{"id":23047,"date":"2016-06-30T08:00:03","date_gmt":"2016-06-30T00:00:03","guid":{"rendered":"\/\/m.iemloyee.com\/?p=23047"},"modified":"2016-06-30T00:02:45","modified_gmt":"2016-06-29T16:02:45","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81%ef%bd%9cnature%e5%ad%90%e5%88%8a-am-macromolecules%e9%ab%98%e5%88%86%e5%ad%90%e6%9d%90%e6%96%99%e5%ad%a6%e6%9c%af%e8%bf%9b%e5%b1%95%e6%b1%87%e6%80%bb%e3%80%90160","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=23047","title":{"rendered":"\u9876\u520a\u52a8\u6001\uff5cNature\u5b50\u520a\/ AM\/ Macromolecules\u9ad8\u5206\u5b50\u6750\u6599\u5b66\u672f\u8fdb\u5c55\u6c47\u603b\u3010160629\u671f\u3011"},"content":{"rendered":"

\u672c\u671f\u5bfc\u8bfb\uff1a<\/strong>\u4eca\u5929\u9ad8\u5206\u5b50\u6750\u6599\u5468\u62a5\u7ec4\u9080\u60a8\u4e00\u8d77\u6765\u770b\u770bNature\u5b50\u520a\/ Advanced Materials\/ Macromolecules\u671f\u520a\u9ad8\u5206\u5b50\u6750\u6599\u9886\u57df\u6700\u65b0\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u672c\u671f\u5185\u5bb9\u9884\u89c8\uff1a1\u3001\u201c\u5408\u6210\u5de5\u5177\u7bb1\u201d\u2014\u2014\u751f\u7269\u57fa\u805a\u78b3\u9178\u916f\uff1b2\u3001\u4e00\u79cd\u5c06\u590d\u5408\u6c34\u51dd\u80f6\u8f6c\u53d8\u6210\u975e\u5e38\u575a\u97e7\u4e14\u53ef\u5feb\u901f\u6062\u590d\u7684\u53cc\u7f51\u7edc\u6c34\u51dd\u80f6\u7684\u901a\u7528\u6d78\u900f\u7b56\u7565\uff1b3\u3001\u7ed3\u5408\u53ef\u9006\u52a0\u6210-\u65ad\u88c2\u94fe\u8f6c\u79fb\u805a\u5408\u4e0e\u4e09\u5511\u5549\u4e8c\u916e-\u4e8c\u70ef\u70b9\u51fb\u53cd\u5e94\u9ad8\u6548\u5236\u5907\u6d17\u74f6\u5237\u72b6\u805a\u5408\u7269\u7684\u65e0\u91d1\u5c5e\u201cGrafting Onto\u201d\u65b9\u6cd5\uff1b4\u3001\u73af\u6c27\u884d\u751f\u7269\u548c\u4e8c\u6c22\u9999\u8c46\u7d20\u5728\u78f7\u8148\u8d85\u5f3a\u78b1\u50ac\u5316\u4e0b\u7684\u5f00\u73af\u4ea4\u66ff\u5171\u805a\uff1b5\u3001\u6d3b\u6027\u805a\u5408\u7269\u7f51\u7edc\u4e2d\u7684\u7269\u7406\u51dd\u80f6\u5316\u73b0\u8c61\u7684\u5fae\u6d41\u53d8\u5b66\u7814\u7a76\uff1b6\u3001\u73af\u72b6\u805a\u5408\u7269\u7684\u67d4\u987a\u6027\u5982\u4f55\u5f71\u54cd\u805a\u5408\u7269\u7ed3\u7684\u5b9a\u4f4d\uff1b7\u3001\u73bb\u7483\u66ff\u4ee3\u54c1\u7684\u65b0\u8fdb\u5c55\u2014\u2014\u5408\u6210\u6c34\u51dd\u80f6\u6750\u6599\u7684\u5408\u5e76\u5e26\u7535\u4e0e\u7ea4\u7ef4\u7ed3\u6784\uff1b8\u3001\u5229\u7528\u6c1f\u5316\u786b(VI)\u4ea4\u6362(SuFEx)\u548c\u94dc\u50ac\u5316\u53e0\u6c2e-\u7094\u70c3\u73af\u52a0\u6210(CuAAC)\u53cd\u5e94\u8fdb\u884c\u9009\u62e9\u6027\u6b63\u4ea4\u540e\u805a\u5408\u6539\u6027\u3002<\/p>\n

1\u3001Nature Communications\uff1a\u201c\u5408\u6210\u5de5\u5177\u7bb1\u201d\u2014\u2014\u751f\u7269\u57fa\u805a\u78b3\u9178\u916f
\n<\/strong><\/p>\n

\"image001\"<\/p>\n

\u56fe1 \u805a\u67e0\u6aac\u70ef\u916f\u7684\u5408\u6210\u8def\u7ebf<\/strong><\/p>\n

\u5b8c\u5168\u751f\u7269\u57fa\u7684\u805a\u67e0\u6aac\u70ef\u916f\u662f\u4e00\u79cd\u70ed\u5851\u6027\u805a\u5408\u7269\uff0c\u5b83\u53ef\u4ee5\u7531\u67e0\u6aac\u70ef\u6c27\u5316\u7269\uff08\u4ece\u67e0\u6aac\u4e2d\u63d0\u53d6\uff0c\u5728\u67d1\u6a58\u76ae\u4e2d\u53d1\u73b0\uff09\u548cCO2\u5171\u805a\u5408\u6210\u3002\u805a\u67e0\u6aac\u70ef\u916f\u7684\u6bcf\u4e2a\u91cd\u590d\u5355\u5143\u542b\u4e00\u4e2a\u53cc\u952e\uff0c\u8fd9\u53ef\u7528\u4e8e\u8fdb\u4e00\u6b65\u7684\u5316\u5b66\u6539\u6027\u3002\u8fd9\u4e9b\u5316\u5b66\u6539\u6027\u53ef\u4efb\u610f\u8c03\u63a7\u8102\u80aa\u65cf\u805a\u78b3\u9178\u916f\u7684\u6027\u80fd\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u5fb7\u56fd\u62dc\u7f57\u4f0a\u7279\u5927\u5b66\u7684A. Greiner\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u7684\u7814\u7a76\u6210\u679c\u8868\u660e\u805a\u67e0\u6aac\u70ef\u916f\u662f\u5b8c\u7f8e\u7684\u7eff\u8272\u5e73\u53f0\u805a\u5408\u7269\uff0c\u53ef\u7528\u4e8e\u5408\u6210\u591a\u79cd\u529f\u80fd\u6750\u6599\u3002\u8fd9\u9879\u7814\u7a76\u4e2d\u6240\u5c55\u793a\u7684\u76f8\u5173\u4f8b\u5b50\u6709\u4ece\u5de5\u7a0b\u70ed\u5851\u6027\u5851\u6599\u5230\u6a61\u80f6\u7684\u8f6c\u53d8\u3001\u6c38\u4e45\u6027\u6297\u83cc\u6d3b\u6027\u7684\u52a0\u5165\u3001\u805a\u78b3\u9178\u916f\u7684\u4eb2\u6c34\u5316\u548cpH\u4f9d\u8d56\u578b\u6eb6\u89e3\u5ea6\u3002\u6700\u7ec8\uff0c\u7814\u7a76\u4eba\u5458\u5f00\u53d1\u4e86\u4e00\u79cd\u5408\u6210\u8def\u7ebf\uff0c\u53ef\u5236\u5907\u5177\u6709\u6539\u8fdb\u7684\u70ed\u52a0\u5de5\u6027\u80fd\u7684\u5b8c\u5168\u9971\u548c\u7684\u4ea7\u7269\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Bio-based polycarbonate as synthetic toolbox<\/a> (Nature Communications, 2016, DOI: 10.1038\/ncomms11862)<\/p>\n

