{"id":229894,"date":"2021-11-19T12:20:33","date_gmt":"2021-11-19T04:20:33","guid":{"rendered":"\/\/m.iemloyee.com\/?p=229894"},"modified":"2021-11-19T11:20:49","modified_gmt":"2021-11-19T03:20:49","slug":"%e5%8d%97%e6%b4%8b%e7%90%86%e5%b7%a5%e6%a5%bc%e9%9b%84%e6%96%87sci-adv-%ef%bc%9a%e5%8e%9f%e4%bd%8d%e6%b4%bb%e5%8c%96br%e9%99%90%e5%9f%9fni%e5%9f%ba%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e9%aa%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=229894","title":{"rendered":"\u5357\u6d0b\u7406\u5de5\u697c\u96c4\u6587Sci. Adv.\uff1a\u539f\u4f4d\u6d3b\u5316Br\u9650\u57dfNi\u57fa\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u7a7a\u5fc3\u68f1\u67f1\u5b9e\u73b0\u9ad8\u6548\u7684\u7535\u5316\u5b66\u6790\u6c27"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u968f\u7740\u5168\u7403\u80fd\u6e90\u9700\u6c42\u7684\u65e5\u76ca\u589e\u957f\u548c\u73af\u5883\u7684\u9010\u6b65\u6076\u5316\uff0c\u8feb\u5207\u9700\u8981\u5f00\u53d1\u9ad8\u6548\u7684\u3001\u53ef\u6301\u7eed\u7684\u548c\u78b3\u4e2d\u548c\u7684\u80fd\u6e90\u8f6c\u6362\u548c\u5b58\u50a8\u6280\u672f\u3002\u867d\u7136\u7535\u89e3\u6c34\u53ef\u4ee5\u8f7b\u677e\u83b7\u5f97\u7eff\u8272\u7684\u6c22\u80fd\uff0c\u4f46\u662f\u5b9e\u73b0\u7535\u89e3\u69fd\u7684\u5de5\u4e1a\u89c4\u6a21\u5316\u5e94\u7528\uff0c\u8feb\u5207\u9700\u8981\u80fd\u591f\u514b\u670d\u7f13\u6162\u7684\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u52a8\u529b\u5b66\u7684\u6c27\u7535\u50ac\u5316\u5242\u3002\u4f46\u662f\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u50ac\u5316\u5242\u8868\u9762\u7ed3\u6784\u7684\u53d8\u5316\u975e\u5e38\u590d\u6742\uff0c\u5bfc\u81f4\u539f\u4f4d\u8868\u5f81\u6280\u672f\u8868\u5f81\u50ac\u5316\u8fc7\u7a0b\u4e2d\u50ac\u5316\u5242\u7684\u7ed3\u6784\u548c\u7535\u5b50\u7ed3\u6784\u6f14\u53d8\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u4e3a\u4e86\u5b9e\u65f6\u8ddf\u8e2a\u50ac\u5316\u5242\u7684\u7ed3\u6784\u6f14\u53d8\uff0c\u9700\u8981\u5bfb\u627e\u4e00\u79cd\u5177\u6709\u4e30\u5bcc\u3001\u5206\u5e03\u826f\u597d\u4e14\u7ed3\u6784\u5747\u5300\u7684\u6d3b\u6027\u4f4d\u70b9\u7684\u9ad8\u6548\u50ac\u5316\u6750\u6599\u3002\u5728\u9178\u6027\/\u78b1\u6027\u6761\u4ef6\u4e0b\uff0c\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\/\u884d\u751f\u7684\u7535\u50ac\u5316\u5242\u7684\u53d1\u5c55\uff0c\u5f15\u8d77\u4e86\u79d1\u7814\u5de5\u4f5c\u8005\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u5c24\u5176\u662f\u65b0\u5174\u7684\u5bfc\u7535MOF\u80fd\u591f\u63d0\u4f9b\u4e30\u5bcc\u4e14\u5747\u4e00\u7684\u6d3b\u6027\u4f4d\u70b9\u3001\u9ad8\u5bfc\u7535\u6027\u3001\u5927\u8868\u9762\u79ef\u4ee5\u53ca\u4e30\u5bcc\u7684\u5b54\u9699\u7387\uff0c\u53ef\u4ee5\u7528\u4e8e\u50ac\u5316\u673a\u5236\u7684\u7814\u7a76\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u63d0\u9ad8\u5bfc\u