b\u91cf\uff0c\u8bc1\u5b9e\u4e86Te\u542b\u91cf\u5448\u76f8\u540c\u7684\u4e0a\u5347\u8d8b\u52bf\u3002\u6b64\u5916\uff0c\u6709\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\uff0c\u9634\u79bb\u5b50Te\u53d6\u4ee3\u53ef\u4ee5\u6291\u5236CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u4e2d\uff08103\uff09\u548c\uff08110\uff09\u6676\u9762\u7684\u6676\u4f53\u53d6\u5411\uff0c\u4e3a\u534a\u5bfc\u4f53\u6750\u6599\u7684\u5408\u6210\u63d0\u4f9b\u4e86\u4e00\u79cd\u5b9e\u7528\u7684\u6676\u4f53\u5de5\u7a0b\u7b56\u7565\u3002\u672c\u6587\u8fd8\u5229\u7528\u900f\u5c04\u7535\u955c(TEM)\u5bf9\u4f18\u5316\u540e\u7684CuS<sub>1-x<\/sub>Te<sub>x<\/sub>(x=0.04)\u7eb3\u7c73\u7247\u8fdb\u884c\u4e86\u8868\u5f81\u3002\u5178\u578b\u7684\u4f4e\u500d\u900f\u5c04\u7535\u955c\u56fe\u50cf(\u56fe2d)\u663e\u793a\u51fa\u6e05\u6670\u7684\u4e09\u7ef4\u5c42\u72b6\u82b1\u6837\uff0c\u5176\u76f4\u5f84\u4e3a1.5-2.5\u03bcm\u3002\u653e\u5927\u900f\u5c04\u7535\u955c\u56fe\u50cf(\u56fe2e)\u53d1\u73b0\uff0c\u82b1\u6837\u7531\u8d85\u8584\u7eb3\u7c73\u7247\u7ec4\u6210\uff0c\u5177\u6709\u900f\u660e\u7684\u51e0\u4f55\u77f3\u58a8\u70ef\u7279\u5f81\u3002\u6b64\u5916\uff0c\u6839\u636eHRTEM\u548cXRD\u7684\u7ed3\u679c\uff0c\u4e0e\u539f\u59cb\u7684CuS\u7eb3\u7c73\u7247\u76f8\u6bd4\uff0cTe\u53d6\u4ee3\u7684CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u7684\uff08102\uff09\u6676\u9762\u7684\u95f4\u8ddd\u7565\u6709\u589e\u5927\u3002\u7136\u800c\uff0c\u4e0e\u4ee5\u5f80\u7684\u7814\u7a76\u76f8\u6bd4\uff0c\u5c42\u95f4\u8ddd\u7684\u8f7b\u5fae\u81a8\u80c0\u5e76\u4e0d\u660e\u663e\uff0c\u5bf9Mg<sup>2+<\/sup>\u6269\u6563\u7684\u5f71\u54cd\u53ef\u4ee5\u5ffd\u7565\u4e0d\u8ba1\u3002<\/p>\n<p>\u56fe2. CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u7684\u5316\u5b66\u6210\u5206\u548c\u7ed3\u6784\u7279\u5f81<\/p>\n<p><a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/2-10.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232131\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/2-10.jpg\" alt=\"\" width=\"745\" height=\"627\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/2-10.jpg 745w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/2-10-300x252.jpg 300w\" sizes=\"(max-width: 745px) 100vw, 745px\" \/><\/a><\/p>\n<p>\u56fe3. CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u7684\u540c\u6b65\u8f90\u5c04XAFS\u8868\u5f81<\/p>\n<p><a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/3-11.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232132\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/3-11.jpg\" alt=\"\" width=\"764\" height=\"593\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/3-11.jpg 764w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/3-11-300x233.jpg 300w\" sizes=\"(max-width: 764px) 100vw, 