2\u3001Advanced Materials\uff1a\u4e00\u79cd\u5c06\u590d\u5408\u6c34\u51dd\u80f6\u8f6c\u53d8\u6210\u975e\u5e38\u575a\u97e7\u4e14\u53ef\u5feb\u901f\u6062\u590d\u7684\u53cc\u7f51\u7edc\u6c34\u51dd\u80f6\u7684\u901a\u7528\u6d78\u900f\u7b56\u7565<\/strong><\/p>\n

\"image002\"<\/p>\n

\u56fe2 \u5c06\u590d\u5408\u6c34\u51dd\u80f6\u8f6c\u53d8\u4e3a\u6df7\u5408\u53cc\u7f51\u7edc\uff08DN\uff09\u6c34\u51dd\u80f6\u7684\u8f6c\u53d8\u673a\u5236<\/strong><\/p>\n

\u6c34\u51dd\u80f6\u5177\u6709\u4e09\u7ef4\u7684\u4ea4\u8054\u7f51\u7edc\u7ed3\u6784\u548c\u53ef\u8c03\u63a7\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u519c\u4e1a\u6297\u65f1\u3001\u6c61\u67d3\u6cbb\u7406\u3001\u836f\u7269\u8f93\u9001\u548c\u7ec4\u7ec7\u5de5\u7a0b\u7b49\u9886\u57df\u3002\u7136\u800c\uff0c\u4f20\u7edf\u6c34\u51dd\u80f6\u56fa\u6709\u7684\u4f4e\u673a\u68b0\u5f3a\u5ea6\u5927\u5927\u9650\u5236\u4e86\u5176\u5e94\u7528\uff0c\u5c24\u5176\u662f\u5728\u575a\u786c\u3001\u7262\u56fa\u3001\u8010\u51b2\u51fb\u7684\u627f\u91cd\u8f6f\u7ec4\u7ec7\uff08\u5982\u808c\u8171\uff0c\u8f6f\u9aa8\u548c\u97e7\u5e26\u7b49\uff09\u65b9\u9762\u3002\u901a\u8fc7\u62b5\u6297\u88c2\u7eb9\u7684\u5f62\u6210\u548c\u6269\u5927\uff0c\u5c06\u7ed3\u6784\u88c1\u526a\u5747\u5300\u5e76\u7ed3\u5408\u80fd\u91cf\u8017\u6563\u673a\u5236\uff0c\u88ab\u666e\u904d\u8ba4\u4e3a\u662f\u63d0\u9ad8\u6c34\u51dd\u80f6\u673a\u68b0\u6027\u80fd\u7684\u6709\u6548\u7b56\u7565\u3002\u53cc\u7f51\u7edc\uff08DN\uff09\u6c34\u51dd\u80f6\u662f\u7531\u4e24\u79cd\u6027\u80fd\u5dee\u5f02\u660e\u663e\u7684\u975e\u5bf9\u79f0\u7f51\u7edc\u6784\u6210\uff0c\u5176\u4e2d\u521a\u6027\u548c\u8106\u6027\u7f51\u7edc\u53ef\u4f5c\u4e3a\u201c\u727a\u7272\u952e\u201d\u6709\u6548\u5206\u6563\u80fd\u91cf\u800c\u67d4\u8f6f\u6709\u97e7\u6027\u7684\u7f51\u7edc\u5219\u53ef\u5728\u53d8\u5f62\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u6c34\u51dd\u80f6\u7684\u5b8c\u6574\u6027\u3002\u4e0d\u540c\u4e8e\u4f20\u7edf\u7684\u5316\u5b66-\u5316\u5b66\u4ea4\u8054\u7684DN\u6c34\u51dd\u80f6\uff0c\u6df7\u5408\u7269\u7406-\u5316\u5b66\u4ea4\u8054\u7684DN\uff08\u6df7\u5408DN\uff09\u6c34\u51dd\u80f6\u7531\u4e8e\u53ef\u9006\u7269\u7406\u7f51\u7edc\u7684\u74e6\u89e3-\u518d\u4ea4\u8054\u884c\u4e3a\uff0c\u800c\u5177\u6709\u7a81\u51fa\u7684\u81ea\u6062\u590d\u6027\u80fd\u548c\u4f18\u826f\u7684\u8010\u75b2\u52b3\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u6df7\u5408DN\u51dd\u80f6\u5f88\u53ef\u80fd\u4f1a\u6210\u4e3a\u627f\u91cd\u7ec4\u7ec7\u7684\u66ff\u4ee3\u54c1\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u7684\u5434\u5fb7\u6210\u7814\u7a76\u5458\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u53d1\u660e\u4e86\u4e00\u79cd\u5c06\u590d\u5408\u6c34\u51dd\u80f6\u8f6c\u53d8\u6210\u975e\u5e38\u575a\u97e7\u4e14\u53ef\u5feb\u901f\u6062\u590d\u7684\u53cc\u7f51\u7edc\u6c34\u51dd\u80f6\u7684\u901a\u7528\u6d78\u900f\u7b56\u7565\u3002\u4ed6\u4eec\u9996\u5148\u5c06\u77ed\u94feCS\uff08\u5728\u4e2d\u6027\u6c34\u4e2d\u6eb6\u89e3\u5ea6\u9ad8\uff09\u901a\u8fc7\u6c22\u952e\u6574\u5408\u5230\u5171\u4ef7\u805a\u4e19\u70ef\u9170\u80fa\u7f51\u7edc\u4e2d\uff0c\u6784\u5efa\u4e86\u4e00\u79cd\u590d\u5408\u6c34\u51dd\u80f6\uff08PAM-CS\u590d\u5408\u6c34\u51dd\u80f6\uff09\uff1b\u7136\u540e\u91c7\u7528\u4e00\u79cd\u7b80\u5355\u7684\u6d78\u900f\u7b56\u7565\uff08soaking strategy\uff09\uff0c\u901a\u8fc7CS\u5fae\u6676\u548c\u7f20\u7ed3\u7f51\u7edc\u7684\u5f62\u6210\uff0c\u5c06\u590d\u5408\u6c34\u51dd\u80f6\u8f6c\u53d8\u6210\u5177\u6709\u9ad8\u673a\u68b0\u6027\u80fd\u7684\u6df7\u5408DN\u6c34\u51dd\u80f6\uff08PAM-CS DN\u6c34\u51dd\u80f6\uff09\u3002PAM-CS DN\u6c34\u51dd\u80f6\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u6297\u62c9\u5f3a\u5ea6\uff08\u22482 MPa\uff09\u3001\u8d85\u9ad8\u7684\u97e7\u6027\uff08\u65ad\u88c2\u80fd\u91cf\uff1a\u224810 kJ m \u22122\uff09\uff0c\u826f\u597d\u7684\u81ea\u6062\u590d\u7279\u6027\uff08\u677e\u5f1b4h\u540e\u8d85\u8fc790%\u7684\u56de\u590d\u7387\uff09\u3001\u826f\u597d\u7684\u627f\u8f7d\u80fd\u529b\u53ca\u6297\u649e\u3001\u6297\u75b2\u52b3\u80fd\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>A Universal Soaking Strategy to Convert Composite Hydrogels into Extremely Tough and Rapidly Recoverable Double-Network Hydrogels<\/a> (Advanced Materials, 2016, DOI: 10.1002\/adma.201601742)<\/p>\n

