{"id":229639,"date":"2021-11-13T06:30:08","date_gmt":"2021-11-12T22:30:08","guid":{"rendered":"\/\/m.iemloyee.com\/?p=229639"},"modified":"2021-11-12T21:55:20","modified_gmt":"2021-11-12T13:55:20","slug":"%e9%a1%b6%e5%88%8a%e9%80%9f%e8%a7%88%ef%bd%9c3%e7%af%87science%e3%80%811%e7%af%87nature-mof%e5%a4%a7%e7%88%86%e5%8f%91%ef%bc%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=229639","title":{"rendered":"\u9876\u520a\u901f\u89c8\uff5c3\u7bc7Science\u30011\u7bc7Nature\u00a0MOF\u5927\u7206\u53d1\uff01"},"content":{"rendered":"<p><strong><b>Science\uff1a<\/b><\/strong><strong><b>\u5364\u5316\u94c5\u9499\u949b\u77ff\u548cMOF\u73bb\u7483\u7684\u6db2\u76f8\u70e7\u7ed3<\/b><\/strong><\/p>\n<p>\u5364\u5316\u94c5\u9499\u949b\u77ff(LHP)\u534a\u5bfc\u4f53\u5177\u6709\u4f18\u5f02\u7684\u5149\u7535\u6027\u80fd\u3002\u7136\u800c\uff0c\u5b83\u4eec\u7684\u5e94\u7528\u969c\u788d\u5728\u4e8e\u5b83\u4eec\u7684\u591a\u6001\u6027\u3001\u5bf9\u6781\u6027\u6eb6\u5242\u7684\u4e0d\u7a33\u5b9a\u6027\u3001\u76f8\u5206\u79bb\u548c\u5bf9\u94c5\u79bb\u5b50\u6d78\u51fa\u7684\u654f\u611f\u6027\u3002\u00a0\u6606\u58eb\u5170\u5927\u5b66\u7684\u738b\u8fde\u6d32\u548c\u4faf\u7ecf\u7eac\u8054\u5408\u5251\u6865\u5927\u5b66\u7684Thomas D. Bennett\u3001\u5229\u5179\u5927\u5b66\u7684Sean M. Collins\u7b49\u4eba\u62a5\u544a\u4e86\u4e00\u7cfb\u5217\u53ef\u6269\u5c55\u7684\u590d\u5408\u6750\u6599\uff0c\u901a\u8fc7\u6db2\u76f8\u70e7\u7ed3\u7684LHP\u548c\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u73bb\u7483\u3002\u73bb\u7483\u4f5c\u4e3aLHP\u7684\u57fa\u4f53\uff0c\u901a\u8fc7\u754c\u9762\u76f8\u4e92\u4f5c\u7528\u6709\u6548\u5730\u7a33\u5b9a\u975e\u5e73\u8861\u9499\u949b\u77ff\u76f8\u3002\u8fd9\u4e9b\u76f8\u4e92\u4f5c\u7528\u4e5f\u949d\u5316LHP\u8868\u9762\u7f3a\u9677\uff0c\u5e76\u8d4b\u4e88\u660e\u4eae\uff0c\u7a84\u5e26\u5149\u81f4\u53d1\u5149\u4e0e\u5bbd\u8272\u57df\uff0c\u7528\u4e8e\u5236\u9020\u767d\u5149\u53d1\u5149\u4e8c\u6781\u7ba1(LED)\u3002\u53ef\u52a0\u5de5\u7684\u590d\u5408\u6750\u6599\u663e\u793a\u51fa\u9ad8\u7a33\u5b9a\u6027\u7684\u6c34\u548c\u6709\u673a\u6eb6\u5242\uff0c\u4ee5\u53ca\u66b4\u9732\u5728\u70ed\uff0c\u5149\uff0c\u7a7a\u6c14\u548c\u73af\u5883\u6e7f\u5ea6\u3002\u8fd9\u4e9b\u7279\u6027\uff0c\u8fde\u540c\u5b83\u4eec\u7684\u94c5\u81ea\u9694\u79bb\u80fd\u529b\uff0c\u53ef\u4ee5\u4f7fLHP\u5177\u6709\u7a81\u7834\u6027\u7684\u5e94\u7528\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cLiquid-phase sintering of lead halide perovskites\u00a0and metal-organic framework glasses\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002DOI:\u00a010.1126\/science.abf4460<\/p>\n<p>\u56fe1\u00a0\u4e0d\u540c\u70e7\u7ed3\u6e29\u5ea6\u4e0b(CsPbI<sub>3<\/sub>)<sub>0.25<\/sub>(a<sub>g<\/sub>ZIF-62)<sub>0.75<\/sub>\u590d\u5408\u6750\u6599\u7684\u5236\u5907<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229640\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72471-11.png\" alt=\"\" width=\"600\" height=\"650\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72471-11.