764px\" \/><\/a><\/p>\n<p>3.Te\u53d6\u4ee3CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u7684\u50a8\u9541\u6027\u80fd<\/p>\n<p>\u672c\u6587\u5c06\u5236\u5907\u7684Te\u53d6\u4ee3CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u4f5c\u4e3a\u9ad8\u6027\u80fd\u53ef\u5145\u7535\u9541\u7535\u6c60\u7684\u6f5c\u5728\u9634\u6781\u6750\u6599\uff0c\u5e76\u6d4b\u8bd5\u4e86\u5b83\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u5178\u578b\u7684CV\u66f2\u7ebf\u9664\u4e86\u7b2c\u4e00\u4e2a\u5faa\u73af\u5916\u5747\u53ef\u4fdd\u6301\u76f8\u4f3c\u7684\u8f6e\u5ed3\uff0c\u8868\u660e\u5728Mg(HMDS)<sub>2<\/sub>-AlCl<sub>3<\/sub>\/\u4e59\u4e8c\u9187\u4e8c\u7532\u919a(GDME)\u7535\u89e3\u8d28\u4f53\u7cfb\u4e2dCuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u9634\u6781\u5177\u6709\u826f\u597d\u7684\u5316\u5b66\u53ef\u9006\u6027\u3002\u4e0e\u7b2c\u4e00\u4e2a\u5faa\u73af\u76f8\u6bd4\uff0c\u6c27\u5316\u5cf0\u548c\u8fd8\u539f\u5cf0\u5411\u8d1f\u7535\u4f4d\u65b9\u5411\u7565\u6709\u79fb\u52a8\u3002\u8fd9\u4e00\u73b0\u8c61\u662f\u7531\u4e8eCuS<sub>1-x<\/sub>Tex\u7eb3\u7c73\u7247\u9634\u6781\u5728\u7b2c\u4e00\u4e2a\u5faa\u73af\u4e2d\u7684\u53d1\u751f\u8868\u9762\u6d3b\u5316\u5f15\u8d77\u7684\u3002CV\u66f2\u7ebf\u4e0a\u4f4d\u4e8e0.41V\u30011.42V\u30011.72V\u548c1.96 V\u76844\u4e2a\u660e\u663e\u6c27\u5316\u5cf0\uff0c\u4ee5\u53ca0.87V\u548c0.98V\u7684\u4e24\u4e2a\u8fd8\u539f\u5cf0\u80fd\u591f\u88ab\u5f88\u597d\u7684\u533a\u522b\u3002\u8fd9\u4e9b\u7279\u5f81\u5cf0\u5206\u522b\u4e0eCu<sup>2+<\/sup>\u5411Cu<sup>+<\/sup>\u548cCu<sup>+<\/sup>\u5411Cu\u7684\u53ef\u9006\u7535\u5316\u5b66\u8f6c\u5316\u8fc7\u7a0b\u6709\u5173\u3002CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u5177\u6709\u8f83\u9ad8\u7684\u521d\u59cb\u653e\u7535\u5bb9\u91cf\uff0c\u4e3a350mAhg<sup>-1<\/sup>\uff0c\u4f46\u662f\u5728\u4e4b\u540e\u7684\u5faa\u73af\u4e2d\u5bb9\u91cf\u51fa\u73b0\u5927\u5e45\u5ea6\u964d\u4f4e\uff0c\u4e14\u7eb3\u7c73\u7247\u7684\u521d\u59cb\u5e93\u4ed1\u6548\u7387\u4e5f\u76f8\u5bf9\u8f83\u4f4e\uff0c\u53ea\u670916.73%\u3002\u8fd9\u4e9b\u73b0\u8c61\u5e94\u8be5\u662f\u7531\u4e8e\u4e0d\u53ef\u9006\u7684\u526f\u53cd\u5e94\u548c\u56fa\u4f53\u7535\u89e3\u8d28\u819c\u7684\u5f62\u6210\u9020\u6210\u7684\u3002\u800c\u5728\u968f\u540e\u7684\u5faa\u73af\u4e2d\u7eb3\u7c73\u7247\u53ef\u4ee5\u4fdd\u6301\u8d85\u8fc799.96%\u7684\u6781\u9ad8\u5e93\u4ed1\u6548\u7387\u3002\u6b64\u5916\uff0cCuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u5bf9\u786c\u7535\u8377\u52a0\u8f7d\u6709\u826f\u597d\u7684\u8010\u53d7\u6027\uff0c\u5373\u4f7f\u57281000 mA g<sup>\u22121<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u4e5f\u53ef\u4ee5\u8fbe\u5230100 mAh g<sup>\u22121<\/sup>\u7684\u9ad8\u5bb9\u91cf\u3002CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u5bf9\u7535\u6d41\u53d8\u5316\u5177\u6709\u826f\u597d\u7684\u901f\u7387\u80fd\u529b\u3002\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u7ed3\u675f\u540e\uff0c\u5f53\u7535\u6d41\u5bc6\u5ea6\u6062\u590d\u4e3a20 mA g<sup>\u22121<\/sup>\u65f6\uff0c\u5176\u5bb9\u91cf\u53ef\u4ee5\u6062\u590d\u5230397mAh