3\u3001Macromolecules\uff1a\u7ed3\u5408\u53ef\u9006\u52a0\u6210-\u65ad\u88c2\u94fe\u8f6c\u79fb\u805a\u5408\u4e0e\u4e09\u5511\u5549\u4e8c\u916e-\u4e8c\u70ef\u70b9\u51fb\u53cd\u5e94\u9ad8\u6548\u5236\u5907\u6d17\u74f6\u5237\u72b6\u805a\u5408\u7269\u7684\u65e0\u91d1\u5c5e\u201cGrafting Onto\u201d\u65b9\u6cd5<\/strong><\/p>\n

\"image003\"<\/p>\n

\u56fe3 \u6d17\u74f6\u5237\u72b6\u805a\u5408\u7269\u7684\u65e0\u91d1\u5c5e\u201cGrafting Onto\u201d\u5236\u5907\u65b9\u6cd5<\/strong><\/p>\n

\u6d17\u74f6\u5237\u72b6\u805a\u5408\u7269\uff08bottlebrush polymers\uff09\u662f\u63a5\u679d\u805a\u5408\u7269\u4e2d\u7684\u4e00\u79cd\u72ec\u7279\u7c7b\u578b\uff0c\u5176\u4fa7\u94fe\u5bc6\u96c6\u5730\u63a5\u679d\u5728\u7ebf\u6027\u805a\u5408\u7269\u4e3b\u94fe\u4e0a\u3002\u805a\u5408\u7269\u4fa7\u94fe\u95f4\u7684\u7a7a\u95f4\u6392\u65a5\u5927\u5927\u5ef6\u957f\u4e86\u805a\u5408\u7269\u4e3b\u94fe\uff0c\u4f7f\u6d17\u74f6\u5237\u72b6\u805a\u5408\u7269\u5448\u73b0\u4e00\u79cd\u5ef6\u7eed\u6027\u7684\u8815\u866b\u72b6\u5206\u5b50\u5f62\u6001\u3002\u6d17\u74f6\u5237\u72b6\u805a\u5408\u7269\u72ec\u7279\u7684\u5206\u5b50\u7ed3\u6784\u4f7f\u5176\u5728\u8bb8\u591a\u9886\u57df\u4e2d\u5177\u6709\u91cd\u8981\u7684\u5e94\u7528\uff0c\u4f8b\u5982\u5149\u5b50\u5b66\u3001\u5149\u523b\u6280\u672f\u3001\u8d85\u8f6f\u5f39\u6027\u4f53\u3001\u836f\u7269\u8f93\u9001\u7b49\uff0c\u6b64\u5916\u5b83\u8fd8\u662f\u5236\u5907\u4e00\u7ef4\u7eb3\u7c73\u6750\u6599\u7684\u7406\u60f3\u7684\u5206\u5b50\u6a21\u677f\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u7684\u5f20\u79d1\u7814\u7a76\u5458\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5c06\u53ef\u9006\u52a0\u6210-\u65ad\u88c2\u94fe\u8f6c\u79fb\uff08RAFT\uff09\u805a\u5408\u4e0e\u4e09\u5511\u5549\u4e8c\u916e\uff08TAD\uff09-\u4e8c\u70ef\u7684Diels-Alder\u73af\u5316\u52a0\u6210\u53cd\u5e94\u76f8\u7ed3\u5408\uff0c\u5f00\u53d1\u4e86\u4e00\u79cd\u53ef\u9ad8\u6548\u5236\u5907\u6d17\u74f6\u5237\u72b6\u805a\u5408\u7269\u7684\u65e0\u91d1\u5c5e\u201cgrafting onto\u201d\u65b9\u6cd5\u3002\u91c7\u7528\u8be5\u5236\u5907\u65b9\u6cd5\uff0c\u5728\u4e8c\u70ef\u4e2d\u52a0\u5165\u8f7b\u5fae\u6469\u5c14\u8fc7\u91cf\uff081.2\u500d\uff09\u7684TAD\u4ec51min\u540e\uff0c\u5f97\u5230\u7684\u6d17\u74f6\u5237\u72b6\u805a\u5408\u7269\u7684\u63a5\u679d\u5bc6\u5ea6\u5c31\u9ad8\u8fbe90%\u3002\u7ecf\u8fc7\u4e0d\u523010min\u7684\u5076\u8054\u53cd\u5e94\u540e\u5176\u63a5\u679d\u5bc6\u5ea6\u53ef\u8fdb\u4e00\u6b65\u63d0\u9ad8\u3002\u901a\u8fc7\u539f\u5b50\u529b\u663e\u5fae\u955c\uff08AFM\uff09\u53ef\u4ee5\u89c2\u5bdf\u5230\u5176\u8815\u866b\u72b6\u5206\u5b50\u5f62\u6001\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Efficient Metal-Free \u201cGrafting Onto\u201d Method for Bottlebrush Polymers by Combining RAFT and Triazolinedione\u2013Diene Click Reaction <\/a>(Macromolecules, 2016, DOI: 10.1021\/acs.macromol.6b00782)<\/p>\n

