{"id":231672,"date":"2022-01-06T06:14:44","date_gmt":"2022-01-05T22:14:44","guid":{"rendered":"\/\/m.iemloyee.com\/?p=231672"},"modified":"2022-01-05T20:15:02","modified_gmt":"2022-01-05T12:15:02","slug":"%e5%8d%97%e4%ba%ac%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6%e9%82%b5%e5%ae%97%e5%b9%b3adv-mater-%ef%bc%9a%e6%b0%a7%e5%8c%96%e6%b0%94%e6%b0%9b%e4%b8%8b%e9%98%b3%e7%a6%bb%e5%ad%90%e9%80%89%e6%8b%a9%e6%80%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=231672","title":{"rendered":"\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u90b5\u5b97\u5e73Adv. Mater.\uff1a\u6c27\u5316\u6c14\u6c1b\u4e0b\u9633\u79bb\u5b50\u9009\u62e9\u6027\u6eb6\u51fa\u5236\u5907\u7eb3\u7c73\u9897\u7c92\u4fee\u9970\u7684\u9499\u949b\u77ff\u578b\u8d28\u5b50\u9676\u74f7\u71c3\u6599\u7535\u6c60\u9634\u6781"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u4eac\u5de5\u4e1a\u5927\u5b66<\/strong>\u7684\u90b5\u5b97\u5e73\u6559\u6388\u3001\u6768\u5e7f\u660e\u526f\u6559\u6388<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u544a\u4e86\u4e00\u79cd\u5728\u6c27\u5316\u6c14\u6c1b\u4e2d\u7eb3\u7c73\u9897\u7c92\u9009\u62e9\u6027\u6eb6\u51fa\u7684\u7eb3\u7c73\u590d\u5408\u9634\u6781\u7528\u4e8ePCFCs\u3002\u901a\u8fc7\u5bf9\u6210\u5206\u548c\u9633\u79bb\u5b50\u975e\u5316\u5b66\u8ba1\u91cf\u7684\u63a7\u5236\uff0c\u8bbe\u8ba1\u3001\u5408\u6210\u5e76\u7814\u7a76\u4e86Ba0.95<\/sub>(Co0.4<\/sub>Fe0.4<\/sub>Zr0.1<\/sub>Y0.1<\/sub>)0.95<\/sub>Ni0.05<\/sub>O3-\u03b4<\/sub>\uff08BCFZYN-095\uff09\u524d\u9a71\u4f53\uff0c\u53ca\u5176\u7145\u70e7\u540e\u5f62\u6210\u7684\u7eb3\u7c73\u590d\u5408\u6750\u6599\uff0c\u5305\u62ec\u4e3b\u8981\u9499\u949b\u77ff\u6c27\u5316\u7269\u76f8\u548c\u5bcc\u96c6\u5728\u9499\u949b\u77ff\u6c27\u5316\u7269\u8868\u9762\u7684\u6b21\u8981NiO\u76f8\u3002\u9499\u949b\u77ff\u6c27\u5316\u7269\u76f8\u901a\u8fc7\u9633\u79bb\u5b50\u4fc3\u8fdb\u4e86\u8d28\u5b50\u4f20\u5bfc\uff0c\u800cNiO\u7eb3\u7c73\u9897\u7c92\u5219\u4fc3\u8fdb\u4e86\u6c27\u6c14\u7684\u8868\u9762\u4ea4\u6362\u8fc7\u7a0b\uff0c\u5bfc\u81f4\u4e86\u5353\u8d8a\u7684\u6027\u80fd\uff0c\u5728650\u2103\u65f6\u6700\u5927\u5cf0\u503c\u529f\u7387\u5bc6\u5ea6\u4e3a1040 mW cm-2<\/sup>\uff0c\u5728550\u2103\u65f6\u5177\u6709400\u5c0f\u65f6\u7684\u51fa\u8272\u7a33\u5b9a\u6027\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>A New Durable Surface Nanoparticles-Modified Perovskite Cathode for Protonic Ceramic Fuel Cells from Selective Cation Exsolution under Oxidizing Atmosphere<\/strong>\u201d\u53d1\u8868\u5728Advanced Materials<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 BCFZYN-095<\/strong>\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

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\uff08b\uff09BCFZYN-095\u7684Rietveld\u7cbe\u4fee\u56fe\uff1b<\/p>\n

\uff08c\uff09BCFZYN-095\u7684HR-TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08d\uff09BCFZYN-095\u7684EDX\u56fe\u3002<\/p>\n

\u56fe<\/strong> 2 BCFZYN-095<\/strong>\u7684\u4ef7\u6001\u5206\u6790<\/strong><\/p>\n

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\uff08c) BCFZYN-100\u548cBCFZYN-095\u7684Ni K-\u8fb9XANES\u5149\u8c31\uff1b<\/p>\n