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72471-11-277x300.png 277w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>Science\uff1a<\/b><\/strong><strong><b>\u4e3b\u52a8\u673a\u68b0\u5438\u9644\u6027\u9a71\u52a8\u6cf5\u76d2<\/b><\/strong><\/p>\n<p>\u5728\u8fc7\u53bb\u7684\u4e00\u4e2a\u4e16\u7eaa\u4e2d\uff0c\u5438\u9644\u5728\u5e73\u8861\u7cfb\u7edf\u4e2d\u88ab\u5e7f\u6cdb\u7814\u7a76\uff0c\u91cd\u70b9\u662f\u4e0e\u7269\u7406\u5438\u9644\u548c\u5316\u5b66\u5438\u9644\u7684\u7535\u5b50\u76f8\u4e92\u4f5c\u7528\u76f8\u5173\u7684\u8303\u5fb7\u534e\u76f8\u4e92\u4f5c\u7528\u3002\u5728\u8fd9\u91cc\uff0c\u7f8e\u56fd\u897f\u5317\u5927\u5b66J. F. Stoddart\u56e2\u961f\u5c06\u5176\u5df2\u7ecf\u5f00\u53d1\u7684\u5206\u5b50\u6cf5\u56fa\u5b9a\u5728MOF\u8868\u9762\uff0c\u5b9e\u73b0\u4e86\u80fd\u91cf\u9a71\u52a8\u7684\u6eb6\u6db2\u4e2d\u5e26\u7535\u8377\u73af\u7684\u975e\u5e73\u8861\u673a\u68b0\u5438\u9644\uff0c\u98a0\u8986\u4e86\u4f20\u7edf\u7684\u7269\u7406\u5438\u9644\u548c\u5316\u5b66\u5438\u9644\uff0c\u521b\u7acb\u4e86\u4e00\u79cd\u5168\u65b0\u6982\u5ff5\uff1a\u673a\u68b0\u5438\u9644\uff0c\u8fd9\u662f\u7531\u975e\u5e73\u8861\u6cf5\u6d66\u7684\u7ed3\u679c\u5f62\u6210\u7684\u673a\u68b0\u952e\u4e4b\u95f4\u7684\u5438\u9644\u5242\u548c\u5438\u9644\u8d28\u3002\u8fd9\u79cd\u6d3b\u6027\u5438\u9644\u6a21\u5f0f\u5df2\u5728\u5206\u5b50\u6cf5\u9635\u5217\u63a5\u679d\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\u8868\u9762\u5b9e\u73b0\u3002\u5438\u9644\u7269\u4ece\u4e00\u4e2a\u660e\u786e\u754c\u5b9a\u7684\u9694\u95f4(\u4f53)\u8f6c\u79fb\u5230\u53e6\u4e00\u4e2a\u660e\u786e\u754c\u5b9a\u7684\u9694\u95f4(\u754c\u9762)\uff0c\u4ece\u800c\u4ee5\u5316\u5b66\u7535\u5bb9\u5668\u7684\u5f62\u5f0f\u5f62\u6210\u5de8\u5927\u7684\u52bf\u68af\u5ea6\uff0c\u5176\u4e2d\u80fd\u91cf\u4ee5\u4e9a\u7a33\u6001\u50a8\u5b58\u3002\u673a\u68b0\u5438\u9644\u4ece\u6839\u672c\u4e0a\u6269\u5c55\u4e86\u5438\u9644\u73b0\u8c61\u7684\u8303\u56f4\u548c\u6f5c\u529b\uff0c\u5e76\u63d0\u4f9b\u4e86\u4e00\u79cd\u53d8\u9769\u6027\u7684\u65b9\u6cd5\u6765\u63a7\u5236\u8868\u9762\u548c\u754c\u9762\u7684\u5316\u5b66\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cActive mechanisorption driven by pumping cassettes\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002DOI:10.1126\/science.abk1391<\/p>\n<p>\u56fe2\u00a0\u5206\u5b50\u6cf5\u5728MOF\u7eb3\u7c73\u7247\u4e0a\u7684\u673a\u68b0\u5438\u9644<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229641\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72472-10.png\" alt=\"\" width=\"600\" height=\"878\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72472-10.