4\u3001Macromolecules\uff1a\u73af\u6c27\u884d\u751f\u7269\u548c\u4e8c\u6c22\u9999\u8c46\u7d20\u5728\u78f7\u8148\u8d85\u5f3a\u78b1\u50ac\u5316\u4e0b\u7684\u5f00\u73af\u4ea4\u66ff\u5171\u805a<\/strong><\/p>\n

\"image004\"<\/p>\n

\u56fe4 \u73af\u6c27\u884d\u751f\u7269\u548c\u4e8c\u6c22\u9999\u8c46\u7d20\u5728\u78f7\u8148\u8d85\u5f3a\u78b1\u50ac\u5316\u4e0b\u7684\u7684\u5f00\u73af\u4ea4\u66ff\u5171\u805a\u793a\u610f\u56fe<\/strong><\/p>\n

\u78f7\u8148\u57fa\u662f\u4e00\u79cd\u975e\u79bb\u5b50\u6709\u673a\u8d85\u5f3a\u78b1\uff0c\u5b83\u5728\u5c0f\u5206\u5b50\u548c\u9ad8\u5206\u5b50\u7684\u6709\u673a\u50ac\u5316\u5408\u6210\u9886\u57df\u90fd\u5907\u53d7\u5173\u6ce8\u3002\u5b83\u5177\u6709\u5f3a\u78b1\u6027\u3001\u975e\u4eb2\u6838\u6027\u3001\u76f8\u5bf9\u8f83\u4f4e\u7684\u6c14\u654f\u6027\u3001\u5728\u6781\u6027\/\u975e\u6781\u6027\u6eb6\u5242\u4e2d\u826f\u597d\u7684\u6eb6\u89e3\u6027\uff0c\u4ee5\u53ca\u6613\u4e8e\u5904\u7406\u3001\u5de5\u4f5c\u6e29\u5ea6\u8303\u56f4\u5e7f\u7b49\u7279\u70b9\u3002\u56e0\u6b64\uff0c\u78f7\u8148\u57fa\u7684\u5e94\u7528\u5341\u5206\u5e7f\u6cdb\uff0c\u4f8b\u5982\u53ef\u4f5c\u4e3a\u591a\u79cd\u5355\u4f53\u7684\u9634\u79bb\u5b50\u805a\u5408\/\u51c6\u9634\u79bb\u5b50\u805a\u5408\u7684\u9ad8\u6548\u50ac\u5316\u5242\/\u4fc3\u8fdb\u5242\uff0c\u5305\u62ec\uff08\u7532\u57fa\uff09\u4e19\u70ef\u9178\uff0c\u73af\u916f\uff0c\u73af\u6c27\u884d\u751f\u7269\uff0c\u73af\u7845\u6c27\u70f7\u548c\u73af\u72b6\u78b3\u9178\u916f\u7b49\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u534e\u5357\u7406\u5de5\u5927\u5b66\u7684\u8d75\u4fca\u9e4f\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u91c7\u7528\u78f7\u8148\u8d85\u5f3a\u78b1\uff08t-BuP4\uff09\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u5c063,4-\u4e8c\u6c22\u9999\u8c46\u7d20\uff08\u7f29\u5199\u4e3aDHC\uff0c\u4e00\u79cd\u4ece\u81ea\u7136\u754c\u63d0\u53d6\u7684\u516d\u5143\u915a\u5185\u916f\uff09\u4e0e\u51e0\u79cd\u73af\u6c27\u884d\u751f\u7269\uff08\u73af\u6c27\u4e59\u70f7\u3001\u73af\u6c27\u4e19\u70f7\u30011,2-\u73af\u6c27\u4e01\u70f7\uff0c\u73af\u6c27\u82ef\u4e59\u70ef\u548c2-\u4e59\u57fa\u5df1\u57fa\u7f29\u6c34\u7518\u6cb9\u919a\uff09\u8fdb\u884c\u5f00\u73af\u9634\u79bb\u5b50\u5171\u805a\u3002\u5149\u8c31\u5206\u6790\u8868\u660e\uff0c\u4ea7\u7269\u82b3\u9999\u805a\u919a\u916f\u5448\u73b0\u51fa\u5b8c\u7f8e\u7684\u4ea4\u66ff\u5355\u4f53\u5e8f\u5217\uff0c\u5b83\u7531\u7ebf\u6027\u4ea4\u66ff\u5171\u805a\u7269\u548c\u6469\u5c14\u8d28\u91cf\u76f8\u5bf9\u8f83\u4f4e\uff08\u7531\u5206\u5b50\u5185\u916f\u4ea4\u6362\u53cd\u5e94\u5bfc\u81f4\uff09\u7684\u73af\u72b6\u4ea4\u66ff\u5171\u805a\u7269\u7ec4\u6210\u3002\u8be5\u4ea4\u66ff\u5171\u805a\u7269\u5177\u6709\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u4e14\u4e0e\u76f8\u5e94\u7684\u73af\u6c27\u884d\u751f\u7269\u7684\u5747\u805a\u7269\u76f8\u6bd4\uff0c\u5177\u6709\u66f4\u9ad8\u7684\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Ring-Opening Alternating Copolymerization of Epoxides and Dihydrocoumarin Catalyzed by a Phosphazene Superbase<\/a> (Macromolecules, 2016, DOI: 10.1021\/acs.macromol.6b00840)<\/p>\n

5\u3001Macromolecules\uff1a\u6d3b\u6027\u805a\u5408\u7269\u7f51\u7edc\u4e2d\u7684\u7269\u7406\u51dd\u80f6\u5316\u73b0\u8c61\u7684\u5fae\u6d41\u53d8\u5b66\u7814\u7a76<\/strong><\/p>\n

\"5\"<\/p>\n

\u56fe5 (A)\u7269\u7406\u6027\u51dd\u80f6\u5f62\u6210\u8fc7\u7a0b\u793a\u610f\u56fe\u3002\u7ea2\u8272\u4ee3\u8868\u5206\u5b50\u7c07\u7684\u5f1b\u8c6b\u90e8\u5206\uff0c\u7070\u8272\u4ee3\u8868\u975e\u5f1b\u8c6b\u90e8\u5206\u3002\u5728(i)-(iii)\u4e2d\u53ea\u663e\u793a\u4e86\u6700\u5927\u7684\u5206\u5b50\u7c07\uff1b(B)\u6700\u957f\u5f1b\u8c6b\u65f6\u95f4\u7684\u793a\u610f\u56fe\uff1b(C)\u96f6\u526a\u5207\u7c98\u5ea6\u793a\u610f\u56fe<\/strong><\/p>\n

