{"id":230632,"date":"2021-12-10T06:30:09","date_gmt":"2021-12-09T22:30:09","guid":{"rendered":"\/\/m.iemloyee.com\/?p=230632"},"modified":"2021-12-09T18:31:31","modified_gmt":"2021-12-09T10:31:31","slug":"%ef%bc%88%e5%b7%b2%e6%a0%a1%e7%a8%bf%e4%bb%b6%ef%bc%89%e5%8d%97%e5%a4%a7%e4%b8%ad%e7%a7%91%e5%a4%a7-nature%e5%ad%90%e5%88%8a%ef%bc%9a%e6%8f%90%e9%ab%98123%e5%80%8d%ef%bc%81%e7%94%b5%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=230632","title":{"rendered":"\u5357\u5927&#038;\u4e2d\u79d1\u5927 Nature\u5b50\u520a\uff1a\u63d0\u9ad8123\u500d\uff01\u7535\u5316\u5b66\u53d1\u5149\u65b0\u7a81\u7834"},"content":{"rendered":"<p><strong>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n<p>\u7535\u5316\u5b66\u53d1\u5149\uff08Electrochemiluminescence, 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\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/2.webp_-2-300x255.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/2.webp_-2-768x654.jpg 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/>\uff08a-b\uff09<em>t<\/em>-COF\u3001<em>b<\/em>-COF\u548c<em>a<\/em>-COF\u7684PL\u5149\u8c31\u548c\u80fd\u7ea7\uff1b<\/p>\n<p>\uff08c\uff09\u4e09\u79cdCOFs\u4fee\u9970\u7684GCE\u5728\u542b\u670920 mM TPrA\uff08\u5149\u7535\u500d\u589e\u7ba1\u7535\u538b=700 V\uff09\u76840.10 M PBS\uff08pH=6.8\uff09\u4e2d\u7684ECL\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08d-f\uff09\u9876\u89c6\u56fe\u4e2d<em>t<\/em>-COF\u3001<em>b<\/em>-COF\u548c<em>a<\/em>-COF\u7684HOS\u548cLUS\u3002<\/p>\n<p><strong>\u56fe\u4e09\u3001<em>t<\/em>-COF\u7684\u7ed3\u6676\u5ea6\u8c03\u8282ECL<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-230636\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/3.webp_-2.jpg\" alt=\"\" width=\"800\" height=\"763\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/3.webp_-2.jpg 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/3.webp_-2-300x286.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/3.webp_-2-768x732.jpg 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/>\uff08a\uff09MC-TFPA\u548cMC-TAPT\u5728\u542b\u670920 mM TPrA\u76840.10 M PBS\uff08pH=6.8\uff09\u4e2d\u7684ECL\u6a21\u5f0f\uff1b<\/p>\n<p>\uff08b\uff09TAPT\u3001TFPA\u548c<em>t<\/em>-COF\u7684TCSPC\u75d5\u8ff9\uff1b<\/p>\n<p>\uff08c-d\uff09ECL\u5bf9\u7ed3\u6676\u5ea6\u7684\u4f9d\u8d56\u6027\u548c\u5bf9\u5e94\u7684<em>t<\/em>-COFs\u7684PXRD\u5149\u8c31\u3002<\/p>\n<p><strong>\u56fe\u56db\u3001<em>t<\/em>-COF\u7684\u8d28\u5b50\u5316\u8c03\u8282\u53ccECL\u5cf0<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-230637\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/4.webp_-2.jpg\" alt=\"\" width=\"800\" height=\"448\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/4.webp_-2.jpg 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/4.webp_-2-300x168.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/4.webp_-2-768x430.jpg 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/>\uff08a-b\uff09<em>t<\/em>-COFs\u4fee\u9970\u7684GCEs\u57280.10 M PBS\u4e2d\u53ca\u4e0d\u540cpH\u503c\u4e0b\u53cc\u5cf0ECL\u6a21\u5f0f\uff0c\u5305\u542b20 mM TPrA\u548cCV\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08c\uff09\u5728\u4e0d\u540cpH\u503c\u4e0b\uff0c\u5728\u542b\u6709100 mM TPrA\u76840.10 M PBS\u4e2d\u6536\u96c6\u7684<em>t<\/em>-COF\u7684ECL\u5149\u8c31\uff1b<\/p>\n<p>\uff08d\uff09\u76f8\u5bf9\u7684ECL\u6548\u7387\uff08\u03a6<sub>ECL<\/sub>\/\u03a6<sub>ECL,0<\/sub>\uff09\u5bf9pH\u503c\u7684\u4f9d\u8d56\u6027\uff1b<\/p>\n<p>\uff08e\uff09\u539f\u59cb\u548c\u8d28\u5b50\u5316<em>t<\/em>-COF\u7684\u7ed3\u6784\u4ee5\u53ca\u6709\u6548\u7535\u5b50\u548c\u7a7a\u7a74\u8d28\u91cf\u3002<\/p>\n<p><strong>\u56fe\u4e94\u3001<em>t<\/em>-COF\u7684\u7ade\u4e89\u6027\u6c27\u5316ECL\u673a\u7406<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-230638\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/5.webp_-1.jpg\" alt=\"\" width=\"800\" height=\"340\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/5.webp_-1.jpg 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/5.webp_-1-300x128.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/12\/5.webp_-1-768x326.jpg 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/>\uff08a\uff09t-COF\u7684ECL\u548cPL\u5149\u8c31\uff1b<\/p>\n<p>\uff08b\uff09\u7b2c\u4e00\u6fc0\u53d1\u6001\u548c\u57fa\u6001\u4e4b\u95f4<em>t<\/em>-COF\u7535\u8377\u5bc6\u5ea6\u7684\u5dee\u5f02\uff1b<\/p>\n<p>\uff08c-d\uff09\u63ba\u6742\u4e0d\u540c\u7535\u5b50\u6570\u7684<em>t<\/em>-COF\u7684\u76f8\u5bf9\u80fd\u91cf\u548c\u6001\u5bc6\u5ea6\uff1b<\/p>\n<p>\uff08e\uff09\u901a\u8fc7\u7f51\u72b6\u7535\u8377\u8f6c\u79fb\u7684ECL 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href=\"https:\/\/www.nature.com\/articles\/s41467-021-27127-5\" target=\"_blank\" rel=\"noopener\">Intrareticular charge transfer regulated electrochemiluminescence of donor-acceptor covalent organic frameworks<\/a><\/strong>. <em>Nature Communications<\/em>, <strong>2021<\/strong>, DOI: 10.1038\/s41467-021-27127-5.<\/p>\n<p>\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u7535\u5316\u5b66\u53d1\u5149\uff08Electrochemiluminescence, ECL\uff09\u662f\u4e00\u79cd\u901a\u8fc7\u7535\u5316\u5b66\u53cd\u5e94\u4ea7\u751f\u6fc0\u53d1\u6001\u7684\u53d1\u5149\u8fc7\u7a0b\u3002\u5176\u4e2d\uff0cECL\u7684\u6548\u7387\u4e3b\u8981\u53d6\u51b3\u4e8e\u53d1\u5c04&#8230;<\/p>\n","protected":false},"author":7770,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[4767],"class_list":["post-230632","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-ecl"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/230632"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/7770"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=230632"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/230632\/revisions"}],"predecessor-version":[{"id":230680,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/230632\/revisions\/230680"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=230632"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=230632"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=230632"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}