{"id":230854,"date":"2021-12-21T06:11:24","date_gmt":"2021-12-20T22:11:24","guid":{"rendered":"\/\/m.iemloyee.com\/?p=230854"},"modified":"2021-12-20T21:11:33","modified_gmt":"2021-12-20T13:11:33","slug":"mof-8%e7%af%87%e9%a1%b6%e5%88%8a%e9%80%9f%e8%a7%88","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=230854","title":{"rendered":"MOF 8\u7bc7\u9876\u520a\u901f\u89c8"},"content":{"rendered":"

AM<\/strong>\uff1a\u63a7\u5236<\/strong>2D<\/strong>\u535f\u5549\u57fa<\/strong>MOF<\/strong>\u7684\u5c42\u6570\u5bf9<\/strong>CO2<\/sub><\/strong>\u7684\u5149\u8026\u5408\u7535\u8fd8\u539f\u4f5c\u7528<\/strong><\/p>\n

\u5728\u77f3\u58a8\u70ef\u6210\u529f\u7684\u542f\u53d1\u4e0b\uff0c\u4e00\u7cfb\u5217\u5355\u5c42\u6216\u5c11\u5c42\u4e8c\u7ef4(2D)\u6750\u6599\u5728\u8fc7\u53bb\u5341\u5e74\u4e2d\u88ab\u5f00\u53d1\u548c\u5e94\u7528\u3002\u6e05\u534e\u5927\u5b66Wang Xun\u6559\u6388\u7b49\u4eba\u62a5\u9053\u4e86\u4e00\u79cd\u7b80\u4fbf\u7684\u6eb6\u5242\u70ed\u6cd5\u5236\u5907\u5355\u5c42\u548c\u53cc\u5c42\u4e8c\u7ef4\u535f\u5549\u57fa\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\u7684\u65b9\u6cd5\u3002\u4ece\u5355\u5206\u5b50\u5c42\u5230\u53cc\u5206\u5b50\u5c42\u7684\u7ed3\u6784\u8f6c\u53d8\u9a71\u52a8\u4e86\u4e0d\u540c\u7684\u7535\u5b50\u6027\u8d28\u548c\u91cd\u7ec4\u884c\u4e3a\uff0c\u6700\u7ec8\u5bfc\u81f4\u4e86\u4e0d\u540c\u7684CO2<\/sub>\u7535\u50ac\u5316\u9014\u5f84\u3002\u7531\u4e8eCu-O4<\/sub>\u4f4d\u70b9\u91cd\u7ec4\uff0c\u5355\u5c42\u503e\u5411\u4e8eCO2 <\/sub>– C2<\/sub>\u9014\u5f84\uff0cCO\u548cHCOO–<\/sup>\u662f\u53cc\u5206\u5b50\u5c42\u7684\u4e3b\u8981\u4ea7\u7269\u3002\u5728\u5149\u8026\u5408\u7535\u50ac\u5316\u4e2d\uff0cC2<\/sub>\u5316\u5408\u7269\u7684\u6cd5\u62c9\u7b2c\u6548\u7387(FE)\u5728\u5355\u5206\u5b50\u5c42\u4e0a\u6bd4\u9ed1\u6697\u6761\u4ef6\u4e0b\u63d0\u9ad8\u4e86\u8fd14\u500d(FEC2<\/sub>\u5728-1.4 V\u65f6\u4ece11.9%\u63d0\u9ad8\u523041.1%)\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5149\u573a\u5bf9\u53cc\u5206\u5b50\u5c42\u7684\u5f71\u54cd\u5fae\u4e0d\u8db3\u9053\u3002\u901a\u8fc7\u5b9e\u9a8c\u8868\u5f81\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u7814\u7a76\u4e86\u5149\u8bf1\u5bfc\u9009\u62e9\u6027\u4f18\u5316\u3002\u8fd9\u9879\u5de5\u4f5c\u5f00\u8f9f\u4e86\u4e00\u79cd\u65b0\u7684\u53ef\u80fd\u6027\uff0c\u901a\u8fc7\u8c03\u6574\u4e8c\u7ef4\u6750\u6599\u7684\u5c42\u6570\u6765\u8c03\u6574\u78b3\u4ea7\u7269\u7684\u9009\u62e9\u6027\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cTailoring layer number of 2D porphyrin-based MOF towards photocoupled electroreduction of CO2<\/sub>\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AM\u4e0a\u3002DOI: 10.1002\/adma.202107293<\/p>\n