\u8bb8\u591a\u805a\u5408\u7269\u6750\u6599\u5728\u5916\u754c\u6e29\u5ea6\u3001\u9178\u78b1\u5ea6\u6539\u53d8\u540e\u90fd\u4f1a\u7ecf\u5386\u6db2-\u56fa\u8f6c\u53d8\u6216\u6eb6\u80f6-\u51dd\u80f6\u8f6c\u53d8\u3002\u5728\u4e00\u5b9a\u70ed\u529b\u5b66\u6761\u4ef6\u4e0b\u53ef\u4ee5\u89c2\u5bdf\u5230\u5171\u4ef7\u952e\uff08\u5316\u5b66\u51dd\u80f6\uff09\u5728\u8f6c\u53d8\u8fc7\u7a0b\u4e2d\u53d1\u751f\u4e86\u6d41\u53d8\u5b66\u4e2d\u96f6\u526a\u5207\u7c98\u5ea6\u7684\u5206\u6563\u73b0\u8c61\u3002\u805a\u5408\u7269\u7531\u4e8e\u652f\u5316\u5206\u5b50\u7c07\u7684\u5f62\u6210\u5bfc\u81f4\u5206\u5b50\u8d28\u91cf\u4e0a\u7684\u5206\u6563\uff0c\u8fdb\u800c\u53d1\u751f\u4e86\u4e0a\u8ff0\u7c98\u5ea6\u7684\u53d8\u5316\u3002\u6b64\u5916\uff0c\u51dd\u80f6\u70b9\u9644\u8fd1\u7684\u5927\u5206\u5b50\u7c07\u5728\u7a7a\u95f4\u4e0a\u5448\u73b0\u4e00\u79cd\u81ea\u76f8\u4f3c\u6027\uff0c\u56e0\u800c\u4f1a\u6709\u81ea\u8eab\u7279\u6b8a\u7684\u529b\u5b66\u6cd5\u5219\uff0c\u5728\u51dd\u80f6\u70b9\u9644\u8fd1\u53d1\u751f\u7c98\u5ea6\u5f1b\u8c6b\uff0c\u5373Winter and Chambon\u6cd5\u5219\u3002\u4e0e\u56fa\u4f53\u5f62\u6001\u7684\u5316\u5b66\u51dd\u80f6\u76f8\u6bd4\uff0c\u6e17\u900f\u5728\u6db2\u4f53\u4e2d\u3001\u53ef\u6d41\u52a8\u7684\u7269\u7406\u51dd\u80f6\u662f\u7531\u4e00\u4e9b\u6613\u65ad\u88c2\u4f46\u6613\u91cd\u5efa\u7684\u4ea4\u8054\u7ec4\u6210\uff0c\u4f46\u5176\u5b58\u5728\u7684\u5bff\u547d\u8981\u77ed\u4e8e\u89c2\u5bdf\u65f6\u95f4\u3002\u56e0\u800c\u7814\u7a76\u7269\u7406\u51dd\u80f6\u5728\u5176\u5b58\u5728\u5bff\u547d\u5185\u7684\u6027\u80fd\u7279\u5f81\u6709\u52a9\u4e8e\u5168\u9762\u7cfb\u7edf\u7684\u4e86\u89e3\u6eb6\u80f6-\u51dd\u80f6\u7684\u8f6c\u53d8\u8fc7\u7a0b\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u7f8e\u56fd\u4f0a\u5229\u8bfa\u4f0a\u7406\u5de5\u5b66\u9662\u7684Tsutomu Indei\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u7814\u7a76\u4e86\u805a(\u4e59\u70ef\u9187)\u787c\u7802\u6eb6\u6db2\u7684\u6d41\u53d8\u5b66\u7279\u5f81\u4ee5\u53ca\u5176\u5728\u6eb6\u6db2\u4e2d\u7684\u5e03\u6717\u5206\u5b50\u6269\u6563\u5206\u5e03\u60c5\u51b5\uff0c\u4ed6\u4eec\u53d1\u73b0\u5728\u67d0\u4e00\u4e2a\u7279\u5b9a\u7684\u787c\u7802\u6d53\u5ea6\u4e0b\uff0c\u6839\u636e\u5fae\u6d41\u53d8\u5b66\u4f30\u8ba1\uff0c\u52a8\u6001\u6a21\u91cf\u5728\u9891\u7387\u5927\u4e8e\u7ec8\u7aef\u6d41\u6001\u65f6\u5448\u73b0\u51fa\u5e42\u5f8b\u5206\u5e03\u3002\u540c\u65f6\u7814\u7a76\u4eba\u5458\u6269\u5c55\u4e86\u4f20\u7edf\u5316\u5b66\u51dd\u80f6\u7684\u7406\u8bba\u6765\u89e3\u91ca\u7269\u7406\u51dd\u80f6\u7684\u7ebf\u6027\u7c98\u5ea6\uff0c\u7406\u8bba\u63a8\u5bfc\u7684\u52a8\u6001\u6a21\u91cf\u4e0e\u5b9e\u9a8c\u7ed3\u679c\u76f8\u7b26\u3002\u6240\u6709\u7684\u4e8b\u5b9e\u8bc1\u660e\uff0c\u6e17\u900f\u7684\u7f51\u7edc\u7ed3\u6784\u5c31\u662f\u5728\u4e00\u4e2a\u7279\u5b9a\u7684\u787c\u7802\u6d53\u5ea6\u4e0b\u5f62\u6210\u7684\u3002\u53e6\u5916\uff0c\u7814\u7a76\u4eba\u5458\u5728\u4f30\u8ba1\u7684\u51dd\u80f6\u70b9\u9644\u8fd1\u53d1\u73b0\u4e00\u4e2a\u5f02\u5e38\u57df\uff0c\u5176\u7c98\u5ea6\u5728\u4ea4\u8054\u8303\u56f4\u5185\u51e0\u4e4e\u662f\u72ec\u7acb\u7684\uff0c\u4ed6\u4eec\u5bf9\u6b64\u89e3\u91ca\u4e3a\u5728\u53ef\u6d41\u52a8\u7684\u5f31\u7269\u7406\u51dd\u80f6\u4e2d\u7684\u9ad8\u539f\u7c98\u5ea6\u662f\u56fa\u5b9a\u7684\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Microrheological Study of Physical Gelation in Living Polymeric Networks <\/a>(Macromolecules, 2016, DOI: 10.1021\/acs.macromol.6b00745)<\/p>\n