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72472-10-205x300.png 205w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>Science\uff1a<\/b><\/strong><strong><b>\u6539\u5584\u5927\u6c14\u96c6\u6c34\u7684\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u4e2d\u6c34\u7ed3\u6784\u7684\u6f14\u53d8<\/b><\/strong><\/p>\n<p>\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u7684Omar M. Yaghi\u8054\u5408\u5fb7\u56fd\u67cf\u6797\u6d2a\u5821\u5927\u5b66\u7684Joachim Sauer\u548c\u7f8e\u56fd\u829d\u52a0\u54e5\u5927\u5b66\u7684Laura Gagliardi\u7b49\u4eba\u901a\u8fc7\u5927\u91cf\u7684\u5355\u6676X\u5c04\u7ebf\u884d\u5c04\u6d4b\u91cf\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\uff0c\u89e3\u91ca\u4e86\u6700\u5148\u8fdb\u7684\u96c6\u6c34\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6MOF-303\u7684\u5145\u6c34\u673a\u7406\u3002\u7b2c\u4e00\u4e2a\u6c34\u5206\u5b50\u4e0e\u6781\u6027\u6709\u673a\u8fde\u63a5\u5206\u5b50\u7d27\u5bc6\u7ed3\u5408\uff0c\u7136\u540e\u518d\u5438\u6536\u6c34\u5206\u5b50\u5f62\u6210\u5b64\u7acb\u7684\u6c34\u56e2\u7c07\uff0c\u7136\u540e\u662f\u901a\u8fc7\u56e2\u7c07\u5f62\u6210\u94fe\u7ed3\u6784\uff0c\u6700\u540e\u662f\u6c34\u7f51\u7edc\u3002\u5728\u00a02000 \u6b21\u5438\u6536\u548c\u91ca\u653e\u5faa\u73af\u540e\uff0c\u5438\u9644\u5242\u4fdd\u7559\u4e86\u7ea6 97% \u7684\u539f\u59cb\u5de5\u4f5c\u5bb9\u91cf\u3002\u6c34\u7ed3\u6784\u7684\u8fd9\u79cd\u6f14\u53d8\u5bfc\u81f4\u6211\u4eec\u53ef\u4ee5\u901a\u8fc7\u591a\u5143\u65b9\u6cd5\u6765\u4fee\u6539\u5b54\u9699\uff0c\u4ece\u800c\u7cbe\u786e\u5730\u8c03\u8282\u7b2c\u4e00\u4e2a\u6c34\u5206\u5b50\u7684\u7ed3\u5408\u5f3a\u5ea6\uff0c\u5e76\u63a7\u5236\u5438\u6c34\u884c\u4e3a\u3002\u8fd9\u5bfc\u81f4\u4e86\u66f4\u9ad8\u7684\u4ea7\u6c34\u91cf\uff0c\u4ee5\u53ca\u518d\u751f\u6e29\u5ea6\u548c\u7113\u7684\u53ef\u8c03\u6027\uff0c\u5e76\u4e14\u4e0d\u4f1a\u5f71\u54cd\u5bb9\u91cf\u548c\u7a33\u5b9a\u6027\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cEvolution of water structures in metal-organic frameworks for improved atmospheric water harvesting\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002<\/p>\n<p>\u56fe3\u00a0\u591a\u5143MOF\u7cfb\u5217\u7684\u8868\u5f81<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229642\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72473-9.png\" alt=\"\" width=\"600\" height=\"737\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72473-9.