\u56fe1 2D MOF\u6784\u5efa\u4e0e\u8868\u5f81<\/p>\n

\"\"<\/p>\n

AFM<\/strong>\uff1a\u8d85\u8584<\/strong>MOF<\/strong>\u7eb3\u7c73\u7247\u7528\u4e8e\u9ad8\u6027\u80fd\u6676\u4f53\u7ba1\u7684\u7eb3\u7c73\u6d6e\u6805\u5b58\u50a8\u8bbe\u5907<\/strong><\/p>\n

MOF\u662f\u4fe1\u606f\u5b58\u50a8\u3001\u53ef\u7a7f\u6234\u7535\u5b50\u3001\u5149\u7535\u5668\u4ef6\u7b49\u9886\u57df\u65b0\u5174\u7684\u4e00\u7c7b\u91cd\u8981\u529f\u80fd\u6750\u6599\u3002\u7535\u5b50\u6216\u7a7a\u7a74\u7684\u76f8\u4e92\u4f5c\u7528\u5bf9\u4e8eMOF\u7684\u7cfb\u7edf\u7814\u7a76\u548c\u76f8\u5173\u7ed3\u6784-\u6027\u80fd\u76f8\u5173\u6027\u7684\u7814\u7a76\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u897f\u5317\u5de5\u4e1a\u5927\u5b66\u9ec4\u7ef4\u9662\u58eb\u7b49\u4eba\u91c7\u7528\u4e9a10 nm\u539a\u5ea6\u7684\u56db(4-\u7fa7\u57fa\u82ef\u57fa)\u535f\u5549\u94dc\u7684MOF\u7eb3\u7c73\u7247\u4f5c\u4e3a\u7535\u8377\u6355\u83b7\u5c42\uff0c\u5e94\u7528\u4e8e\u6c14\u6db2\u754c\u9762\u7ec4\u88c5\u53ca\u540e\u7eed\u51b2\u538b\u5de5\u827a\u5236\u5907\u7684\u6709\u673a\u7535\u573a\u6548\u5e94\u6d6e\u6805\u6676\u4f53\u7ba1\u5b58\u50a8\u5668\u4ef6\u4e2d\u3002\u4f5c\u4e3a\u7535\u8377\u4fd8\u83b7\u70b9\uff0c\u4e0e\u4f7f\u7528\u5176\u5bf9\u5e94\u914d\u4f53\u56db(4-\u7fa7\u57fa\u82ef\u57fa)\u535f\u5549\u4f5c\u4e3a\u6355\u83b7\u5143\u7d20\u7684\u5b58\u50a8\u5668\u4ef6\u76f8\u6bd4\uff0c\u5177\u6709\u8d85\u8584\u7eb3\u7c73\u5b54\u9635\u5217\u7684MOF\u7eb3\u7c73\u7247\u663e\u8457\u6539\u5584\u3002\u4e0e\u62a5\u9053\u4e2d\u5e7f\u6cdb\u5e94\u7528\u7684\u91d1\u7eb3\u7c73\u9897\u7c92\u3001\u77f3\u58a8\u70ef\u3001\u5927\u5206\u5b50\u7eb3\u7c73\u6750\u6599\u7b49\u7eb3\u7c73\u6d6e\u6805\u6750\u6599\u76f8\u6bd4\uff0c\u5728-80 V\u7684\u7f16\u7a0b\u7535\u538b\u4e0b\uff0c\u77ed\u8109\u51b2(\u224820 ms)\u5728\u5668\u4ef6\u4e0a\u5f97\u5230\u224837.5 V\u7684\u53ef\u89c2\u7684\u8bb0\u5fc6\u7a97\uff0c\u4fdd\u6301\u65f6\u95f4\u8d85\u8fc7104<\/sup> s\uff0c\u826f\u597d\u7684\u5f00\u5173\u6bd4>103<\/sup>\u3002\u6b64\u5916\uff0c\u7531\u91d1\u5c5e\u548c\u6709\u673a\u7ec4\u5206\u7ec4\u6210\u7684\u6742\u5316\u7ed3\u6784\u4f7f\u5176\u5177\u6709\u7535\u5b50\u548c\u7a7a\u7a74\u6355\u83b7\u80fd\u529b\u3002\u8fd9\u4e00\u7814\u7a76\u6210\u679c\u5bf9\u672a\u6765\u5fae\u7535\u5b50\u7814\u7a76\u4e2d\u6709\u673a-\u65e0\u673a\u6df7\u5408\u7535\u5b50\u7684\u57fa\u7840\u7814\u7a76\u6709\u4e00\u5b9a\u7684\u63a8\u52a8\u4f5c\u7528\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cUltrathin Metal\u2013Organic Framework Nanosheets as Nano-Floating-Gate for High Performance Transistor Memory Device\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AFM\u4e0a\u3002DOI: 10.1002\/adfm.202110784<\/p>\n