7535MOF\u7684\u6d3b\u6027\uff0c\u79bb\u5b50\u9650\u5236\u7b56\u7565\u548c\u7ed3\u6784\u8bbe\u8ba1\u80fd\u591f\u589e\u52a0\u50ac\u5316\u53cd\u5e94\u7684\u6709\u6548\u6d3b\u6027\u4f4d\u70b9\uff0c\u52a0\u5f3a\u4e86\u50ac\u5316\u8fc7\u7a0b\u4e2d\u53ef\u68c0\u6d4b\u7684\u539f\u4f4d\/\u64cd\u4f5c\u5149\u8c31\u4fe1\u53f7\u3002\u7136\u800c\uff0c\u7531\u4e8e\u91d1\u5c5e\u79bb\u5b50\u548c\u82b3\u9999\u57fa\u6709\u673a\u914d\u4f53\u7684\u5f3a\u87af\u5408\u548c\u5feb\u901f\u6210\u6838\uff0c\u7cbe\u786e\u63a7\u5236\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u7684\u5bfc\u7535MOF\u7684\u5408\u6210\u4ecd\u7136\u975e\u5e38\u5177\u6709\u6311\u6218\u6027\uff0c\u79bb\u5b50\u9650\u5236\u5bfc\u7535\u4e2d\u7a7aMOF\u57fa\u7eb3\u7c73\u7ed3\u6784\u7684\u53d1\u5c55\u4f5c\u4e3a\u4e00\u79cd\u6709\u524d\u9014\u7684\u6c27\u7535\u50ac\u5316\u5242\u4ecd\u5f88\u5c11\u88ab\u63a2\u7d22\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66<\/strong>\u7684\u697c\u96c4\u6587\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u91c7\u7528X\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u5149\u8c31\uff0c\u63a2\u6d4b\u4e86OER\u8fc7\u7a0b\u4e2d\uff0cBr\u9650\u57df\u7684\u5bfc\u7535Ni\u57fa\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08Br-Ni-MOF\uff09\u4e2d\u7a7a\u68f1\u67f1\u7684\u539f\u4f4d\u6d3b\u5316\u53cd\u5e94\u8fc7\u7a0b\u3002\u89c2\u5bdf\u5230Br-Ni-MOF\u5230\u03b2-Ni(OH)2<\/sub>\u7c7b\u4f3c\u7269\u7684\u8fde\u7eed\u7ed3\u6784\u8f6c\u53d8\uff0c\u7136\u540e\u5728OER\u671f\u95f4\u968f\u540e\u8f6c\u53d8\u4e3a\u03b3-NiOOH\u76f8\u3002\u8fd9\u79cd\u540e\u5f62\u6210\u7684\u03b3-NiOOH\u7c7b\u4f3c\u7269\u8868\u73b0\u51fa\u9ad8OER\u6027\u80fd\uff0c\u572810 mA cm\u2212<\/sup>2<\/sup>\u65f6\u5177\u6709306 mV\u7684\u8fc7\u7535\u4f4d\u548c\u5728300 mV\u8fc7\u7535\u4f4d\u4e0b0.051 s\u2212<\/sup>1<\/sup>\u7684\u9ad8TOF\uff0c\u4f7fBr-Ni-MOF\u6210\u4e3a\u4e00\u79cd\u9ad8\u6548\u7684\u6c27\u7535\u50ac\u5316\u5242\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0cBr\u548cNi\u539f\u5b50\u4e4b\u95f4\u7684\u5f3a\u7535\u5b50\u8026\u5408\u52a0\u901f\u4e86\u5173\u952e*O\u4e2d\u95f4\u4f53\u7684\u751f\u6210\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u5feb\u901f\u7684OER\u52a8\u529b\u5b66\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>In situ activation of Br-confined Ni-based metal-organic framework hollow prisms toward efficient electrochemical oxygen evolution<\/strong>\u201d\u53d1\u8868\u5728Science Advance<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 Br-Ni-MOF <\/strong>\u7a7a\u5fc3\u68f1\u67f1\u7684\u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong> 2 Ni-pre@Ni-MOF<\/strong>\u548c<\/strong>Br-Ni-MOF<\/strong>\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff0cB\uff09Ni-pre@Ni-MOF\u6838\u58f3\u68f1\u67f1\u7684FESEM\u56fe\u50cf\uff1b<\/p>\n