6\u3001Macromolecules\uff1a\u73af\u72b6\u805a\u5408\u7269\u7684\u67d4\u987a\u6027\u5982\u4f55\u5f71\u54cd\u805a\u5408\u7269\u7ed3\u7684\u5b9a\u4f4d<\/strong><\/p>\n

\"6\"<\/p>\n

\u56fe6 \u7531500\u4e2a\u5355\u4f53\u7ec4\u6210\u7684\u805a\u5408\u7269\u793a\u610f\u56fe\uff0c\u5176\u4e2d\u9ec4\u8272\u4ee3\u8868\u67d4\u987a\u6027\u90e8\u5206(100\u4e2a\u5355\u4f53)\uff0c\u7ea2\u8272\u4ee3\u8868\u521a\u6027\u90e8\u5206(400\u4e2a\u5355\u4f53). (a) \u805a\u5408\u7269\u7ed3\u5b8c\u5168\u5728\u67d4\u987a\u6027\u90e8\u5206\u7684\u5206\u5b50\u6a21\u62df\u793a\u610f\u56fe\uff0c\u521a\u6027\u90e8\u5206\u5448\u5f2f\u66f2\u72b6. (b) \u4e0d\u53d7\u7a7a\u95f4\u4f4d\u7f6e\u6240\u9650\u5236\u7684\u805a\u5408\u7269\u7ed3\u5206\u5b50\u6a21\u62df\u793a\u610f\u56fe.<\/strong><\/p>\n

\u7ebf\u6027\u7684\u957f\u94fe\u805a\u5408\u7269\u5728\u7a00\u6eb6\u6db2\u4e2d\u6613\u53d1\u751f\u81ea\u7f20\u7ed5\u73b0\u8c61\uff0c\u5e76\u4e14\u5728\u63a5\u5934\u5904\u6253\u7ed3\u5f62\u6210\u73af\u72b6\u805a\u5408\u7269\u3002\u8fd9\u4e2a\u73b0\u8c61\u5728\u5206\u5b50\u751f\u7269\u5b66\u4e2d\u5341\u5206\u5e38\u89c1\uff0c\u4f8b\u5982\u62d3\u6251\u7f20\u7ed5\u53ef\u4ee5\u907f\u514d\u7ec6\u83ccDNA\u5728\u590d\u5236\u540e\u53d1\u751f\u5206\u79bb\uff0c\u5e76\u9700\u8981\u7279\u5b9a\u7684\u9176\u6765\u6e05\u9664\u4e24\u6761DNA\u94fe\u8fde\u63a5\u5904\u7684\u7ed3\u3002\u7ed3\u7684\u5b58\u5728\u4f1a\u5f71\u54cd\u75c5\u6bd2DNA\u51dd\u805a\u5728\u5916\u58f3\u5185\u7684\u7a7a\u95f4\u7ec4\u7ec7\u3002\u8fc7\u53bb\u4eba\u4eec\u5bf9\u73af\u72b6\u805a\u5408\u7269\u7ed3\u7684\u5404\u9879\u6027\u80fd\u5c55\u5f00\u7814\u7a76\uff0c\u4f46\u662f\u5bf9\u62d3\u6251\u6027\u80fd\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u4ee5\u53ca\u805a\u5408\u7269\u672c\u8eab\u7684\u5316\u5b66\u6027\u8d28\u5e76\u672a\u7cfb\u7edf\u638c\u63e1\uff0c\u76f4\u5230\u6700\u8fd1\u624d\u53d1\u73b0\u5176\u4e0e\u805a\u5408\u7269\u7ed3\u90e8\u5206\u7684\u7a7a\u95f4\u9650\u5236\u6709\u5173\uff0c\u6bd4\u5982\u805a\u5408\u7269\u672c\u8eab\u7684\u67d4\u987a\u6027\u5c31\u4f1a\u5f71\u54cd\u6210\u7ed3\u7684\u6982\u7387\u4ee5\u53ca\u5176\u5728\u805a\u5408\u7269\u957f\u94fe\u4e0a\u7684\u4f4d\u7f6e\u548c\u5c3a\u5bf8\u5927\u5c0f\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u610f\u5927\u5229\u5e15\u591a\u74e6\u5927\u5b66\u7684Enzo Orlandini\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5bf9\u4e00\u79cd\u542b\u4e09\u53f6\u8349\u5f62\u805a\u5408\u7269\u7ed3\u7684\u4e8c\u5d4c\u6bb5\u67d4\u987a-\u521a\u6027\u805a\u5408\u7269\u73af\u6a21\u578b\u8fdb\u884c\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u3002\u5728\u7814\u7a76\u4e2d\u4ed6\u4eec\u53d1\u73b0\u5982\u679c\u4e24\u79cd\u5d4c\u6bb5\u8db3\u591f\u957f\uff0c\u8db3\u4ee5\u5bb9\u7eb3\u805a\u5408\u7269\u7ed3\u7684\u5b58\u5728\uff0c\u90a3\u4e48\u63d0\u9ad8\u6e29\u5ea6\u5c31\u53ef\u4ee5\u5c06\u7ed3\u7684\u4f4d\u7f6e\u4ece\u67d4\u987a\u6027\u90e8\u5206\u79fb\u52a8\u5230\u521a\u6027\u90e8\u5206\u3002\u751a\u81f3\u5728\u4f4e\u6e29\u73af\u5883\u4e0b\uff0c\u5373\u4f7f\u975e\u5e38\u77ed\u7684\u4e00\u6bb5\u67d4\u987a\u6027\u94fe\uff0c\u6210\u7ed3\u7684\u6982\u7387\u4e5f\u5f88\u9ad8\u3002\u6b64\u5916\uff0c\u7814\u7a76\u4eba\u5458\u8fd8\u6ce8\u610f\u5230\u805a\u5408\u7269\u7ed3\u7684\u672b\u7aef\u90fd\u6709\u4e00\u79cd\u5b9a\u4f4d\u5728\u5728\u4e24\u79cd\u5d4c\u6bb5\u7ed3\u5408\u5904\u7684\u503e\u5411\u3002\u6210\u7ed3\u4f4d\u7f6e\u4e0e\u4e0d\u5747\u4e00\u7684\u5f2f\u66f2\u7a0b\u5ea6\u4e4b\u95f4\u62e5\u6709\u76f8\u5173\u6027\uff0c\u4f7f\u5f97\u4eba\u4eec\u8ba4\u4e3a\u5c06\u9176\u7f6e\u4e8eDNA\u5355\u94fe\u7684\u7f3a\u53e3\u6216\u8005\u65ad\u53e3\u5904\u4f1a\u66f4\u597d\u5730\u6765\u6539\u53d8\u5176\u94fe\u7684\u5168\u5c40\u62d3\u6251\u7ed3\u6784\u3002\u4f46\u7814\u7a76\u4eba\u5458\u4e5f\u53d1\u73b0\uff0c\u6700\u521d\u6324\u5728\u67d4\u987a\u6027\u90e8\u5206\u7684\u805a\u5408\u7269\u7ed3\u5c3a\u5bf8\u8981\u6bd4\u6b63\u5e38\u7684\u7ed3\u6765\u7684\u5c0f\uff0c\u5e76\u4e14\u4f1a\u957f\u671f\u5904\u4e8e\u4e9a\u7a33\u5b9a\u72b6\u6001\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>How Local Flexibility Affects Knot Positioning in Ring Polymers<\/a> (Macromolecules, 2016, DOI: 10.1021\/acs.macromol.6b00712)<\/p>\n

