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\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u9170\u57fa\u81ea\u7531\u57fa\u662fC-C\u952e\u5f62\u6210\u53cd\u5e94\u4e2d\u7684\u901a\u7528\u5408\u6210\u4e2d\u95f4\u4f53\uff0c\u5982Giese\u52a0\u6210\u53cd\u5e94\u3001Minici\u9170\u5316\u53cd\u5e94\u7b49\u3002\u7136\u800c\uff0c\u4f20\u7edf\u5236\u53d6\u9170\u57fa\u81ea\u7531\u57fa\u7684\u65b9\u6cd5\u901a\u5e38\u9700\u8981\u9ad8\u6e29\u3001\u7d2b\u5916\u7ebf\u7167\u5c04\u6216\u4f7f\u7528\u6709\u5bb3\u8bd5\u5242\u7b49\u82db\u523b\u6761\u4ef6\u3002\u5229\u7528\u919b\u751f\u6210\u9170\u57fa\u81ea\u7531\u57fa\u662f\u6700\u76f4\u63a5\u3001\u539f\u5b50\u548c\u6b65\u9aa4\u6700\u7ecf\u6d4e\u7684\u9014\u5f84\u3002\u901a\u8fc7\u5229\u7528\u919b\u539f\u6599\u4f5c\u4e3a\u9170\u57fa\u81ea\u7531\u57fa\u524d\u4f53\uff0c\u5df2\u7ecf\u5f00\u53d1\u51fa\u8fc7\u591a\u7684\u9170\u57fa-C\u952e\u5f62\u6210\u53cd\u5e94\u3002\u8fd9\u79cd\u952e\u7684\u5f62\u6210\u901a\u5e38\u901a\u8fc7\u4e0d\u9971\u548c\u70ef\u70c3\u6216\uff08\u6742\uff09\u82b3\u70c3\u7684\u9170\u57fa\u81ea\u7531\u57fa\u52a0\u6210\u6765\u5b9e\u73b0\uff0c\u5bfc\u81f4\u9170\u57fa-C\uff08sp3<\/sup>\uff09\u6216\u9170\u57fa-C\uff08sp2<\/sup>\uff09\u952e\u7684\u5f62\u6210\u3002\u4f46\u662f\uff0c\u919b\u7c7b\u7684\u9170\u57faX\uff08X=S, N, D\uff09\u548c\u9170\u57fa-C\uff08sp\uff09\u952e\u7684\u6784\u5efa\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u8fd8\u6ca1\u6709\u5f97\u5230\u5145\u5206\u7684\u63a2\u7d22\u3002\u76f4\u63a5\u5149\u50ac\u5316\u6c22\u539f\u5b50\u8f6c\u79fb\uff08HAT\uff09\u5728C-H\u529f\u80fd\u5316\u65b9\u9762\u53d6\u5f97\u4e86\u91cd\u5927\u7a81\u7834\u3002\u867d\u7136\u9634\u79bb\u5b50\u66d9\u7ea2Y\u901a\u5e38\u7528\u4f5c\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5242\uff0c\u4f46\u662f\u4e2d\u6027\u66d9\u7ea2Y\u662f\u4e00\u79cd\u4f18\u79c0\u7684\u76f4\u63a5HAT\u5149\u50ac\u5316\u5242\uff0c\u53ef\u5728\u7b80\u5355\u548c\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u6fc0\u6d3b\u5e7f\u6cdb\u7684C-H\u952e\u4ee5\u5236\u5907\u76f8\u5e94\u7684\u78b3\u81ea\u7531\u57fa\u3002\u66d9\u7ea2Y\u80fd\u591f\u4ece\u919b\u539f\u6599\u4e2d\u83b7\u5f97\u9170\u57fa\u81ea\u7531\u57fa\uff0c\u919b\u539f\u6599\u5206\u522b\u4e0e\u70ef\u70c3\u548c\u7094\u70c3\u8fdb\u884c\u4e0d\u5bf9\u79f01, 