g<sup>\u22121<\/sup>\u3002\u5bf9\u4e8e\u7eaf\u786b\u5316\u94dc\u7eb3\u7c73\u7247\uff0c\u5728\u76f8\u540c\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u53ea\u80fd\u63d0\u4f9b\u76f8\u5f53\u4f4e\u7684\u6bd4\u5bb9\u91cf\uff0c\u4ece\u8fd9\u91cc\u53ef\u4ee5\u770b\u51faTe\u9634\u79bb\u5b50\u53d6\u4ee3\u7684CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u5728\u7535\u6c60\u5bb9\u91cf\u65b9\u9762\u6709\u7740\u663e\u8457\u7684\u63d0\u5347\u3002\u9ad8Te\u542b\u91cf(x=0.22\u62160.23)\u7684CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u4e5f\u8868\u73b0\u51fa\u4e86\u826f\u597d\u7684\u50a8\u9541\u6027\u80fd\u3002CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u8fd8\u663e\u793a\u51fa\u8f83\u5f3a\u7684\u957f\u5bff\u547d\u5faa\u73af\u80fd\u529b\u3002\u5728\u7ecf\u53861500\u6b21\u5faa\u73af\u540e\uff0c\u6bcf\u4e2a\u5faa\u73af\u7684\u5bb9\u91cf\u8870\u51cf\u4ec5\u7ea6\u4e3a0.069%\u3002\u7814\u7a76\u8fd8\u53d1\u73b0\uff0c\u9634\u79bb\u5b50Te\u53d6\u4ee3\u7684CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u4e2d\uff0cCu\u4f4d\u70b9\u7684\u914d\u4f4d\u73af\u5883\u5177\u6709\u8c03\u8c10\u6548\u5e94\uff0c\u56e0\u6b64\u6709\u671b\u5728\u7535\u5316\u5b66\u50a8\u9541\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u9634\u79bb\u5b50\u7535\u5316\u5b66\u53cd\u5e94\u3002<\/p>\n<p>\u56fe4. CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n<p><a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/4-10.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232133\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/4-10.jpg\" alt=\"\" width=\"796\" height=\"619\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/4-10.jpg 796w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/4-10-300x233.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/4-10-768x597.jpg 768w\" sizes=\"(max-width: 796px) 100vw, 796px\" \/><\/a><\/p>\n<p>4.\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406<\/p>\n<p>\u672c\u6587\u901a\u8fc7\u975e\u539f\u4f4dXPS\u3001XRD\u548cTEM\u6d4b\u8bd5\uff0c\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86\u6750\u6599\u7684\u50a8\u9541\u673a\u7406\u3002\u7b2cI\u9636\u6bb5\u5230\u7b2cIV\u9636\u6bb5\u7684Mg 2p XPS\u5149\u8c31(\u56fe6c)\u8868\u660eMg<sup>2+<\/sup>\u79bb\u5b50\u662f\u901a\u8fc7\u76f4\u63a5\u63d2\u5165\u5bbf\u4e3b\u9634\u6781\u6750\u6599\u4e2d\u6765\u5f62\u6210\u786b\u5316\u9541\u3002\u5728V\u6001\u4e2d\u5b58\u5728\u7684Mg 2p\u5cf0\u8868\u660e\uff0c\u786b\u5316\u9541\u9010\u6e10\u88ab\u8fd8\u539f\uff0c\u91ca\u653e\u51faMg<sup>2+<\/sup>\u79bb\u5b50\u3002\u7b2cI\u9636\u6bb5\u7684Cu 