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72473-9-244x300.png 244w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>Na<\/b><\/strong><strong><b>ture<\/b><\/strong><strong><b>\uff1a\u4e09\u7ef4\u591a\u5b54\u91d1\u5c5e\u6709\u673a\u6676\u4f53<\/b><\/strong><\/p>\n<p>\u81ea20\u4e16\u7eaa70\u5e74\u4ee3\u9996\u6b21\u62a5\u9053\u805a\u73af\u70f7\u548c\u805a\u8f6e\u70f7\u4ee5\u6765\uff0c\u7531\u8fde\u9501\u9aa8\u67b6\u7ec4\u6210\u7684\u6750\u6599\u5177\u6709\u4ec0\u4e48\u6837\u7684\u7279\u6b8a\u529b\u5b66\u6027\u80fd\u4e00\u76f4\u662f\u6750\u6599\u79d1\u5b66\u4e2d\u4e00\u4e2a\u957f\u671f\u5b58\u5728\u7684\u95ee\u9898\u3002\u65e5\u672c\u4e1c\u4eac\u5927\u5b66Hiroshi Sato\u548cTakuzo Aida\u7b49\u4eba\u62a5\u544a\u4e86\u4e00\u79cd\u4e09\u7ef4\u591a\u5b54\u91d1\u5c5e\u6709\u673a\u6676\u4f53\uff0c\u5b83\u7684\u7279\u6b8a\u4e4b\u5904\u5728\u4e8e\u5176\u7ecf\u7ebf\u548c\u7eac\u7ebf\u4ec5\u901a\u8fc7\u94fe\u8fde\u63a5\u3002\u8be5\u591a\u5b54\u6676\u4f53\u7531\u56db\u65b9\u6676\u683c\u7ec4\u6210\uff0c\u968f\u7740\u5ba2\u4f53\u5206\u5b50\u7684\u91ca\u653e\u3001\u5438\u6536\u548c\u4ea4\u6362\uff0c\u751a\u81f3\u5728\u4f4e\u6e29\u8303\u56f4\u5185\u968f\u6e29\u5ea6\u53d8\u5316\u800c\u52a8\u6001\u6539\u53d8\u5176\u51e0\u4f55\u5f62\u72b6\u3002\u6cbfa\/b\u8f74\u5c06\u6676\u4f53\u7f29\u8fdb\uff0c\u5728N,N-\u4e8c\u7532\u57fa\u7532\u9170\u80fa\uff08DMF\uff09\u4e2d\u7684\u6768\u6c0f\u6a21\u91cf\u4e3a1.77\u00b10.16GPa\uff0c\u5728\u56db\u6c22\u544b\u5583\u4e2d\u7684\u6768\u6c0f\u6a21\u91cf\u4e3a1.63\u00b10.13GPa\uff0c\u662f\u76ee\u524d\u62a5\u9053\u7684\u591a\u5b54\u91d1\u5c5e-\u6709\u673a\u6676\u4f53\u4e2d\u6700\u4f4e\u503c\u3002\u6d41\u4f53\u9759\u529b\u538b\u7f29\u8868\u660e\uff0c\u8be5\u5f39\u6027\u591a\u5b54\u6676\u4f53\u6cbf\u5176c\u8f74\u53d8\u5f62\u6700\u591a\uff0c\u5728\u538b\u7f29\u81f30.88 GPa\u65f6\u53d1\u751f5%\u7684\u6536\u7f29\u800c\u6ca1\u6709\u7ed3\u6784\u635f\u574f\u3002\u540c\u65f6\u57280.46 GPa\u4e0b\u83b7\u5f97\u7684\u6676\u4f53\u7ed3\u6784\u8868\u660e\uff0c\u94fe\u63a5\u7684\u5927\u73af\u5728\u6536\u7f29\u65f6\u5e73\u79fb\u3002\u4eec\u671f\u671b\u6211\u4eec\u7684\u673a\u68b0\u8fde\u9501\u5206\u5b50\u4e3a\u57fa\u7840\u7684\u8bbe\u8ba1\u662f\u4e00\u4e2a\u8d77\u70b9\uff0c\u53d1\u5c55\u5177\u6709\u7279\u6b8a\u529b\u5b66\u6027\u80fd\u7684\u591a\u5b54\u6750\u6599\u3002\u4f8b\u5982\uff0c\u53ef\u6324\u538b\u591a\u5b54\u6676\u4f53\u53ef\u80fd\u89e3\u51b3\u5b9e\u73b0\u5ba2\u4f53\u7684\u9ad8\u5438\u6536\u548c\u91ca\u653e\u80fd\u529b\u7684\u5173\u952e\u56f0\u96be\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cAn elastic metal\u2013organic crystal with a densely catenated backbone\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u4e0a\u3002DOI:\u00a010.1038\/s41586-021-03880-x<\/p>\n<p>\u56fe4\u00a0<sup>CTN<\/sup>MOF\u7684\u6e29\u5ea6\u548c\u5ba2\u4f53\u4f9d\u8d56\u6027\u7ed3\u6784\u8f6c\u53d8<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229643\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72474-8.png\" alt=\"\" width=\"600\" height=\"450\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72474-8.