4-\u52a0\u6210\u53cd\u5e94\u548c\u81ea\u7531\u57faSmiles\u91cd\u6392\u53cd\u5e94\u3002\u968f\u7740\u66d9\u7ea2Y-HAT\u5149\u50ac\u5316\u7cfb\u7edf\u7684\u4e0d\u65ad\u6df1\u5165\uff0c\u4f5c\u8005\u8bbe\u60f3\u5176\u4e0e\u781c\u57faSOMophiles\u7684\u5408\u5e76\u53ef\u4ee5\u4e3a\u919b\u57faC-H\u529f\u80fd\u5316\u63d0\u4f9b\u4e00\u4e2a\u901a\u7528\u5e73\u53f0\uff0c\u4ee5\u83b7\u5f97\u5404\u79cd\u7c7b\u578b\u7684\u529f\u80fd\u6027\u9170\u57fa\u5316\u5408\u7269\u3002
\n \"\"\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u5434\u6770\u6559\u6388\u548c\u8f89\u745e\u5168\u7403\u7814\u53d1\u4e2d\u5fc3Shengquan Duan\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u5229\u7528\u4e2d\u6027\u66d9\u7ea2Y-\u6c22\u539f\u5b50\u8f6c\u79fb\uff08HAT\uff09\u4e0e\u919b\u7684\u5149\u50ac\u5316\u4f5c\u7528\u83b7\u5f97\u9170\u57fa\u81ea\u7531\u57fa\u7684\u4fbf\u6377\u7eff\u8272\u65b9\u6cd5\u3002\u751f\u6210\u7684\u9170\u57fa\u81ea\u7531\u57fa\u5229\u7528\u5404\u79cd\u529f\u80fd\u5316\u781c\uff08X-SO2<\/sub>R\u2019\uff09\u8fdb\u884cSOMophilic\u53d6\u4ee3\uff0c\u4ee5\u63d0\u4f9b\u589e\u503c\u9170\u57fa\u4ea7\u7269\u3002\u66d9\u7ea2Y\u5149\u50ac\u5316\u548c\u781c\u57faSOMophilic\u7684\u7ed3\u5408\u4e3a\u5e7f\u6cdb\u7684\u919b\u57faC-H\u529f\u80fd\u5316\u63d0\u4f9b\u4e86\u4e00\u4e2a\u591a\u529f\u80fd\u5e73\u53f0\uff0c\u5305\u62ec\u6c1f\u7532\u786b\u57fa\u5316\u3001\u82b3\u57fa\u786b\u5316\u3001\u7094\u57fa\u5316\u3001\u70ef\u57fa\u5316\u548c\u53e0\u6c2e\u5316\u3002\u66d9\u7ea2Y-HAT\u5149\u50ac\u5316\u5177\u6709\u64cd\u4f5c\u7b80\u5355\u3001\u4ef7\u683c\u4f4e\u5ec9\u3001\u65e0\u91d1\u5c5e\u3001\u65e0\u6c27\u5316\u5242\u548c\u65e0\u6dfb\u52a0\u5242\u7684\u7eff\u8272\u5c5e\u6027\u3002\u56e0\u6b64\uff0c\u8be5\u5408\u6210\u65b9\u6cd5\u5177\u6709\u7eff\u8272\uff08\u5982\u4e0d\u542b\u91d1\u5c5e\u3001\u6709\u5bb3\u6c27\u5316\u5242\u548c\u6dfb\u52a0\u5242\uff09\u3001\u7ecf\u6d4e\u3001\u6c27\u5316\u8fd8\u539f\u4e2d\u6027\u3001\u53ef\u5728\u8fde\u7eed\u6d41\u6280\u672f\u7684\u8f85\u52a9\u4e0b\u8fdb\u884c\u6269\u5927\u5408\u6210\u7b49\u4f18\u70b9\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cDivergent functionalization of aldehydes photocatalyzed by neutral eosin Y with sulfone reagents\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNature Communications<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u4e0d\u540c\u7684\u919b\u57faC\u2013H\u529f\u80fd\u5316<\/strong>
\n \"\"\uff08a\uff09\u9009\u5b9a\u7684\u73b0\u6709\u919b\u57faC-H\u529f\u80fd\u5316\uff1b<\/p>\n