2p\u8c31\u663e\u793a\u4e86Cu<sup>+<\/sup>\u548cCu<sup>2+<\/sup>\u7684\u4e24\u4e2a\u62df\u5408\u5cf0\uff0c\u5176\u4e2d\u73b0\u6709\u7684Cu<sup>+<\/sup>\u7684\u4ea7\u751f\u6765\u6e90\u4e24\u4e2a\u9636\u6bb5\u7684\u81ea\u653e\u7535\u8fc7\u7a0b\uff1aCu<sup>2+<\/sup>\u8fd8\u539f\u4e3aCu<sup>+<\/sup>\uff0c\u4ee5\u53caCu<sup>+<\/sup>\u8fd8\u539f\u4e3aCuO\u3002\u5f53\u653e\u7535\u81f31.2V(II)\u65f6\uff0cCuO\u5f3a\u5ea6\u7565\u6709\u589e\u52a0\uff0cCu<sup>2+<\/sup>\u5f3a\u5ea6\u964d\u4f4e\uff0c\u8bf4\u660eCuS\u5148\u8f6c\u79fb\u5230Cu<sub>2<\/sub>S\uff0c\u7136\u540e\u8f6c\u79fb\u5230Cu\u3002\u5728\u8fdb\u4e00\u6b65\u653e\u7535\u81f30.9V\u65f6\uff0cCuO\u5f3a\u5ea6\u8fdb\u4e00\u6b65\u589e\u52a0\uff0cCu<sup>2+<\/sup>\u5f3a\u5ea6\u5219\u964d\u4f4e\u3002\u800cCu<sup>+<\/sup>\u7684\u5f3a\u5ea6\u51e0\u4e4e\u6ca1\u6709\u53d8\u5316\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e24\u79cd\u8f6c\u5316\u53cd\u5e94\u7684\u76f8\u4e92\u8865\u507f\u6240\u81f4\u3002\u4f9d\u6b21\u653e\u7535\u52300.1V\u65f6\uff0cCuS\u76f8\u7684\u884d\u5c04\u5cf0\u503c\u9010\u6e10\u51cf\u5c0f\u5230\u6700\u5c0f\u503c\uff0c\u800cCuO\u76f8\u7684\u5cf0\u503c\u589e\u52a0\u5230\u6700\u5927\u5f3a\u5ea6\u3002\u8fd9\u8868\u660eCuS\u548cCu<sub>2<\/sub>S\u4e0eCu\u7684\u76f8\u4f4d\u53d1\u751f\u4e86\u53d8\u5316\u3002\u6b64\u5916\uff0c\u65b0\u4ea7\u751fMgS\u76f8\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e86CuS\u57fa\u9634\u6781\u6750\u6599\u53d1\u751f\u4e86\u8f6c\u5316\u53cd\u5e94\u3002\u6700\u540e\uff0c\u5f53\u5145\u7535\u56de\u52302.1V\u65f6\uff0cCuO\u76f8\u7684\u5f3a\u5ea6\u964d\u4f4e\uff0c\u4f46\u4ecd\u7136\u5b58\u5728\uff0c\u8fd9\u8bf4\u660eCu\u5e76\u6ca1\u6709\u5b8c\u5168\u8f6c\u5316\u4e3aCuS\u6216Cu<sub>2<\/sub>S\u3002<\/p>\n<p>\u56fe5. CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u7684\u7535\u5316\u5b66\u52a8\u529b\u5b66\u5206\u6790<\/p>\n<p><a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/5-9.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232134\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/5-9.jpg\" alt=\"\" width=\"865\" height=\"698\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/5-9.jpg 865w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/5-9-300x242.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/5-9-768x620.jpg 768w\" sizes=\"(max-width: 865px) 100vw, 865px\" \/><\/a><\/p>\n<p>\u56fe6. CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\u5206\u6790\u548c\u53cd\u5e94\u5fae\u89c2\u5f62\u8c8c\u5206\u6790<\/p>\n<p><a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/6-6.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232135\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/6-6.jpg\" alt=\"\" width=\"852\" height=\"792\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/6-6.jpg 852w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/6-6-300x279.