\uff08C\uff0cD\uff09Ni-pre@Ni-MOF\u6838\u58f3\u68f1\u67f1\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08E\uff0cF\uff09Br-Ni-MOF\u7a7a\u5fc3\u68f1\u67f1\u7684FESEM\u56fe\u50cf\uff1b<\/p>\n

\uff08G\uff0cH\uff09Br-Ni-MOF\u7a7a\u5fc3\u68f1\u67f1\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08I\uff09\u5355\u4e2aBr-Ni-MOF\u7a7a\u5fc3\u68f1\u67f1\u7684HAADF-STEM\u56fe\u50cf\u548c\u76f8\u5e94\u7684\u5143\u7d20Mapping\u56fe\u3002<\/p>\n

\u56fe<\/strong> 3 Br-Ni-MOF<\/strong>\u7684<\/strong>XAFS<\/strong>\u548c<\/strong>XPS<\/strong>\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A-C\uff09NiO\u3001\u03b2-Ni(OH)2<\/sub>\u3001Ni-MOF\u548cBr-Ni-MOF\u7a7a\u5fc3\u68f1\u67f1\u7684Ni K-edge\u7684EXAFS\u5149\u8c31\uff1ak2<\/sup>\u03c7\uff08k\uff09\u632f\u8361\u66f2\u7ebf\u3001\u5085\u7acb\u53f6\u53d8\u6362\u66f2\u7ebf\u548c\u5c0f\u6ce2\u53d8\u6362\uff08WT\uff09\u7b49\u9ad8\u7ebf\u56fe\uff1b<\/p>\n

\uff08D\uff0cE\uff09Br-Ni-MOF\u7a7a\u5fc3\u68f1\u67f1\u7684Ni 2p XPS\u5149\u8c31\u548cBr 3p XPS\u5149\u8c31\u3002<\/p>\n

\u56fe<\/strong> 4 Br-Ni-MOF<\/strong>\u7684<\/strong>\u7535\u50ac\u5316\u6027\u80fd\u8bc4\u4f30<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff0cB\uff09Ni-MOF\u548cBr-Ni-MOF\u7a7a\u5fc3\u68f1\u67f1\u7684lsv\u66f2\u7ebf\u548c10 mA cm-2<\/sup>\u4e0b\u6d3b\u5316\u524d\u540e\u7684\u8fc7\u7535\u4f4d\uff1b<\/p>\n

\uff08C\uff0cD\uff09RuO2<\/sub>\u3001Ni-MOF\u548cBr-Ni-MOF\u7684\u5854\u83f2\u5c14\u659c\u7387\u548cTOF\u503c\uff1b<\/p>\n

\uff08E\uff09\u57281.05 V\u65f6\uff0cNi-MOF\u548cBr-Ni-MOF\u7684\u626b\u901f\u4e0e\u7535\u6d41\u5bc6\u5ea6\uff08\u0394J\/2<\/sub>\uff09\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n

\uff08F\uff09\u572810 mA cm-2<\/sup>\u4e0b\uff0cRuO2<\/sub>\u3001Ni-MOF\u548cBr-Ni-MOF\u7684\u5faa\u73af\u6027\u80fd\u56fe\u3002<\/p>\n