\u56fe2 Cu-CTL\u4e8c\u7ef4MOF\u7ed3\u6784\u793a\u610f\u56fe\u3001\u57fa\u4e8eCu-CTL\u7eb3\u7c73\u7247\u7684OFET\u5b58\u50a8\u5668\u4ef6\u53caCu-CTL\u7eb3\u7c73\u7247\u8584\u819c\u8868\u5f81<\/p>\n

\"\"<\/p>\n

AFM<\/strong>\uff1a<\/strong>MOF<\/strong>\u7eb3\u7c73\u6676\u4f53\u751f\u7269\u6a21\u677f\u5728\u5c0f\u578b\u673a\u5668\u4eba\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n

\u751f\u7269\u6a21\u677f\u662f\u5236\u9020\u5c0f\u578b\u8bbe\u5907\u7684\u4e00\u79cd\u5f3a\u5927\u65b9\u6cd5\u3002\u82cf\u9ece\u4e16\u8054\u90a6\u7406\u5de5\u5b66\u9662Salvador Pan\u00e9\u7b49\u4eba\u62a5\u9053\u4e86\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOF)\u7eb3\u7c73\u6676\u4f53\u5728\u87ba\u65cb\u85fb\u751f\u7269\u6a21\u677f\u78c1\u87ba\u65cb\u7ed3\u6784\u4e0a\u7684\u7ec4\u88c5\u3002\u7ed3\u679c\u8868\u660e\uff0c\u8be5\u65b9\u6cd5\u5177\u6709\u901a\u7528\u6027\uff0c\u53ef\u7528\u4e8e\u4e0d\u540c\u529f\u80fd\u7684\u751f\u7269\u6a21\u677f\u7ed3\u6784\u7684MOF\u7cfb\u7edf\u914d\u7f6e\u3002MOF\u7eb3\u7c73\u6676\u4f53\u5728\u78c1\u6027\u6d82\u5c42\u87ba\u65cb\u751f\u7269\u6a21\u677f\u4e0a\u7684\u6210\u529f\u7ec4\u88c5\u662f\u901a\u8fc7\u7528\u660e\u80f6\u88c5\u9970\u78c1\u6027\u8868\u9762\u5b9e\u73b0\u7684\uff0c\u660e\u80f6\u662f\u4e00\u79cd\u5929\u7136\u7684\u5927\u5206\u5b50\uff0c\u5176\u5408\u6210\u94fe\u53ef\u4ee5\u901a\u8fc7\u9759\u7535\u4f5c\u7528\u951a\u5b9aMOF\u7eb3\u7c73\u6676\u4f53\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u660e\u80f6\u662f\u4e00\u79cd\u70ed\u54cd\u5e94\u6750\u6599\uff0c\u5b83\u53ef\u4ee5\u4eceMOF\u7eb3\u7c73\u6676\u4f53\u8d27\u7269\u4e2d\u91ca\u653e\u78c1\u6027\u751f\u7269\u6a21\u677f\u3002\u56e0\u6b64\uff0c\u8be5\u7cfb\u7edf\u53ef\u4ee5\u4f5c\u4e3a\u5177\u6709\u591a\u79cd\u529f\u80fd\u7684\u9ad8\u96c6\u6210\u78c1\u9a71\u52a8\u5fae\u578b\u673a\u5668\u4eba\u4f7f\u7528\u3002\u4e3a\u6b64\uff0c\u8fd9\u4e9b\u590d\u5408\u87ba\u65cb\u7ed3\u6784\u7684\u6f5c\u529b\u88ab\u8bc1\u660e\u662f\u57fa\u4e8eMOF\u7684\u5c0f\u578b\u673a\u5668\u4eba\uff0c\u5e94\u7528\u4e8e\u751f\u7269\u533b\u5b66\u548c\u73af\u5883\u4fee\u590d\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cBiotemplating of Metal\u2013Organic Framework Nanocrystals for Applications in Small-Scale Robotics\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AFM\u4e0a\u3002DOI: 10.1002\/adfm.202107421<\/p>\n

\u56fe3 \u751f\u7269\u6a21\u677f\u5316MOFBOT\u7684\u793a\u610f\u56fe\u53ca\u539f\u7406\u56fe<\/p>\n