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72474-8-300x225.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>A<\/b><\/strong><strong><b>FM<\/b><\/strong><strong><b>\uff1a\u4e00\u79cd\u9ad8\u900f\u6c14\u6027\u5316\u5b66\u9632\u62a4\u7684MOF\u7ea4\u7ef4\u50ac\u5316\u5242<\/b><\/strong><\/p>\n<p>\u7ea4\u7ef4\u590d\u5408\u6750\u6599\u5728\u8f83\u5927\u7684\u8868\u9762\u79ef\u548c\u589e\u5f3a\u5206\u5b50\u5728\u4ecb\u8d28\u4e2d\u7684\u4f20\u8f93\u65b9\u9762\u5177\u6709\u660e\u663e\u7684\u4f18\u52bf\uff0c\u4f7f\u5176\u80fd\u591f\u5e94\u7528\u4e8e\u4e0d\u540c\u7684\u9886\u57df\u3002\u5c3d\u7ba1\u76ee\u524d\u7684\u5408\u6210\u65b9\u6cd5\u5f97\u5230\u4e86\u957f\u8db3\u7684\u53d1\u5c55\uff0c\u4f46\u5bf9\u4e8e\u5c06\u529f\u80fd\u6750\u6599\u7684\u7279\u6027\u4e0e\u590d\u5408\u6750\u6599\u7684\u5438\u6536\u3001\u4f20\u8f93\u548c\u50ac\u5316\u6027\u80fd\u76f8\u5173\u8054\u7684\u7ed3\u6784-\u6027\u80fd\u5173\u7cfb\u7684\u7814\u7a76\u4ecd\u7136\u5f88\u5c11\u3002\u5317\u5361\u7f57\u6765\u7eb3\u5dde\u7acb\u5927\u5b66Dennis T. Lee\u3001Gregory N. Parsons\u7b49\u4eba\u62a5\u9053\u4e86\u5c06UiO-66-NH<sub>2<\/sub>\u00a0\u00a0MOF\u548c\u8c03\u5236\u7684MOF<sub>HCl<\/sub>\u8584\u819c\u539f\u4f4d\u96c6\u6210\u5230\u805a\u5408\u7269\u7ea4\u7ef4\u4f53\u7cfb\u4e2d\uff0c\u5e76\u901a\u8fc7\u5faa\u73af\u751f\u957f\u7684\u65b9\u6cd5\u63a7\u5236MOF\u7684\u542b\u91cf\u3002\u9996\u6b21\u5bf9\u805a\u4e19\u70ef\u975e\u7ec7\u9020\u5e03\u8868\u9762\u6d82\u8986Zr\u57faMOFs\u8fdb\u884c\u4e86\u7cfb\u7edf\u7684\u7ed3\u6784-\u6027\u80fd-\u529f\u80fd\u5206\u6790\u3002\u7ec7\u7269\u4e0a\u7684MOF\u5206\u6570\u548cMOF\u5fae\u7ed3\u6784\u4e2d\u7684\u7f3a\u9677\u5bc6\u5ea6\u662f\u901a\u8fc7\u539f\u4f4d\u79cd\u5b50\u751f\u957f\u63a7\u5236\u7684\uff0c\u5176\u4e2d\u7ea4\u7ef4\u8868\u9762\u901a\u8fc7\u539f\u5b50\u5c42\u6c89\u79ef\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u8fdb\u884c\u9884\u5904\u7406\u3002\u6027\u80fd\u6700\u4f73\u7684MOF-fiber\u590d\u5408\u6750\u6599\u5bf9\u6a21\u62df\u7269-\u5bf9\u785d\u57fa\u82ef\u57fa\u78f7\u9178\u76d0\u7684\u50ac\u5316\u6c34\u89e3\u901f\u5ea6\u5feb\uff0ct<sub>1\/2<\/sub>\u00a0&lt; 5 