\u56fe<\/strong> 5<\/strong> OER<\/strong>\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684<\/strong>Operando XAFS<\/strong>\u6d4b\u91cf<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A-C\uff09\u4e0d\u540c\u7535\u4f4d\u4e0b\uff0cOER\u53cd\u5e94\u65f6Br-Ni-MOF\u7684Ni K-edge\u7684EXAFS\u5149\u8c31\u7684k2<\/sup>\u03c7\uff08k\uff09\u632f\u8361\u66f2\u7ebf\u3001FT\u66f2\u7ebf\u548cWT\u7b49\u9ad8\u7ebf\u56fe\uff1b<\/p>\n

\uff08D\uff0cE\uff09\u5728OER\u8fc7\u7a0b\u4e2d\uff0cBr-Ni-MOF\u7a7a\u5fc3\u68f1\u67f1\u7684Ni K-edge XANES\u5149\u8c31\u548cNi\u7269\u79cd\u7684\u6c27\u5316\u6001\u6f14\u53d8\u3002<\/p>\n

\u56fe<\/strong> 6 Br-Ni-MOF<\/strong>\u7684<\/strong>DFT<\/strong>\u6a21\u62df<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff09Br-Ni-MOF\u7684\u90e8\u5206\u6001\u5bc6\u5ea6\uff08PDOS\uff09\uff1b<\/p>\n

\uff08B\uff09Ni-MOF\u548cBr-Ni-MOF\u7684Ni 3d\u7684\u8ba1\u7b97DOS\uff1b<\/p>\n

\uff08C\uff09Ni-MOF\u548cBr-Ni-MOF\u7684OER\u81ea\u7531\u80fd\u56fe\u3002<\/p>\n

\uff08D\uff09Br-Ni-MOF\u7684OER\u50ac\u5316\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u8bbe\u8ba1\u548c\u5408\u6210\u4e86Br\u2212<\/sup>\u9650\u57dfNi-MOF\u4e2d\u7a7a\u68f1\u67f1\uff08Br-Ni-MOF\uff09\u3002\u901a\u8fc7\u539f\u4f4d\u540c\u6b65\u8f90\u5c04\u5149\u8c31\u6280\u672f\uff0c\u5728\u539f\u5b50\u6c34\u5e73\u4e0a\u89c2\u5bdf\u5230OER\u8fc7\u7a0b\u4e2dBr-Ni-MOF\u7a7a\u5fc3\u68f1\u67f1\u7684\u8fde\u7eed\u7ed3\u6784\u6f14\u53d8\u3002\u5728\u7ed3\u6784\u8f6c\u53d8\u8fc7\u7a0b\u4e2d\uff0c\u03b2-Ni(OH)2<\/sub>\u7c7b\u4f3c\u7269\u9996\u5148\u5728\u9884\u50ac\u5316\u9636\u6bb5\u5f62\u6210\uff0c\u7136\u540e\u5728\u50ac\u5316OER\u9636\u6bb5\u751f\u6210\u4e9a\u7a33\u6001\u9ad8\u6d3b\u6027\u03b3-NiOOH\u7c7b\u4f3c\u7269\u3002\u7406\u8bba\u8ba1\u7b97\u9884\u6d4b\u4e86Br\u2212<\/sup>\u79bb\u5b50\u5bf9\u6539\u5584Br-Ni-MOF\u7a7a\u5fc3\u68f1\u67f1OER\u6027\u80fd\u7684\u4f5c\u7528\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u6c27\u7535\u50ac\u5316\u5242\u539f\u4f4d\u5f62\u6210\u7684\u6d3b\u6027\u7ed3\u6784\u63d0\u4f9b\u5efa\u8bbe\u6027\u7684\u89c1\u89e3\uff0c\u5e76\u53ef\u80fd\u4e3a\u8bbe\u8ba1\u7528\u4e8e\u53ef\u6301\u7eed\u80fd\u6e90\u5b58\u50a8\u548c\u8f6c\u6362\u7684\u9ad8\u6548\u7535\u50ac\u5316\u5242\u63d0\u4f9b\u4e00\u4e9b\u65b0\u7684\u7075\u611f\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>In situ activation of Br-confined Ni-based metal-organic framework hollow prisms toward efficient electrochemical oxygen evolution<\/a>\uff08Science Advance \u00a0DOI: 10.1126\/sciadv.abk0919\uff09\u3002<\/p>\n

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