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ACS Nano<\/strong>\uff1a<\/strong>MOF-<\/strong>\u7ec6\u83cc\u6742\u5316\u4f53\u901a\u8fc7\u4e73\u9178\u5206\u89e3\u4ee3\u8c22\u52a9\u63a8\u5316\u7597<\/strong><\/p>\n

\u80bf\u7624\u5fae\u73af\u5883\u4e2d\u8fc7\u91cf\u7684\u4e73\u9178\u5e38\u5bfc\u81f4\u5316\u7597\u6548\u679c\u4e0d\u4f73\u3002\u5728\u6b64\uff0c\u6b66\u6c49\u5927\u5b66\u9648\u5dcd\u6d77\u3001\u5f20\u5148\u6b63\u7b49\u4eba\u6784\u5efa\u4e86\u4e00\u79cdSO@MDH\u81ea\u9a71\u52a8\u751f\u7269\u53cd\u5e94\u5668\uff0c\u901a\u8fc7\u5c06\u96c6\u6210\u88c5\u8f7d\u4e86\u5316\u7597\u836f\u7269DOX\u7684MOF\u6750\u6599MIL-101\u7eb3\u7c73\u9897\u7c92\/\u900f\u660e\u8d28\u9178\uff08MDH\uff09\u4e0eSO\u96c6\u6210\uff0c\u53ef\u8fbe\u5230\u654f\u5316\u5316\u7597\u7684\u76ee\u7684\u3002\u7531\u4e8eSO\u81ea\u8eab\u7684\u5411\u7624\u6027\u548c\u7535\u5b50\u9a71\u52a8\u547c\u5438\u4f5c\u7528\uff0c\u751f\u7269\u6742\u5316SO@MDH\u53ef\u4ee5\u4e3b\u52a8\u9776\u5411\u548c\u5b9a\u6b96\u7f3a\u6c27\u548c\u5bcc\u8425\u517b\u5316\u80bf\u7624\u533a\u57df\uff0c\u5e76\u5728\u5c06\u7535\u5b50\u8f6c\u79fb\u5230Fe3+<\/sup>\u7684\u540c\u65f6\u538c\u6c27\u4ee3\u8c22\u4e73\u9178\uff0c\u8fd9\u662fMIL-101\u7eb3\u7c73\u9897\u7c92\u7684\u5173\u952e\u6210\u5206\u3002\u56e0\u6b64\uff0c\u7624\u5185\u4e73\u9178\u4f1a\u6301\u7eed\u5206\u89e3\u4ee3\u8c22\uff0c\u540c\u65f6Fe3+<\/sup>\u8fd8\u539f\u4e3aFe2+<\/sup>\uff0c MIL-101\u6846\u67b6\u964d\u89e3\uff0c\u4ece\u800c\u52a0\u901f\u836f\u7269\u91ca\u653e\uff0c\u5b9e\u73b0\u6709\u6548\u5316\u7597\u3002\u540c\u65f6\uff0c\u4ea7\u751f\u7684Fe2+<\/sup>\u4f1a\u88ab\u80bf\u7624\u5fae\u73af\u5883\u4e2d\u4e30\u5bcc\u7684\u8fc7\u6c27\u5316\u6c22\u8fc5\u901f\u6c27\u5316\uff0c\u751f\u6210Fe3+<\/sup>\uff0c\u8fdb\u800c\u6709\u5229\u4e8e\u5faa\u73af\u5206\u89e3\u4e73\u9178\uff0c\u4fc3\u8fdb\u5316\u7597\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u7624\u5185\u6444\u5165\u4e73\u9178\u53ef\u663e\u8457\u6291\u5236\u591a\u836f\u8010\u836f\u76f8\u5173ABCB1\u86cb\u767d(\u53c8\u79f0p-\u7cd6\u86cb\u767d(P-gp))\u7684\u8868\u8fbe\uff0c\u4ece\u800c\u5f81\u670d\u8010\u836f\u80bf\u7624\u3002SO@MDH\u5177\u6709\u8f83\u9ad8\u7684\u80bf\u7624\u7279\u5f02\u6027\uff0c\u5728\u6291\u5236\u80bf\u7624\u751f\u957f\u3001\u514b\u670d\u591a\u836f\u3001\u8010\u836f\u65b9\u9762\u5177\u6709\u826f\u597d\u7684\u5316\u7597\u6548\u679c\uff0c\u8bc1\u5b9e\u4e86\u5176\u5728\u80bf\u7624\u6cbb\u7597\u4e2d\u7684\u6f5c\u5728\u524d\u666f\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cA Self-Driven Bioreactor Based on Bacterium\u2212Metal\u2212Organic Framework Biohybrids for Boosting Chemotherapy via Cyclic Lactate Catabolism\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728ACS Nano\u4e0a\u3002DOI: 10.1021\/acsnano.1c06123<\/p>\n