min\u3002\u5728\u6ca1\u6709\u7f13\u51b2\u7684\u60c5\u51b5\u4e0b\u8fdb\u884c\u4e86\u771f\u5b9e\u7684GD\u964d\u89e3\uff0c\u5e76\u7814\u7a76\u4e86\u5176\u5438\u9644\u548c\u6269\u6563\u7279\u6027\uff0c\u6709\u6548\u5730\u9650\u5236\u4e86\u4e0d\u5229\u7684\u84b8\u6c7d\u6e17\u900f\u3002\u53e6\u5916\uff0c\u8be5\u590d\u5408\u6750\u6599\u7684\u6c34\u6c7d\u8f93\u9001\u901f\u7387\u4e3a15000 g m<sup>\u22122 <\/sup>day<sup>\u22121<\/sup>\uff0c\u660e\u663e\u4f18\u4e8e\u5176\u4ed6\u5e02\u9762\u4e0a\u53ef\u4e70\u5230\u7684\u5316\u5b66\u9632\u62a4\u7ec7\u7269\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\u5b9e\u73b0\u7684\u5316\u5b66\u4fdd\u62a4\u590d\u5408\u6750\u6599\u514b\u670d\u4e86\u900f\u6c14\u6027\/\u89e3\u6bd2\u7684\u6743\u8861\uff0c\u5e76\u663e\u793a\u4e86\u8be5\u6750\u6599\u5728\u73b0\u5b9e\u9886\u57df\u5e94\u7528\u7684\u524d\u666f\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cHighly Breathable Chemically-Protective MOF-Fiber Catalysts\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AFM\u4e0a\u3002DOI: 10.1002\/adfm.202108004<\/p>\n<p>\u56fe5\u00a0MOF\u6d82\u5c42\u805a\u5408\u7269\u7ea4\u7ef4\u6846\u67b6\u7684\u5408\u6210\u8fc7\u7a0b\u793a\u610f\u56fe<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229644\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72475-8.png\" alt=\"\" width=\"600\" height=\"319\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72475-8.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72475-8-300x160.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>J<\/b><\/strong><strong><b>ACS<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><strong><b>\u4e8c\u7ef4MOF\u5149\u52a8\u529b\u79bb\u5b50\u6cbb\u7597\u7259\u5468\u708e<\/b><\/strong><\/p>\n<p>\u5bf9\u4e8e\u7531\u591a\u79cd\u53e3\u8154\u75c5\u539f\u4f53\u5f15\u8d77\u7684\u7259\u5468\u708e\u7b49\u6162\u6027\u75be\u75c5\uff0c\u4f20\u7edf\u7684\u624b\u672f\u5e72\u9884\u548c\u6297\u751f\u7d20\u6cbb\u7597\u6548\u679c\u5dee\uff0c\u751a\u81f3\u65e0\u6548\uff0c\u5f80\u5f80\u5bfc\u81f4\u7ec4\u7ec7\u7684\u8fdb\u884c\u6027\u7834\u574f\uff0c\u751a\u81f3\u7259\u9f7f\u8131\u843d\uff0c\u4ee5\u53ca\u5168\u8eab\u6027\u75be\u75c5\u3002\u5728\u6b64\uff0c\u5929\u6d25\u5927\u5b66\u5434\u6c34\u6797\u3001MIT\u5f20\u5174\u624d\u3001\u6e56\u5317\u5927\u5b66\u5218\u9999\u6885\u7b49\u4eba\u901a\u8fc7\u539f\u5b50\u5c42\u6c89\u79ef\u8bbe\u8ba1\u4e86\u4e00\u79cd\u539f\u5b50\u5c42Fe<sub>2<\/sub>O<sub>3<\/sub>\u4fee\u9970\u7684\u4e8c\u7ef4\u535f\u5549MOF(CuTCPP)\u7cfb\u7edf(CuTCPP- Fe<sub>2<\/sub>O<sub>3<\/sub>)\uff0c\u5c06\u5176\u63ba\u5165\u805a\u4e59\u4e8c\u9187\u57fa\u8d28\u4e2d\u4ee5\u5f62\u6210\u5149\u54cd\u5e94\u8f6f\u818f\u3002\u7ecf\u8fc7\u539f\u5b50\u5c42\u6c89\u79ef\u8868\u9762\u5de5\u7a0b\u540e\uff0c\u589e\u5f3a\u4e86\u4e8c\u7ef4\u5149\u50ac\u5316\u6d3b\u6027\uff0cMOF\u5f02\u8d28\u754c\u9762\u5177\u6709\u8f83\u4f4e\u7684\u5438\u9644