{"id":230444,"date":"2021-12-09T06:30:01","date_gmt":"2021-12-08T22:30:01","guid":{"rendered":"\/\/m.iemloyee.com\/?p=230444"},"modified":"2021-12-08T17:42:16","modified_gmt":"2021-12-08T09:42:16","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e5%85%b0%e5%b7%9e%e5%8c%96%e7%89%a9%e6%89%80%e6%af%95%e8%bf%8e%e6%99%ae%e7%a0%94%e7%a9%b6%e5%9b%a2%e9%98%9fnat-commun-%ef%bc%9a%e6%8e%ba%e6%b0%ae%e6%bf%80%e6%b4%bbnifeox","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=230444","title":{"rendered":"\u4e2d\u79d1\u9662\u5170\u5dde\u5316\u7269\u6240\u6bd5\u8fce\u666e\u7814\u7a76\u56e2\u961fNat. Commun.\uff1a\u63ba\u6c2e\u6fc0\u6d3bNiFeOx\u50ac\u5316\u5242\uff0c\u6709\u6548\u63d0\u9ad8BiVO4\u5149\u9633\u6781\u7684\u6790\u6c27\u6d3b\u6027\u548c\u7a33\u5b9a\u6027"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u5229\u7528\u592a\u9633\u80fd\u5b9e\u73b0\u9ad8\u6548\u5149\u7535\u50ac\u5316\u5206\u89e3\u6c34\u5236\u6c22\uff0c\u5df2\u7ecf\u6210\u4e3a\u89e3\u51b3\u5f53\u4eca\u6240\u9762\u4e34\u7684\u80fd\u6e90\u548c\u73af\u5883\u95ee\u9898\u6700\u7406\u60f3\u7684\u6280\u672f\u9014\u5f84\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u5728\u592a\u9633\u80fd\u5149\u7535\u50ac\u5316\uff08PEC\uff09\u5206\u89e3\u6c34\u4f53\u7cfb\u4e2d\uff0c\u5149\u9633\u6781\u8868\u9762\u7531\u4e8e\u6d89\u53ca\u590d\u6742\u7684\u56db\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u5bfc\u81f4\u5176\u6c34\u6c27\u5316\u52a8\u529b\u5b66\u6781\u4e3a\u7f13\u6162\uff0c\u4e25\u91cd\u5236\u7ea6\u4e86\u592a\u9633\u80fd-\u6c22\u80fd\u7684\u6574\u4f53\u8f6c\u6362\u6548\u7387\u3002\u8fd1\u5e74\u6765\uff0c\u5728\u5149\u9633\u6781\u8868\u9762\u6784\u7b51\u53cc\u91d1\u5c5e\u6790\u6c27\uff08OER\uff09\u50ac\u5316\u5242\u5df2\u7ecf\u88ab\u8bc1\u660e\u53ef\u4ee5\u6709\u6548\u5730\u4fc3\u8fdb\u5149\u9633\u6781\/\u7535\u89e3\u6db2\u754c\u9762\u95f4\u7535\u8377\u5206\u79bb\uff0c\u964d\u4f4e\u53cd\u5e94\u8fc7\u7535\u4f4d\u4ece\u800c\u52a0\u5feb\u8868\u9762\u6c34\u6c27\u5316\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u5c3d\u7ba1OER\u50ac\u5316\u5242\u5728\u63d0\u9ad8BiVO4<\/sub>\u00a0\u7684PEC\u6d3b\u6027\u65b9\u9762\u53d1\u6325\u4e86\u91cd\u8981\u4f5c\u7528\uff0c\u4f46\u662f\u76ee\u524d\u5f97\u5230\u7684\u5149\u7535\u6d41\u5bc6\u5ea6\u4ecd\u8fdc\u4f4e\u4e8e\u5176\u7406\u8bba\u503c\uff087.5 mA cm-2<\/sup>\uff09\u3002\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5170\u5dde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u6bd5\u8fce\u666e\u7814\u7a76\u5458\u8bfe\u9898\u7ec4\u901a\u8fc7\u5f15\u5165\u6c2e\u539f\u5b50\u8fdb\u4e00\u6b65\u4f18\u5316\u53cc\u91d1\u5c5eOER\u50ac\u5316\u5242\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u5b9e\u73b0\u4e86BiVO4<\/sub>\u00a0\u5149\u9633\u6781PEC\u6d3b\u6027\u7684\u663e\u8457\u63d0\u5347\uff0c\u5e76\u9610\u8ff0\u4e86\u5176\u5728PEC\u6790\u6c27\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684\u4f5c\u7528\u673a\u5236\uff0c\u4e3a\u6784\u5efa\u9ad8\u6548\u3001\u7a33\u5b9a\u7684\u5149\u7535\u50ac\