\u56fe4 SO@MDH\u751f\u7269\u6742\u5408\u4f53\u53ca\u5176\u4f18\u8d8a\u7684\u6cbb\u7597\u6548\u679c\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

ACS Energy Lett.<\/strong>\uff1a\u8d28\u5b50\u4f20\u5bfc\u6c22\u952e\u6709\u673a\u6846\u67b6\u6750\u6599<\/strong><\/p>\n

\u56fa\u6001\u8d28\u5b50\u5bfc\u7535\u6750\u6599\u5728\u5404\u79cd\u7535\u5316\u5b66\u5668\u4ef6\u4e2d\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u5305\u62ec\u4f5c\u4e3a\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u71c3\u6599\u7535\u6c60\u3002\u8fd1\u5e74\u6765\uff0c\u6c22\u952e\u6709\u673a\u9aa8\u67b6(HOFs)\u7684\u7814\u7a76\u5728\u5404\u79cd\u5e94\u7528\u9886\u57df\u53d6\u5f97\u4e86\u957f\u8db3\u7684\u8fdb\u5c55\uff0c\u5176\u4e2d\u4e00\u4e9b\u9aa8\u67b6\u5177\u6709\u9ad8\u7a33\u5b9a\u6027\u548c\u6c38\u4e45\u6027\u5fae\u5b54\u9699\u3002HOF\u4e2d\u56fa\u6709\u7684\u5b9a\u4e49\u660e\u786e\u7684H\u952e\u7f51\u7edc\u4f7f\u5b83\u4eec\u6210\u4e3a\u591a\u529f\u80fd\u5e73\u53f0\u7684\u56fa\u6001\u8d28\u5b50\u5bfc\u4f53\uff0c\u5176\u7535\u5bfc\u7387\u9ad8\u8fbe10\u22121<\/sup> S cm\u22121<\/sup>\u3002\u5370\u5ea6\u7406\u5de5\u5b66\u9662Madhab C. Das\u7b49\u4eba\u5728\u8fd9\u96c6\u4e2d\u7efc\u8ff0\u4e86HOFs\u4f5c\u4e3a\u8d28\u5b50\u5bfc\u4f53\u7684\u53d1\u5c55\uff0c\u540c\u65f6\u7b80\u8981\u4ecb\u7ecd\u4e86\u65e9\u671f\u5173\u4e8e\u8d28\u5b50\u5bfc\u7535\u6c22\u952e\u6709\u673a\u7cfb\u7edf\u7684\u62a5\u9053\u3002\u5173\u4e8e\u8d28\u5b50\u5bfc\u7535\u6027\u7684\u5176\u4ed6\u672f\u8bed\u7684\u62a5\u544a\uff0c\u5982\u8d85\u5206\u5b50\u6709\u673a\u6846\u67b6(SOFs)\uff0c\u591a\u5b54\u6709\u673a\u76d0(POSs)\uff0c\u6216\u591a\u5b54\u5206\u5b50\u6676\u4f53(PMCs)\uff0c\u4e5f\u88ab\u8003\u8651\u5728\u5185\u3002\u6240\u6709\u7684\u52aa\u529b\u90fd\u662f\u4e3a\u4e86\u7ec4\u7ec7\u548c\u5206\u7c7b\u8d28\u5b50\u5bfc\u7535\u7684HOFs\uff0c\u4ee5\u66f4\u6df1\u5165\u5730\u4e86\u89e3\u8bbe\u8ba1\u539f\u5219\u548c\u5b9e\u73b0\u8fd9\u79cd\u5bfc\u7535\u6027\u80fd\u7684\u5173\u952e\u7279\u5f81\u3002\u8ba8\u8bba\u4e86HOFs\u4f5c\u4e3a\u8d28\u5b50\u5bfc\u4f53\u7684\u4f18\u52bf\u3001\u6f5c\u5728\u6311\u6218\u548c\u524d\u666f\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cProton-Conducting Hydrogen-Bonded Organic Frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728ACS Energy Lett.\u4e0a\u3002DOI: 10.1021\/acsenergylett.1c02045<\/p>\n