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2022\/01\/6-6-768x714.jpg 768w\" sizes=\"(max-width: 852px) 100vw, 852px\" \/><\/a><\/p>\n<p>\u3010\u5c0f\u7ed3\u3011<\/p>\n<p>\u672c\u6587\u5f00\u53d1\u4e86\u4e00\u79cd\u5fae\u6ce2\u5316\u5b66\u5408\u6210\u65b9\u6cd5\u6765\u5236\u5907\u9634\u79bb\u5b50Te\u53d6\u4ee3\u7684CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\uff0c\u7528\u4ee5\u4f5c\u4e3a\u53ef\u5145\u7535\u9541\u7535\u6c60\u7684\u9ad8\u6027\u80fd\u9634\u6781\u6750\u6599\u3002\u5229\u7528\u5728\u786b\u539f\u5b50\u7684\u9634\u79bb\u5b50\u4f4d\u70b9\u8fdb\u884cTe\u9634\u79bb\u5b50\u53d6\u4ee3\uff0c\u53ef\u4ee5\u63d0\u5347\u6750\u6599\u7684\u7535\u5316\u5b66\u52a8\u529b\u5b66\u6027\u80fd\uff0c\u63d0\u9ad8\u5176\u6c27\u5316\u8fd8\u539f\u53ef\u9006\u6027\u3002\u6b64\u5916\uff0c\u8fc7\u91cfTe\u5bfc\u81f4\u7535\u5316\u5b66\u6027\u80fd\u964d\u4f4e\u7684\u539f\u56e0\u53ef\u80fd\u662f\u4e09\u7ef4\u5206\u5c42CuS\u7eb3\u7c73\u7247\u53d1\u751f\u5f62\u8c8c\u574d\u584c\uff0c\u524a\u5f31\u4e86\u539f\u672c\u7531Te\u53d6\u4ee3\u5f15\u8d77\u7684\u50a8\u9541\u52a8\u529b\u5b66\u63d0\u5347\u7684\u5e45\u5ea6\u3002CuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247CV\u66f2\u7ebf\u8868\u660e\uff0c\u9634\u79bb\u5b50Te\u53d6\u4ee3\u53ef\u4ee5\u964d\u4f4e\u8f6c\u5316\u53cd\u5e94\u7684\u52bf\u5792\uff0c\u4ece\u800c\u63d0\u9ad8\u52a8\u529b\u5b66\u548c\u6c27\u5316\u8fd8\u539f\u7684\u53ef\u9006\u6027\u3002\u6b64\u5916\uff0cCuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u572820 mAg<sup>\u22121<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u53ef\u4ee5\u63d0\u4f9b446 mAh g<sup>\u22121<\/sup>\u7684\u9ad8\u6bd4\u5bb9\u91cf\uff0c\u5e76\u4e14\u57281500\u4e2a\u5145\u653e\u7535\u5faa\u73af\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u957f\u5bff\u547d\u7a33\u5b9a\u6027\uff0c\u5176\u5bb9\u91cf\u8870\u51cf\u7387\u6bcf\u5468\u671f\u4ec5\u4e3a0.0345% A g<sup>\u22121<\/sup>\u3002\u4e0e\u4e4b\u524d\u62a5\u9053\u7684\u5176\u4ed6\u9634\u6781\u6750\u6599\u76f8\u6bd4\uff0cCuS<sub>1-x<\/sub>Te<sub>x<\/sub>\u7eb3\u7c73\u7247\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u4e5f\u663e\u793a\u51fa\u826f\u597d\u7684\u901f\u7387\u80fd\u529b\u548c\u8010\u53d7\u6027\uff0c\u5373\u4f7f\u57281Ag<sup>\u22121<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5176\u7406\u60f3\u5bb9\u91cf\u4ecd\u53ef\u4ee5\u4fdd\u6301\u5728100mAh g<sup>\u22121<\/sup>\u3002\u9634\u79bb\u5b50Te\u53d6\u4ee3\u7684\u6539\u6027\u7b56\u7565\u53ef\u4ee5\u8c03\u8282CuS\u57fa\u9634\u6781\u6750\u6599\u7684Cu<sup>0<\/sup>\/Cu<sup>+<\/sup>\u7535\u5bf9\u7684\u6c27\u5316\u8fd8\u539f\u8f6c\u5316\uff0c\u63d0\u9ad8\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u6709\u52a9\u4e8e\u8fdb\u4e00\u6b65\u63a2\u7d22\u6700\u5177\u524d\u666f\u7684\u9541\u79bb\u5b50\u5145\u7535\u7535\u6c60\u3002<\/p>\n<p><strong>\u3010\u6587\u7ae0\u94fe\u63a5\u3011<\/strong><\/p>\n<p>Anionic Te-Substitution Boosting the Reversible Redox in CuS Nanosheet Cathodes for Magnesium Storage<\/p>\n<p><a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acsnano.1c10253\">https:\/\/pubs.acs.org\/doi\/10.1021\/acsnano.1c10253<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u7814\u7a76\u80cc\u666f\u3011 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