\uff08d) BCFZYN-100\u548cBCFZYN-095\u7684O 1s\u7684XPS\u5149\u8c31\u3002<\/p>\n

\u56fe<\/strong> 3 BCFZYN-095-095<\/strong>\u7684\u9ad8\u6e29\u7279\u5f81<\/strong><\/p>\n

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\uff08b\uff09\u5728100-800\u2103\u4e4b\u95f4\uff0cBCFZYN-100\u548cBCFZYN-095\u7684O2<\/sub>-TPD\u56fe\uff1b<\/p>\n

\uff08c\uff09\u5728500-700\u2103\u4e4b\u95f4\uff0cBCFZYN-100\u548cBCFZYN-095\u62df\u5408\u7684Dchem<\/sub>\u548ckchem<\/sub>\u503c\uff1b<\/p>\n

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\uff08e\uff09\u5728450-650\u2103\u6e29\u5ea6\u8303\u56f4\u5185\uff0cBCFZYN-100\u548cBCFZYN-095\u7684\u8d28\u5b50\u7535\u5bfc\u7387\uff1b<\/p>\n

\uff08f\uff09\u572850-800\u00b0C\u65f6\uff0cBCFZYN-100\u548cBCFZYN-095\u7684\u0394L\/L0\u7684\u7ed3\u679c\u3002<\/p>\n

\u56fe<\/strong> 4 <\/strong>BCFZYN-095<\/strong>\u5728\u6c27\u79bb\u5b50\u5bfc\u4f53\u4e2d\u7684\u7535\u6c60\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728\u7a7a\u6c14\u4e2d\uff0c500-650\u2103\u8303\u56f4\u5185\uff0cBCFZY-100\u3001BCFZY-095\u3001BCFZYN-100\u3001BCFZYN-095\u548cm-BCFZYN-095\u7535\u6781\u7684ASRs Arrhenius\u56fe\uff1b<\/p>\n

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\uff08c\uff0cd\uff09\u5355\u7535\u6c60\u7684I-V\u3001I-P\u66f2\u7ebf\u548c\u5bf9\u5e94\u6e29\u5ea6\u4e0b\u7684\u963b\u6297\u56fe\u3002<\/p>\n

\u56fe<\/strong> 5<\/strong> BCFZYN-095<\/strong>\u5728\u8d28\u5b50\u5bfc\u4f53\u4e2d\u7684\u7535\u6c60\u6027\u80fd<\/strong><\/p>\n

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\uff08a\uff09BCFZY-100\u3001BCFZY-095\u3001BCFZYN-100\u3001BCFZYN-095\u548cm-BCFZYN-095\u7684ASRs Arrhenius\u56fe\uff1b<\/p>\n

\uff08b\uff09\u5728550\u00b0C\u4e0d\u540c\u6c34\u5206\u538b\u7684\u6e7f\u7a7a\u6c14\u4e2d\uff0cBCFZYN-095\u7535\u6781\u7684EIS\u56fe\uff1b<\/p>\n

\uff08c\uff09\u5728550\u00b0C\u4e0d\u540c\u6c34\u5206\u538b\u7684\u6e7f\u7a7a\u6c14\u4e2d\uff0cBCFZYN-095\u7535\u6781\u7684DRT\u56fe\uff1b<\/p>\n

\uff08d\uff09\u5728500\u00b0C\u76845% H2<\/sub>O-\u7a7a\u6c14\u4e2d\uff0cBCFZYN-100\u548cBCFZYN-095\u7535\u6781\u7684DRT\u56fe\uff1b<\/p>\n

\uff08e\uff09\u5728550\u00b0C\u76845% H2<\/sub>O-\u7a7a\u6c14\u4e2d\uff0c\u57fa\u4e8eBZCYYb\u652f\u6491\u7684\u5bf9\u79f0\u7535\u6c60\uff0cBCFZYN-095\u7535\u6781\u7684ASRs\u7684\u65f6\u95f4\u4f9d\u8d56\u6027\u3002<\/p>\n

\uff08f\uff0cg\uff09450-650\u00b0C\u65f6\uff0cNi+BZCYYb|BZCYYb|BCFZYN-095\u5355\u7535\u6c60\u7684I-V\u3001I-P\u66f2\u7ebf\u548c\u963b\u6297\u56fe\uff1b<\/p>\n

\uff08h\uff09BCFZYN-095\u590d\u5408\u9634\u6781\u548c\u6587\u732e\u4e2d\u590d\u5408\u9634\u6781\u7684PPDs\u7684\u6bd4\u8f83\uff1b<\/p>\n

\uff08i\uff09\u57280.2 A cm-2<\/sup>\u548c550\u00b0C\u65f6\uff0cBCFZYN-095\u7684\u5355\u7535\u6c60\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5<\/strong>A New Durable Surface Nanoparticles-Modified Perovskite Cathode for Protonic Ceramic Fuel Cells from Selective Cation Exsolution under Oxidizing Atmosphere<\/a>\uff08Advanced Materials \u00a0DOI: 10.1002\/adma.202106379\uff09\u3002<\/p>\n

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