\u56fe5 \u8d28\u5b50\u4f20\u5bfcHOFs\u7684\u5206\u7c7b<\/p>\n

\"\"<\/p>\n

Angew.<\/strong>\uff1a\u5177\u6709\u4f18\u5316\u5b54\u7eb3\u7c73\u7a7a\u95f4\u7684\u9ad8\u5438\u6c34\u7387<\/strong>MOF<\/strong>\u7528\u4e8e\u5ba4\u5185\u6e7f\u5ea6\u81ea\u52a8\u63a7\u5236\u548c\u6c61\u67d3\u7269\u6e05\u9664<\/strong><\/p>\n

\u5ba4\u5185\u7a7a\u6c14\u8d28\u91cf\u5bf9\u4eba\u7c7b\u65e5\u5e38\u751f\u6d3b\u548c\u5065\u5eb7\u81f3\u5173\u91cd\u8981\uff0c\u6cb8\u77f3\u3001\u7845\u51dd\u80f6\u7b49\u5438\u9644\u5242\u5e7f\u6cdb\u7528\u4e8e\u7a7a\u6c14\u9664\u6e7f\u548c\u6709\u5bb3\u6c14\u4f53\u6355\u83b7\u3002\u5728\u6b64\uff0c\u4e2d\u5c71\u5927\u5b66\u82cf\u6210\u52c7\u6559\u6388\u7b49\u4eba\u62a5\u9053\u4e86\u4e00\u79cd\u5b54\u7eb3\u7c73\u7a7a\u95f4\u540e\u5de5\u7a0b\u7b56\u7565\uff0c\u4ee5\u4f18\u5316\u5177\u6709\u957f\u671f\u7a33\u5b9a\u6027\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u7684\u4eb2\u6c34\u6027\u3001\u5438\u6c34\u6027\u548c\u7a7a\u6c14\u51c0\u5316\u80fd\u529b\uff0c\u4ece\u800c\u63d0\u4f9b\u4e00\u79cd\u5177\u6709\u81ea\u4e3b\u591a\u529f\u80fd\u7684\u6c34\u5206\u63a7\u5236\u548c\u6c61\u67d3\u7269\u9694\u79bb\u7684\u7406\u60f3\u5019\u9009\u6750\u6599\u3002\u901a\u8fc7\u5bf9\u5178\u578bUiO-67\u5b54\u9699\u7eb3\u7c73\u7a7a\u95f4\u4e2d\u5e26\u6709\u758f\u6c34\u548c\u4eb2\u6c34\u57fa\u56e2\u7684\u6709\u673a\u8fde\u63a5\u7269\u7684\u4e0d\u540c\u8c03\u8282\uff0c\u7814\u7a76\u4eba\u5458\u7b5b\u9009\u51fa\u4e00\u79cd\u4e2d\u7b49\u4eb2\u6c34\u6027\u7684MOF\uff08UiO-67-4Me-NH2<\/sub>-38%\uff09\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u70ed\u7a33\u5b9a\u6027\u3001\u6c34\u89e3\u6027\u548c\u9178\u78b1\u7a33\u5b9a\u6027\uff0c\u5176S\u578b\u5438\u6c34\u7b49\u6e29\u7ebf\u6070\u597d\u4f4d\u4e8e\u63a8\u8350\u7684\u8212\u9002\u5065\u5eb7\u7684\u5ba4\u5185\u901a\u98ce\u76f8\u5bf9\u6e7f\u5ea6\u8303\u56f4\u5185\uff0845%\u221265% RH\uff09\uff0c\u5bf9\u5065\u5eb7\u7684\u4e0d\u826f\u5f71\u54cd\u964d\u81f3\u6700\u4f4e\uff0840-60% RH\uff09\u3002\u5b83\u5728\u5438\u6c34\u6548\u7387\u3001\u53bb\u9664\u6c61\u67d3\u7269\u3001\u53ef\u5faa\u73af\u5229\u7528\u548c\u518d\u751f\u7b49\u65b9\u9762\u5177\u6709\u72ec\u7279\u7684\u7279\u6027\uff0c\u5728\u6709\u9650\u7684\u5ba4\u5185\u73af\u5883\u4e2d\u5177\u6709\u5f88\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cHigh Water Adsorption MOFs with Optimized Pore-Nanospaces for Autonomous Indoor Humidity Control and Pollutants Removal\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002DOI: 10.1002\/anie.202112097<\/p>\n

\u56fe6 MOFs\u5b54\u7eb3\u7c73\u7a7a\u95f4\u7684\u540e\u671f\u5de5\u7a0b\u7814\u7a76<\/p>\n