u5316\u4f53\u7cfb\u63d0\u4f9b\u4e86\u65b0\u7684\u5b9e\u9a8c\u548c\u7406\u8bba\u652f\u6301\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u4e2d\u56fd\u79d1\u5b66\u9662\u5170\u5dde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u6bd5\u8fce\u666e\u7814\u7a76\u5458\u8bfe\u9898\u7ec4\u901a\u8fc7\u4e00\u79cd\u6e29\u548c\u7684\u7b49\u79bb\u5b50\u4f53\u5904\u7406\u7684\u65b9\u6cd5\u5728NiFeOx<\/sub>\u50ac\u5316\u5242\u4e2d\u5f15\u5165\u4f4e\u7535\u8d1f\u6027\u7684N\u539f\u5b50\uff0c\u5b9e\u73b0\u4e86\u5bf9\u5176\u7535\u5b50\u7ed3\u6784\u7684\u5408\u7406\u8c03\u63a7\uff0c\u63d0\u5347\u4e86BiVO4<\/sub>\u5149\u9633\u6781\u7684PEC\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002\u57281.23 VRHE<\/sub>\uff08AM 1.5G\uff0c100 mW cm-2<\/sup>\uff09\u4e0b\uff0c\u6240\u5236\u5907\u7684BiVO4<\/sub>\/N:NiFeOx<\/sub>\u5149\u9633\u6781\u7684\u5149\u7535\u6d41\u5bc6\u5ea6\u53ef\u8fbe6.4 mA cm-2<\/sup>\uff0c\u5e76\u5177\u6709\u8f83\u597d\u7684PEC\u6c34\u6c27\u5316\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u4e00\u7cfb\u5217\u5b9e\u9a8c\u548c\u7406\u8bba\u8ba1\u7b97\u5206\u6790\u7ed3\u679c\u8bc1\u5b9e\uff1a\u7531\u4e8eN\u539f\u5b50\u76f8\u5bf9\u4e8eO\u539f\u5b50\u5177\u6709\u8f83\u5f31\u7684\u5438\u7535\u5b50\u80fd\u529b\uff0c\u56e0\u6b64\u901a\u8fc7N\u539f\u5b50\u53d6\u4ee3O\u539f\u5b50\u53ef\u4ee5\u4f7f\u5f97\u5230NiFeOx<\/sub>\u50ac\u5316\u5242\u4e2dFe\u548cNi\u4f4d\u70b9\u5904\u4e8e\u7535\u5b50\u5bcc\u96c6\u7684\u72b6\u6001\u3002\u5e76\u4e14\uff0c\u5728\u8be5\u4f53\u7cfb\u4e2d\uff0cNi\u4f4d\u70b9\u53ef\u4ee5\u8fdb\u4e00\u6b65\u901a\u8fc7\u5411BiVO4<\/sub>\u8868\u9762\u7684V\u4f4d\u70b9\u63d0\u4f9b\u7535\u5b50\uff0c\u4ece\u800c\u80fd\u591f\u6709\u6548\u5730\u6291\u5236V5+<\/sup>\u7684\u6eb6\u89e3\uff0c\u63d0\u9ad8\u4e86PEC\u6c34\u6c27\u5316\u7684\u7a33\u5b9a\u6027\u3002\u540c\u65f6\uff0cFe\u4f4d\u70b9\u589e\u5f3a\u4e86\u5bf9\u5149\u751f\u7a7a\u7a74\u7684\u6ce8\u5165\u80fd\u529b\uff0c\u52a0\u5feb\u4e86\u8868\u9762OER\u53cd\u5e94\u7684\u8fdb\u884c\uff0c\u6700\u7ec8\u5b9e\u73b0\u4e86BiVO4<\/sub>\u9ad8\u6548\u7684PEC\u5206\u89e3\u6c34\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002\u8be5\u5de5\u4f5c\u901a\u8fc7\u5728\u5149\u9633\u6781\u8868\u9762\u6784\u5efa\u9ad8\u6548\u3001\u7a33\u5b9a\u7684OER\u50ac\u5316\u5242\uff0c\u5b9e\u73b0\u4e86PEC\u6d3b\u6027\u7684\u663e\u8457\u63d0\u5347\uff0c\u5e76\u4e14\u9610\u8ff0\u4e86\u5176\u5728PEC\u6790\u6c27\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684\u4f5c\u7528\u673a\u5236\uff0c\u4e3a\u5149\u7535\u6781\u7684\u8fdb\u4e00\u6b65\u5f00\u53d1\u548c\u5e94\u7528\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u548c\u7b56\u7565\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201cNitrogen-incorporation activates NiFeOx<\/sub>\u00a0catalysts for efficiently boosting oxygen evolution activity and stability of BiVO4<\/sub>\u00a0photoanodes\u201d\u53d1\u8868\u5728\u4e86Nat. Commun<\/em><\/strong>.\u4e0a\u3002\"\"<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n