\uff08b\uff09\u4f7f\u7528\u781c\u8bd5\u5242\u901a\u8fc7HAT\u5149\u50ac\u5316\u5b9e\u73b0\u4e0d\u540c\u7684\u919b\u57faC-H\u529f\u80fd\u5316\u3002<\/p>\n

\u56fe\u4e8c\u3001C-H\u6c1f\u7532\u57fa\u786b\u9187\u5316\u7684\u919b\u7c7b\u8303\u56f4<\/strong>
\n \"\"\u53cd\u5e94\u6761\u4ef6\uff1a1\uff080.3 mmol\uff09\u30012\uff080.2 mmol\uff09\u3001\u66d9\u7ea2Y\uff084 mol%\uff09\u548c\u53d4\u4e01\u9187\uff082.0 mL\uff09\uff0c\u5728\u5145\u6ee1\u6c29\u6c14\u7684Schlenk\u7ba1\uff0820 mL\uff09\u4e2d\u3001470 nm\u5149\uff0818 W LED\uff09\u7167\u5c04\u3001\u5ba4\u6e29\u4e0b\uff08~27 \u00b0C\uff09\u53cd\u5e94\u3002<\/p>\n

\u56fe\u4e09\u3001\u5229\u7528\u82b3\u57fa\u4e9a\u78fa\u9178\u4f5c\u4e3a\u65e0\u5473\u786b\u8bd5\u5242\u5b9e\u73b0\u919b\u57faC-H\u786b\u9187\u5316\u53cd\u5e94<\/strong>
\n \"\"\uff08a\uff09\u5728\u919b\u57faC-H\u6c1f\u7532\u57fa\u786b\u9187\u5316\u53cd\u5e94\u4e2d\u89c2\u5bdf\u5230\u4f5c\u4e3a\u526f\u4ea7\u7269\u7684\u786b\u916f4<\/strong>\uff1b<\/p>\n

\uff08b\uff09\u5f62\u6210\u526f\u4ea7\u72694<\/strong>\u7684\u53ef\u80fd\u539f\u56e0\uff1b<\/p>\n

\uff08c\uff09\u65e0\u5473\u919b\u57faC-H\u786b\u9187\u5316\u7684\u7814\u7a76\u8fdb\u5c55\u3002<\/p>\n

\u56fe\u56db\u3001\u65e0\u5473\u919b\u57faC-H\u786b\u9187\u5316\u7684\u5e95\u7269\u62d3\u5c55<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e94\u3001\u919b\u57faC-H\u82b3\u57fa\u786b\u9187\u5316\u7684\u53ef\u80fd\u673a\u5236<\/strong>
\n \"\"\uff08a\uff09\u4e0d\u540cS-\u82ef\u57fa\u6765\u6e90\u7684\u8bc4\u4f30\uff1b<\/p>\n

\uff08b\uff09\u66d9\u7ea2Y\u5149\u50ac\u5316\u4ece\u82ef\u57fa\u4e9a\u78fa\u91785a<\/strong>\u5f62\u6210S-\u82ef\u57fa\u82ef\u786b\u4ee3\u78fa\u9178\u76d09a<\/strong>\uff1b<\/p>\n

\uff08c\uff09\u81ea\u7531\u57fa\u6355\u83b7\u5b9e\u9a8c\uff1b<\/p>\n

\uff08d\uff0918<\/sup>O-\u6807\u8bb0\u5b9e\u9a8c\uff1b<\/p>\n

\uff08e\uff09\u53ef\u80fd\u7684\u5408\u7406\u673a\u5236\u3002<\/p>\n

\u56fe\u516d\u3001\u919b\u57faC-H\u7094\u57fa\u5316\u7684\u5e95\u7269\u8303\u56f4<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e03\u3001\u919b\u57faC-H\u591a\u6837\u5316\u548c\u6d41\u52a8\u4e2d\u7684\u6269\u5927\u5408\u6210<\/strong>
\n \"\"\uff08a\uff09\u919b\u57faC-H\u53e0\u6c2e\u5316\u548c\u4e59\u70ef\u57fa\u5316\uff1b<\/p>\n