\"\"<\/p>\n

JACS<\/strong>\uff1a\u5355\u4f4d\u70b9<\/strong>\/<\/strong>\u7eb3\u7c73\u7c07\u534f\u540c\u4f5c\u7528\u4fc3\u8fdb\u5149\u654f<\/strong>MOF<\/strong>\u7684<\/strong>CO2<\/sub><\/strong>\u7fb0\u57fa\u5316<\/strong><\/p>\n

\u592a\u9633\u80fd\u9a71\u52a8\u7684CO2<\/sub>\u7fb0\u57fa\u5316\u53d6\u4ee3\u6709\u6bd2\u7684CO\u4f5c\u4e3aC1\u6765\u6e90\u662f\u76f8\u5f53\u6709\u8da3\u7684;\u7136\u800c\uff0c\u7531\u4e8eCO2<\/sub>\u5206\u5b50\u7684\u60f0\u6027\uff0c\u8fd9\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u5728\u6b64\uff0c\u5929\u6d25\u7406\u5de5\u5927\u5b66\u5f20\u5fd7\u660e\u3001\u90ed\u9882\u7b49\u4eba\u5c06\u94b4\u5355\u4f4d\u70b9\u548c\u8d85\u7ec6CuPd\u7eb3\u7c73\u7c07\u50ac\u5316\u5242\u6574\u5408\u5230\u535f\u5549\u57fa\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u4e2d\uff0c\u6784\u5efa\u590d\u5408\u5149\u50ac\u5316\u5242(Cu1<\/sub>Pd2<\/sub>)z<\/sub>@PCN-222(Co) (z = 1.3\u30012.0\u548c3.0 nm)\u3002\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\uff0c\u6fc0\u53d1\u7684\u535f\u5549\u53ef\u4ee5\u540c\u65f6\u5c06\u7535\u5b50\u8f6c\u79fb\u5230Co\u5355\u4f4d\u70b9\u548cCuPd\u7eb3\u7c73\u56e2\u7c07\u4e0a\uff0c\u4e3aCO2<\/sub>\u5149\u8fd8\u539f\u548cSuzuki\/Sonogashira\u53cd\u5e94\u7684\u8026\u5408\u63d0\u4f9b\u4e86\u53ef\u80fd\u3002(Cu1<\/sub>Pd2<\/sub>)1.3<\/sub>@PCN-222(Co)\u7684\u591a\u7ec4\u5206\u534f\u540c\u4e0d\u4ec5\u53ef\u4ee5\u66ff\u4ee3\u5371\u9669\u7684CO\u6c14\u4f53\uff0c\u800c\u4e14\u53ef\u4ee5\u663e\u8457\u4fc3\u8fdb\u4e8c\u82ef\u7532\u916e\u5728CO2<\/sub>\u4e2d\u7684\u5149\u5408\u4f5c\u7528\uff0c\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u6536\u7387\u8d85\u8fc790%\uff0c\u9009\u62e9\u6027\u8fbe97%\u3002\u7cfb\u7edf\u7814\u7a76\u6e05\u695a\u5730\u63ed\u793a\u4e86\u8fd9\u4e9b\u590d\u5408\u50ac\u5316\u5242\u4e2d\u4e0d\u540c\u7ec4\u5206\u7684\u529f\u80fd\u548c\u534f\u4f5c\uff0c\u7a81\u51fa\u4e86\u5229\u7528\u6e29\u5ba4\u6c14\u4f53CO2<\/sub>\u4f5c\u4e3aC1\u6e90\u5f00\u53d1\u53ef\u6301\u7eed\u7fb0\u57fa\u5316\u53cd\u5e94\u65b9\u6848\u7684\u65b0\u89c6\u89d2\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cFeeding Carbonylation with CO2<\/sub> via the Synergy of Single-Site\/Nanocluster Catalysts in a Photosensitizing MOF\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002DOI: 10.1021\/jacs.1c08908<\/p>\n

\u56fe7 (Cu1<\/sub>Pd2<\/sub>) 1.3 <\/sub>@PCN- 222\uff08Co\uff09\u591a\u7ec4\u5206\u534f\u540c\u4f5c\u7528\u4e0b\u7684\u9ad8\u6548\u5149\u50ac\u5316<\/p>\n

\"\"<\/p>\n

Nature Commun.<\/strong>\uff1a\u57fa\u4e8e<\/strong>MOFs<\/strong>\u7684\u7eb3\u7c73\u5236\u5242\u5728\u6c27\u5316\u5e94\u6fc0\u548c\u9499\u8d85\u8f7d\u534f\u540c\u6297\u80bf\u7624\u6cbb\u7597\u4e2d\u5b9e\u73b0\u53cc\u91cd\u7ebf\u7c92\u4f53\u635f\u4f24<\/strong><\/p>\n