\u56fe1. <\/b><\/strong>\u5149\u7535\u6781<\/b><\/strong>\u7684\u5f62\u8c8c\u548c\u7ed3\u6784\u8868\u5f81\uff1a<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff09BiVO4<\/sub>\u548c\uff08b\uff09BiVO4<\/sub>\/N:NiFeOx\u5149\u9633\u6781\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff09BiVO4<\/sub>\/N:NiFeOx\u5149\u9633\u6781\u7684HR-TEM\u56fe\u50cf\u548c\uff08d\uff09TEM-EDS\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n

\u56fe2. \u5149\u7535\u5316\u5b66<\/b><\/strong>\u5206\u89e3\u6c34<\/b><\/strong>\u6d4b\u8bd5<\/b><\/strong>\"\"<\/p>\n

BiVO4<\/sub>\/N:NiFeOx<\/sub>\u5149\u9633\u6781\u57280.5 M K3<\/sub>BO3<\/sub>\u00a0\uff08pH=9.5\uff09\u7535\u89e3\u6db2\u4e2d\u5c55\u793a\u51fa\u4f18\u5f02\u7684PEC\u5206\u89e3\u6c34\u6d3b\u6027\u3002\u57281.23 VRHE<\/sub>\u4e0b\uff0c\u83b7\u5f97\u4e866.4 mA cm\u2212<\/sup>2<\/sup>\u7684\u5149\u7535\u6d41\u5bc6\u5ea6\uff0c\u5e76\u4e14\u5728\u6574\u4e2a\u6d4b\u8bd5\u8fc7\u7a0b\u4e2d\u5177\u6709\u826f\u597d\u7684\u5149\u7535\u6d41\u7a33\u5b9a\u6027\uff0c\u540c\u65f6OER\u8d77\u59cb\u7535\u4f4d\u4e5f\u660e\u663e\u964d\u4f4e\uff0c\u5176\u504f\u538b\u8f85\u52a9\u5149\u7535\u8f6c\u5316\u6548\u7387\uff08ABPE\uff09\u57280.73 VRHE<\/sub>\u65f6\u53ef\u8fbe1.9%\uff0c\u4ee5\u53ca\u5165\u5c04\u5149\u5b50-\u7535\u5b50\u8f6c\u6362\u6548\u7387\uff08IPCE\uff09\u5728360\u00a0nm\u53ef\u8fbe\u523093%\uff0c\u540c\u65f6\u5177\u6709\u9ad8\u6548\u7684\u754c\u9762\u7535\u8377\u8f6c\u79fb\u548c\u5206\u89e3\u6c34\u4ea7\u6c22\u4ea7\u6c27\u80fd\u529b\u3002<\/p>\n