\u80fd\u548c\u8f83\u9ad8\u7684\u7535\u8377\u8f6c\u79fb\u91cf\uff0c\u8fd9\u4e3b\u8981\u662f\u7531\u4e8e\u91d1\u5c5e-\u8fde\u63a5\u952e\u6865\u63a5\u5355\u5143\u7684\u534f\u540c\u4f5c\u7528\u3001\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\u548c\u826f\u597d\u7684\u805a\u5149\u7f51\u7edc\u3002\u8fd9\u4f7f\u5f97\u8fd9\u79cd\u8868\u9762\u5de5\u7a0b\u5316\u7684\u4e8c\u7ef4MOF\u5f02\u8d28\u7ed3\u901a\u8fc7\u5c40\u90e8\u6d3b\u6027\u6c27\uff08ROS\uff09\u548c\u91ca\u653e\u79bb\u5b50\u7684\u534f\u540c\u4f5c\u7528\u5bf9\u591a\u79cd\u53e3\u8154\u75c5\u539f\u4f53\u5177\u6709\u5e7f\u6cdb\u7684\u6297\u83cc\u6d3b\u6027\u3002\u8fd9\u79cd\u5149\u52a8\u529b\u79bb\u5b50\u7597\u6cd5\u5177\u6709\u5feb\u901f\u7684\u6297\u83cc\u6d3b\u6027\uff0c\u7f13\u89e3\u708e\u75c7\uff0c\u6539\u5584\u8840\u7ba1\u751f\u6210\uff0c\u6bd4\u4e34\u5e8a\u62a5\u9053\u7684\u7259\u5468\u708e\u6cbb\u7597\u5177\u6709\u66f4\u597d\u7684\u6cbb\u7597\u6548\u679c\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201c2D MOF Periodontitis Photodynamic Ion Therapy\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002DOI: 10.1021\/jacs.1c07875<\/p>\n<p>\u56fe6\u00a0\u4e8c\u7ef4MOF\u5149\u52a8\u529b\u79bb\u5b50\u6cbb\u7597\u7259\u5468\u708e\u793a\u610f\u56fe<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229645\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72476-8.png\" alt=\"\" width=\"600\" height=\"406\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72476-8.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72476-8-300x203.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>JACS<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><strong><b>CO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u5230\u591a\u5b54<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF\u7684\u5ba4\u6e29\u8f6c\u5316<\/b><\/strong><\/p>\n<p>\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u5c06CO<sub>2<\/sub>\u8f6c\u5316\u4e3a\u529f\u80fd\u6750\u6599\u662f\u5b9e\u73b0\u78b3\u4e2d\u548c\u793e\u4f1a\u7684\u91cd\u5927\u6311\u6218\u3002MOF\u4f5c\u4e3a\u53ef\u8bbe\u8ba1\u7684\u591a\u5b54\u6750\u6599\u5df2\u5f97\u5230\u5e7f\u6cdb\u7684\u7814\u7a76\u3002\u5c3d\u7ba1CO<sub>2<\/sub>\u662f\u4e00\u79cd\u6709\u5438\u5f15\u529b\u7684\u53ef\u518d\u751f\u8d44\u6e90\uff0c\u4ece\u4e8c\u6c27\u5316\u78b3\u4e2d\u5408\u6210MOFs\u4ecd\u672a\u88ab\u63a2\u7d22\u3002\u5728\u6ca1\u6709\u9ad8\u80fd\u53cd\u5e94\u7269\u548c\/\u6216\u4e25\u82db\u6761\u4ef6\u4e0b\uff0cCO<sub>2<\/sub>\u7684\u5316\u5b66\u60f0\u6027\u963b\u788d\u4e86\u5176\u8f6c\u5316\u4e3a\u5178\u578b\u7684MOF\u8fde\u63a5\u7269\uff0c\u5982\u7fa7\u9178\u76d0\u3002\u5728\u8fd9\u91cc\uff0c\u4eac\u90fd\u5927\u5b66\u7684Satoshi