\u4ee5\u4e9a\u7ec6\u80de\u7ec6\u80de\u5668\u4e3a\u9776\u70b9\u8fdb\u884c\u591a\u7ea7\u635f\u4f24\u7684\u6297\u80bf\u7624\u6cbb\u7597\u5df2\u663e\u793a\u51fa\u5f88\u5927\u7684\u524d\u666f\u3002\u5728\u6b64\uff0c\u4e2d\u79d1\u9662\u8fc7\u7a0b\u5de5\u7a0b\u7814\u7a76\u6240Guanghui Ma\u3001Wei Wei \u53caZhiyuan Tian\u7b49\u4eba\u62a5\u9053\u4e86\u4e00\u79cd\u6838-\u58f3\u578b\u7eb3\u7c73\u8bd5\u5242\uff0c\u8be5\u8bd5\u5242\u4ee5\u94c1(III)\u7fa7\u9178\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6(MOFs)\u4e3a\u58f3\uff0c\u4e0a\u8f6c\u5316\u7eb3\u7c73\u9897\u7c92(UCNPs)\u4e3a\u6838\uff0c\u8fd1\u7ea2\u5916(NIR)\u5149\u89e6\u53d1\u534f\u540c\u589e\u5f3a\u7ebf\u7c92\u4f53\u7684\u6c27\u5316\u5e94\u6fc0\u548c\u9499\u8d85\u8f7d\u3002MOFs\u5916\u58f3\u4e0a\u7684\u53f6\u9178\u4fee\u9970\u4f7f\u7eb3\u7c73\u5236\u5242\u7684\u7ec6\u80de\u5438\u6536\u6548\u7387\u66f4\u9ad8\u3002\u57fa\u4e8eUCNPs\u7684\u4e0a\u8f6c\u6362\u80fd\u529b\uff0c\u8fd1\u7ea2\u5916\u5149\u4ecb\u5bfcFe3+<\/sup>\u8fd8\u539f\u4e3aFe2+<\/sup>\uff0c\u540c\u65f6\u6fc0\u6d3b\u5149\u9178\u53d1\u751f\u5668(pHP)\u5305\u57cb\u5728MOFs\u8154\u5185\uff0c\u4f7f\u6e38\u79bbFe2+<\/sup>\u91ca\u653e\u548c\u7ec6\u80de\u5185\u5fae\u73af\u5883\u9178\u5316\u3002\u8fc7\u6c27\u5316\u6c22\u5728\u7ebf\u7c92\u4f53\u4e2d\u8fc7\u8868\u8fbe\u3001\u9ad8\u6d3b\u6027Fe2+<\/sup>\u548c\u9178\u6027\u73af\u5883\u534f\u540c\u5f3a\u5316Fenton\u53cd\u5e94\uff0c\u4ea7\u751f\u81f4\u547d\u7684\u7f9f\u57fa\u81ea\u7531\u57fa(\u2022OH)\uff0c\u800c\u8840\u6d46\u5149\u9178\u5316\u8bf1\u5bfc\u9499\u5185\u6d41\uff0c\u5bfc\u81f4\u7ebf\u7c92\u4f53\u9499\u8d85\u8f7d\u3002\u7eb3\u7c73\u5236\u5242\u57fa\u4e8e\u53cc\u7ebf\u7c92\u4f53\u635f\u4f24\u7684\u6cbb\u7597\u80fd\u529b\u5df2\u5728\u4f53\u5185\u7ec6\u80de\u548c\u60a3\u8005\u6e90\u6027\u80bf\u7624\u79fb\u690d\u6a21\u578b\u4e2d\u660e\u786e\u8bc1\u5b9e\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMOFs-based nanoagent enables dual mitochondrial damage in synergistic antitumor therapy via oxidative stress and calcium overload\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Commun.\u4e0a\u3002DOI: 10.1038\/s41467-021-26655-4<\/p>\n

\u56fe8 FMUP\u7eb3\u7c73\u5236\u5242\u7684\u6784\u5efa\u53ca\u5176\u6f5c\u5728\u7684\u6297\u764c\u673a\u5236\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u6587\u4e2d\u6240\u8ff0\u5982\u6709\u4e0d\u59a5\u4e4b\u5904\uff0c\u6b22\u8fce\u8bc4\u8bba\u533a\u7559\u8a00~<\/p>\n

\u672c\u6587\u7531Junas\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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