7\u3001Macromolecules\uff1a\u73bb\u7483\u66ff\u4ee3\u54c1\u7684\u65b0\u8fdb\u5c55\u2014\u2014\u5408\u6210\u6c34\u51dd\u80f6\u6750\u6599\u7684\u5408\u5e76\u5e26\u7535\u4e0e\u7ea4\u7ef4\u7ed3\u6784<\/strong><\/p>\n

\"7\"<\/p>\n

\u56fe7 \u4ea4\u8054\u7684\u80f6\u51dd\u7cd6\u805a\u5408\u7269\u51dd\u80f6\u793a\u610f\u56fe\u3002\u805a\u5408\u7269\u57fa\u5e95\uff08\u84dd\u8272\uff09\u4e0e\u80f6\u51dd\u7cd6\u7f51\u67b6\u4ea4\u8054\u5728\u4e00\u8d77\uff08\u9ed1\u8272\uff09\u3002\u80f6\u51dd\u7cd6\u7f51\u67b6\u5728\u4e8c\u4ef7\u79bb\u5b50\u7684\u4f5c\u7528\u4e0b\u53d1\u751f\u4e86\u87ba\u65cb\u7f20\u7ed5\u8f6c\u53d8\u3002<\/strong><\/p>\n

\u73bb\u7483\u4f53\u662f\u4e00\u79cd\u51dd\u80f6\u72b6\u7269\u8d28\uff0c\u5b83\u5145\u586b\u5728\u773c\u775b\u5185\u90e8\u7684\u7a7a\u8154\u5904\uff0c\u7ef4\u6301\u7740\u773c\u775b\u7684\u5f62\u72b6\uff0c\u5438\u6536\u9707\u52a8\u5e76\u4f20\u9012\u5149\u548c\u79bb\u5b50\u3002\u5b83\u7684\u6210\u5206\u770b\u4f3c\u590d\u6742\uff0c\u5b9e\u9645\u4e0a\u6c34\u51dd\u80f6\u5c31\u662f\u7531\u4e24\u79cd\u4e92\u76f8\u7a7f\u63d2\u7684\u7f51\u72b6\u7ed3\u6784\u7ec4\u6210\u3002\u7c98\u591a\u7cd6\u548c\u900f\u660e\u8d28\u9178\u5f62\u6210\u4e86\u9ad8\u5ea6\u7f20\u7ed5\u7684\u7f51\u67b6\u7ed3\u6784\uff0c\u81a8\u80c0\u540e\u4f7f\u80f6\u539f\u7ea4\u7ef4\u7f51\u7edc\u60ac\u6d6e\u8d77\u6765\u3002\u73bb\u7483\u4f53\u529f\u80fd\u7f3a\u5931\u4f1a\u5bfc\u81f4\u591a\u79cd\u773c\u75be\uff0c\u5982\u89c6\u7f51\u819c\u8131\u843d\u7b49\u3002\u5229\u7528\u6c14\u4f53\u6216\u5176\u4ed6\u5408\u6210\u6750\u6599\u4ee3\u66ff\u73bb\u7483\u4f53\u6548\u679c\u5e76\u4e0d\u7406\u60f3\uff0c\u800c\u4e14\u4e0d\u80fd\u957f\u671f\u4f7f\u7528\u3002\u7406\u60f3\u7684\u66ff\u4ee3\u6750\u6599\u5e94\u8be5\u4e0e\u539f\u59cb\u7ec4\u7ec7\u7684\u4f20\u8f93\u548c\u52a8\u6001\u7279\u6027\u975e\u5e38\u63a5\u8fd1\uff0c\u5e76\u4e14\u4e0d\u4f1a\u7834\u574f\u5468\u56f4\u7684\u7ec4\u7ec7\u7ec6\u80de\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u7f8e\u56fd\u9a6c\u8428\u8bf8\u585e\u5927\u5b66\u5b89\u59c6\u65af\u7279\u5206\u6821\u7684Murugappan Muthukumar\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u7814\u7a76\u4eba\u5458\u5728\u4f53\u5916\u5408\u6210\u4e86\u7531\u7532\u57fa\u4e19\u70ef\u9178(MAA)\u3001\u7532\u57fa\u4e19\u70ef\u9170\u80fa(MAm)\u548c\u53cc\u5f02\u4e01\u70ef\u9170\u80f1\u80fa(BMAC)\u4e0e\u80f6\u51dd\u7cd6\u4ea4\u8054\u7684\u805a\u5408\u7269\u3002\u8fd9\u4e00\u65b0\u914d\u65b9\u5305\u542b\u5e26\u7535\u7684\u5355\u4f53\u548c\u7ea4\u7ef4\u5316\u7684\u7ed3\u6784\uff0c\u80fd\u4e0e\u4eba\u4f53\u7ec4\u7ec7\u66f4\u597d\u7684\u878d\u5408\u3002\u8fd9\u79cd\u51dd\u80f6\u7531\u4e8e\u7535\u8377\u5bc6\u5ea6\u7684\u589e\u52a0\u5728\u80fd\u591f\u5f88\u597d\u5730\u81a8\u80c0\u7684\u540c\u65f6\u4e5f\u63d0\u9ad8\u4e86\u542b\u6c34\u91cf\uff0c\u51dd\u80f6\u7cd6\u7684\u52a0\u5165\u4f7f\u5f97\u5176\u5f3a\u5ea6\u5f97\u4ee5\u63d0\u5347\u3002\u5e76\u4e14\u5b83\u80fd\u7ef4\u6301\u826f\u597d\u7684\u5149\u5b66\u6e05\u6670\u5ea6\uff0c\u8fd0\u8f93\u7279\u6027\u4e0e\u5929\u7136\u73bb\u7483\u4f53\u4e5f\u5341\u5206\u76f8\u4f3c\u3002\u53e6\u5916\uff0c\u8fd9\u79cd\u53ef\u63a7\u5408\u6210\u7684\u805a\u5408\u7269\u80fd\u957f\u671f\u4fdd\u6301\u7a33\u5b9a\uff0c\u4e0d\u4f1a\u635f\u5bb3\u4eba\u4f53\u7ec4\u7ec7\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Development of a Vitreous Substitute: Incorporating Charges and Fibrous Structures in Synthetic Hydrogel Materials<\/a> (Macromolecules, 2016, DOI: 10.1021\/acs.macromol.6b00885)<\/p>\n