Horike\u7b49\u4eba\u63d0\u51fa\u4e86\u73af\u4e8c\u80fa\u54cc\u55ea(H<sub>2<\/sub>PZ)\u4f5c\u4e3a\u524d\u9a71\u4f53\uff0c\u63d0\u51fa\u4e86\u5728\u73af\u5883\u6e29\u5ea6\u548c\u538b\u529b\u4e0b\u5229\u7528CO<sub>2<\/sub>\u4f5c\u4e3a\u539f\u6599\uff0c\u4e00\u9505\u6cd5\u8f6c\u5316\u6210\u9ad8\u7ed3\u6676\u5ea6\u7684MOFs\u3002\u901a\u8fc7\u6865\u63a5\u4e8c\u6c28\u57fa\u7532\u9178\u916f\u539f\u4f4d\u5408\u6210\u4e86\u7acb\u65b9\u578b[Zn<sub>4<\/sub>O(piperazine dicarbamate)<sub>3<\/sub>]\u3002\u7814\u7a76\u8868\u660e\uff0c\u8be5MOF\u6750\u6599\u5177\u6709\u8f83\u9ad8\u7684\u6bd4\u8868\u9762\u79ef(2366m<sup>2<\/sup>\u00a0g<sup>-1<\/sup>)\u548cCO<sub>2<\/sub>\u542b\u91cf(&gt;30 wt %)\u3002\u867d\u7136\u4e8c\u6c28\u57fa\u7532\u9178\u916f\u8fde\u63a5\u7269\u5728\u70ed\u529b\u5b66\u4e0a\u662f\u4e0d\u7a33\u5b9a\u7684\uff0c\u5e76\u4e14\u5f88\u5bb9\u6613\u91ca\u653eCO<sub>2<\/sub>\uff0c\u4f46\u662f\u5728MOF\u6676\u683c\u4e2d\u5f62\u6210\u4e86\u4e00\u4e2a\u6269\u5c55\u7684\u914d\u4f4d\u7f51\u7edc\uff0c\u8db3\u4ee5\u7a33\u5b9a\u8be5\u8fde\u63a5\u7269\uff0c\u4ece\u800c\u62e5\u6709\u7a33\u5b9a\u7684\u6c38\u4e45\u5b54\u9699\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cOne-Pot, Room-Temperature Conversion of CO<sub>2<\/sub>\u00a0into Porous Metal Organic Frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002DOI:\u00a010.1021\/jacs.1c08227<\/p>\n<p>\u56fe7\u00a0CO<sub>2<\/sub>\u8f6c\u5316\u4e3a\u4e8c\u6c28\u57fa\u7532\u9178\u916f\u8fde\u63a5\u7269\u5408\u6210MOFs<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229646\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72477-8.png\" alt=\"\" width=\"600\" height=\"456\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72477-8.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/11\/\u56fe\u72477-8-300x228.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>A<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><strong><b>\u4eceMOF\u52302D\u5355\u6676<\/b><\/strong><strong><b>\u7684\u8d85\u5feb<\/b><\/strong><strong><b>\u8f6c\u53d8<\/b><\/strong><\/p>\n<p>\u5355\u6676\u5230\u5355\u6676(SCSC)\u7684\u8f6c\u53d8\u5728\u6676\u4f53\u5de5\u7a0b\u4e2d\u5f15\u8d77\u4e86\u76f8\u5f53\u5927\u7684\u5174\u8da3\uff0c\u56e0\u4e3a\u5b83\u63d0\u4f9b\u4e86\u4e00\u4e2a\u521b\u9020\u65b0\u6750\u6599\u7684\u5173\u952e\u5e73\u53f0\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5316\u5b66\u952e\u5bf9\u6676\u683c\u5e94\u53d8\u7684\u8010\u53d7\u6027\u6709\u9650\uff0c\u5f53\u7ed3\u6784\u53d1\u751f\u5de8\u5927\u53d8\u5316\u65f6\uff0c\u4fdd\u6301\u7ed3\u6676\u5ea6\u662f\u4e00\u9879\u6311\u6218\u3002\u5728\u8fd9\u91cc\uff0c\u6b66\u6c49\u5927\u5b66Mengqi Zeng\u3001Lei 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