\u56fe3. \u5149\u8c31\u548c\u7535\u5316\u5b66<\/b><\/strong>\u6027\u8d28<\/b><\/strong>\"\"<\/p>\n

N:NiFeOx<\/sub>\u50ac\u5316\u5242\u5728\u4fc3\u8fdbBiVO4<\/sub>\u7535\u8377\u5206\u79bb\u548c\u5ef6\u957f\u8f7d\u6d41\u5b50\u5bff\u547d\u65b9\u9762\u5177\u6709\u8f83\u597d\u7684\u80fd\u529b\uff0c\u5e76\u4e14\u5177\u6709\u8f83\u4f4e\u7684\u8fc7\u7535\u4f4d\u548c\u8f83\u9ad8\u7684\u6c34\u6c27\u5316\u7535\u6d41\u3002<\/p>\n

\u56fe4. \u8868\u9762\u5316\u5b66\u6001\u548c\u7535\u5b50\u7ed3\u6784\u5206\u6790<\/b><\/strong>\"\"<\/p>\n

XPS\u548cDFT\u5206\u6790\u7ed3\u679c\u8bc1\u5b9eN\u539f\u5b50\u7684\u5f15\u5165\u80fd\u591f\u6709\u6548\u5730\u8c03\u8282NiFeOx<\/sub>\u50ac\u5316\u5242\u7684\u7535\u5b50\u7ed3\u6784<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u8be5\u7814\u7a76\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u7b80\u5355\u7684\u6c2e\u539f\u5b50\u5f15\u5165\u65b9\u6cd5\u8c03\u63a7NiFeOx<\/sub>\u50ac\u5316\u5242\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u5b9e\u73b0BiVO4<\/sub>\u5149\u9633\u6781\u57281.23 V vs. RHE\uff08AM 1.5 G\uff0c100 mW cm-2<\/sup>\uff09\u4e0b6.4 mA cm-2<\/sup>\u5149\u7535\u6d41\u5bc6\u5ea6\uff0c\u5e76\u4e14\u5177\u6709\u4f18\u5f02\u7684PEC\u7a33\u5b9a\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u6784\u5efa\u9ad8\u6548\u548c\u7a33\u5b9a\u7684OER\u50ac\u5316\u5242\uff0c\u5236\u5907\u9ad8\u6548PEC\u5668\u4ef6\u63d0\u4f9b\u4e86\u65b0\u7684\u7814\u7a76\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/b><\/strong>\uff1aNitrogen-incorporation activates NiFeO<\/u>x<\/sub><\/u>\u00a0catalysts for efficiently boosting oxygen evolution activity and stability of BiVO<\/u>4<\/sub><\/u>\u00a0photoanodes<\/u><\/a>\uff08Nat. Commun.\uff0c2021, 12, 6969; DOI\uff1a10.1038\/s41467-021-27299-0\uff09<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5229\u7528\u592a\u9633\u80fd\u5b9e\u73b0\u9ad8\u6548\u5149\u7535\u50ac\u5316\u5206\u89e3\u6c34\u5236\u6c22\uff0c\u5df2\u7ecf\u6210\u4e3a\u89e3\u51b3\u5f53\u4eca\u6240\u9762\u4e34\u7684\u80fd\u6e90\u548c\u73af\u5883\u95ee\u9898\u6700\u7406\u60f3\u7684\u6280\u672f\u9014\u5f84\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u5728\u592a\u9633\u80fd\u5149\u7535\u50ac\u5316\uff08PEC\uff09\u5206\u89e3\u6c34\u4f53\u7cfb\u4e2d\uff0c\u5149\u9633\u6781…<\/p>\n","protected":false},"author":2109,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[116,2671,3503,4759],"class_list":["post-230444","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-catalyst","tag-2671","tag-3503","tag-4759"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/230444"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2109"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=230444"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/230444\/revisions"}],"predecessor-version":[{"id":230450,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/230444\/revisions\/230450"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=230444"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=230444"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=230444"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}