8\u3001Macromolecules\uff1a\u5229\u7528\u6c1f\u5316\u786b(VI)\u4ea4\u6362(SuFEx)\u548c\u94dc\u50ac\u5316\u53e0\u6c2e-\u7094\u70c3\u73af\u52a0\u6210(CuAAC)\u53cd\u5e94\u8fdb\u884c\u9009\u62e9\u6027\u6b63\u4ea4\u540e\u805a\u5408\u6539\u6027<\/strong><\/p>\n

\"8\"<\/p>\n

\u56fe8 \u5229\u7528SuFEx\u5bf9\u805aN-\u5f02\u4e19\u57fa\u4e19\u70ef\u9170\u80fa\u8fdb\u884c\u884d\u751f\u5316\u7684\u51dd\u80f6\u6e17\u900f\u8272\u8c31\u7d2b\u5916-\u53ef\u89c1\u5149\u68c0\u6d4b\u4eea\u56fe\u8c31\u3002\u5e73\u9762\u5750\u6807\u4ee3\u8868\u6ce2\u957f\u548c\u6d17\u8131\u65f6\u95f4\uff0cz\u8f74\u4ee3\u8868\u5438\u6536\u5f3a\u5ea6\u3002<\/strong><\/p>\n

\u5bf9\u5927\u5206\u5b50\u8fdb\u884c\u9009\u62e9\u6027\u540e\u5408\u6210\u5316\u5b66\u6539\u6027\u53ef\u4ee5\u7528\u6765\u6539\u53d8\u6216\u589e\u5f3a\u6240\u9700\u7684\u6027\u80fd\u548c\u529f\u80fd,\u5236\u5907\u51fa\u7684\u72ec\u7279\u6750\u6599\u53ef\u7528\u4e8e\u9ad8\u5206\u5b50\u79d1\u5b66\u3001\u533b\u5b66\u548c\u6750\u6599\u7814\u7a76\u3002\u7ecf\u5178\u7684\u5316\u5b66\u53cd\u5e94\u5982\u5f00\u73af\u53cd\u5e94\u3001Diels-Alder\u52a0\u6210\u53cd\u5e94\u3001\u6d3b\u6027\u916f\u5076\u8054\u53cd\u5e94\u7b49\u5728\u8fc7\u53bb\u51e0\u5341\u5e74\u4e2d\u8fc5\u901f\u7684\u53d1\u5c55\u3002\u4e3a\u4e86\u540c\u65f6\u80fd\u5728\u5b9e\u9a8c\u5ba4\u548c\u5de5\u4e1a\u751f\u4ea7\u4e2d\u5e94\u7528\uff0c\u9700\u8981\u7ee7\u7eed\u884d\u751f\u5316\u7684\u5b98\u80fd\u56e2\u5355\u4f53\u5206\u5b50\u5fc5\u987b\u7b26\u5408\u805a\u5408\u53cd\u5e94\u7684\u6761\u4ef6\uff0c\u529f\u80fd\u5316\u5904\u7406\u5e94\u8be5\u5728\u5316\u5b66\u4e0a\u4e92\u76f8\u6b63\u4ea4\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u7f8e\u56fd\u5357\u52a0\u5dde\u5927\u5b66\u7684Valery V. Fokin\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u4f7f\u7528\u529f\u80fd\u6027\u805a\u82ef\u4e59\u70ef\u548c\u805a\u4e19\u70ef\u9170\u80fa\u4f5c\u4e3a\u652f\u67b6\u6765\u9a8c\u8bc1\u6c1f\u5316\u786b(VI)\u4ea4\u6362(SuFEx)\u548cCuAAC\u53cd\u5e94\u7684\u540e\u805a\u5408\u6539\u6027\u80fd\u529b \u3002\u4e0a\u8ff0\u4e24\u79cd\u805a\u5408\u7269\u5305\u542b\u6709\u6c1f\u4ee3\u786b\u9178\u76d0\u548c\u82b3\u9999\u7532\u7845\u70f7\u57fa\u919a\u7684\u7ec4\u5408\u4ee5\u53ca\u53e0\u6c2e\u5316\u4fa7\u94fe\u3002\u9644\u7740\u5728\u5408\u9002\u7684\u5b98\u80fd\u56e2\u4e0a\u7684\u8367\u5149\u67d3\u6599\u53ef\u4ee5\u6301\u7eed\u8054\u7cfb\u89c2\u5bdf\u5230\u5171\u805a\u7269\u7684\u652f\u6491\u7ed3\u6784\uff0c\u5e76\u4e14\u6709\u9009\u62e9\u6027\u7684\u3001\u5b9a\u91cf\u7684\u6765\u89c2\u5bdf\u4e0e\u4e4b\u53cd\u5e94\u7684\u53e6\u4e00\u79cd\u7269\u8d28\u3002\u5b9e\u9a8c\u7ed3\u679c\u8bc1\u5b9e\uff0c\u5c06SuFEx\u4e0eCuAAC\u4e24\u79cd\u5de5\u827a\u7ec4\u5408\u5728\u4e00\u8d77\u662f\u975e\u5e38\u6709\u6548\u5e76\u4e14\u901a\u7528\u7684\uff0c\u5b83\u53ef\u4ee5\u5728\u6ca1\u6709\u4fdd\u62a4\u57fa\u56e2\u7684\u57fa\u672c\u5b9e\u9a8c\u6761\u4ef6\u4e0b\u7684\u5bf9\u4e00\u79cd\u5171\u805a\u7269\u8fdb\u884c\u4e09\u6b63\u4ea4\u529f\u80fd\u5316\uff0c\u8fd9\u4e00\u70b9\u975e\u5e38\u96be\u80fd\u53ef\u8d35\u7684\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Selective and Orthogonal Post-Polymerization Modification using Sulfur(VI) Fluoride Exchange (SuFEx) and Copper-Catalyzed Azide-Alkyne Cycloaddition (CuAAC) Reactions<\/a> (Macromolecules, 2016, DOI: 10.1021\/acs.macromol.6b00101)<\/p>\n

\u672c\u671f\u6587\u732e\u6c47\u603b\u7531\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u6750\u6599\u5b66\u4e60\u5c0f\u7ec4\u6210\u5458Sea\u548c\u5b54\u5cfb\u6db5\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

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