\uff08b\uff09\u5728\u8fde\u7eed\u6d41\u52a8\u5fae\u7ba1\u53cd\u5e94\u5668\u4e2d\u7684\u6269\u5927\u53cd\u5e94\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u5c06\u4e2d\u6027\u66d9\u7ea2Y-HAT\u5149\u50ac\u5316\u4e0e\u5404\u79cd\u781c\u57faSOMOphiles\u5408\u5e76\u4ee5\u76f4\u63a5\u6784\u5efa\u9170\u57fa-S\u3001\u9170\u57fa-C\u548c\u9170\u57fa-N\u952e\uff0c\u5c55\u793a\u4e86\u4e00\u4e2a\u591a\u529f\u80fd\u7684\u919b\u57faC-H\u529f\u80fd\u5316\u5e73\u53f0\u3002\u4e0d\u540c\u4e8e\u73b0\u6709\u7684\u50ac\u5316\/\u5316\u5b66\u8ba1\u91cf\u7cfb\u7edf\uff0c\u66d9\u7ea2Y-\u781c\u7cfb\u7edf\u5c06\u4f5c\u4e3a\u4e00\u79cd\u66f4\u7eff\u8272\u548c\u53ef\u6301\u7eed\u7684\u65b9\u6cd5\uff0c\u66f4\u5bb9\u6613\u5904\u7406\u919b\u57fa\u529f\u80fd\u5316\uff0c\u5e76\u5177\u6709\u4ee5\u4e0b\u7279\u70b9\u3002\uff081\uff09PhSO2<\/sub>-SCHx<\/sub>Fy<\/sub>\u00a02<\/strong>\u88ab\u8bc1\u660e\u5bf9\u4e8e\u4e0e\u591a\u79cd\u919b\u8fdb\u884c\u65e0\u91d1\u5c5e\u3001\u65e0\u6dfb\u52a0\u5242\u548c\u65e0\u6c27\u5316\u5242\u7684\u6c1f\u7532\u57fa\u786b\u9187\u5316\u53cd\u5e94\u7279\u522b\u6709\u6548\u3002\u6c1f\u7532\u786b\u57fa\u5316\u53cd\u5e94\u5728\u8fde\u7eed\u6d41\u52a8\u6761\u4ef6\u4e0b\u8fdb\u884c\uff0c\u53ef\u4ee5\u8fbe\u5230\u6bcf\u592915 g\u7684\u751f\u4ea7\u7387\u3002\uff082\uff09\u82b3\u57fa\u4e9a\u78fa\u9178\uff08ArSO2<\/sub>H\uff09\u4f5c\u4e3a\u4e00\u79cd\u65e0\u5473\u4e14\u6613\u4e8e\u83b7\u53d6\u7684\u8bd5\u5242\uff0c\u7528\u4e8e\u919b\u7684\u82b3\u57fa\u786b\u9187\u5316\u3002\u521d\u6b65\u673a\u7406\u7814\u7a76\u8868\u660e\uff0c\u539f\u4f4d\u751f\u6210\u7684\u82b3\u57fa\u786b\u4ee3\u78fa\u9178\u76d0\uff08ArSO2<\/sub>-SAr\uff09\u7269\u79cd\u53c2\u4e0e\u4e86\u968f\u540e\u7684\u81ea\u7531\u57fa\u53d6\u4ee3\u6b65\u9aa4\u3002\uff083\uff09\u9170\u57fa-C(sp)\u952e\u662f\u901a\u8fc7\u9170\u57fa\u81ea\u7531\u57fa\u52a0\u6210-\u78fa\u9170\u57fa\u81ea\u7531\u57fa\u6d88\u9664\u4e0e\u7532\u78fa\u9170\u57fa\u7094\u70c3\u6210\u529f\u5f62\u6210\u7684\u3002\uff084\uff09\u5229\u7528\u81ea\u7531\u57fa\u52a0\u6210\u6d88\u9664\u7684\u591a\u529f\u80fd\u6027\uff0c\u8be5\u7b56\u7565\u8fdb\u4e00\u6b65\u6269\u5c55\u5230\u919b\u57faC-H\u53e0\u6c2e\u5316\u548c\u70ef\u57fa\u5316\u3002\u603b\u4e4b\uff0c\u4f5c\u8005\u5b9e\u9a8c\u5ba4\u76ee\u524d\u6b63\u5728\u7814\u7a76\u5c06C-H\u5e95\u7269\u8303\u56f4\u6269\u5c55\u5230\u4e30\u5bcc\u7684\u70f7\u70c3\u5e76\u5c06\u781c\u57faSOMophilic\u8bd5\u5242\u7684\u5316\u5b66\u7a7a\u95f4\u6269\u5c55\u5230\u65b0\u7684\u53cd\u5e94\u6a21\u5f0f\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDivergent functionalization of aldehydes photocatalyzed by neutral eosin Y with sulfone reagents<\/a><\/strong>. Nature Communications<\/em>, 2021<\/strong>, DOI: 10.1038\/s41467-021-27550-8.<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

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